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6. The molarity of the solution prepared by
CONCENTRATION TERMS
dissolving 6.3 g of oxalic acid (H2C2O4.2H2O)
1. A 6.50 molal solution of KOH (aq.) has a
in 250 mL of water in mol
density of 1.89 g cm–3. The molarity of the
solution is ________ mol dm–3. (Round off to L–1 is x × 10–2. The value of x is ________.
the Nearest Integer). (Nearest integer)
[Atomic masses: K :39.0 u; O :16.0 u; H :1.0 u] [Atomic mass : H : 1.0, C : 12.0, O : 16.0]
2. When 35 mL of 0.15 M lead nitrate solution is
7. Sodium oxide reacts with water to produce
mixed with 20 mL of 0.12 M chromic sulphate
sodium hydroxide. 20.0 g of sodium oxide is
solution, ________ × 10–5 moles of lead
dissolved in 500 mL of water. Neglecting the
sulphate precipitate out. (Round off to the
change in volume, the concentration of the
Nearest Integer).
resulting NaOH solution is ________ ×10–1 M.
3. The mole fraction of a solute in a 100 molal
aqueous solution _______ × 10–2. (Nearest integer)
(Round off to the Nearest Integer). [Atomic mass : Na = 23.0, O = 16.0, H = 1.0]
[Given : Atomic masses : H : 1.0 u, O : 16.0 u]
4. An aqueous KCl solution of density 1.20 g mL–1 8. If 80 g of copper sulphate CuSO4·5H2O is
dissolved in deionised water to make 5 L of
has a molality of 3.30 mol kg–1. The molarity of
solution. The concentration of the copper
the solution in mol L–1 is ________ (Nearest
sulphate solution is x × 10–3 mol L–1. The value
integer) of x is _________.

[Molar mass of KCl = 74.5] [Atomic masses Cu : 63.54 u, S : 32 u, O : 16 u,

H : 1 u]
5. 100 mL of Na3PO4 solution contains 3.45 g of
sodium. The molarity of the solution is
_____×10–2 mol L–1 . (Nearest integer)
[Atomic Masses-Na : 23.0 u, O : 16.0 u, P : 31.0
u]

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SOLUTION 1245.85
Volume of solution = ml
1. Official Ans. by NTA (9) 1.2
Sol. 6.5 molal KOH = 1000gm solvent has 3.3  1.2
So molarity =  1000  3.17
6.5 moles KOH 1245.85
5. Official Ans. by NTA (50)
so wt of solute = 6.5 × 56
= 364 gm Na3PO4 Na3PO4 3Na
Sol.
wt of solution = 1000 + 364 = 1364 3.45g
1364
Volume of solution = m 100ml Sol.
1.89
moleof solute therefore molarity of Na3PO4 Solution =
Molarity =
Vsolution in Litre n Na3 PO4
6.5  1.89  1000 volume of solution in L

1364 1 3.45
 mol
= 9.00  3 23
2. Official Ans. by NTA (525) 0.1L
Sol. 3 Pb (NO3)2 + Cr2 (SO4)3  3PbSO4 + 2Cr(NO3)3 = 0.5 = 50 × 10–2
35 ml 20 ml 6. Official Ans. by NTA (20)
0.15 M 0.12 M weight/M W
Sol. [H2C2O4.2H2O] =
VL
= 5.25 m.mol = 2.4 m.mol 5.25 m.mol
–3
= 5.25 × 10 mol 6.3 / 126
x × 10–2 =
–3 250 / 1000
therefore moles of PbSO4 formed = 5.25 × 10
x = 20
–5
= 525 × 10 7. Official Ans. by NTA (13)
3. Official Ans. by NTA (64) Sol. Na2O + H2O  2NaOH
Sol. 100 molal aqueous solution means there is 20
moles
62
100 mole solute in 1 kg = 1000 gm water.
20
Now, Moles of NaOH formed = 2
62
n solute 40
mole-fraction of solute =
n solute  n solvent [NaOH]  62  1.29 M = 13 × 10–1 M
500
100 1800 1000
=   0.6428 (Nearest integer)
1000 2800
100  8. Official Ans. by NTA (64)
18
–2 80
= 64.28 × 10 Sol. Moles of CuSO4·5H2O =
249.54
4. Official Ans. by NTA (3) 80
Sol. 1000 kg solvent has 3.3 moles of KCl Molarity = = 64.117 × 10–3
249.54
1000 kg solvent 3.3 × 74.5 gm KCl 5
 245.85 Nearest integer, x = 64
Weight of solution = 1245.85 gm