Tenthclass-Newsyllabus-Studymaterial-Chemistryem-Classification - of - Elements - 9
Tenthclass-Newsyllabus-Studymaterial-Chemistryem-Classification - of - Elements - 9
com
Chapter -9
SYNOPSIS
From the earliest times, scientists have been trying to classify the available elements
on the basis of their properties.
In modern periodic table eighteen groups and seven periods. There are ‘s’ block, ‘p’ block,
‘d’ block and ‘f’ block elements.
www.sakshieducation.com
www.sakshieducation.com
Atomic radius, Ionization energy, electron affinity, Electro negativity are the main
characteristic of the enlacements both in groups and periods
2Mark Questions
2. s - block and p - block elements except 18th group elements are sometimes called
as ‘Representative elements’ based on their abundant availability in the nature.
Is it justified? Why?
A. s - block and p - block elements except 18th group elements are called ‘Representative
elements’.
All these elements have incomplete shells. So they are chemically reactive to
obtain stable electronic configuration of noble gases ns2np6.
www.sakshieducation.com
www.sakshieducation.com
ii. Across a period, from left to right, metallic character decreases. i.e., non-metallic
character increases.
A.
www.sakshieducation.com
www.sakshieducation.com
a) X = 2
b) Y = 2, 6
c) Z = 2, 8, 2
iii) Element ‘X’ belongs to 18th group, because its 1st shell completely filled with
electrons.
6. Identify the element that has the largest atomic radius in each pair of the
following and mark it with a symbol (9). (AS1)
www.sakshieducation.com
www.sakshieducation.com
A.
www.sakshieducation.com
www.sakshieducation.com
8. Identify the element that has the lower Ionization energy in each pair of the
following and mark it with a symbol (9).
(i) Mg or Na
(ii) Li or O
(iii) Br or F
(iv) K or Br
A. i) Mg (or) Na ⎯ Na (9)
9. Why was the basis of classification of elements changed from the atomic mass to
the atomic number?
A. i) The properties of elements depends upon the number of electrons present in the
valence shell which are related to atomic number.
ii) Thus the properties of different elements can be compared if we know their atomic
numbers.
iii) On the other hand, atomic mass can in no way determine the chemical properties
of elements, because it does not vary regularly with gradation in the chemical
properties of elements.
iv) So, the basis, of the classification of elements changed from atomic mass to the
atomic number.
www.sakshieducation.com
www.sakshieducation.com
10. On the basis of atomic numbers predict to which block the elements with atomic
number 9, 37, 46 and 64 belongs to?
A. The elements with atomic number a, belong to group 17 (VIIA). So, it belongs to p-
block.
The element with atomic number 37, belongs to Group 1(IA). So, it belongs to s-
block.
The elements with atomic number 46, belongs to Group10 (vIIB). So, it belongs to d-
block.
The elements with atomic number 64, belongs to Lanthanides. So, it belongs to f-
block.
11. An element X belongs to 3rd period and group 2 of the periodic table. State
b) The valency
So, it is a metal.
12. An element has atomic number 19. Where would you expect this element in the
periodic table and why?
www.sakshieducation.com
www.sakshieducation.com
So, the differentiating electron enters into 4th shell. So, the element belongs to 4th
period. So the element belongs to 4th period.
∴The element with atomic number 19 belongs to 4th period and I group.
13. Collect the information about reactivity of VIII A group elements (noble gases)
from internet or from your school library and prepare a report on their special
character when compared to other elements of periodic table.
A. The VIIIA group elements are chemically inactive. All of them have stable “octet” in
their valence shells except helium the nobel gases have high ionization energy and
zero electron affinity values. Consequence to this loosing or gaining an electron or
sharing of electrons is difficult.
But some compounds of these gases have been prepared under suitable conditions.
Xenon (Xe) shows a tendency to lose an electron and exist in a positive oxidation
state. Therefore it reacts with highly electronegative elements like F2 & O2 only .
ii) Its properties resemble with both Alkali metals (IA) and halogens (VIIIA) because
it can loose one electron like alkali metals as well as gain one electron as halogens
iii) So, it is placed at the top of both alkali metals and halogens.
15. How do you appreciate the role of electronic configuration of the atoms of
elements in periodic classification?
A. According to modern periodic law, the properties of elements are the periodic function
of their atomic number or electronic configuration.
www.sakshieducation.com
www.sakshieducation.com
So, the classification of elements have done basing on electronic configuration. The
electronic having same outer shell electronic configuration are kept in the same group.
The elements have same chemical properties.
So, I appreciate the role of electronic configuration of the atoms of element which
plays a key role in the process of classification of elements.
1 Mark Questions
1. Name two elements that you would expect to have chemical properties similar to
Mg. What is the basis for your choice?
A. Calcium (Ca) and strontium (Sr) are the two elements, which are similar to Mg in
chemical properties.
Because, they belong to the same group IIA. All the elements which are in the
same group have same electronic configuration and same chemical properties.
2. Using the periodic table, predict the formula of compound formed between and
element X of group 13 and another element Y of group 16.
Valency of X is 13 Valency = 18 – 16 = 2
(X2 Y3)
www.sakshieducation.com
www.sakshieducation.com
A. The Physical and chemical Properties of the elements are the periodic functions of
their Electronic Configurations of the atoms.
5. How does the valency vary in a period on going from left to right?
A. The valency starts from a and increases upto 4 and then decreases to get o, while
mulling from left to right.
A. Dobereiner stated that when elements with similar properties are taken
three at a time and arranged in the ascending order of their atomic weights,
the atomic weight of the middle element is the average of the atomic
A. i) 4f elements from 58Ce to 11Lu posses almost the same properties as 57 la. So they
were called as Lanthanoids.
ii) 5f elements from 90Th to 103Lr posses almost the same properties as 89Ac. So they
were called as Actinoids.
www.sakshieducation.com
www.sakshieducation.com
4 Mark Questions
1. Newlands proposed the law of octaves. Mendeleeff suggested eight groups for
elements in his table. How do you explain these observations in terms of modern
periodic classification?
A. Newlands proposed the law of octaves. According to newlads law of octaves, every
eighth elements starting from a given one be a repetition of the first with regard to its
properties.
Mendeleeff suggested eight groups for elements in his table. The elements in the same
group have same properties that means every eighth element starting from a given
element have same property with that.
In terms of modern concept, after completion of one shell. The properties of elements
are repeated. After completion of one shell of the properties of elements are repeated.
So, Newlands law of octaves and Mendeleeff’s suggestion of eight groups for
elements are also reliable according to modern concepts.
2. What are the limitations of Mendeleeff’s periodic table? How could the modern
periodic table overcome the limitations of Mendeleeff’s table?
www.sakshieducation.com
www.sakshieducation.com
Eg: Li, Na, K of IA group have little resemblance with Cu, Ag, Au of IB group.
4) Some similar elements are separated: Some similar elements like ‘copper and
mercury’ ‘Silicon and thallium’, etc, are placed in different groups of periodic table.
5) Position of Isotopes: Isotopes of elements are placed in the same position in the
table. Modern periodic table removes various anomalous of Mendeleeff’s table in the
following way:
3. Define modern periodic law. Discuss the construction of the long of the periodic
table.
Modern periodic law: The Physical and chemical Properties of the elements are the
periodic functions of their Electronic Configurations.
i) The modern periodic table has eighteen vertical columns known as groups and
seven horizontal rows known as periods.
ii) Elements are arranged in the order of increasing atomic numbers in periods.
iii) In groups the elements are placed having similar electronic configuration a
having similar number of electrons in their outermost shells.
www.sakshieducation.com
www.sakshieducation.com
s-block elements: The elements with valence shell electronic configuration ns1 and
sn2 are called s-block elements.
p-block elements: The elements with valence shell electronic configuration ns2np6
are called p-block elements.
d-block elements: The elements with valence shell configuration ns2np6(n- 1)d1 to
ns2np6(n-1)d10 are called d-block elements. These are also called as Transition
elements.
f-block elements: The elements in which orbitals are being filled in their atoms are
called f-block elements. These elements are also called as inner transition elements.
Inert gases:
The elements with complete outermost shell configuration (ns2np6) are known
as inert gases. He, Ne, Ar, Kr, Xe and radon do not react with any other elements. So
these are called inert gases.
www.sakshieducation.com
www.sakshieducation.com
4.Explain how the elements are classified into s, p, d and f block elements in the
periodic table and give the advantages of this kind of classification.
A. Depending on the valency shell electronic configuration elements are classified into s,
p, d and f block
s-block elements: The elements with valence shell electronic configuration ns1 and
sn2 are called s-block elements.
p-block elements: The elements with valence shell electronic configuration ns2np1-6
are called p-block elements. s and p block elements are known as representative
elements.
d-block elements: The elements with valence shell electronic configuration ns2(n-
1)d1-10 are called d-block elements.
f-block elements: The elements in which f-block are being filled in their atoms are
called f-block elements. These are known as Inner Transition elements.
Advantage:
The division of elements into blocks is useful to divide the elements into groups.
Every group has the elements with same valence electronic configuration. So they
have similar chemical properties
www.sakshieducation.com
www.sakshieducation.com
A.1s2 2s2
A. 1) A and D elements belongs to same period, since their outmost shell is same (II
period)
C and D elements belongs to same period, since their outermost shell is same
(III period)
2) Element A,B belongs to same group because of their similar outermost electronic
configuration.
3) Element D is the Noble gas due to its completely filled electronic configuration in
its outermost orbit.
4) The element the C - 1s2 2s2 2p6 3s2 3p3 belongs to III period & 15th group (VA)
6. Write down the characteristics of the elements having atomic number 17.
7. a) State the number of valence electrons, the group number and the period
number of each element given in the following table:
Aluminum
b) State whether the following elements belong to a Group (G), Period (P) or
Neither Group nor Period (N).
Elements G/P/N
Li,C,O
Mg, Ca, Ba
Br, Cl, F
C,S, Br
Al, Si, Cl
www.sakshieducation.com
www.sakshieducation.com
Li, Na, k
C,N,O
K, Ca, Br.
A. a)
b)
Elements G/P/N
Li,C,O D
Mg, Ca, Ba G
Br, Cl, F G
C,S, Br N
Al, Si, Cl P
www.sakshieducation.com
www.sakshieducation.com
Li, Na, k G
C,N,O P
K, Ca, Br. P
A. i) In a period, nuclear charge increases from left to right so, Y has low nuclear than X.
ii) In a period, atomic radius decreases from left to right so, X has low atomic radius
than Y.
iii) In a period, ionization energy increases from left to right so, X has high
ionization energy than Y.
iv) In a period, electro negativity increases from left to right so, X has high electro
v) In a period, metallic character decreases from left to right so, Y has more metallic
character than X.
www.sakshieducation.com
www.sakshieducation.com
(b) Explain the ionization energy order in the following sets of elements:
a) Na, Al, Cl
b) Li, Be, B
c) C, N, O
d) F, Ne, Na
a) Atomic radius:
The distance between the centers of the nucleus to the outermost shell of an
atom is called atomic radius.
In groups: Atomic radius increases from top to bottom in a group. This is due to the
addition of new shell.
www.sakshieducation.com
www.sakshieducation.com
b) Ionization energy:
The energy required to remove an electron from the outer most orbit of a neutral
gaseous is called ionization energy.
c) Electron affinity:
d) Electro negativity:
The electro negativity of an element is defined as the relative tendency of its atom to
attract electrons towards it when it is bounded to the atoms of another element.
Na < Al < cl
All these elements belong to same period. The order of their atomic size is
[Na > Al > Cl]. As we move from left to right in a period Ionization energy increases.
www.sakshieducation.com
www.sakshieducation.com
The penetration power of 2p is less compared to 2s. So, it is easy to remove electron
from 2p.
Nitrogen has half filled configuration in degenerated orbital. So, it is more stable
compare to C & O, so, N has high ionization energy.
Ne is an inert gas, so it has highest ionization energy. Na has larger size compare
to F. So, it has low ionization energy.
These elements belongs to same group the atomic size of these elements is in the order
of Ca > Mg > Ba.
10. Aluminum does not react with water at room temperature but reacts with both
dil. HCl and NaOH solutions. Verify these statements experimentally. Write your
observations with chemical equations. From these observations, can we conclude
that Al is a metalloid?
A. Metalloids are elements which resemble both metals and non-metals. The valency
shell of metalloids contain 3, 4, 5, 6 elements starting from periods 2 to 5 respectively.
Al belongs to 3rd period. It contains 3 valence electrons. So, it is not a metalloid as it
contains 3 valence electrons instead of 4.
Al doesn’t react with water at room temperature. But it reacts at high temperature with
water
www.sakshieducation.com
www.sakshieducation.com
From the above reactions, we conclude that all react with both acids as well as bases.
So, it is Amphoteric.
A. The tendency of an element to lose electron and form positive ions is called metallic
character.
The elements to the left of the periodic table i.e., IA group have greater tendency to
lose electrons so, they are strong metals. Li, Na, K, Rb, Cs (IA) are strong metals as
they lose one electron and posses high reactivity.
As we go down in a group the atomic size increases and electrons in the outer shell
experiences less nuclear attractions and so can lose electron easily. Thus increased
metallic character.
A. 1) Mendeleeff arranged the element known at that time in a chart in a systematic order
in the increasing order of their atomic weight.
www.sakshieducation.com
www.sakshieducation.com
2) Mendeleeff tried to explain the similarities of elements in the same group in terms
of their common valency.
4) Each group is divided into 2 sub- group A and B. The elements within any sub
group resemble each other to great extent.
5) A period comprises the entire range of elements after which properties repeat
themselves. There are 7 periods in the Mendeleeff’s periodic table.
6) Based on the arrangements of the elements in the table he predicted that some
elements were missing and left blank spaces at the appropriate places in the table.
7) His predicted properties were almost the same as the observed properties of those
elements after their discovery.
8) In this way, without knowing the electronic configuration of the atoms of elements
Mendeleeff still could arrange the elements nearly close to the arrangements in the
modern periodic table.
13. How the positions of elements in the periodic table help you to predict its
chemical properties? Explain with an example.
A. Position of elements in the periodic table helps us to predict their chemical properties
i.e, If the elements are present at extreme left or extreme right, they are highly reactive
metals & non metals respectively.
• The elements which are almost left in the periodic table are metals and highly
reactive.
Eg: Li, Na, K, Mg & Ca etc, are left in the periodic table these are metals and highly
reactive.
• The elements which are right in the periodic table are non-metals and gases.
Eg: O, F, Cl, S etc, are right in the periodic table. These are non metals.
• The elements which are in the 18th group are noble gases and inert for chemical
reactions
www.sakshieducation.com
www.sakshieducation.com
Eg: He, Ne, Ar etc, are noble gases which are in 18th group (VIIIA). These are inert
for chemical reactions.
www.sakshieducation.com
www.sakshieducation.com
a) 2 b) 8 c) 18 d) 32
[ ]
a) 9 b) 14 c) 15 d) 17
a) nitrogen(Z=7) b) fluorine(Z=9)
c) phosphorous(Z=15) d) argon(Z=18)
5. IE2 ⎯ IE1 [ ]
a) α b) = c) > d) None
Key:
1) b; 2) c; 3) b; 4) d; 5) c.
www.sakshieducation.com
www.sakshieducation.com
I. Group-I Group-II
1. Alkali family [ ] A) Be
2. Noble gas [ ] B) Na
3. Halogen family [ ] C) N
4. Boron family [ ] D) Cl
Key:
1. B; 2. E; 3. D; 4. C; 5. A.
electrons filled
1. s. orbital [ ] A) 6
2. p [ ] B) 2
3. d [ ] C) 14
4. f [ ] D) 2h2
Key:
1. B; 2. A; 3. E; 4. C; 5. D.
www.sakshieducation.com
www.sakshieducation.com
electronic configuration
Key:
1. E; 2. C; 3. A; 4. B; 5. D.
www.sakshieducation.com
www.sakshieducation.com
Important Tables
1. Group A, B, C, D, E elements atomic weight, Arithmetic mean
www.sakshieducation.com
www.sakshieducation.com
www.sakshieducation.com