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Chem TP 2020 21

The document outlines a teaching plan for an Organic Chemistry course. It details the topics, chapters, and concepts that will be covered in each month of the first term. Key areas include stereochemistry, heterocyclic compounds, and organic reaction mechanisms. Evaluation includes internal examinations and student seminars.

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0% found this document useful (0 votes)
25 views72 pages

Chem TP 2020 21

The document outlines a teaching plan for an Organic Chemistry course. It details the topics, chapters, and concepts that will be covered in each month of the first term. Key areas include stereochemistry, heterocyclic compounds, and organic reaction mechanisms. Evaluation includes internal examinations and student seminars.

Uploaded by

saheedvk
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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K.C.E.

Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Jayashri D. Bhirud
FACULTY: Science DEPARTMENT: Chemistry
CLASS: S.Y. B.Sc SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH- 232: Organic Chemistry Chemistry-III
FIRST TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED

June

July

August

UNIT III: Heterocyclic Compound


Classification and nomenclature, Structure, aromaticity in
5-numbered rings containing one heteroatom (Furan,
September
Pyrrole, Thiophene).
Synthesis: Paal-Knorr furan synthesis, Knorr pyrrole 5h
synthesis, Paal-Knorr Thiophene Synthesis.
5h
Reactions with Mechanism: nitration sulphonation,
Friedel-Crafts Acylation of Furan, Pyrrole, Thiophene and

UNIT II: Steriochemistry


October
conformational and configurational isomers
Geometrical isomerism: cis–trans and, syn-anti
isomerism E/Z notations, with Cahn–Ingold–Prelog
priority rules.
UNIT II: Steriochemistry 5h
Optical Isomerism: Optical Activity, Specific Rotation,
Chirality/Asymmetry, Enantiomers, Molecules with two
or more chiral centres, diastereomers, meso structures,
Racemic mixture and methods of resolution. Absolute
configuration, R/S designations with Cahn–Ingold–
November Prelog priority rules.
Conformational isomerism: Factor affecting on stability
of Conformation, conformational structure and stability of
ethane, butane, cyclohexane, chair and boat forms, axial
and equatorial bonds in cyclohexane, factors affecting
stability of conformations. Baeyer’s angle strain theory.
Internal Examination

December

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Jayashri D. Bhirud
FACULTY: Science DEPARTMENT: Chemistry
CLASS: S.Y. B.Sc SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH- 242 Inorganic Chemistry-II

SECOND TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit I Basic Concept of Coordination Chemistry 8h
A) Introduction, Double salt’s and coordination
compounds,coordination complexes and complex ions,
coordination number, Unidentate,bidentate
February and poly-dentate ligands, chelating ligands and
chelates,charge on complex or complex ion,physical
methods use in the study of complexes, Nomenclature of
coordination compound.

B)Werners Theory – Assumptions, Isomerism, EAN


rule, stability of complexes ionand Factors affecting
stability of complex ion, stereochemistry of coordination 8h
compoundwith coordination Number 4 and
6, Isomerism in coordination compounds.
March
UNIT II: d-block Elements and Their Properties
Elements of first, second and third transition series,
General characteristics of d-block elementsa)
Metallic character b) Molar volume and densities c)
Atomic radii d) Ionic Radii
UNIT II: d-block Elements and Their Propertie
Melting and boiling points f) Ionization Energies g) 8h
Reactivity h) Oxidation statesi) Standard electrode
potential j) Reducing Properties k) Colour l) Magnetic
propertiesm) Catalytic Properties n) Tendency to form
April Complexes
UNIT III: Acids, Bases and Solvent Chemistry
A) Introduction, Terms- Solvent,Solute,Solution,Solvation
& Hydration,
Dielectric Constant, Non-aqueous
solvents,classification,chemistry of liquid
ammonia,N2O4 and BrF3.

UNIT III: Acids, Bases and Solvent Chemistry


B) Donor and acceptor properties of solvent,Levelling &
Differentiating Solvents, Co-Solvating Agents.
C) Molten salts & their classification, Uses, solvents for 6h
electrochemical reactions, purity of solvents.
D) Definition and approaches- i) solvent system concept –
Merits/Advantages, Limitations ii) Lux-flood concept &
May its application iii) Lewis concept-Limitations,Merits etc.
iv)Generalized Acid-base concepts, Advantages,
Limitations.
E) Hard and soft acids and bases: definitions, Pearson
HSAB concept.
Internal Examination

March

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMIC YEAR: 2020-21


NAME OF TEACHER: Dr. Jayashri D. Bhirud
FACULTY: Science DEPARTMENT: Chemistry
CLASS: M.Sc. II SUBJECT: M.Sc II Organic Chemistry
PAPER CODE and TITLE OF PAPER: CHO-302: Steriochemistry

FIRST TERM

NO.OF
REMARK
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES
S
REQUIRED

June --

--
July

Unit I: Fundamentals in Stereochemistry


Measurement of optical activity, optical activity due to
stereoplane, helicity, enantiomeric excess, determination of 09
optical purity, Absolute and relative stereochemistry,
August
Investigating the stereochemistry of a compound, Chiral
compounds with no stereogenic centres. Conformations
of Ethane and n-butane: Restricted rotation about single bond.
Origin of conformational energy, Angle and Pitzer Strain.
Unit III: Stereochemistry of six membered rings
Conformational analysis of cyclohexane (structure associated 16
with energy), Monosubstituted cyclohexane, 1, 2-disubstituted
with same substituent (e.g. 1, 2-Dimethylcyclohexane), with
September
two different substituents (e.g. 1-isopropyl-2-dimethyl
cyclohexane), 1, 2-disubstituted cyclohexane (e.g. 1, 3-
Dimethylcyclohexane). Conformations of heterocycles.
Conformations of common sugars.Anomeric effect.
Stereochemistry of polycyclic compounds
Norboranes (exo, endo, syn and anti nomenclature), NGP
reactions in Norbornane, Hydrindanes (Bicyclo [4.3.0] Nonane,
fused rings in steroids nucleus, and bridge alkaloids. 16
Unit II: Asymmetric synthesis and its applications
October
Asymmetric synthesis with chiral substrates - Cram‘s rule,
FelkinAnh rule, Cram‘s chelate model, use of chiral
auxiliaries,.
First Internal Examination
Seminar
chiral reagents and catalysts in asymmetric synthesis. 08
Enantiomeric Excess and Optical Purity.Stereoselective
Reactions: aldol reactions (Zimmermann traxler model),
asymmetric hydrogenation (BINAP), asymmetric epoxidation
November
(+DET/-DET) and asymmetric dihydroxylation (DHQD)
2PHAL/(DHQ) 2PHAL.
Second Internal Examination
Assingment
Unit IV: ORD and CD 11
Linearly and circularly polarized light, Circular birefringence
and circular dichroism, ORD and
December
CD curves, Cotton effect and its applications, The Octant rule
and the axial α–haloketone rule
with applications.
Assignment

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMIC YEAR: 2020-21


NAME OF TEACHER: Dr. Jayashri D. Bhirud
FACULTY: Science DEPARTMENT: Chemistry
CLASS: M.Sc. II SUBJECT: M.Sc II Organic Chemistry
PAPER CODE and TITLE OF PAPER: CHO-305A: A) Physical methods in structure
determination

FIRST TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED

June --

--
July

1
Unit I: H-NMR Spectroscopy
Principle of NMR, spin-spin coupling, (n+1) rule, coupling
constant, vicinal and germinal coupling, long range coupling, 16
factors affecting coupling constant, first order spectra, More
complex spin-spin system like AB, AX, AX2, ABX, AMX,
ABC. Proton exchange reaction and hydrogen bonding,
chemical exchange, rotation about single bond with partial
August double bond character, simplification of complex spectra-
double resonance, shift reagents, Nuclear Over- Hauser effect
(NOE), Deuterium exchange, solvent effects, Detection of
solvent peaks in 1H NMR spectra, NMR of intra and
intermolecular hydrogen bond, C-H-N, C-H-O, Ar-HO=C.
Applications of 1H NMR: Magnetic Resonance Imaging
(MRI). Problems Based on 1H NMR spectroscopy.
MCQ based test
Unit II: 13C NMR spectroscopy
Elementary ideas, Instrumental difficulties, Proton decoupled 16
spectra, off-resonance technique, Chemical shifts of solvents,
chemical shift of carbons, factors affecting on chemical shifts,
calculations of chemical shifts of alkane, olefin, alkyne,
September
aromatic, Heteroaromatic, carbonyl carbons, oxime carbon and
nitrile carbon, chemical shift features of hydrocarbons, effect
of substituents on chemical shifts. Problems based on 13C NMR
spectroscopy. NMR spectroscopy of Nuclei other 1H and 13C.
Assignment
Two dimensional NMR spectroscopy (2D NMR)
1H-1H COSY, 13C-1H (HETCOR, HMQC, HMBC), 13C-13C
INADEQUATE, Interpretation of2D spectra and examples.
Unit III: Electron Spin Resonance Spectroscopy 09
Introductiuon, basic principle, zero field splitting and kramers
degeneracy, factors effecting the “g” values, hyperfying
October
splitting, determination of “g” values. Instumentation, working
of instruments, sensitivity, concentration, choice of
solvent.Presentation of ESR spectra, application of ESR to
study the free radicals, structure determination, reaction
velocities.
First Internal Examination
Unit IV: Mass Spectrometry 09
Instrumentation, various methods of ionization (field
ionization, field desorption, ESI, FAB, MALDI), different
detectors [magnetic analyzer, ion cyclotron analyzer,
November Quadrupoule mass filter, time of flight (TOF)]. Mass Spectral
fragmentation of Organic compounds containing common
functional groups, Nitrogen rule, McLafferty rearrangement,
Molecular Ion peak.
Second Internal Examination
Metastable peak, isotope peaks, Mass spectral fragmentation of 10
organic compounds with respect of their structure
determination. Problem based on Mass Spectrometry.
Unit V: Problems based on U.V., I.R., NMR, CMR, Mass
and 2D NMR spectroscopy
December
a) Problems based on joint application of U.V., I.R., NMR,
CMR, Mass and 2D NMR spectroscopy
b) Determination of structure of organic compounds from U.V.,
I.R., NMR, CMR, Mass and 2D NMR spectra.
Assignment

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Jayashri Dinkar Bhirud
FACULTY: Science DEPARTMENT: Chemistry
CLASS: MSc-II SUBJECT: Organic Chemistry
PAPER CODE and TITLE OF PAPER: CHO-401 Natural Product
SECOND TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit III: Multi-step synthesis of natural products 12h
Synthesis of the following natural products with special
reference to reagents used,
stereochemistry and functional group transformations:
i) Reserpine (Woodward synthesis) ii)Longifoline (Corey
March
synthesis) iii) Estrone iv) Strychnine (Overman‘s synthesis) v)
Fredericamycin-vi) Juvabione
Unit II:Chemistry of Natural Products 5h
Structure, stereochemistry and biogenesis of Hardwickiic acid
Prostaglandin: Classification, general structure, biological 5h
importance, Structure elucidation & total
synthesis of PGE2, PGF1α, and podophllyotoxins.
Unit IV: Vitamins 12h
a)Classification, sources and biological importance of vitamin
B1, B2, B6, folic acid, B12, C,
D1, E (α-tocopherol), K1, K2, H (β- biotin).
b) synthesis of the following:
Vitamin B1 including synthesis of pyrimidine and thiazole
April moieties
Vitamin B2 from 3, 4-dimethylaniline and D(-)ribose
Vitamin B6 from: Ethoxyacetylacetone and cyanoacetamide
Vitamin E (α-tocopherol) from trimethylquinol and phytyl
bromide
Vitamin K1 from 2-methyl-1, 4-naphthaquinone and phytol.
Vitamin Folic acid from Guanidine and ethyl cyano acetate.
First Internal Test
Seminar
Unit V: Enzyme 10h
a) Chemistry of enzymes:
Introduction, nomenclature and classification of enzymes.
Properties of enzymes: i) Enzyme
efficiency/catalytic power; ii) Enzyme specificity: a)
stereospecificity b) reaction specificity c)
substract specificity, Mechanism of enzyme action: a) Fischer‘s
lock and key‘ b) Koshland
induced fit hypothesis. Concept and identification of active
site. Factors affecting enzyme
kinetics: Substrate concentration, enzyme concentration,
temperature, pH, product concentration
etc. Reversible and irreversible inhibition
May Structure, stereochemistry and biogenesis of Hardwickiic acid.

b) Enzyme catalyzed organic reactions


Hydrolysis, hydroxylation, oxidation and reduction
Unit I:Terpenoids, Steroids and Alkaloids
a) Biosynthesis of terpenoids
6h
Introduction to Terpenoids, Mevalonate pathway: Biosynthesis
of mevalonic acid, Conversion
of MVA into isopentyl pyrophosphate, Polymerisation of
isopentyl pyrophosphate,
Second Internal test
Assingment
monoterpenes–geranyl cation and its derivatives,
sesquiterpenes–farnesyl cation and its
derivatives, diterpenoids, tri and tetra terpenoids 10h
b) Structure and biological function of steroids:
Cholesterol, Bile acid, Oestrogen, Progesteron and Corticides
June
(No synthesis).
c) Biosynthesis of Alkaloids: Introduction, phenylethylamine
group, pyrolidine group,
pipyridine group, pyrolidine-pyridine group, tropane group and
Indole group.

March

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Manoj A. Pande
FACULTY: Science DEPARTMENT: Chemistry
CLASS: FYBSc SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH- 111: Inorganic Chemistry I

FIRST TERM

NO.OF
REMARK
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES
S
REQUIRED
June --

July

….
August

September …..
CH-111 General Introduction, Importance & Scope of Chemistry,
Concept of Elements, atoms & Compounds, Atomic models,
Discussion on different Atomic model: Dalton, Thomoson, Rutherford
etc. Review of: Bohr’s theory, Hydrogen Spectrum and limitations of
05
October Bohr's theory

Review of: Bohr’s theory, Hydrogen Spectrum and limitations of 10


Bohr's theory, limitations of Bohr's theory cont. & Dual Nature of
electron & derivation of de Broglie equationde Broglie, idea of
de-Broglie matter waves, Derivation, Characteristics of matter
November
waves, problems on de-Broglie equation, Problems on de-Broglie
equation Cont.; Heisenberg’s Uncertainty Principle: Statement,
Phy. Concept, Phy. Concept & Numerical Problems,

Scrodinger equ, Phy.Significance of psi*; quantum numbers. 08


Quantum Numbers with their significance cont. problems on QN,
Shapes of orbitals, Rules for filling
electrons in various orbitals Aufbau Princ.,Paulis Ex. Prinple
December

Writing electronic conf of elements cont.; Principle of Extra 05


stability: Symmetrical Distribution & Exchange Energy,
January Anomalous elect. Conf. Writing ele. Conf of Ions. Revision &
Summarization of Unit I First Assessment test 1( Practice Test)
Unit-II Covalent Bonding: Def., Postulates of VBT, Formation 06
of H2 molecule, Limitations. Unit-II Formation of H2 molecule
on the basis of VBT, Limitations of VBT. CH-111 Limitations
of VBT. Cont., Directional Characteristics of Covalent Bond,
February Overlap Criteria & Bond strength, Hybridization. CH-111
Hybridization cont.: sp,sp2, sp3,: examples, geometry. Factors
determining shape of molecules. CH-111 sp3 hybridization,
factors affecting shape of molecule, VSEPR theory: main pts &
limitations,
Topic: CH-111 Inorg Chem. Problems on VSEPR, MOT: 10
introduction, overview of VBT, main pts of MOT, LCAO. MO
diagram of Homonuclear & Heteronuclear molecules. Ionic
Bonding: General characteristics of ionic bonding. Energy
consideration in ionic bonding,
lattice energy and solvation energy and their importance in the
March context of stability and solubility
of ionic compounds.Statement of Born-Landé equation for
calculation of lattice energy, Born-
Haber cycle and its applications, polarizing power and
polarizability.Fajan’s rules, ionic
character in covalent compounds, bond moment, dipole
moment and percentage ionic character.

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University,
Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of
Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMIC YEAR: 2020- 2021


NAME OF TEACHER: Dr Manoj A. Pande
FACULTY: Science DEPARTMENT: Chemistry
CLASS: FY B.Sc. SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER:
SECOND TERM

NO.OF
LECTUR
REMAR
MONTH THEORY / PRACTICALS TO BE COVERED ES
KS
REQUIR
ED

July

August

September

October

November

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Manoj A. Pande
FACULTY: Science DEPARTMENT: Chemistry
CLASS: TYBSc SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH-504: Ind. Chemistry

FIRST TERM

NO.OF
REMARK
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES
S
REQUIRED
June --

July

August

Introduction to CH-504 Ind. Chemistry 17


Introduction to Unit -1 of CH-504. Basic Requirement of
Chemical Industry., Basic Requirement of Ind. Chem.
Raw Materials and Unit Processes
Unit Operation; Comparison between Unit operation & Unit
Process
video after lecture for better understanding of Unit operation &
Processes shared You tube link.Quality Assurance; Quality
September Control and Process Control
R & D Department, Pollution Control, Human Resource Dept.
Safety Measures, Economics of Chem. React. & Classification
of Reactions.
Classification of reactions cont. & Batch - Continuous Process
Yield calculation; Theoretical, Practical and %. Conversion,
Selectivity and Yield
Conversion and Selectivity of Chemical Reaction;
Intellectual Property & Types of IP
Types of IP Rights;
Copy right and Trademark, Types of IP Rights; Patent Act &
Advantages of IP Patent; Advantages of IP rights. IP Rights in 15
India. ISO & BIS. Comparison.
Patent Agent Exam Information You tube video link shared.
October BIS syllabus & Pattern: You tube video link shared

Patent Agent Exam Information You tube video link shared.


BIS syllabus & Pattern. Overview and Revision of CH-504 Unit-I
General Aspect of Ind. Chem.
CH-504 Ind. Chem. Unit-V Introduction, Ind. synthesis of Acetone: 12
Principle, Reaction, process & application.

CH-504 Unit I Synthesis of acetone: process, Block dia. &


application.; synthesis of methanol: Reaction

CH-504 Ind. synthesis of methanol: Reaction, Synthesis, Block dia. &


application. Ind. synthesis of Isopropanol: Reaction

CH-504 Ind. synthesis of Isopropanol: Reaction, Synthesis, Block


dia. & application

CH-504 Ind. synthesis of Acetylene: Reaction, Synthesis, Block dia.


November & application

CH-504 Ind. synthesis of Toluene: Reaction, Synthesis, Block dia. &


application

CH-504 applicationof Toluene cont. Ind. synthesis of Glycerol:


Reaction, Synthesis, Block dia. & application

CH-504 cont. Ind. synthesis of Glycerol: Reaction, Synthesis, Block


dia. & application

CH-504 Unit-V Revision & Summarization

Ind.Chem. Unit-2 Sugar Introduction; Sugar Ind in Maharashtra & 08


Ind Ind.Chem.Unit-2 Sugar Ind. Importance of Sugar Ind.;
Manufacture of Cane SugarInd.Chem.Unit-2 Sugar Ind. Importance
of Sugar Ind.; Manufacture of Cane Sugar
December
cane molassess Fermentatiom ind. …. Coffey still
Coffey still Wine beer

Topic: CH 504 U4 Petroleum 05


Ind.:occuranc,producer,exploration method & composition.
Petroleum : composition & refining

Refining of petroleum, Cracking, catalytic reforming & hydrocracking,


Knocking, Anti Knock compd.

cracking cont.; knocking, antiknocking; octane no.


January
Cetane no diff

Petrohol, Power alcohol: Manufacture, advantages &


Disadvantages; manufacture of petrol: Bergius method.

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University,
Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of
Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMIC YEAR: 2020- 2021


NAME OF TEACHER: Dr Manoj A. Pande
FACULTY: Science DEPARTMENT: Chemistry
CLASS: FY B.Sc. SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH604 Ind. Chem.
SECOND TERM

NO.OF
LECTUR
REMAR
MONTH THEORY / PRACTICALS TO BE COVERED ES
KS
REQUIR
ED
Unit 5 Dyes, Drugs and Pharmaceuticals. 12
March

UNIT 4: Soap and Detergents 12


April

UNIT 3: Pesticide Chemistry 20


May UNIT 2: Chemistry of Perfumes

UNIT 1: Chemistry of Cosmetics 12


June

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Manoj A. Pande
FACULTY: Science DEPARTMENT: Chemistry
CLASS: TYBSc SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH-503: Organic Chemistry

FIRST TERM

NO.OF
REMARK
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES
S
REQUIRED
June --

July

Basic concepts of ORM. Unit IV, Aromatic Substitution 15


reaction: Arenium ion mechanism, Mechanism of Nitration &
FC Alkylation acylation, Mechanism of Sulphonation,
Halogenation and Diazo coupling Reaction, IPSO Substitution,
August Effect of substituent group I; Activating & Deactivating group

Nucleophilic Aromatic Substitution Reaction

Addition-Elimination Mechanism, Benzyne Int. Mechanism

Evidences for addition-elimination reaction & Benzyne 15


Mechanism, Chichibabin Reaction
Examples Overview and Revision of CH-503 Unit-IV.
Introduction to CH-503 Unit I
September SN1 Reaction & SN2 Reaction, SNi Mechanism
Scope of Nucleophilic Substitution Reaction at Allylic & Vinylic C
NGP, Overview and Revision of CH-503 Unit -I Nucleophilic
Subst. @ Sat C Revision & Summarization.

Introduction to CH-503 Unit II Electrophilic addition to C=C.


Types: Electrophilic addition and Nucleophilic addition; 12
Mechanism of Electrophilic addition. AdE2 Mechanism.
Addtn of HX and Orientation of addtn
October
Markovnikov's Rule & Examples

Support for Carbocation formation in MR; Anti-Morkovnikov’s Rule.


and Terms Chemo/Regio/Stereo selectivity. Stereochemistry of Add
HX to Alkene Mechanism
Evidences to support Halogenation Mechanism (Bromination)&
Factors affecting Anti stereosect. Effect of Sust. on rate of Addition.

Factors affecting Anti Stereoselectivity of

Reaction Hydrogenation: Reaction, Mechanism & examples continue


and Cis Hydroxylation
Cis Hydroxylation Definition, reaction various reagents.

Trans Hydroxylation Definition, reaction various reagents,


mechanism & examples Ozonolysis

Mechanism of Ozonolysis, Precautions, Application & examples 06


Hydroboration-Oxidation Statement.

November CH-503 Unit-II Revision & Summarization.

Nucleophilic addition to c-o double bond introduction structure 15


reactivity. Cont.Factors affecting reactivity of carbonyl gp;
Mechanism of addition of HCN.Addition of alcohol watwr

Shapes of orbitals Thiol am

Statement Reaction Mechanism application of aldol, perkin


Cannizzaro reaction. wittig reaction

Reformatsky Reaction: statement, reaction, mechanism & applicat


December
Reducing agents NaBH4 & LiAlH4 Synthesis, Reactions,
mechanism, application, diff.

Topic: CH-503 U5 Ell.React: intro, exampls, mech.of 1,2eli., E2 elli:


reaction, kinectics & Mech.

E2, E1 & E1CB reaction, mechanism, evidences & conditions

E2vs E1 ; Sust vs Eli.

Sn1 vs e1 breats rue 10

January :dehydrohalogenation,dehalogenation,dehydration;Hoffmann &


Saytzeff eli.. Revision and Problem solving for Uni. Exam

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra
University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured
“College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMIC YEAR: 2020- 2021


NAME OF TEACHER: Dr Manoj A. Pande
FACULTY: Science DEPARTMENT: Chemistry
CLASS: FY B.Sc. SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: Organic Spectroscopy
SECOND TERM

NO.OF
LECTUR
REMAR
MONTH THEORY / PRACTICALS TO BE COVERED ES
KS
REQUIR
ED
Unit I Introduction to spectroscopy 15
February

Mass spectroscopy 5
March

Unit 2 UV spectroscopy 12
April

UNIT 3. Infra-red Spectroscopy 12


May

UNIT 4. NMR Spectroscopy 12


June

UNIT 5. Combined Problems Based on UV, IR, NMR & 12


Mass
June
(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Rajendra D. Patil
FACULTY:Science DEPARTMENT: Chemistry
CLASS: FYBSc SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH- 112: Organic Chemistry I

FIRST TERM

NO.OF
REMARK
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES
S
REQUIRED
June --

July

August

September
Unit I. Fundamentals of Organic Chemistry
October Introduction, Inductive Effect and Resonance Effect. 02

Unit I. Fundamentals of Organic Chemistry 06

Cleavage of Bonds: Homolysis and Heterolysis.

Structure, shape and reactivity of organic molecules:


Nucleophiles and electrophiles. Reactive Intermediates:
November
Carbocations, Carbanions and free radicals.
Strength of organic acids and bases: Comparative study with
emphasis on factors affecting pKvalues. Aromaticity:
Benzenoids and Hückel’s rule.
Revision of Unit I

Unit II.IUPAC Nomenclature of Organic Compounds 08

Rules for IUPAC nomenclature for: Saturated hydrocarbons,


unsaturated hydrocarbons, organic compounds containing one
December
functional group, organic compounds containing functional
group and multiple bonds, organic compounds containing two
or more than two functional groups.

Unit II. IUPAC Nomenclature of Organic Compounds 08


January
Cyclic organic compounds, bicyclic organic compounds,
Aromatic compounds.
Revision of Unit II.

Unit III. Aliphatic Hydrocarbons

Alkanes: (Upto 5 Carbons). Preparation: Catalytic


hydrogenation, Wurtz reaction, Kolbe’s synthesis, from
Grignard reagent. Reactions: Free radical Substitution:
Halogenation.

Alkenes: (Upto 5 Carbons) Preparation: Elimination reactions:


Dehydration of alcohols anddehydrohalogenation of alkyl
halides (Saytzeff’s rule): cis alkenes (Partial catalytic
hydrogenation) and trans alkenes (Birch reduction). Reactions:
cis-addition (alk. KMnO4) and trans-addition
(bromine).Addition of HX (Markownikoff’s and anti-
Markownikoff’s addition), Hydration, Ozonolysis,
oxymecuration-demercuration, Hydroboration-oxidation.

Alkynes: (Upto 5 Carbons) Preparation: Acetylene from CaC2 06


and conversion into higher alkynes; by dehalogenation of tetra
halides and dehydrohalogenation of vicinal-dihalides.
February
Reactions: formation of metal acetylides, addition of bromine
and alkaline KMnO4, ozonolysis and oxidation with hot
alkaline KMnO4.

Revision of Unit III.

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJIJAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Rajendra D. Patil
FACULTY:Science DEPARTMENT: Chemistry
CLASS: SYBSc SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH- 230: IT Skill for Chemist

FIRST TERM

NO.OF
REMARK
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES
S
REQUIRED
June --
Unit I. Introductory Writing Activities
Introduction to word processor.
July
02

Unit I. Introductory Writing Activities

Introduction to structure drawing (Chem Sketch/ Chem Draw) 06


software.Incorporating chemical structures, chemical
August equations, and expressions from chemistry into wordProcessing
documents.

Revision of Unit I.

Unit II Handling Numeric Data


08
Spreadsheet software (Excel), creating a spreadsheet, entering
September andformatting information, basic functions and formulae,
creating charts, tablesand graphs. Incorporating tables and
graphs into word processingdocuments.

Unit II Handling Numeric Data

Simple calculations, plotting graphs using a spreadsheet


(Planck’s distribution law, radial distribution curves for 06
hydrogenic orbitals, gas kinetic theory, and data from phase
October equilibria studies). Graphical solution.

Revision of Unit I.

Unit III Numeric Modelling


Simulation of pH metric titration curves.
Unit III Numeric Modeling 06

Excel functions LINEST and LeastSquares. Numerical curve


fitting, linear regression (rate constants fromconcentration time
November
data, molar extinction coefficients from absorbance
data), numerical differentiation (e.g. handling data from
potentiometric andpH metric titrations, pKa of weak acid),

First Internal Examination.

Unit III Numeric Modelling 02

Numerical integration (e.g. entropy/enthalpy change from heat


capacity data).
December
Revision of Unit III.Assignment.

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJIJAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Rajendra D. Patil
FACULTY:Science DEPARTMENT: Chemistry
CLASS: M.Sc. II SUBJECT: M.Sc. II Organic Chemistry
PAPER CODE and TITLE OF PAPER: CHO-301: Organic Reaction Mechanism

THIRD TERM

NO.OF
REMARK
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES
S
REQUIRED

June
--
Unit I: Electronic Effect and Reactive intermediates

Effect of structure on reactivity: Inductive effect, 05


July Electromeric effect, Resonance, Hyperconjugation, and steric
effects, Hammett equation and linear free energy relationship,
Substituent and reaction constant, Taft equation.
Unit I: Electronic Effect and Reactive intermediates

Thermodynamic and kinetic requirements for reactions, 10


thermodynamically and kinetically controlled reactions,
Hammonds postulate, transition states and intermediates,
Kinetic & non kinetic methods of determining mechanisms,
identification of products and determination of the presence of
August
an intermediate, isotopic labeling, and kinetic isotope effects.

Reactive intermediates:
Formation, structure, stability, and reactions of carbocations,
carbanions, carbenes, nitrenes and free radicals.
Revision of Unit I.

Unit II: Aromatic Electrophilic Substitution and


Elimination Reactions 15

Aromatic Electrophilic Substitution:


The arenium ion mechanism, orientation and reactivity, energy
profile diagrams. The o/p ratio, ipso attack, orientation in
September
benzene ring with more than one substituents, orientation in
other ring system. Diazonium coupling, Gatterman-Koch
reaction, Pechman reaction, Houben–Hoesch reaction.

Elimination Reactions:
The E1, E2 and E1CB mechanisms and orientation of the
double bond, Saytzeff and Hoffman‟s rule, Effect of substrate
structure, attacking base, leaving group and medium,
Mechanism and orientation in pyrolytic elimination.

Revision of Unit II.

Unit III: Carbanion

a) Carbanion:Formation, stability and related name reactions.


Aldol Condensation, BenzoinCondensation, Michael addition, 10
October Mannich reaction, Reimer-Tiemann reaction, Knoevengal
reaction, Dieckmann reaction, Perkin reaction, Stobbe reaction,
Halogenation of Ketone (Acid &Base catalysed), Darzen
Condensation reaction and Claisen Ester condensation.

Unit III: Carbanion 12

b) Enamines: Formation and Applications.


Revision of Unit III.

Unit IV: Umpolung

Umpolung Reactivity:
November
Dipole inversion, generation of acyl anion, use of 1,3-dithiane,
methylthiomethylsulphoxide, bis-Phenylthiomethane,
Metallatedenol ethers, alkylidenedithiane, Ketone dithioacetals,
and 2-propenethiobismethyl thioallyl anion.

b) Phosphorous, Nitrogen and Sulphur ylid


Preparation, Reactions, Applications and Stereochemistry.

First Internal Examination

c) Organoboranes 08

Preparation and properties of organoborane reagents (RBH2,


R2BH, R3B, 9-BBN, catecholborane, Thexylborane,
cyclohexylborane.Hydroboration mechanism, stereo
andregioselectivity.Uses of hydroboration in synthesis of
primary, secondary, tertiary alcohols,aldehydes, and
December ketones.Synthesis of EE, EZ, and ZZdienes and
alkynes.Allylboranes- synthesis,
mechanism and uses.

d) Organo silicon and Tin


Me3SiCl, Peterson Olefination and Me3SiH, TBTH and AIBN.
Revision of Unit IV.
Assignment

(Teacher) (Director and Head)


K.C.E.Society’s
MOOLJIJAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. Rajendra D. Patil
FACULTY:Science DEPARTMENT: Chemistry
CLASS: M.Sc. II SUBJECT: M.Sc. II Organic Chemistry
PAPER CODE and TITLE OF PAPER: CHO-306: Photochemistry, Free radical and
Pericyclic reactions

FIRST TERM

NO.OF
REMARK
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES
S
REQUIRED
June --
Unit I: Photochemistry

Introduction and basic principles, photochemical excitation of 04


July
the molecule, electronic transitions, spin multiplicity, Jablonski
diagram.

Unit I: Photochemistry

Laws of photochemistry-GrothursDrapper Law and Einstein's 10


Law of Photochemical Equivalence. Quantum yield,
Photosentization and quenching process.
Revision of Unit I.

August Unit II: Photochemistry of Organic Compound

a) Carbonyl compounds
Norrish Type I, α-cleavage: Acyclic saturated ketones,
saturated cyclic ketones. β-cleavage reaction, hydrogen
abstraction, Norrish Type II, and Intermolecular photo
reduction.

Unit II: Photochemistry of Organic Compound


11
a) Carbonyl compounds
Paterno-Buchireaction and reaction of enone with alkenes.
b) Photo Rearrangements
Cyclohexanone rearrangements, Di-π-methane (DPM)
September
rearrangemet, and Aza-Di-π-methanerearrangement
c) Photochemistry of alkenes
Cis-trans isomerization, dimerization, photochemistry of
conjugated diene in solution
d) Photochemistry of Aromatic compounds
Isomerization, addition of alkenes to benzenoid compounds,
addition of oxygen and aromatic photo substitution.
e) Photofries rearrangement and Barton reaction.
Revision of Unit II.

Unit III: Free Radicals

Formation, stability, types of free radical reactions, free radical


substitution, cyclizationmechanism, mechanism at an aromatic 12
October
substrate, neighbouring group assistance and effect ofsolvent
on reactivity.NBS allylic bromination, aldehyde oxidation,
autooxidaton, alkynes coupling, arylation ofaromatic
compounds by diazonium salts.
Unit III: Free Radicals 11
Sand-Meyer reaction and Hunds-Diecker reaction.
Revision of Unit II.

Unit IV: Pericyclic Reactions-I

a) Introduction, construction of π MO orbitals of ethylene and


November 1,3-butadiene, symmetry in π MOorbitals, Frontier Moleculer
Orbitals (FMO), PMO, and Excited states.

b) Electrocyclic reactions: Introduction, con-rotatory and dis-


rotatory motions in ring openingand ring closing reactions (4n
and 4n+2 π system), FMO method for ring opening and closing
of4n and 4n+2 π system.
Revision of Unit III.First Internal Examination

Unit V: Pericyclic Reactions-II 12

a) Cycloaddition reactions
Introduction, [2+2] cycloaddition (FMO method
andstereochemistry), [2+4] cycloaddition(FMO method and
stereochemistry), Diels-Alder reaction, retrocycloaddition,
Chelotropicreactions and 1,3-dipolar cycloaddition.

December
b) Sigma tropic rearrangements
Introduction, classification and nomenclature, Mechanism and
FMO, Sigmatropic shifts of alkylgroup, Cope rearrangement,
Claisen rearrangements, fluxional molecules and ENE reaction.

c) Applications of Pericyclic Reactions


Synthesis of Vitamin-D and Endiandric acid.

Revision of Unit IV.Assignment

(Teacher) (Director and Head)


Signature Signature
K.C.E.Society’s
MOOLJIJAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University,
Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College
of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]

TEACHING PLAN

ACADEMICYEAR: 2020-21

NAME OF TEACHER: Dr. Rajendra D. Patil

FACULTY:Science DEPARTMENT: Chemistry

CLASS: F. Y. B.Sc. SUBJECT: Chemistry

PAPER CODE and TITLE OF PAPER: CH-122 and Organic Chemistry

Second TERM
Lectures
Month Topic Remarks
Allotted
May -
Unit 1. Aromatic hydrocarbons 06
Preparation of benzene from phenol, by
decarboxylation, from acetylene, from benzene
sulphonic acid.

Reactions of benzene: Nitration, halogenation


and sulphonation. Friedel-Craft’s reaction
alkylation and acylation. Side chain oxidation of
alkyl benzenes.

Revision of Unit 1.

Unit 2. Alkyl and Aryl Halides 04

a) Alkyl Halides:

SN1, SN2 and SNi reactions.

Preparation of alkyl halide from alkenes and


alcohols.

Reactions of alkyl halide: hydrolysis, nitrite &


nitro formation, nitrile & isonitrile formation.
Williamson’s ether synthesis. Elimination vs
substitution.

June Unit 2. Alkyl and Aryl Halides 04

b) Aryl Halides:
Preparation of Chloro, bromo and iodo-benzene
from phenol, Sandmeyer reactions.

Reactions of Chlorobenzene: Aromatic


nucleophilic substitution- replacement by –OH
group. Effect of substituent on nucleophilic
substitution. Benzyne Mechanism.

Reactivity and Relative strength of C-Halogen


bond in alkyl, allyl, benzyl, vinyl and aryl halides.

Revision of Unit 2.

Unit 3. Alcohols, Phenols and Ethers

a) Alcohols:
Preparation of 1о, 2о and 3о alcohols using
Grignard reagent, Ester hydrolysis, Reduction of
aldehydes, ketones, carboxylic acid and esters.
06
Reactions of alcohols: With sodium, HX (Lucas
test), esterification, oxidation with PCC, alk.
KMnO4, acidic dichromate, conc. HNO3.
Oppeneauer oxidation, Diols: oxidation of diols.
Pinacol-Pinacolone rearrangement.

July b) Phenols: 04
Preparation of phenol: Cumene hydroperoxide
method, from diazonium salts.
Reactions of phenol:
Nitration, halogenation and sulphonation, Reimer-
Tiemann Reaction, Gattermann-Koch Reaction,
Houben–Hoesch Condensation, Schotten
Baumann Reaction.

c) Ethers :Cleavage of ethers with HI.


Revision of Chapter-3

Chapter-4 Aldehydes and ketones


Preparation of formaldehyde, acetaldehyde,
acetone and benzaldehyde from acid chlorides and
from nitriles.

Reactions of aldehyde and ketones – Reaction 06


with HCN, ROH, NaHSO3, NH2-G derivatives.
Iodoform test, Aldol Condensation, Cannizzaro’s
reaction, Wittig reaction, Benzoin condensation,
Clemmensen reduction, Wolff Kishner reduction,
Meerwein-Pondorff Verley reduction.

Revision of Chapter-4

Exams

Signature :……………………………………… Signature: …………………………………

Director/Head Name of Teacher: ……………………………………


K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]

TEACHING PLAN

ACADEMICYEAR: 2020-21
NAME OF TEACHER: Dr. R. D. Patil
FACULTY: Science DEPARTMENT: Chemistry
CLASS: S.Y. B.Sc SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH- 240: Basic Analytical Chemistry
FOURTH TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit-1: Introduction to Analytical Chemistry
Introduction to Analytical Chemistry and its interdisciplinary
nature. Concept of sampling. Importance of accuracy, precision
March and sources of error in analytical measurements. Presentation of
experimental data and results, from the point of view of
significant figures.
Unit II : Chromatography
Definition, general introduction on principles of
chromatography, paper chromatography, TLC etc.
April a. Paper chromatographic separation of mixture of metal ion
(Fe3+ and Al3+).
b. To compare paint/dyes/organic samples by TLC method.
Unit III : Analysis of Water Sample and Food Products

A] Analysis of water sample


Definition of pure water, sources responsible for contaminating
May water, water sampling methods, water purification methods.
a. Determination of pH, acidity and alkalinity of a water
sample.
b. Determination of dissolved oxygen (DO) of a water sample

B] Analysis of Food Products


Nutritional value of foods, idea about food processing, food
preservations and adulteration.
June a. Identification of adulterants in some common food items like
salt, coffee powder, chilli powder, turmeric powder and pulses, 5h
etc.
b. Analysis of preservatives and colouring matter.

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJIJAITHACOLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University,
Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College
of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]

TEACHING PLAN
ACADEMICYEAR: 2020-21

NAME OF TEACHER: Dr. Rajendra D. Patil

FACULTY:Science DEPARTMENT: Chemistry

CLASS: M.Sc II SUBJECT: Organic Chemistry

PAPER CODE and TITLE OF PAPER: CHO-402: Advanced synthetic organic chemistry

Fourth TERM
Review
Lectures Action plan if
Month Topic (Complete/
Allotted incomplete
Incomplete)
March Unit I: Metal mediated 10
organic synthesis

Transition metal complexes in


organic synthesis
Cu, Pd, Ni, Co, Fe (Metal
mediated C-C and C-X bond
formation reactions: Suzuki,
Heck, Sonogashira, Stille,
Fukuyama, Kumada, Hiyama,
Negishi, Buchwald-Hartwig,
Noyori, Reppe, Oxo process
and Ullman coupling.
April Unit I: Metal mediated 05
organic synthesis

Metathesis: Grubbs 1st and 2nd


generation catalyst, Olefin cross
coupling (OCM), ring closing
(RCM) and ring opening
(ROM) metathesis,
applications.

Revision of Unit 1.

Unit II: Olefin formation 08


reactions
Wittig, Horner-Wordworth-
Emmons, Shapiro, Bamford-
Stevens, McMurry, Julia-
Lythgoe and Peterson
olefination reactions, Titanium-
carbene mediated olefination:
Tebbe, Petasis and Nysted
reagent.

Revision of Unit 2.

Unit III: Ring formation


reactions 03
Pausan-Khand, Bergman and
Nazerov Cyclization.
May Unit III: Ring formation 04
reactions

Re Click chemistry: criterion


for click reaction, Sharpless
azides cycloadditions.

Other important reactions:


Baylis Hilman, Eschenmoser-
Tanabe fragmentation,
Mitsunobu reaction.

Revision of Unit-3.

Unit IV: Use of Boron and


Silicon in organic synthesis 06
Revision of Unit-4.

Unit V:Designing of organic


synthesis 06
a) Protection and de-protection
of hydroxyl, amino, carboxyl,
ketone and aldehyde functions
as illustrated in the synthesis of
polypeptide and polynucleotide,
Umpolung in organic synthesis.
June Unit V:Designing of organic 18
synthesis

b) Retrosynthesis
An introduction to synthons and
synthetic equivalents,
functional group inter
conversions.
One group Disconnections
:Disconnections of simple
alcohols, simple olefins, Aryl
ketones, control,
Disconnections of simple
ketones & acids.
Two group Disconnections :
1,3-Dioxygenated skeletons, β-
hydroxy carbonyl compounds,
α-β unsaturated carbonyl
compounds, 1,3-dicarbonyl
compounds, 1,5-dicarbonyl
compounds–Use of Mannich
reaction
Two group Disconnections :
The 1,2-Dioxygenation pattern
–α -hydroxy carbonyl
compounds, 1,2 diols, Illogical
electrophiles ,1,4-
Dioxygenation pattern - 1,4
dicarbonyl compounds, γ
hydroxy carbonyl compounds,
other illogical synthons, 1,6
dicarbonyl compounds,
pericyclic reactions,
Heteroatoms & heterocyclic
compounds.
Exams

Signature :……………………………………… Signature: …………………………………

Director/Head Name of Teacher: ……………………………………


Khandesh College Education Society’s
Moolji Jaitha College, Jalgaon
An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. R. R. Mahire Class: T. Y. B. Sc. (Chemistry)
Subject/Paper : CH-502 Inorganic Chemistry Faculty: Science
(Sem-V) (2020-21)

Review
Lectures Action plan if
Month Topic (Complete/
Allotted incomplete
Incomplete)
August UNIT-1: Structure and 09
Reactivity of Molecules
Valence Shell Electron Pair
Repulsion Theory (VSEPR),
Shapes of simple molecules and
ions containing lone-and bond-
pairs of electrons multiple
bonding, prediction of shapes of
irregular molecules and ions
like - Sulphur tetra fluoride,
Bromine trifluoride,
Dichloroiodate
(I) anion, Penta fluoro telluurate
(IV) anion, Tetrachloroiodate
(III) anion, Nitrogen dioxide,
Phosphorus trihalides, Carbonyl
fluoride, Summary of VSEPR
rules Drawbacks of VSEPR
theory.
September UNIT 2: Modern Theories of 09
Coordination Compound Part
–A:
Assumptions, Werner theory
and isomerism, EAN, Stability
of complex ion, Factors
affecting stability of complex
ion, Irving William series,
Stabilization of unstable
oxidation
state, Stereochemistry of
coordination compound with
C.N. 4 and 6, Isomerism in
coordination compounds
October UNIT 3: Modern Theories of 09
Coordination Compound Part

Page 1 of 3
–B:
Assumptions of V.B.T., V.B.
Theory as applied to structural
and bonding in complexes of 3d
series elements. Examples of
square planar, Tetrahedral and
Octahedral complexes, inner
and
outer orbital complexes,
Magnetic properties of
complexes of 3d series
elements, limitations of
V.B.T., Assumptions of CFT,
Degeneracy of ‘d’ orbital’s,
Application of CFT to
octahedral
complexes, Weak and strong
ligand field splitting,
spectrochemical series.

November UNIT 4: Modern Theories of 09


Coordination Compound Part
–C:
Definition of C.F.S.E.,
Calculation of C.F.S.E. in weak
and strong field octahedral
complexes, Evidences of
C.F.S.E., Factor’s affecting 10
Dq, CFT and magnetic
properties, spin only magnetic
moment equation, Electron
occupancy in CFT, Application
of CFT to tetrahedral a nd
Calculation of C.F.S.E. in
tetrahedral complexes.
Tetragonal
distortions from octahedral
geometry, Jahn-Teller theorem
Application of CFT to square
planer complexes, Problems
related to calculation of spin
only magnetic moment for
square planer, tetrahedral and
octahedral complexes (for high
spin and low spin
complexes)
December UNIT 5: Modern Theories of 09
Coordination Compound Part
–D:
Crystal field effects- Variation
of lattice energies, enthalpies of
hydration and crystal radii
variations in halides of first and
second row transition metal
series and spinel structures,

Page 2 of 3
limitations of CFT,
experimental evidences in
support of metal ligand bond
overlaps. ACFT, Assumptions 09
of Molecular orbital theory,
composition of ligand group
orbitals, Molecular
orbital treatment (Qualitative)
of octahedral complexes (strong
& weak field), Effect of
pibonding, Charge transfer
spectra, Comparison of VBT,
CFT and MOT.

Signature: Signature:
Director/Head Name of Teacher: Dr. R. R. Mahire

Page 3 of 3
Khandesh College Education Society’s
Moolji Jaitha College, Jalgaon
An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. R. R. Mahire Class: T. Y. B. Sc. (Chemistry)
Subject/Paper : CH-602 Chemistry of Inorganic Solids Faculty: Science
(Sem-VI) (2020-21)

Review
Lectures Action plan if
Month Topic (Complete/
Allotted incomplete
Incomplete)
March UNIT 1: Synthetic Methods of 09
Nanomaterials
Introduction to Nano science,
nanostructure and
nanotechnology (basic idea),
Size dependent
properties of nanomaterials
(basic idea) a) Semiconducting
nanoparticles b) Metallic
nanoparticles. Synthesis routes
of nanomaterials: a) Bottom up
approaches i) Chemical vapor
deposition (CVD) ii) Spray
pyrolysis iii) Sol gel process b)
Top down approaches:
mechanical alloying, Role of
surfactant in shape and size
control of nanomaterials
UNIT 2: Inorganic Solids of 06
Technological Importance
Inorganic pigments, Coloured
solids, White and black
pigments, Molecular materials
and fullerides, Molecular
material chemistry – One
dimensional metals, Molecular
magnets

April UNIT 2: Inorganic Solids of 03


Technological Importance
, Inorganic liquid crystals, Solid
electrolytes (a) solid cationic
electrolytes (b) solid anionic
Electrolytes.

Page 1 of 2
UNIT 3: Cement and Lime 09
Classification of cement,
Ingredients and their role,
Manufacture of cement and the
setting process. Quick setting
cements. Manufacture of lime
and applications.

UNIT 4: Fertilizers
Plant Nutrients, Different types 04
of fertilizers, need for
fertilizers, requisite qualities of
fertilizers, symptom of
deficiency,
May UNIT 4: Fertilizers 05
Manufacture of following
fertilizers:- Urea, Ammonium
nitrate, Calcium ammonium
nitrate, Ammonium phosphate,
Super phosphates, Compound
and Mixed fertilizers,
Potassium chloride and
Potassium sulphate.
UNIT 5: Alloys 09
Classification of alloys, Ferrous
and Non-ferrous alloys,
Specific properties of elements
in
alloys, Manufacture of steel,
Removal of silicon,
decarburization,
demagnetization and
desulphurization. Composition
and properties of different types
of steels.

Signature: Signature:
Director/Head Name of Teacher: Dr. R. R. Mahire

Page 2 of 2
Khandesh College Education Society’s
Moolji Jaitha College, Jalgaon
An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. R. R. Mahire Class : M. Sc.-II (Analytical Chemistry)
Subject/Paper : CHA-302 Modern separation science Faculty: Science
(Sem-III) (2020-21)

Review
Lectures Action plan if
Month Topic (Complete/
Allotted incomplete
Incomplete)
August Unit I: Chromatography: 10
General Principles
Definition and types of
chromatography, Theoretical
Principles underlying
Chromatographic techniques,
Theories of Chromatography:
(a) Plate Theory, (b) Rate
Theory, Behavior of solutes,
Column efficiency and band
broadening, Resolution,
Column process, Reduced
variable, Time of analysis,
Qualitative & quantitative
analysis, Problems.
September Unit II: Gas Chromatography 10
Optimization of experimental
condition, Retention time and
Retention volume, Detectors:
Thermionic, Flame
photometric, Helium and
Coulson conductivity detectors,
Qualitative and Quantitative
analysis, Problems.

October Unit III: High Performance 10


Liquid Chromatography
Introduction, GC and HPLC,
Instrumentation, Refractive
index detector, luminescence
detector, ultraviolet detector
and electrochemical detector,
Quantitative analysis and data
display,

Page 1 of 2
November Unit III: High Performance 05
Liquid Chromatography
Derivatisation technique in
HPLC, Chiral columns, C8 and
C18 columns, Applications.
Unit IV: Ion exchange 05
chromatography
Definition, Principle, Cation
Exchangers, Anion Exchangers,
Regeneration, Ion Exchange
Column Used in
Chromatographic Seperations,
December Unit IV: Ion exchange 05
chromatography
Selection of suitable systems,
Ion exchange capacity, Ion
Exchange Techniques,
Applications of Ion exchangers.

Unit V: Solvent Extraction 05


and Membrane-Based
Methods
Distribution coefficient,
distribution ratio, percent
extracted, solvent extraction of
metals, accelerated and

January Unit V: Solvent Extraction 10


and Membrane-Based
Methods
microwave assisted extraction,
solid phase extraction and solid
phase microextraction,
problems.
Reverse Osmosis- Working of
techniques and Applications
Electrodialysis - Membrane
working of techniques and
Applications, membranes
materials, Ultracentrifugation

Signature: Signature:
Director/Head Name of Teacher: Dr. R. R. Mahire

Page 2 of 2
Khandesh College Education Society’s
Moolji Jaitha College, Jalgaon
An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. R. R. Mahire Class : M. Sc.-II (Analytical Chemistry)
Subject/Paper : CHA-305B Bio-analysis & analysis of Faculty: Science
food (Sem-III) (2020-21)

Review
Lectures Action plan if
Month Topic (Complete/
Allotted incomplete
Incomplete)
August Unit I: Human Nutrition, 10
Biological Value of Food
Human nutrition, Biological
value of food, Estimation of
carbohydrates, Fats, Proteins,
Amino
Acids.
September Unit II: Food Analysis 10
Analysis of food: Milk, Cereals,
Flour, Spices, Flavors’ and
Condiments, Honey, jam and
jelly, Non-alcoholic beverages
(Tea and Coffee).
October Unit III: Determination of 10
food preservatives
Fluorides, Oxidizing agent-
Peroxide, Organic Preservative,
Formaldehyde, Formic acid ,
Ether extractive preservative,
Separation of organic
preservative and sweetening
agents,

November Unit III: Determination of 05


food preservatives
Volatile fatty acid in bakery
product, 2 Aminopyridine in
orange.

Unit IV: Collection of 05


Specimens and Analysis of
Blood and urine
Blood: Collection of Blood
specimens, storage and
preservation, Urine: Collection

Page 1 of 2
of Urine, physical
characteristics of urea,
preservation and storage.
December Unit IV: Collection of 10
Specimens and Analysis of
Blood and urine
Determination of blood and
plasma glucose by glucose
oxidase method, Determination
of urine for glucose,
Determination of ketone bodies
in blood, Oral Glucose
tolerance test. Determination
of blood hemoglobin,
determination of urea in urine
by urease method and by direct
colorimetry, Estimation of Na,
K, Ca by flame photometry,
inorganic phosphate by
colorimetry.

January Unit V: Forensic Analysis 10


Introduction, Forensic
examination of biological
fluids, stains semen, hair and
other materials.
Forensic Toxicology: Isolation,
identification and determination
of following 1) Narcoticsheroin
and cocaine. 2) Stimulants-
caffeine, amphetamines. 3)
Depressants- Barbiturates,
Benzodiazepines.

Signature: Signature:
Director/Head Name of Teacher: Dr. R. R. Mahire

Page 2 of 2
Khandesh College Education Society’s
Moolji Jaitha College, Jalgaon
An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. R. R. Mahire Class: M. Sc.-II (Analytical Chemistry)
Subject/Paper : CHA-406 Applications of nanotechnology Faculty: Science
(Sem-IV) (2020-21)

Review
Lectures Action plan if
Month Topic (Complete/
Allotted incomplete
Incomplete)
March Unit I: Nano- The expanding 10
Horizon
Introduction, Fundamentals of
nano, Nanoscale phenomena,
Significance of nanomaterials
and its impact, Classification of
nanomaterials, need for it,
issues and other perspectives,
Prospective
applications.
Unit II: Fabrication of 05
Nanomaterials
Top-down and Bottom-up
approaches, Gas phase
synthesis.
April Unit II: Fabrication of 05
Nanomaterials
Liquid phase synthesis, Solid
phase synthesis, Lithography.
Unit III: Nanomaterial
Evaluation:
Need for material studies,
Structural property studies, 10
Morphological analysis, Optical
property studies.

Page 1 of 2
May Unit III: Nanomaterial 05
Evaluation:
Electrical property studies,
Magnetic property studies,
Mechanical property studies.
Unit IV: Nanomaterials for 10
Environmental Remediation
Environmental remediation by
chemical degradation/ Removal
of contaminants, Nanomaterials
as sorbents, Nanofiltration- for
clean water, Dendrimers- the
nanoreactors for remediation,
carbon nanomaterials- Versatile
new Adsorbents, Nanoscale
biopolymers, Future prospects.
June Unit V: Societal Implications 15
of Nanotechnology
Societal implications,
Physicochemical properties of
Nanomaterials, Health hazards,
Nanotoxicology, Significance
of toxicity studies, Current
perspectives.

Signature: Signature:
Director/Head Name of Teacher: Dr. R. R. Mahire

Page 2 of 2
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]

TEACHING PLAN

ACADEMICYEAR: 2021-2022
NAME OF TEACHER: Sonal B Uplapwar
FACULTY: Science DEPARTMENT: Chemistry
CLASS: M.Sc.II (Analytical Chemistry) SUBJECT: Analytical Chemistry
PAPER CODE and TITLE OF PAPER: CHA-301: Concepts of analytical chemistry
FIRST TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit I: Analytical Science: A perspective 12
&
August Unit II

Unit II: Statistical analysis and validation 12

September

Unit III: Good laboratory practice: Quality assurance of analytical 12


measurements
October

Unit IV: Introduction to intellectual property rights 12

November

Unit V: Introduction to patent 12

December

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]

TEACHING PLAN

ACADEMICYEAR: 2021-2022
NAME OF TEACHER: Sonal B Uplapwar
FACULTY: Science DEPARTMENT: Chemistry
CLASS: M.Sc II SUBJECT: Analytical chemistry
PAPER CODE and TITLE OF PAPER: CHA-401: Spectroscopic methods of analysis
SECOND TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit I: Electron spectroscopy 14

March

Unit II: X-ray methods of analysis 18


Unit III: Atomic mass spectroscopy
April

Unit V: Atomic absorption spectrophotometry 18

May

Unit IV: Nuclear magnetic resonance spectroscopy 10

June

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]

TEACHING PLAN

ACADEMICYEAR: 2020-2021
NAME OF TEACHER: Sonal B Uplapwar
FACULTY: Science DEPARTMENT: Chemistry
CLASS: M.Sc.II (Analytical Chemistry) SUBJECT: Analytical Chemistry
PAPER CODE and TITLE OF PAPER: CHA-306: Instrumental methods of analysis
FIRST TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit I: Polarography 12

August

Unit II: Amperometric titration 12

September

Unit III: Electrogravimetric analysis 12


October

Unit IV: Coulometric analysis 12


November

Unit V: Automated analysis 12


December

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]

TEACHING PLAN

ACADEMICYEAR: 2020-2021
NAME OF TEACHER: Sonal B Uplapwar
FACULTY: Science DEPARTMENT: Chemistry
CLASS: TYBSc SUBJECT: Analytical Instrumentation
PAPER CODE and TITLE OF PAPER: CH-505: Analytical Instrumentation
FIRST TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit I: Spectrometry 12

August

Unit II: Infrared spectrometry 12

September

Unit III A: Emission spectrometry 12


Unit III B: Atomic Absorption spectrophotometry
October

Unit IV: Potentiometry 12

November

Unit V: pHmetry 12
December

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University, Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]

TEACHING PLAN

ACADEMICYEAR: 2021-2022
NAME OF TEACHER: Sonal B Uplapwar
FACULTY: Science DEPARTMENT: Chemistry
CLASS: TYBSc SUBJECT: Analytical Techniques
PAPER CODE and TITLE OF PAPER: CH-605: Analytical Techniques
SECOND TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit I: Solvent Extraction 12

January

Unit II: High performance liquid chromatography 12


February

Unit III: Gas chromatography 12

March

Unit IV: Ion exchange chromatography 12

April

Unit V: Thermal methods 12

May

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University,
Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of
Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMIC YEAR: 2020- 2021


NAME OF TEACHER: Padvi Sandip Narpat
FACULTY: Science DEPARTMENT: Chemistry
CLASS: F.Y.B.Sc. SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH-112 Organic Chemistry-I
FIRST TERM

NO.OF
LECTUR
REMAR
MONTH THEORY / PRACTICALS TO BE COVERED ES
KS
REQUIR
ED
Unit-1 Fundamental of Organic Chemistry
08
Physical effects, Electronic Displacements: Inductive
Effect, Electromeric Effect, Resonance and
Hyperconjugation, Cleavage of bonds: Homolysis and
Heterolysis, Structure, shape and reactivity of organic
molecules: Nucleophiles and Electrophiles ,Reactive

October Intermediates: Carbocations, Carbanions and Free


radicals,Strength of organic acids and bases: comparative
study with emphasis on factors affecting pK
values,Aromaticity and Huckel’s Rule
Unit-2 IUPAC Nomenclature of Organic Compound
Rules for IUPAC nomenclature for 1) Saturated
01
Hydrocarbons
2)Unsaturated Hydrocarbons –Alkenes & Alkynes
06
3)Organic copound containing one functional group
And multiple bonds 4)Organic compounds containing two
November or more than two functional groups.
5)Cyclic Organic Compound 6)Bicyclic Organic
03
Compound 7)Aromatic Compounds
Unit-3 Aliphatic Hydrocarbons
Alkanes: (upto 5 carbons) Preparation : Catalytic
07
Hydrogenation ,Wurtz Reaction ,Kolbe’s Synthesis, From
Grignard Reagent, Reactions: Free Radical Substitution:
Halogenation
Alkenes: (upto 5 carbons) Preparation
December
:Eliminationreactions,Dehydration of Alcohols and
dehydrohalogenation of alkyl halides (Saytzeff’s Rule):
Cis alkenes (Partial Catalytic hydrogenation) and Trans
alkenes (Birch Reduction). Reactions: Cis – Addition
(alk.KMnO4) and Trans –Addition (Bromine),Addition of
HX (Markovnikoff’s and Anti-Markovnikoff’s Addition ),
Hydration ,Ozonolysis ,Oxymercuration-demercuration,
Hydroboration-oxidation.
Alkynes: (upto 5 carbons) Preparation: Acetylene from
05
CaC2 and conversion into higher alkynes ,by
dehalogenation of tetra halides and dehydrohalogenation
January
of vicinal-dihalides,Reactions: formation of metal
acetylides,addition of bromine and alkaline KMnO4,
Ozonolysis and oxidation with hot alkaline KMnO4
Exam

February

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University,
Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of
Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMICYEAR: 2020- 2021


NAME OF TEACHER: Padvi Sandip Narpat
FACULTY: Science DEPARTMENT: Chemistry
CLASS: F.Y.B.Sc. SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CH-122 Organic Chemistry-II
SECOND TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit- 1 Aromatic Hydrocarbon 06
Preparation- From Phenol ,by decarboxylation,From
acetylene, from benzene sulphonic acid
Reactions-Electrophilic Substitution - Nitration ,
Halogenation , Sulphonation, Friedel Crafts Alkylation &
March
Acylation, Side chain reaction

Unit- 2 Alkyl and Aryl Halide


a) Alkyl Halide-Types of Nucleophilic ( SN1, SN2,SNi) 02
reactions. Preparation- from Alkene and Alcohols.
Reactions-Hydrolysis , nitrite and nitro formation ,nitrile 06
& isonitrile formation, Williamsons ether synthesis
Elimination Vs Substitution, b) Aryl Halide-Preaparation
(chloro, bromo, iodo benzene)From Phenol , Sandmeyer
Reaction. Reaction (chlorobenzene) -Aromatic
Nucleophilic Substitution ( replacement by -OH group),
Effect of nitro substitutent. Benzyne Mechanism:
KNH2/NH3 (or NaNH2/NH3) Reactivity and relative
April
strength of C-X bond in Alkyl, Allyl,Benzyl, Vinyl and
Aryl Halide

Unit-3 Alcohols, Phenols and Ethers


a)Alcohols-Preparation of Primary, secondary, tertiary
alcohols ,using Grignard Reagent , Ester hydrolysis, 01
Reduction of aldehydes , ketones ,carboxylic acid and
esters.
Reactions- with sodium , HX (Lucas Test), Esterification , 07
oxidation (with PCC , alk. KMnO4, acid dichromate ,
conc . HNO3 ), Oppeneaur Oxidation Diols - oxidation of
May
diols , Pinacol- Pinacolone rearangement.
b)Phenols- Preparation Cumenehydroperoxide method ,
from diazonium salts. Reactions- Electrophilic
Substitution- Nitration , halogenation and sulphonation ,
Reimer- Tiemann Reaction , Gattermann-Koch Reaction ,
Houben - Hoesch Condensation,Chotten Baumann
Reactions.

c) Ethers (Aliphatic And Aromatic)- Cleavage of ethers


with HI 02

Unit-4 Aldehydes And Ketones (Aliphatic and


Aromatic ) 06
( Formaldehyde , Acetaldehyde, Acetone and
June
Benzaldehyde ) Preparation- from acid chlorides and
from nitriles . Reactions- Reaction with HCN , ROH ,
NaHSO3,NH2-G derivatives , Iodoform Test, Aldol
Condensation , Cannizaros reaction , witig reaction ,
Benzoin Condensation , Clemensen reduction and Wolff
Kishner reduction , Meerwein -Pondorff varly reduction.

July Exam

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University,
Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of
Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMIC YEAR: 2020- 2021


NAME OF TEACHER: Padvi Sandip Narpat
FACULTY: Science DEPARTMENT: Chemistry
CLASS: M.Sc.-I SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CHO-106/CHA-106 Organic Chemistry-I
FIRST TERM

NO.OF
MONTH THEORY / PRACTICALS TO BE COVERED LECTURES REMARKS
REQUIRED
Unit-1 Nucleophilic Substitution 15
A) Aliphatic Nucleophilic substitution:
B) SN2, SN1 , Mixed SN2, SN1 and SNi mechanism , the
neighbouring group mechanism, neighbouring group
participation by π- & σ- bonds , Anchimeric Assistance ,
The SN 1 mechanism, Nucleophilic substitutions at an
allylic, aliphatic and a vinylic carbon. Reactivity effects of

February substrate structure, attacking nucleophile, leaving group and


reaction medium.
Aromatic Nucleophilic Substitution : SNAr, Benzyne
mechanism. Reactivity: Effect of substrate, leaving group
and attacking nucleophile. The Von Richter, Sommelet-
Hauser and Smiles rearrangements.
Unit-2 Aromatic Electrophilic Substitution
01
Arenium ion mechanism, orientation and reactivity.
energy profile diagram, calculation of partial rate factor, the 14
ortho/ para ratio, Ipso substitution, Orientation in other ring
systems such as Naphthalene, Anthracene, six and five
March
membered heterocycles, Diazonium coupling, Vilsmeier
reaction, and Gattermann–Koch reaction.
Unit-3 Addition Reaction
Addition to carbon-carbon multiple bonds and carbon
02
heteroatom multiple bonds- Mechanism and stereochemical
aspects of addition reaction involving electrophile

Structural effects and reactivity: Halogenations, 08


Hydrohalogenation, Hydration, Hydroxylation,
Hydroboration, Epoxidation, Carbene addition,
Hydrogenation, and Ozonolysis.
Unit-4 Linear Free Energy Relationship
April
Hammett plot, Hammett equation, substituent and reaction
06
constants, physical significance of substituent and reaction
constants, substituent constant involving through
conjugation. Use of Hammett plot and equation. Deviations
from straight line plot. Concave upward deviation.
Concave downward deviation. Steric effects, Taft equation, 04
Steric parameters, solvent effects, and change of reaction
constant.
Unit-5 Stereochemistry
Concept of chirality and molecular dissymmetry,
10
Recognition of symmetry elements and chiral centers,
May
Prochiral relationship, homotopic, enantiotopic and
disteriotopic groups and faces. Recemic modifications and
their resolution, R and S nomenclature. Geometrical
isomerism E and Z in C, N, S, P containing compounds,
Prochiralrelationship,stereospecific and stereoselective
reactions, optical activity in biphenyls,spiranes,allenes
Exam
June

(Teacher) (H.O.D.)
Signature Signature
K.C.E.Society’s
MOOLJI JAITHA COLLEGE, JALGAON
“An Autonomous College Affiliated to K.B.C., North Maharashtra University,
Jalgaon”
NAAC Reaccredited “A” Grade (CGPA: 3.15) (3rd Cycle)| UGC honoured “College of
Excellence”
Tel.: 0257 – 2234281, 2237363, Fax: 2237363, e-mail: [email protected]
TEACHING PLAN

ACADEMIC YEAR: 2020- 2021


NAME OF TEACHER: Padvi Sandip Narpat
FACULTY: Science DEPARTMENT: Chemistry
CLASS: M.Sc.-I SUBJECT: Chemistry
PAPER CODE and TITLE OF PAPER: CHO-206/CHA-206 Organic Chemistry-II
SECOND TERM

NO.OF
LECTUR
REMAR
MONTH THEORY / PRACTICALS TO BE COVERED ES
KS
REQUIR
ED
Unit- 1 Spectroscopy 15
PMR: • Fundamentals of PMR, chemical shift, factors
affecting chemical shift, anisotropic effect, spin-spin
coupling, coupling constant, applications to simple
structural problems integration coupling (1st order
analysis). • Introduction to CMR and mass spectrometry. •
July
Problems on UV, IR and PMR.

Unit- 2 Molecular Rearrangement and Reaction 01


Intermediate
Structure of carbenes, nitrenes, carbocations and
carbanions intermediates.
generation and stability of carbenes, nitrenes, carbocations 14
and carbanions intermediates ,Rearrangement reactions
viz. Beckmann, Curtius, Hofmann, Lossen, Favorskii,
Baeyer-Villiger, Wolff, Claisen, Pummerer, Wagner-
Meerwin, Stevens, Dienone-Phenol, Sommelet-Hauser,
August Benzilic acid, Benzidine, Cope, Fries, Neber and Schmidt
reaction.

Unit-3 Name Reaction


Bayer-Villiger Oxidation, Reformatsky, Robinson 02
annulation,
Stork enamine, Sharpless asymmetric epoxidation, Ene, 13
Barton, Hell-Volhard-Zelinsky reaction, Shapiro reaction,
September Chichibabin reaction, Vislmair Hacck reaction, Ulman
reaction, Rosenmund reaction, Darzen reaction,
Knovenagel reaction, and Biginelli reaction.
Unit-4 Synthetic Reagents 04
Oxidation reactions: CrO3, PDC, PCC (Corey’s reagent),
KMnO4, MnO2, Swern oxidation,

SeO2, Pb(OAc)4, Pd-C, OSO4, m-CPBA, O3, NaIO4,


HIO4, chloranil, DDQ, and Oppenauer oxidation. • 11
Reduction reactions: LiAlH4, NaBH4, NaCNBH3, MPV
October
reduction, Na/liquor NH3, H2/Pd-C, Willkinsons catalyst,
DIBAL-H, Wolff Kishner reduction, Zn-Hg/H2O/HCL,
and Bu3SnH.
Exam

November

(Teacher) (H.O.D.)
Signature Signature
Khandesh College Education Society’s

Moolji Jaitha College, Jalgaon


An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. Vasim R. Shaikh Class: T. Y. B. Sc.
(Chemistry)
Sem.-V
Subject/Paper : CH-501: Principles of Physical Faculty: Science
Chemistry-I

Review Action
Lectures
Month Topic (Complete/ plan if
Allotted
Incomplete) incomplete
August Unit-3: Phase Equilibrium: 11
Phases, Components and Degrees
of freedom of a system, Criteria of
phase equilibrium. Gibbs Phase
rule and its thermodynamic
derivation. Derivation of Clausius
–Clapeyron equation and its
importance in phase equilibria.
Phase diagrams of one-component
systems (water and sulphur) and
two component systems involving
eutectics, Congruent and
Incongruent melting points (lead-
silver, FeCl3-H2O only), Related
Numerical.
September Unit-2: Chemical kinetics 11
The concept of reaction rates.
Effect of temperature, Pressure,
Catalyst and other factors on
reaction rates. Order and
molecularity of a reaction.
Derivation of integrated rate
equations for zero, first and
second order reactions (both for
equal and unequal initial
concentrations of reactants) Half–
life of a reaction, Pseudo order
reactions, General methods for
determination of order of a
reaction. Effect of temperature on
reaction rate, Arrhenius equation
(exponential and integrated form),
Collision theory, Concept of
activation energy and its
calculation from Arrhenius
equation, Related numerical.
October Unit-4: Electrochemical Cell: 06
Introduction, overview of
electrode processes, Faradaic and
Non-Faradaic Processes,
Introduction to electrical double
layer, Factors affecting electrode
reaction rate and current.
November Unit-4: Electrochemical Cell: 06
Classification of electrochemical
cell, EMF expression for chemical
cell with and without transference,
Liquid junction potential, Types
of liquid junction potential,
Minimization of liquid junction
potential.

Unit-1: Basic Quantum


Chemistry: Failures of Classical 06
Mechanics, Origin of quantum
mechanics, Particle aspect of
radiation: Blackbody radiation,
Photoelectric effect, Compton
Effect, de Broglie’s hypothesis:
Matter waves, Heisenberg
uncertainty principle, Application
of Heisenberg’s principle.
December Unit-1: Basic Quantum 06
Chemistry: Interpretation of
wave function, Significance of ψ
and ψ2, Normalization of wave
function Operators and operator
algebra, Eigen functions and
Eigen values, various operators in
quantum mechanics: Linear
momentum, Kinetic energy and
Total energy operator (only
equations no derivations),
Postulates of quantum mechanics.

Signature: Signature:
Director/Head Name of Teacher: Dr. Vasim R. Shaikh
Khandesh College Education Society’s

Moolji Jaitha College, Jalgaon


An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. Vasim R. Shaikh Class: T. Y. B. Sc.
(Chemistry)
Sem.-VI
Subject/Paper : CH-601: Principles of Physical Faculty: Science
Chemistry-II

Review Action
Lectures
Month Topic (Complete/ plan if
Allotted
Incomplete) incomplete
March Unit-3: Photochemistry: Laws of 11
photochemistry, Quantum yield,
Examples of low and high quantum
yields, Consequence of light
absorption by atoms and molecules,
Jablonski diagram, Fluorescence,
Phosphorescence, Quenching.
Experimental setup for
determination of quantum yield
with actinometer as detector
Photochemical gas reactions,
Photolysis of ammonia,
Combination of H2 and Cl2 reaction,
Reaction between H2 and Br2,
Photosensitized gas reaction, H2 and
O2, H2 and CO,
Chemiluminescence, Related
numerical.
April Unit-2: Nuclear Chemistry: 12
Introduction, Radioactive
elements, Types of radioactive
decay, Decay schemes, General
characteristic of radioactive decay,
Decay kinetics, Decay constant,
Half-life period, Mean life, Units
of radioactivity.
Application of radioactivity –
Radiochemical principle of tracer
technique; Application of tracer
technique – Chemical
investigation reaction mechanism-
esterification, hydrolysis,
Oxidation - Oxidation of CO,
Structure determination - PCl5
molecules, Thiosulphate ion, C-
14 dating and tritium dating,
Medical applications- Thyroditis,
Bone fracture Healing, Brain
tumor location, Defects in Blood
Circulation.
Nuclear Fusion / Fission as source
of energy with example
Nuclear Pollution: Disposal of
nuclear waste, nuclear disaster and
its management with case study.
Related numerical.

UNIT-4. Crystal Structure: 05


Forms of solids. Symmetry
elements, unit cells, crystal
systems, Bravais lattice types and
identification of lattice planes.
Laws of Crystallography - Law of
constancy of interfacial angles,
Law of rational indices. Miller
indices. X–Ray diffraction by
crystals, Bragg’s law and Bragg’s
method.
May UNIT-4. Crystal Structure: 06
Structures of NaCl, KCl and CsCl
(qualitative treatment only).
Defects in crystals: Shottkey and
Frenkel defects. Liquid Crystal,
Types and Applications. Related
numerical

Unit-1. Investigation of 11
Molecular Structure:
Introduction, Dipole Moment,
Induced dipole moment, Electrical
polarization of molecules.
Orientation of dipole in an electric
field, Debye equation. Method of
determination of dipole moment,
Vapour temperature method,
Molecular structure and dipole
moment
Interaction of electromagnetic
radiation with molecules, Various
types of spectra Rotational,
Vibration and Electronic energy
levels; with principle and example
of each type.
Rotational spectroscopy: Rigid
and non-rigid rotor diatomic
molecule-Moment of inertia,
Energy Levels, Selection rule,
Intensities of spectral lines,
Determination of bond lengths of
diatomic and linear triatomic
molecules, Isotopic substitution.
Related numerical

Signature: Signature:
Director/Head Name of Teacher: Dr. Vasim R. Shaikh
Khandesh College Education Society’s

Moolji Jaitha College, Jalgaon


An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. Vasim R. Shaikh Class: S. Y. B. Sc.
(Chemistry)
Sem.-III
Subject/Paper : CH-231: Physical Chemistry-II Faculty: Science

Review Action
Lectures
Month Topic (Complete/ plan if
Allotted
Incomplete) incomplete
September Unit I: Gaseous State: 08
Introduction, general
characteristics of gases,
parameters (volume, pressure
temperature and number of moles)
of a gas, gas laws (Boyle’s law,
Charles
law, Avogadro’s law), Ideal-gas
equation, kinetic molecular theory
of gases,
deviations from ideal behaviour,
compressibility factor, effect of
pressure
and temperature variation on
deviations, van der Waals
equation.
October Unit I: Gaseous State: 02
liquefaction of gases-critical
phenomenon, van der Waals
equation and
critical constants, related
numericals.

Unit II: Theory of Electrolytic 08


Dissociation: Introduction,
Arrhenius theory of ionization,
migration of ions, relative
speed of ions: Hittorf’s rule,
transport number and its
determination by
Hittorf’s and moving boundary
method, Kohlrausch’s law of
independent
migration of ions and its
application for the calculation of
degree of
dissociation,
November Unit II: Theory of Electrolytic 02
Dissociation: Conductometric
titration: titration of a strong acid
against a
strong base, titration of a weak
acid against a strong base, titration
of a
strong acid against a weak base,
titration of a weal acid against a
weak base.

Unit III: Solutions: Introduction, 05


concentration of solutions, ways
of expressing concentration
(per cent by volume, per cent by
weight, molarity, molality, mole
fraction),
solutions of gases in gases,
Henry’s law, solutions of liquids
in liquids,
solubility of completely miscible
liquids, solubility of partially
miscible
liquids
December Unit III: Solutions: Phenol-water 05
system, triethylamine-water
system, nicotine-water
system, vapour pressures of
liquid-liquid solutions: first type
of mixtures of
miscible liquids, second type of
mixtures of miscible liquids and
third type
of mixtures of miscible liquids,
solutions of solids in liquids.

Signature: Signature:
Director/Head Name of Teacher: Dr. Vasim R. Shaikh
Khandesh College Education Society’s

Moolji Jaitha College, Jalgaon


An “Autonomous College” Affiliated to
Kavayitri Bahinabai Chaudhari North Maharashtra University, Jalgaon

School of Chemical Sciences

TEACHING PLAN
Name of Teacher: Dr. Vasim R. Shaikh Class: S. Y. B. Sc.
(Chemistry)
Sem.-IV
Subject/Paper : CH-241: Physical Chemistry-III Faculty: Science

Review Action
Lectures
Month Topic (Complete/ plan if
Allotted
Incomplete) incomplete
March Unit II: Electromotive Force: 06
Introduction, measurement of
electromotive force of an
unknown cell,
Weston standard cell, reversible
cells, relation between
electromotive force
and free energy, single electrode
potential, standard electromotive
force of a cell, determination of
electromotive of a half-cell,
Nernst equation,
reference electrode, primary
reference electrode: Standard
Hydrogen
Electrode (SHE)
April Unit II: Electromotive Force: 04
Secondary reference electrode:
standard silver-silver
electrode, Calomel electrode,
glass electrode, quinhydrone
electrode,
determination of pH of a solution
using the quinhydrone electrode
and glass
electrode, potentiometric titrations
(acid-base titrations, oxidation-
reduction
titrations and precipitation
titrations), related numericals.

Unit III: Chemical 10


Thermodynamics: Introduction,
enthalpy of a system, molar heat
capacities, relation between
Cp and Cv, Joule-Thomson effect,
concept of entropy, standard
entropy,
cocept of residual entropy,
Clapeyron equation, Clausius-
Clapeyron
equation, integrated form of
Clausius- Clapeyron equation,
applications of
Clausius-Clapeyron equation,
fugacity and activity, partial molar
properties,
chemical potential and its
significance, Gibb’s-Duhem
equation.
May Unit I: Theory of Dilute 10
Solutions:
Introduction, vapour pressure of a
liquid, Raoult’s law of vapour
pressure
colligative properties, lowering of
vapour pressure, relative lowering
of
vapour pressure, relation between
relative lowering of vapour
pressure and
molar mass of solute, elevation of
boiling point, relation between
elevation
of boiling point and molar mass of
solute, Landberger’s method for
the
determination of elevation of
boiling point, depression of
freezing point,
relation between depression of
freezing point and molar mass of
solute,
osmotic pressure, van’s Hoff
equation for osmotic pressure of a
solution,
determination of molar mass of a
solute from osmotic pressure
measurements, related numericals.

Signature: Signature:
Director/Head Name of Teacher: Dr. Vasim R. Shaikh

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