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Polymers 4 MS

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Youssef Elgedely
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48 views5 pages

Polymers 4 MS

Uploaded by

Youssef Elgedely
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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1.

( (i) correct repeat unit [1]

COND evidence of polymer chain [1]

(ii) glucose or maltose [1]

(iii) addition (polymerisation) or no other product


except polymer [1]

condensation (polymerisation) or polymer


and water [1]

(b)
b) sodium hydroxide [1]
COND ammonia or alkaline gas or litmus red to blue [1]
If aluminium added wc =0

(ii) measure pH [1]


more than 1 and less than 7 or
correct colour eg orange or yellow NOT red
NOT green [1]
OR add magnesium or calcium carbonate [1]
weak acid reacts slowly

(c)
c) ethyl acrylate [1]
ester or alkene [1]

(ii) brown to colourless (NOT clear) [1]


correct formula for acid NOT ester [1]

TOTAL = [13]

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2 (a) (i) in which something dissolves [l]
(ii) coITect formula [1]
CH3COOC2Hs or full structural formula

(iii) steam or water or hydration [1]


heat or catalyst [1]

OR bubble into (concentrated) sulphuric acid [1]


add water [1]

oxidised [1]
by air or dichromate or manganate(VII) [1]

(iv) ethanoic acid and butanol [1]

(b) (i) CH20H [1]


CHOH
CH20H

(ii) soap or detergent [1]

(c) (i) Q.Qlyester or condensation polymer NOT terylene [1]

(ii) HOOC- -COOH [1]

[1]

If wrong way around [1] Point of attachment of functional group to "box"


not important

(d) (i) protein or poly peptide or polyamide [I]


(ii) peptide or amide [1]
(iii) amino acids are colourless or become visible/coloured
or to develop it [1]
(iv) using colour or from position ONLY [I ]
OR discussion of Rf [2]
OR compare with known amino acids [2]
TOTAL = 17

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3 (a) molecular formula [1]
Must be able to give isomers, need not be alkenes
two corres.ponding isomers [2]
If do not correspond then MAX [2] out of[3]

(b) (i) ethanol [1]


structure [1]
(ii) ethane [I]
structure [1]

(c) (i) many simple molecules or monomers [1]


form one large one or macromolecule or chain [I]
(ii) addition polymer only one product- the polymer [1]
condensation - polymer and water etc [1]

(iii) correct unit [1]


COND evidence of polymer in structure eg shows
continuation such as terminal bonds [1]

( d) (i) water proof or impervious or flexible or


good adhesion or non-biodegradable or unreactive [ 1]

(ii) steel in contact with water or air [I]

(iii) zinc more reactive


oxygen /water reacts with zinc not iron
sacrificial protection
zinc anodic
steel receives electrons from zinc
zinc forms cations
cell
TWO valid points [3]

TOTAL= 17
..

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Question Answer Marks

4(a) 2
fractional distillation; 1
cracking; 1
(b)(i) add 1
(b)(ii) 2; 1
(b)(iii) 2

M1 chain of 4 carbon atoms with single bonds and continuation bonds;


M2 correctly positioned CH3 side chains;
(c) 2

; ;

(d)(i) (concentrated) sulfuric acid; 1


(d)(ii) ethanoate; 1
(d)(iii) 2

M1 ester link;
M2 rest of molecule;
(d)(iv) te 1

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Question Answer Marks

5(a)(i) more than enough to react (with all the hydrocarbon); 1


OR
(some) oxygen remaining;
5(a
5(a)(ii) cm3; 1
5(a)(iii) 2 : 15 : 10; 1
5(a)(iv) 2
2 : 15 : 10 : 10; 1
C5H10; 1
5(
5(b)(i) 7H16; 1
5(b)(ii) contains a double bond / triple bond / multiple bond; 1
OR
not all bonds are single bonds;
5(b)(iii) 2
test: aqueous bromine / bromine (water) / Br2; 1
result: (orange / yellow / brown) to colourless / decolourised / colour disappears; 1
5
5(c)(i)
(c)(i) add 1
5(c
5(c)(ii) (kg); 1
5(c)(iii) 2
propene: CH2; 1
polypropene: CH2; 1

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