Thermodynamics DPP - 01

1. Which of the following is not a thermodynamic 11. Which of the following is an intensive property?
property of a system? (1) Volume (2) Free energy
(1) H (2) P (3) Entropy (4) Pressure
(3) E (4) w
12. Which is an irreversible process?
2. Out of internal energy (A), temperature (B), pressure (1) Mixing two gases by diffusion
(2) Evaporation of water at 373 K and 1 atm pressure
(C), volume (D), work (E) and enthalpy (F) state
(3) Solidification of water at 273 K and 1 atm pressure
functions are (4) All of these
(1) A, B, C, D, F (2) A, B, C, E, F
(3) A, E, F (4) A, C, E 13. If x and y are arbitrary extensive variable, then
(1) (x + y) is an intensive variable
3. Out of the following, state functions are x
(2) is intensive variable
(1) Entropy (2) Free energy y
(3) Internal energy (4) Enthalpy (3) (x – y) is intensive variable
(4) (x × y) is intensive variable
4. Which of the following is path function?
(1) Enthalpy (2) Heat 14. Entropy is a
(3) Entropy (4) Gibb’s free energy (1) State function and extensive property
(2) State function and intensive property
(3) Path function and extensive property
5. Which among the following is not state function?
(4) Path function and intensive property
(1) Internal energy (2) Free energy
(3) Enthalpy (4) Work 15. Which of the following is not an intensive property?
(1) Entropy (2) Pressure
6. Universe is considered as (3) Temperature (4) Molar volume
(1) Close system (2) Open system
(3) Isolated system (4) None of these 16. A system absorbs 20 kJ heat and does 10 kJ of work.
The internal energy of the system
7. Which of the following is not a state function? (1) Increases by 10 kJ
(1) Heat (2) Internal energy (2) Decreases by 10 kJ
(3) Enthalpy (4) Entropy (3) Increases by 30 kJ
(4) Decreases by 30 kJ
8. Which of the following is path function?
(1) Work 17. A system is provided 50 J of heat and work done on
(2) Gibbs free energy the system is 10 J. The change in internal energy
(3) Internal energy during the process is
(4) Enthalpy (1) 40 J (2) 60 J
(3) 80 J (4) 50 J
9. Out of internal energy (I), boiling point (II), pH (III)
18. The first law of thermodynamics is represented
and standard E.M.F. of the cell (IV) intensive
by the equation:
properties are
(1) E = Q + W (2) E = Q – W
(1) I, II (2) II, III, IV
(3) I, III, IV (4) All of these (3) E = Q (4) Q = W – E

10. Which of the following is/are extensive properties? 19. A system absorbs 60 J of heat and does work
(1) Entropy (2) Density equivalent to 300 J on its surroundings. The
(3) Enthalpy (4) Both (1) and (3) change in internal energy is
(1) 200 J (2) –240 J
(3) 400 J (4) 600 J
20. Which of the following is correct option for free 22. Temperature remains constant during the______
expansion of an ideal gas under adiabatic condition? process.
(1) q = 0, T < 0, w  0 (1) Isochoric (2) Isobaric
(2) q = 0, T  0, w = 0 (3) Isothermal (4) Adiabatic
(3) q  0, T = 0, w = 0
(4) q = 0, T = 0, w = 0 23. For the reaction
C3H8(g) + 502(g) → 3CO2(g) + 4H2O(l) at constant
21. E is always positive when temperature H – U
(1) System absorbs heat and work is done on it (1) + RT (2) – RT
(2) System emits heat and work is done on it
(3) + 3RT (4) – 3RT
(3) System emits heat and no work is done on it
(4) System absorbs heat and work is done by it
 Answer Key
1. (4) 13. (2)
2. (1) 14. (1)
3. (1, 2, 3, 4) 15. (1)
4. (2) 16. (1)
5. (4) 17. (2)
6. (3) 18. (1)
7. (1) 19. (2)
8. (1) 20. (4)
9. (2) 21. (1)
10. (4) 22. (3)
11. (4) 23. (4)
12. (1)