SAFETY DATA SHEET

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1. IDENTIFICATION
Product identifier
Product Name Sulfuric Acid Standard Solution 0.020N (N/50)

Other means of identification

Product Code(s) 20353

Safety data sheet number M00347

Recommended use of the chemical and restrictions on use

Recommended Use Water Analysis. Standard solution.
Uses advised against None.
Restrictions on use None.

Details of the supplier of the safety data sheet

Manufacturer Address
Hach Company, P.O.Box 389, Loveland, CO 80539, USA, +1(970) 669-3050

Emergency telephone number

+1(303) 623-5716 - 24 Hour Service

2. HAZARDS IDENTIFICATION
Classification

Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 1

Hazards not otherwise classified (HNOC)

Not applicable

Label elements

Signal word
Danger

Hazard statements
H318 - Causes serious eye damage

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Precautionary statements
P280 - Wear protective gloves, protective clothing, eye protection, and face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician

Other Hazards Known

None

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable

Mixture

Percent ranges are used where confidential product information is applicable.

Chemical name CAS No Percent HMRIC #

Range
Sulfuric acid 7664-93-9 <1% -
Formaldehyde 50-00-0 <0.1% -
Methanol 67-56-1 <0.1% -

4. FIRST AID MEASURES

Description of first aid measures

General advice Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Get immediate medical advice/attention. Rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area.

Skin contact Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical
attention if irritation develops and persists.

Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.

Self-protection of the first aider Avoid contact with skin, eyes or clothing.

Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.

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Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.

Specific hazards arising from the No information available.

chemical

Hazardous combustion products This material will not burn.

Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
fire-fighters Use personal protection equipment.

6. ACCIDENTAL RELEASE MEASURES

U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous
substances may respond to a spill according to federal regulations (OSHA 29 CFR
1910.120(a)(v)) and per your company's emergency response plan and
guidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside
of the US, only persons properly qualified according to state or local regulations should
respond to a spill involving chemicals.

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.

Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust). Take up mechanically, placing in appropriate containers for disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

Reference to other sections See section 8 for more information. See section 13 for more information.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.

Flammability class Not applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

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Exposure Guidelines

Chemical name ACGIH TLV OSHA PEL NIOSH

Sulfuric acid TWA: 0.2 mg/m3 thoracic TWA: 1 mg/m3 IDLH: 15 mg/m3
CAS#: 7664-93-9 particulate matter (vacated) TWA: 1 mg/m3 TWA: 1 mg/m3
Formaldehyde dermal sensitizer;respiratory TWA: 0.75 ppm IDLH: 20 ppm
CAS#: 50-00-0 sensitizer (vacated) TWA: 3 ppm Ceiling: 0.1 ppm 15 min
STEL: 0.3 ppm (vacated) STEL: 10 ppm TWA: 0.016 ppm
TWA: 0.1 ppm (vacated) Ceiling: 5 ppm
STEL: 2 ppm
Methanol STEL: 250 ppm TWA: 200 ppm IDLH: 6000 ppm
CAS#: 67-56-1 TWA: 200 ppm TWA: 260 mg/m3 TWA: 200 ppm
S* (vacated) TWA: 200 ppm TWA: 260 mg/m3
(vacated) TWA: 260 mg/m3 STEL: 250 ppm
(vacated) STEL: 250 ppm STEL: 325 mg/m3
(vacated) STEL: 325 mg/m3
(vacated) SKN*

Appropriate engineering controls

Engineering Controls Showers
Eyewash stations
Ventilation systems.

Individual protection measures, such as personal protective equipment

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required. Wear
breathing apparatus if exposed to vapors/dusts/aerosols.

Hand Protection Wear suitable gloves.

Eye/face protection Tight sealing safety goggles.

Skin and body protection Wear suitable protective clothing.

General Hygiene Considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product.

Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not allow
into any sewer, on the ground or into any body of water.

Thermal hazards None under normal processing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Liquid

Appearance aqueous solution Color colorless
Odor None Odor threshold No data available

Property Values Remarks • Method

Molecular weight No data available

pH 1.8 @ 20 °C

Melting point / freezing point ~ 0 °C / 32 °F

Initial boiling point and boiling range ~ 100 °C / 212 °F

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Evaporation rate 1 (water = 1)

Vapor pressure 23.777 mm Hg / 3.17 kPa at 25 °C / 77 °F

Relative vapor density 0.03

Specific Gravity 0.985

Partition coefficient Not applicable

Soil Organic Carbon-Water Partition Not applicable

Coefficient
Autoignition temperature No data available

Decomposition temperature No data available

Dynamic viscosity No data available

Kinematic viscosity No data available

Solubility(ies)

Water solubility

Water solubility classification Water solubility Water Solubility Temperature

Soluble > 1000 mg/L 25 °C / 77 °F

Solubility in other solvents

Chemical Name Solubility classification Solubility Solubility Temperature

Acid Soluble > 1000 mg/L 25 °C / 77 °F

Other information

Metal Corrosivity

Steel Corrosion Rate 0.87 mm/yr / 0.03 in/yr

Aluminum Corrosion Rate 1.02 mm/yr / 0.04 in/yr

Volatile Organic Compounds (VOC) Content

See ingredients information below

Chemical name CAS No Volatile organic compounds CAA (Clean Air Act)
(VOC) content
Sulfuric acid 7664-93-9 No data available -
Formaldehyde 50-00-0 No data available X
Methanol 67-56-1 100% X

Explosive properties

Upper explosion limit No data available

Lower explosion limit No data available

Flammable properties

Flash point No data available

Flammability Limit in Air

Upper flammability limit: No data available
Lower flammability limit: No data available

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Oxidizing properties No data available.

Bulk density No data available

10. STABILITY AND REACTIVITY

Reactivity
Not applicable.

Chemical stability
Stable under normal conditions.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

Possibility of hazardous reactions

None under normal processing.

Hazardous polymerization
None under normal processing.

Conditions to avoid
None known based on information supplied.

Incompatible materials
Strong acids. Strong bases. Strong oxidizing agents.

Hazardous decomposition products

Thermal decomposition can lead to release of irritating and toxic gases and vapors.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation No known effect based on information supplied.

Eye contact Severely irritating to eyes. Causes serious eye damage. May cause burns. May cause
irreversible damage to eyes.

Skin contact May cause irritation.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Symptoms Redness. Burning. May cause blindness.

Acute toxicity
Based on available data, the classification criteria are not met

Mixture
No data available.

Ingredient Acute Toxicity Data

Test data reported below.

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Oral Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Rat 100 mg/kg None reported None reported GESTIS
(<0.1%) LD50
CAS#: 50-00-0

Dermal Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Rabbit 270 mg/kg None reported None reported GESTIS
(<0.1%) LD50
CAS#: 50-00-0

Inhalation (Dust/Mist) Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Rat 0.578 mg/L 4 hours None reported LOLI
(<0.1%) LC50
CAS#: 50-00-0

Inhalation (Vapor) Exposure Route

Unknown Acute Toxicity

0% of the mixture consists of ingredient(s) of unknown toxicity.

Acute Toxicity Estimations (ATE)

ATEmix (oral) No information available

ATEmix (dermal) No information available
ATEmix (inhalation-dust/mist) No information available
ATEmix (inhalation-vapor) No information available
ATEmix (inhalation-gas) No information available

Skin corrosion/irritation
Based on available data, the classification criteria are not met.

Mixture
No data available.

Ingredient Skin Corrosion/Irritation Data

Test data reported below.

Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Sulfuric acid Existing human Human None reported None reported Corrosive to skin HSDB
(<1%) experience
CAS#: 7664-93-9
Formaldehyde Standard Draize Human 0.150 mg 72 hours Corrosive to skin RTECS
(<0.1%) Test
CAS#: 50-00-0
Methanol OECD Test 439: In Rabbit None reported 20 hours Not corrosive or ECHA
(<0.1%) Vitro Skin Irritation: irritating to skin
CAS#: 67-56-1 Reconstructed
Human Epidermis

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(Rhe) Test Method

Serious eye damage/irritation

Classification based on data available for ingredients. Causes burns. Risk of serious damage to eyes.

Mixture
No data available.

Ingredient Eye Damage/Eye Irritation Data

Test data reported below.

Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Sulfuric acid Existing human Human None reported None reported Corrosive to eyes HSDB
(<1%) experience
CAS#: 7664-93-9
Formaldehyde Rinse Test Human 1 ppm 6 minutes Corrosive to eyes RTECS
(<0.1%)
CAS#: 50-00-0
Methanol OECD Test 439: In Rabbit 0.05 mL 24 hours Not corrosive or ECHA
(<0.1%) Vitro Skin Irritation: irritating to eyes
CAS#: 67-56-1 Reconstructed
Human Epidermis
(Rhe) Test Method

Respiratory or skin sensitization

Based on available data, the classification criteria are not met.

Mixture
No data available.

Ingredient Sensitization Data

Test data reported below.

Skin Sensitization Exposure Route

Chemical name Test method Species Results Key literature references and
sources for data
Formaldehyde Patch test Human Confirmed to be a skin sensitizer ERMA
(<0.1%)
CAS#: 50-00-0
Methanol OECD Test No. Guinea pig Not confirmed to be a skin sensitizer ECHA
(<0.1%) 406: Skin
CAS#: 67-56-1 Sensitization

Respiratory Sensitization Exposure Route

Chemical name Test method Species Results Key literature references and
sources for data
Formaldehyde IgE Specific Guinea pig Confirmed to be a respiratory CICAD
(<0.1%) Immune Response sensitizer
CAS#: 50-00-0 Test

STOT - single exposure

Based on available data, the classification criteria are not met.

Mixture
No data available.

Ingredient Specific Target Organ Toxicity Single Exposure Data

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Test data reported below.

Oral Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Human 70 mg/kg None reported Gastrointestinal RTECS
(<0.1%) LDLo Kidney, Ureter, or Bladder
CAS#: 50-00-0 Liver
Other changes
Ulcerated stomach
Other changes
Methanol Human 143 mg/kg None reported Lungs, Thorax, or RTECS
(<0.1%) LDLo Respiration
CAS#: 67-56-1 Dyspnea

Inhalation (Vapor) Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Sulfuric acid Human 0.144 mg/L 5 minutes Lungs, Thorax, or RTECS
(<1%) TDLo Respiration
CAS#: 7664-93-9 Dyspnea
Methanol Human 300 mg/L None reported Lungs, Thorax, or RTECS
(<0.1%) TCLo Respiration
CAS#: 67-56-1 Other changes

STOT - repeated exposure

Based on available data, the classification criteria are not met.

Mixture
No data available.

Ingredient Specific Target Organ Toxicity Repeat Exposure Data

Test data reported below.

Oral Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Methanol Monkey 2340 mg/kg 3 days None reported ECHA
(<0.1%)
CAS#: 67-56-1

Inhalation (Vapor) Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Sulfuric acid Human 0.003 mg/L 168 days Musculoskeletal RTECS
(<1%) TCLo Changes in teeth and supporting
CAS#: 7664-93-9 structures
Formaldehyde Human 0.017 mg/L 0.5 days Eye RTECS
(<0.1%) TCLo Lungs, Thorax, or
CAS#: 50-00-0 Respiration
Lacrimation
Other changes

Carcinogenicity
Based on available data, the classification criteria are not met.

Mixture

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No data available.

Ingredient Carcinogenicity Data

Test data reported below.

Chemical name CAS No ACGIH IARC NTP OSHA

Sulfuric acid 7664-93-9 A2 Group 1 Known X
Formaldehyde 50-00-0 A1 Group 1 Known X
Methanol 67-56-1 - - - -

Legend

ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen

IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program) Known - Known Carcinogen
OSHA X - Present

Inhalation (Vapor) Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Formaldehyde Rat 15 mg/L 78 weeks Olfaction RTECS
(<0.1%) Tumors
CAS#: 50-00-0

Germ cell mutagenicity

Based on available data, the classification criteria are not met.

Mixture invitro Data

No data available.

Substance invitro Data

Test data reported below.

Chemical name Test Cell Strain Reported Exposure Results Key literature
dose time references and
sources for data
Sulfuric acid Cytogenetic Hamster ovary 4 mmol/L None reported Positive test result for No information
(<1%) analysis mutagenicity available
CAS#: 7664-93-9
Methanol DNA inhibition Human lymphocyte 300 mmol/L None reported Positive test result for RTECS
(<0.1%) mutagenicity
CAS#: 67-56-1

Mixture invivo Data

No data available.

Substance invivo Data

Test data reported below.

Oral Exposure Route

Chemical name Test Species Reported Exposure Results Key literature

dose time references and
sources for data
Methanol DNA damage Rat 0.405 mg/kg None reported Positive test result for RTECS
(<0.1%) mutagenicity
CAS#: 67-56-1

Inhalation (Vapor) Exposure Route

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Chemical name Test Species Reported Exposure Results Key literature

dose time references and
sources for data
Formaldehyde Micronucleus test Human .000985 mg/L 8.5 years Positive test result for RTECS
(<0.1%) mutagenicity
CAS#: 50-00-0

Reproductive toxicity
Based on available data, the classification criteria are not met.

Mixture
No data available.

Ingredient Reproductive Toxicity Data

Test data reported below.

Oral Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Methanol Rat 4118 mg/kg 10 days Effects on Embryo or Fetus RTECS
(<0.1%) TDLo Specific Developmental
CAS#: 67-56-1 Abnormalities
Ear
Eye
Fetotoxicity (except death e.g.
stunted fetus)
Urogenital System

Inhalation (Dust/Mist) Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Methanol Rat 0.0026 mg/L 22 days Effects on Embryo or Fetus RTECS
(<0.1%) TCLo Fetotoxicity (except death e.g.
CAS#: 67-56-1 stunted fetus)

Inhalation (Vapor) Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Sulfuric acid Rabbit 0.02 mg/L 7 hours Specific Developmental No information available
(<1%) TCLo Abnormalities
CAS#: 7664-93-9 Musculoskeletal system
Formaldehyde Rat 40 mg/L 14 days Effects on Embryo or Fetus RTECS
(<0.1%) TCLo Fetotoxicity (except death e.g.
CAS#: 50-00-0 stunted fetus)

Aspiration hazard
Based on available data, the classification criteria are not met.

12. ECOLOGICAL INFORMATION

Ecotoxicity Based on available data, the classification criteria are not met.

Unknown aquatic toxicity 0% of the mixture consists of components(s) of unknown hazards to the aquatic
environment.

Mixture

Aquatic Acute Toxicity

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No data available.

Aquatic Chronic Toxicity

No data available.

Substance

Aquatic Acute Toxicity

Test data reported below.

Fish

Chemical name Exposure Species Endpoint Reported dose Key literature references and
time type sources for data
Formaldehyde 96 hours Morone saxatilis LC50 6.7 mg/L PEEN
(<0.1%)
CAS#: 50-00-0

Crustacea

Chemical name Exposure Species Endpoint Reported dose Key literature references and
time type sources for data
Formaldehyde 48 Hours Daphnia pulex EC50 5.8 mg/L PEEN
(<0.1%)
CAS#: 50-00-0

Aquatic Chronic Toxicity

No data available.

Persistence and degradability

Mixture
No data available.

Bioaccumulation
There is no data for this product
Mixture
No data available.

Partition coefficient Not applicable

Mobility

Soil Organic Carbon-Water Partition Coefficient Not applicable

Other adverse effects

No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.

Contaminated packaging Do not reuse empty containers.

US EPA Waste Number D002, U154 U122

Chemical name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes

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Formaldehyde U122 Included in waste - U122

50-00-0 streams: K009, K010,
K038, K040, K156, K157
Methanol - Included in waste stream: - U154
67-56-1 F039

Special instructions for disposal If permitted by regulation. Dilute to 3 to 5 times the volume with cold water. Adjust to a pH
between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water
tap completely, slowly pour the reacted material to the drain. Flush system with plenty of
water. Dispose of material in an E.P.A. approved hazardous waste facility.

14. TRANSPORT INFORMATION

DOT Not regulated

TDG Not regulated

IATA Not regulated

IMDG Not regulated

Note: No special precautions necessary.

Additional information

15. REGULATORY INFORMATION

National Inventories
TSCA Complies
DSL/NDSL Complies

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

International Inventories
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL - Existing substances Complies
PICCS Complies
TCSI Complies
AICS Complies
NZIoC Complies

EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

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Chemical name SARA 313 - Threshold Values %

Sulfuric acid (CAS #: 7664-93-9) 1.0
Formaldehyde (CAS #: 50-00-0) 0.1
Methanol (CAS #: 67-56-1) 1.0
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

Chemical name CWA - Reportable CWA - Toxic Pollutants CWA - Priority CWA - Hazardous
Quantities Pollutants Substances
Sulfuric acid 1000 lb - - X
7664-93-9
Formaldehyde 100 lb - - X
50-00-0
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material

Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

Sulfuric acid 1000 lb 1000 lb RQ 1000 lb final RQ
7664-93-9 RQ 454 kg final RQ
Formaldehyde 100 lb 100 lb RQ 100 lb final RQ
50-00-0 RQ 45.4 kg final RQ
Methanol 5000 lb - RQ 5000 lb final RQ
67-56-1 RQ 2270 kg final RQ
U.S. - Department of Homeland Security - Chemical Facility Anti-Terrorism Standards (CFATS) - Security Issues

Chemical name U.S. - Department of Homeland Security - Chemical Facility

Anti-Terrorism Standards (CFATS) - Security Issues
Formaldehyde Release - Toxic (solution)
(<0.1%)
CAS#: 50-00-0

U.S. - DEA (Drug Enforcement Administration) List I & List II

Chemical name U.S. - DEA (Drug Enforcement U.S. - DEA (Drug Enforcement
Administration) - List I or Precursor Administration) - List II or Essential
Chemicals Chemicals
Sulfuric acid Not Listed 50 gallon Export Volume (exports,
(<1%) transshipments and international
CAS#: 7664-93-9 transactions to designated countries
given in 1310.08(b))

US State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals

Chemical name California Proposition 65

Sulfuric acid (CAS #: 7664-93-9) Carcinogen

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Formaldehyde (CAS #: 50-00-0) Carcinogen

Methanol (CAS #: 67-56-1) Developmental

WARNING: This product can expose you to chemicals including Formaldehyde, Methanol, Sulfuric acid, which are known
to the State of California to cause cancer or birth defects or reproductive harm.
For more information, go to http://www.P65Warnings.ca.gov

U.S. State Right-to-Know Regulations

This product may contain substances regulated by state right-to-know regulations.

Chemical name New Jersey Massachusetts Pennsylvania

Sulfuric acid X X X
7664-93-9
Formaldehyde X X X
50-00-0
Methanol X X X
67-56-1

U.S. EPA Label Information

Chemical name FIFRA FDA

Sulfuric acid 180.0910 21 CFR 184.1095
Methanol 180.0910 -

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

Special Comments
None

Additional information

Global Automotive Declarable Substance List (GADSL)

Chemical name Global Automotive Declarable Global Automotive Declarable

Substance List Classifications Substance List Thersholds
Formaldehyde Declarable Substance (LR) 0.1 %
50-00-0 Prohibited Substance (LR)
Prohibited Substance (FI)
Declarable Substance (FI)
Methanol Declarable Substance (FI) 0.6 %
67-56-1 Declarable Substance (LR)
Prohibited Substance (FI)
Prohibited Substance (LR)

NFPA and HMIS Classifications

NFPA Health hazards - 3 Flammability - 0 Instability - 0 Physical and chemical

properties -
HMIS Health hazards - 3 Flammability - 0 Physical hazards - 0 Personal protection -
X
-I

Key or legend to abbreviations and acronyms used in the safety data sheet

EN / AGHS Page 15 / 17
Product Code(s) 20353 Product Name Sulfuric Acid Standard Solution 0.020N (N/50)
Issue Date 17-Jun-2021 Revision Date 08-Feb-2023
Version 3.7 Page 16 / 17

ACGIH ACGIH (American Conference of Governmental Industrial Hygienists)

ATSDR ATSDR (Agency for Toxic Substances and Disease Registry)
CCRIS CCRIS (Chemical Carcinogenesis Research Information System)
CDC CDC (Center for Disease Control)
CEPA CEPA (Canadian Environmental Protection Agency)
CICAD CICAD (Concise International Chemical Assessment Documents)
ECHA ECHA (The European Chemicals Agency)
EEA EEA (European Environment Agency)
EPA EPA (Environmental Protection Agency)
ERMA ERMA (New Zealands Environmental Risk Management Authority)
ECOSARS Estimation through ECOSARS v1.11 part of the Estimation Programs Interface (EPI) SuiteÔ
FDA FDA (Food & Drug Administration)
GESTIS GESTIS (Information System on Hazardous Substances of the German Social Accident
Insurance)
HSDB HSDB (Hazardous Substances Data Bank)
INERIS INERIS (The National Industrial Environment and Risks Institute)
IPCS INCHEM IPCS INCHEM (International Programme on Chemical Safety)
IUCLID IUCLID (The International Uniform Chemical Information Database)
NITE Japan National Institute of Technology and Evaluation (NITE)
NIH NIH (National Institutes of Health)
NIOSH NIOSH (National Institute for Occupational Safety and Health)
LOLI LOLI (List of Lists - An International Chemical Regulatory Database)
NDF no data
NICNAS Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
NIOSH IDLH Immediately Dangerous to Life or Health
OSHA OSHA (Occupational Safety and Health Administration of the US Department of Labor)
PEEN PEEN (Pan European Ecological Network)
RTECS RTECS (Registry of Toxic Effects of Chemical Substances)
SIDS SIDS (Screening Information Dataset) for High Volume Chemicals
SYKE The Finnish Environment Institute (SYKE)
USDA USDA (United States Department of Agriculture)
USDC USDC (United States Department of Commerce)
WHO WHO (World Health Organization)

Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)

MAC Maximum Allowable Concentration Ceiling Ceiling Limit Value

X Listed Vacated These values have no official status. The only

binding levels of contaminants are those listed
in the final OSHA PEL. These lists are for
reference purposes only. Please note that
some reference state regulations of these
"liberated" exposure limits in their state
regulations.

SKN* Skin designation SKN+ Skin sensitization

RSP+ Respiratory sensitization ** Hazard Designation
C Carcinogen R Reproductive toxicant
M mutagen

Prepared By Hach Product Compliance Department

Issue Date 17-Jun-2021

Revision Date 08-Feb-2023

Revision Note None

Disclaimer

EN / AGHS Page 16 / 17
Product Code(s) 20353 Product Name Sulfuric Acid Standard Solution 0.020N (N/50)
Issue Date 17-Jun-2021 Revision Date 08-Feb-2023
Version 3.7 Page 17 / 17

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO

WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF.

Ó2022
HACH COMPANYÓ

End of Safety Data Sheet

EN / AGHS Page 17 / 17