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GOC Short Notes

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513 views13 pages

GOC Short Notes

Uploaded by

samsung.galaxy.tab.345c
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© © All Rights Reserved
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mad. -y- Viel cor NU itome ia OG Substrate —““°9°""_., tintermediate] —— Product + byproducts c,c-, Cc" See ae ote Cats tnt: Peete a CE Caer ae ey Lie OTC Coen tet es Cit) S nea PENS aac) ane ca bh CT ee ae eerie Lary Pee eee TT) DO Ae ae alain eg - CHs-, X-, RO-, H20, NHs PRC ONE S “7 aay ra ~ Electron displacement effects: ioe arn ROM rts ae 3) Hyperconjugation INDUCTIVE EFFECT eee ee Ce aCe Ce Cee Eee lll] etic eA Le) Bee tle) rere rad 555-555 5+ 555-555 ofter the 3rd C atom ol eo eal Ce ee estima Le} Ce et rl eae) ORES En ee) ern Ecol Eel (eel) oe el En Led Eo onto ey Cnt a eet Ramee cee Ee Eee Ee eo oe Applications of Inductive effect RCRA TORT ae hs ceed oe eee t ‘ io D t stability +1 & 1/-1 stability -1 & 1/+1 stability -1 & 1/+1 Cee ee ae rd 2) To compare acidic strength of aliphatic alcohols & carboxylic acids i u ee oe ea) TTI tert ee eco rr iy Ca maa) Lie Cal awe es MX Po Oe ea ee Pe ES yo eae Se IR oa siweey ONCHY PERCONJUGATION delocalisation of e- from filled BMO to adjacent empty orbital PTC ee La ak Ak CMa ene oe alkenes: o - 1* a t ri ri] e a - Hi : ka cl i 4 cy H a carbocation: o-p c 4 rT + Pp fi a al cf tf w Cary re ee) Bee oot hte cl or cl cl ar + 7 A i a a al cl cl cl cl cl er Applications of hyperconjugation ROR LI Tone Cn CLR Gr hs stability < no. of HCS = no. of a-H Ce aa eC ras 2) To compare heat of hydrogenation of alkenes eG eT ae Cee ood Cees Don ) ) . Br, a a a ‘: aa TON 5, 5, an aN F) 3 RESONANCE PCr Ce ee er e-O-CG—G. Po Ua ety resonance hybrid Dro POR ec ae Ue tt Rea RCI a ed UR ecard roth Oe Oe LT CSC A Rue ie eee ed eee OLE ete) ew eee) ee eee ee Re ene E eee Seen ee eee ee et Pe ee ee tes Pet et ee ee et) SoC eee CUT Ree to eto tt) 4) stability < /opp. charge seperation o io AA . pe OC ee RCE tic a aa ‘MESOMERIC EFFECT Ua | Ue ee ee eC a eee alts Sati te ele) Se siaee- Bae PR ee eer) Re tts eee etter) ETT Ph eR ol [too Rotel ee Le Lo} Cerny i Stren Draco DCR ea a oa oe ue Oey Oe eee én cHo ene taaae ens ea oe cee : J withdrawing pores : Ss Iya ee eae Caer DRO Orc ioecrur i Curericr cc uniee ari ei ett ° ce) Uy ao Ps a aa - = See = . O = © a en O = O f Lae eeu Ue ree rae eee iJ os (a ACIDIC STRENGTH Oe On eae curl is Sa cr cer cary csr) cr ToT) ors S > - < coe a ac me na nf or Cory - 3 7 ‘ Perie om con " Penn Seo CTC (0 Portail Basic strength of nitrogenous bases: a? " , PRET a ee ein RES MTA RT ' ' eer COC nL ae Ortho effect in aromatic amines: a a ce Ce eo ee c due to Steric inhibition in a AROMATICITY Huckle’s Rule for Aromaticity: 1) Aromatic - ring + planar + cont. conjugation + (4n+2)Te- 2) Anti aromatic - ring + planar + cont. conjugation + (4n)Te- OR Lee ee ee im @) bearded Boa eo ed [6]-annulene —_[8]-annulene Be aniits Peri Pecans anon, aromatic PO Ir eT lea ear V AROMATICITY folie tdi sa Re SCR UCR Cet iacuts ore} a + aro y ao aro eee) mere a) >) o Ta rae ee ee le lla) on OH, ie a q <2 ee ea) a) 2] i) SIMPLY CONCISE CARBOCATIONS Selita 1) BB> Aro>M>HC>1 rT a rd Pc iiag = a et +HC ees Syren i i ERT " " SO CIEE ay aes Sees foMeet eis] iis a 3 J (@) oes oO (SECs ORCI EOE 28 ee on Pl eur teeta seater) ils y D 2) Ring Expansion - reduces strain & increase stability awene) Q. Which of the following will not rearrange: S Y © means CARBANIONS Stability: eee ee Pea ator] ola ail H-G2cl H-c=el aa i i vars) " " UNCUT eT aa Saar) Q. Compare stabil Ee) Coon FREE RADICALS PSS TT ta Reale) Pcs ee Reo ca 1 av 3) hybridisation : sp? > sp? > sp

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