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/ 51
10.
1.
12:
ed
Baad (C=. (15 (0S =A cones
Elements in the same vertical group of the periodic table have same.
(a) Number of valence electrons (b) Atomic number
(©) Atomic mass (€) Atomic volume
An element having low value of ionization energy and low value of electron
affinity is likely to belong to
(@) Group IA (b) Group IB
(¢) Group VIA (@) Group VIL
Which set of elements is Usted in order of increasing ionization energy?
(a) SbP
() Mg> Al (@) both b and c
Ionization energy depends upon
(a) Nuclear charge (b) Atomic size
(©) Shiclding effect (@) LE depends upon alll of the abot
and nature of orbital Corea | BOTT eeu neue heute ig
Shielding effect across the period
{a) Increases (b) Decreases
(©) Can not be predicted (d) Remains constant
Addition of 2= electron to a uninegative ion is always.
@) Exothermic (b) Endothermic
(c) Data is insufficient (@) Unpredictable
Higher value of electron affinity means
fa) Atom will lose electron easily (b) Atom will gain electron casily
{c) Atom may form di-positive ion (@) The reason is unknown
Metallic characters of alkali metals
(a) Increase down the group (b) Decrease down the group
(©) No regular trend (a) Remain same.
Melting points of VII-A group elements down the group
(a) Increase ()) Decrease
{o) Remain constant (@) No regular trend
‘Oxidation state of an atom represents
{@) Number of electrons gained (b) Number of electrons lost
{e) Apparent charge in compound, . _ (4) Its vacancies
KK
ic) Mg? (d) Cav?
alides in which halogen atoms act as a bridge between two atoms of the
‘other element are called
a) Covalent halides (b) Electronegative halides
} Polymeric halides (@) Polymeric hydrides
ss electronegative elements such as Be, Ga, Al ete form
a) Polymeric halide (b) Covalent halide
(@ an
is solid due to
Strong covalent bond (b) Large value of dipole moment
) High polarizability (@) Strong hydrogen bonding
ue increasing order of acidity of the oxides of Mn is
@) MnO < MnO; < MnO; (b) Mn,0; > MnO, > MnO
(©) MnO, > MnO > Mn.0; (@) MnO, > Mn,0; > MnO :
‘Keeping in view the size of atom which order is correct one?
El Mg>sr (b) Ba > Mg
i lu> Ce (@ Clo1
‘Which one of the following element has highest oxidation state in its
compounds?
fcr
(b) Mn
ao
h of the following cannot exist in solution
(b) He
Fists). Entry Test Seri
(a) Nar 10.
ul.
12.
a3.
14.
15.
I-A elements are named as alkali metals because
(a) Their oxides are basic
(b) Their oxide and hydroxides are water soluble
(o Both ‘a’ and "b’
(@) They are found in earth
‘The word Alkali means
(a) Base ()) Basic salt
(c) Ashes (a) Spirit
Formula of Chile saltpetre is
(a) NaNO. {b) CaCOs,
(o) Ba (NOs)2 (a) NELCI
‘The elements which are very abundant in earth crust are
(@) Si and AC (b) Ca and Mg
(9 Band At (aan
The oxides of beryilium BeO is
(a) Acidic (b) Basic
(c) Amphoterie (@ Neutral
Which clement is necessary for normal leaf development?
fa) St (b) Ba
(c) Mg. {d) Ca
Li is different from its family members due to
{a) small size {b) high charge density
{c) less electropositivity (a) all of the above
Carbonates of lithium are not stable like that of sodium due to
(a) Low electronegativity (b) Low electroposttivity
{c) Low charge density {@) Not kmown yet
Nitrates of which pair of elements give different products om th
decomposition?
(a) Na, K (b) Mg, Ca
(©) Ui, Na (@) Li. Ca
Which one of the following is not an alkali metal?
(@) Francium (0) Caesium
{c) Rubidium {d) Radium
Which of the following sulphates is not soluble in water?
{a) Sodium sulphate (b) Potassium sulphate
{q) Zine sulphate -(@)-Barium sulphate
The element cesium bears resemblance with
(a) Ca (b) Cr
(c) Both of the above (@) None of the above
‘The ore CaSOz.2Ha0 has the general name
(a) Gypsum| {b) Dolomite
(c) Calcite (q) Plaster of Paris
Down's cell is used to prepare
(a) Sodium carbonate (b) Sodium bicarbonate
(c) Sodium metal (a) Sodium hydroxide
Which element is produced at the cathode during the electrolysis of]
in Nelson's cell?
(a) Ha (b) Na
(ce) Ce S| felrrce4 peed
Ammonia may be prepared by heating ammonfum chloride with
(@) Water {b) NaCl
(c) Aqueous sodium hydroxide (@ SO:
Calcium carbide is prepared by heating lime with coke at
fa) 25000C (b) 2600°C
{c) 2700°C (a) 2800°C
Crystals of NazCO3. 10H,0 when exposed to air
{a)'Lose water and remain solid (b) Gain water and remain solid
(6) Gain water and become liquid (q) Remains unchanged.
Which one of the following substances conducts electricity by the
movement of ions?
{@) Graphite (b) Copper
(©) Molten sodium chloride (@) Mercury
Which one of the following gives white precipitate with aqueous solution
of BaC.?
(@) NaFiCos (b) NaNOs,
(6) NasCOs (@) NaxCrO.
Which one of the following carbonate is water insoluble?
(@)NaaCOs (b) KaCOs
(©) (NH)2COs (a) Cacos
The deliquescence is a property in which a solid
(@) Absorbs moisture and remains solid
(6) Absorbs moisture and turns to liquid form
(©) Loses water of crystallization
(@) Increases the number of water of crystallization.
In diaphragm cell, hydrogen is discharged by the reduction of
" (a) Water . (0) HCL
(©) Na‘ (@)Naci
In diaphragm cell, level of brine in anode compartment is kept slightly
higher which prevents
(@) Hydroxide ions to reach anode —_—_(b) Chilorine gas-to mix
(©) Cathode to decay (@) All of the above
Gypsum is applied to the soil as a source of
(@) Ca and P (b) Sand P
(9) Caand S (@) we could not apply
Alkali and alkaline earth metals impart colours when heated over burner.
It is due to
(@) Smaller electronegativity of alkali metals
(b) Smaller ionic radius of these metals
(©) De-excitation of electrons from higher energy levels to low energy level.
(4) Excitation of electrons from low energy levels to higher energy levels.
Which one of the following alkali metals forms only normal oxide when it
reacts with 02? :
fa) Lithium (b) Sodium
(© Potassium (@ Rubidium
First ionization potential of alkaline earth metal is greater than alkali .
metals because
{@) They are more reactive, (0) They have greater atomic radit
{o) They have smaller atomic sizes __(¢) All :
475 Pelee
errr
Which one of the following pairs shows diagonal relationship in 4
periodic table?
(a) Sodium and Lithium (b) Lithium and magnesium
(0 Lithium and beryllium (@) Boron and Beryllium
30. NaOH is named as caustic soda because
(a) It corrodes the organic tissucs (b) It is used in soda water
(c) It reacts with chlorine gas (@) It reacts with fats to form soap
31. Sodium is not observed in +2 oxidation state because of its
(@) high first ionization potential (b) high second ionization potential
(c) high ionic radius {a) high electronegativity
32, Camnalite has chemical formula
(a) KCI (b) KCL MgCle.61120
{c) NazBiOr.10H20 (a) CaCOs.MgCOs
83. Magnesium metal does not burn in the vessel containing
fa) No {b) O2
(c) Noand O2 = (a) Ne
34. Electrolysis of dilute solution of NaCl results at the anode
{a) sodium (b) hydrogen
(©) chlorine (a) oxygen é
35. Second ionization potential of alkali metals are very high due to
(a) being s-block elements (b) inert gas configurations
(¢) ns' electronic configuration (q) being metals
36. Which ion will have maximum value of heat of hydration?
{a Ae (b) Cs"
(©) Bar (a) Mg
37. Which one can form complex?
(a) Na (b) Cr
(Lt @K
38. Which one is natron?
(a) NasCOo (b) NazCOa. 1020
(©) NasCOs.H20 (a) NaHCOs
39. Addition of 2% gypsum in cement
(a) Triggers hydration (b) Triggers hydrolysis:
{c) Prevents rapid hardening {d) All of these
40. Which one is least ionic in nature and decompose on heating.
(a) LOH (b) NaOH
( KOH (@) CsOH
Paty Entry Test Series Ps PRACTICE EXERCISE
10.
<1:
12.
Boron is non-metal whereas Al is metal, it is due to
(a) Small size (b) High nuclear charge
(9) Both a and b {d) No authorized justification yet
Boron in soil has been considered micronutrient for
(a) Soll porocity (6) Proper growth of plants
(¢) alkalinity of soil (a) All
One of the outstanding feature of boron is its ability to form
fa) Molecular addition compounds _(b) Molecular crystals
(€) Semiconductors (@) Ionic compounds
‘Substance which is found in dried up lakes of Tibet and California is
(a) Tincal (b) Borie acid
(c) Calcium carbonate (@ Colemantte
Borax is a white crystalline solid and it is
{a) More soluble in cold water (b) More soluble in hot water
(c) Insoluble in water (@) Soluble only in organic solvents
Which of the following does not give Borax bead test?
@cu (b) Cr
fm @al
Special features of borate glass is that it is
(a) Heat resistant (b) Low melting
(©) Used to prepare chemical garden __ (d) Green in colour
‘The metal which is used in thermite process because of its activity, is
(a) iron (©) copper
(©) aluminium a) zine
Aluminium oxide is
{a} Acidic oxide (0) Basie oxide
(c) Amphoterie oxide (@ It does not exists
Which of the following shows inert pair effect?
{a) boron (b) carbon
{c) silicon (tin
‘Which electronic configuration corresponds to an clement of group IIA?
(@) 1s2,282,2p5 (6) 19?,25?,2p°,38?,3p!
(0) 1°,282,2p* o- (d) 15%,28?,2p°,3s?,3p5,4s2.3d?
‘Tincal isa mineral of .
@al ) Si
OB @ec
Peta) Entry Test Series eeu ke eeu
eed
‘network of silica (SiO), each silicon atom is surrounded by
atoms of oxygen
(2
@6
h one of the following is not a semiconductor?
st (b) Ge
Se (@ sn
thoboric acid is 2.6% soluble in water at 40°C and at 107°C.
() 27%
26%
37% (a) < 2.6%
se process of aluminium extraction is called
Hall process (b) Thermite process
Haber process {@) Contact process
eeause of its ability to combine with both oxygen and nitrogen,
nium metal is used
g) As nitrometer
b) To remove air bubbles from molten metal
§)To produce alloy
B) As insulator
queous solution of borax above 62°C gives crystals of
@) Na2Bi07.4120 {b) NavB.07.5H20
3) NazBsO7.2H20° {d) NavBaOr.10H20
jones differ from silica by a group of .
a) CHs — (b) -OH
HsCO— (d) Oz
hich of the following is not a use of silicones?
Lubricants: (b) Hydraulic brakes
We) Antifreeze (a) Water repellent
oron is non metal while other elements of IIA group are metals. This is
because
{@) it has small size /
(®) it has high nuclear charge /
{o) it forms molecular addition compounds 5
{@) all of the above
C02 is gas while SiO is solid at room temperature.
{a) carbon is non-metal while silicon is semi- metal
{b) CO; is an independent molecule while SiOz has network covalent structure
{c) Carbon forms multiple bond while silicon does not form multiple bonds
{q) Silicon has all sigma bonds,
187
_ i mm | 24.
25,
26.
27.
30.
orca) ce ae Uke aa este
The coloured glassy mass in borax bead test is due to the formation of
(a) metal borate (b) metal meta borate
(c) metal boride (@) metal silicate
Identify the correct statement regarding CO
(a) it combines with H20 to form carbonic acid
(b) it reacts with red blood cells of haemoglobin
(¢) it ts powerful oxidizing agent
(q) it is used to prepare aerated drinks. -
The chief ore of At is:
(@) NasAeFs (0) At,03 2120
(6) ALOstLO (a) AGOs3IBO
If temperature of gallium arsenide is increased then its conductivity
(@) decrease (b) increase
(c) remains constant (d) rst decreases then increases
Borie acid cannot be used
(a) As antiseptic in medicine (b) For washing eyes
(0) In soda bottles (@) For senamel and glazes.
Which of the following will decompose to produce litharge
{a) Pb20 (b) Pb:0,
(©) PbO2 (@) All of the above
Which element can form tripositive ion?
(@) Beryllium (6) Carbon.
(¢) Silicon (@) Aluminium
Which of the following is metasilicie acid?
fa) HSnOs (b) HeSi0s,
(0) HaAsOs (@) HeSbOs
[urs 10.
i.
12.
13.
14.
15.
16.
~ Ror.
PRACTICE EXERCISE i
Which of the following is different with respect to physical appearance?
{a) Arsenic (b) Phosphorus
(¢) Antimony (@) Bismuth
Which one of the followings possesses melting point below 0°C?
(a) Nitrogen, (b) Phosphorus
(c} Carbon (@) Bismuth
Compounds of nitrogen and phosphorus are mostly
fa) tonic (b) covalent
(©) polar (4) all varieties are possible
The most electronegative element among the following is,
(a) Sb : (b)N
(As @P
50; is not absorbed in water directly because ,
(a) Reaction is exothermic (b) [tis insoluble in water
(Q) Dilute acid is produced (a) All of above
Phosphene gas will be produced if phosphorous acid is subjected to
(@) Oxidation (b) Reduction
{c) Decomposition (a) Both b &¢
Which of the following will give phosphoric acid on reaction with water
(a) PCls (b) P20s
{c) POs - (d) All of the above
Which one of following is not a property of pure quartz?
(a) Coloured solid (b) Brittle
{c) Hard (4) All of above
Phosphorus is a Greek word and it means
(a) Light bearing (b) Fire
(©) Impure (@) Tetrahedral
Which of the following does not contain phosphorus? 4
{a) Yolk of egg, (b) Bone
(c) Nerves (a) Steel
‘Allotropic form of phosphorus that is poisonous is
(a) White {b) Red
(¢ Black (@) Violet
Which one of the following is not the use of graphite?
{a) Lead pencils {b) Abrasive
(Lubricant (@) Blectrode of electrolytic cell
‘Acetic anhydride can be obtained by treating ethyl alcohol with
(@) P20; (b) HoSO.
(9) Botha & b (@ PCls
‘The composition of brown ring in nitrate test is
(a) FeSO;.NO (b) FeSOu.NO»
{c) FeSOs.NOs (a) FeSO..N2O
Phosphorous acid upon thermal decomposition yields phosphoric acid and
(a) Phosphine (0) Phosphorus
(c) Water (q) Phosphorus pentoxide
Which one of the following compounds usually smells like garlic?
(@) P:0s (b) P20s
(0) HsPOs (@) All have same smell
‘Kips Meee 202 e (eer Group V-A and Group VI-A Elements
(b) 360°C
(@ 620°C
The element of group VIA, which is a non-metal is
fs (b) Se
{c) Te (@) Po
Phosphoric acid is a weak acid and its basicity is
fa) 0) 3
fe) zero (a) 2
‘All the elements in group VIA are in nature,
fa) hygroscopic (b) metals
{e) polymeric {(@) all of above
‘Which of the elements show passivity when treated with cone. HNOs.
fa) Fe (b) Ae
{) Cr (@) All of the above
Which allotropic form of phosphorous is the most stable?
(a) white (b) black
{c) red (@) Violet
The gas which cannot be dried by conc. H2SOx
(a) SO. (b) Ths
(9) CO, (d) CoH
The chemical composition of cinnabar is
(a) ZnS 0) PbS
(o) Hgs @Fes
FeSO, forms brown ring with
(a) N20 (b) NO.
{NO (a) N20
Oxygen and sulphur resemble in all except
{a) Electronic configuration of valence shell electrons.
(b) Show allotropy
{c) Polymeric
{d) Show same oxidation state
‘Oxygen does not react with all except
fa) Alkali (b) Acta
(c) Water (@) Metals
Arsenic oxides are removed by passing through
(a) Ferric hydroxide (b) Sodium hydroxide
{c) Calcium hydroxide (@) Aluminium hydroxide
In which compound nitrogen has maximum oxidation state
(a) N20 (b) NOx
(c) HNO» (a) HNOs
When sulphuric acid is treated with ethanol, sulphuric acid behaves like
(a) an acid (bj dehydrating agent
(¢) an oxidizing agent (@) as sulphonating agent
—) Among the halogens, the rare element is
(a) Fluorine (b) Chlorine
(©) Astatine (d) Iodine
‘The colour of chlorine gas is
(@) pale yellow (b) greenish yellow
(¢) reddish brown (@) greyish black
‘Van der Waal's forces are stronger in
(a) Py (0) Ch
() Bra @b
‘The most powerful oxidizing agent among the halogens is
@r (0) Ch
(© Bro @b
Which of the following statements is incorrect about fluorine
(@) fluorine is restricted to -1 oxidation state
(b) fluorine follows octet rule and as well as extended octet rule
(6) fluorine has lowest dissociation energy among the halogens
(@) both b and ¢
The halogen which reacts spontaneously with gold(Au) to form Au‘? is
fa) Pa {b) Ch
(9 Bro @kb
Which one of the following is the weakest acid in water
(a) HF (©) HCI
(9 HBr @H
‘The halogen, which reacts very slowly with halogen is 4
{a) Fluorine (0) Chlorine
{c) Bromine (@) Iodine
Which of the following represents the correct electronic configuration of
‘Vil A group elements in the ground state?
(a) ns2p* (©) ns*p*
(c) ns*p* (@) ns%ps
The halogen having highest electron affinity is
{a) Fluorine (b) Chlorine
(c) Bromine (@) Iodine
Which is the strongest acid?
(@) HClO {b) HCIO2
(9 HCO, ‘ {d) HCIO,
ES cores 13.
14.
15.
16.
ave
18.
19.
20.
21,
Pee cue R I Cac
Chapter 5
‘Bromine can be liberated from KBr solution by the action of
(a) Iodine solution (b) Chlorine
{c) Nach (a) KI
Bleaching powder is an example of
(a) Normal salt (b) Double salt
(o) Mixed salt (@) Complex :
Consider the following reaction-
QKCIOs + HxCi0s + H2S0. ——> —KS0x + 2Ha0 + 2COa + Oxide
Which oxide of chlorine is produced in the above reaction?
(a) Cho (b) Cloz
{c) COs (a) CLO; =
Which of the following oxides of iodine is used for quantitative analysis
co? :
(a) LO. {b) 102
(0) bOs (@) Allare equally useful
Consider the following reaction-
3Cl+6NaOH ——> —_NaClO9+ 5NaCl + 3H,0
‘This reaction is
(a) Displacement reaction .
(b) Double displacement reaction
(c) Disproportionation reaction :
(@) Reduction reaction *
Which of the halogen has highest electroncgativity?
{@) Fluorine (b) Chlorine
(c) Bromine _ (@) Iodine
Which of the halogen can displace other three elements?
(a) Fluorine {b) Chlorine
(c} lodine * {@) Bromine .
Which of the following statements is incorrect about halogens?
(a) All are non-metals
(b) All the halogens have electronic configuration ns#p?
{c) They have high electron affinity and ionization energy
{@) All the halogens react with noble gases to form their halides
‘The chemical formula of sodium hypochlorite is
{a) Naclo (b) NaClOa
(@) NaClOs (a) NaClOs
Fluorine can react with
(a) Xe (b) Kr
(9) Rn (d) All of the above
xips Pea ed (eee) BOO or Rim SCRE nica
Bleaching powder is not used for bleaching
-fa) Cotton (b) Costly fabrics
(c) Linen (@) Paper pulb
Which of the following is the weakest reducing agent.
(a) HF (0) HBr
(9 HEL (@) HI
Which of the following is not use of compounds of Fluorine
{@) SbF 18 used for manufacture of pottery
{b) Sodium fluoroacetate is a rat poison
(©) CuFs is used in ceramic industry
(a) None of the above.
In which compound of Xenon, the oxidation state of Xenon is + 6.
(a) XeFs (b) XeOFs
(c) XcOF2 (@) Na:XeOs
Photographic plates are coated with a thin film,
(a) AgNOs, ’ ) Agl
(©) Agel (@) AgBr
‘The anhydride of CIO, is:
(a) CLO 2b) COs.
(© clo. + (@) ChO;
Indicate the correct statement
(a) Cli Is the strongest oxidizing agent _(b) Iz is a volatile solid
(©) Br, is more reactive than Ch (@) Chis insoluble in water
Which one of the following halogens is present in Teflon:
fl {b) Bra
() Ch (a) Fa
Which is the paramagnetic oxide of chlorine:
(@) cho; : (6) CLO.
{o) ClOs (@) all
=: PRACTICE EXERCISE (#2:
ood
Se
1
- Co-ordination number of the transition element in [Pt Cl NOz (NEla):|? is
(2 6
(4 @s
2. Ka(Cu(CN),) which one is correct
(a) Potassium tetra cyano cupperate
{b) Co-ordination number is 2
(c} Ligand is positively charged
(@) Central atom is present in anionic sphere
3. The oxidation number of central metal atom in [Ni(CO),] is
fa) o (b) 2
(4 @6
4. Group VIB of transition elements contains
(a) Zn, Ca, Hg (©) Fe, Ru, Os
(¢) Cr, Mo, W (a) Mn, Te, Re
5. The elements in which d or f orbitals are in the process of completion are
(a) outer transition elements (b) inner transition elements
(6 typical transition elements (@) transition elements
6. The location of transition elements is'in between
(a) lanthanides and actinides (b) s and p block elements
(c) chalcogens.and halogens (@) d and flock elements
7. The melting points and boiling points upto middle of 3d- series
{a) increases (b) decreases
(¢) remain same (a) no regular trend
8. Pure metal 3
(a) corrode slowiy (b) corrode rapidly
(c) does not corrode eastly (a) none of these
9. Compounds attracted by applied strong magnetic field are called
(a) diamagnetic (b) paramagnetic
(€) good conductor (@ ferromagnetic
10. The corzect electronic configuration of ‘Cr’ is
(a) [Arjase3ae (b) [Ar] 45°34
(6) fArl4se3d? (@) [an 4si3ae
11, The oxidation state of transition elements !s usually
(a) variable (b) constant
(o) single (a)infnite
12. When light is exposed to transition element, then electrons jump from
lower orbitals to higher orbitals in
(a) orbitals of f-subshell ()) orbitals of d-subshell
(0) orbitals of p-subshell (d) both a and b eed) Sree ean Cuca)
Non-stoichiometric compounds of transition elements are called
(a) hydrates (b) hydrides
() binary compounds (@) interstitial compounds
When a compound of transition clement is dissolved in a solution of salt,
then it produces
(@) simple ions {b) complex ions
(c) double salts {@) strong anions
‘The specie which donates electrons to central metal atom in co-ordination
sphere is called
(@) anton (0) cation
(c) ligand (a) acid
‘The species which donate two clectron pairs in a coordination compound
is called
(a) ligand (b) mono-dentate ligand
{o) poly-dentate hgand (@) bi-dentate ligand
Which of the following can form a chealate
(a) ammine (b) oxalato
(0) carbonyl (@) cyano
‘The central atom along with ligands is called
(a) complexion (b) coordination sphere
(c) ligand (a) complex compound
‘The compound or complex ion which has a ring in its structure
(a) polydentate ligand (b) chelate
{c) monodentate ligand (@) hydrate
In complex compounds, the oxidation number is written in
{a) English (0) Greek
(¢) Roman number (a) Hebrew
Geometry of the complex compounds usually depends upon
(a) type of ligands
{b) types of hybridization in the elements of ligands
(¢ hybridization of central metal
(a) All of above
When the central atom of coordination compound is spid* hybridization,
the expected geometry will be
(a) tetrahedral (b) square planar
(o trigonal bipyramidal (@ octahedral
Im pig iron, the concentration of C-atom is
fa) 0112 --- 0.25% (0) 2.5 --- 4.5%
{2.0 — 4.0% (a) 0.25 --- 2.5%
225 26.
27,
28.
29.
orc) Transition Elements
In the production of wrought iron.Mg,Si and P are removed in the form of
(a) oxides (b) silicates
(c) slag {d) carbonates
With impurities like P and S, the open hearth furnace is lined with.
{a) SiO» : (b) FexOs
(9) Feo (@) Cao, MgO
‘The oxidation number of Mn in [MnO,}* is
(a) +7 (b) 7
(0) +6 @-6
Which is sold as fertilizer
(a) CaSiOy (b) NaxSiOs
{c) Cas(PO.)2 {d) MnSiO.,
‘any proces of chemical decay of metals due to the action of surroundi
medium is called
(a) activation (b) enameling
(6 corrosion {€) coating
When an active metal like Al comes in contact with less active eleme
like Cu, then it produces
(a) dry cell (©) galvanic cell
{e) electrolytic cell (d)aandb
Which of the following is a typical transition metal?
(a) Se Oy
{Ca (a) Co
horses 64 PRACTICE EXERCISE
Main source of organic compounds is
(@) Animal ci
(©) Coal ome
Octane number can be improved by
{) Isomerization (b) Adding (CaH1-)aPb
(¢) Adding (CHs),P> (@) an
Hydrocarbons which burn with smoky flame are called
(a) Aliphatic (b) Alicyclic
{c) Aromatic (@) Aldehyde
Octane number of 2,2,4-trimethyl pentane is
fa) 100 (b) 90
{(c) 80 @ 70
Propene can exhibit
(@) cis-trans isomerism (0) geometric isomerism
(¢) both a and b (@) none of the above
Geometric isomerism is usually found in
(@) Alkanes (b) Alkenes
(c) Allkynes (@) Esters
Pentane and 2-methyl butane have the same
(a) Boiling point (b) Melting point
(o) Percentage composition (@ Structural formula
Organic compounds that are essentially non-polar and exhibit weak
intermolecular forces have
(@) Low melting points (0) Low vapour pressure
(¢) High bolling points (@) High electrical conductivity
‘The first organic compound was synthesized in laboratory by
(a) Wohler (b) Kolbe
(©) Berzellius (@) Berthelot
According to vital force theory
{a) organic compounds can be synthesized from inorganic compounds
(b) organic compounds cannot be synthesized from inorganic compounds }
(0) organic compounds can be synthesized by animals
{@) organic compounds can be synthesized by plants
First organic compound synthesized in laboratory was
(a) tartaric acid (b) ethyl alcohol
() methanol (@) urea
A double bond consists of
{a) Two sigma bonds {b) Two Pi bonds
(c) One sigma and one Pi bond (@) One sigma and two Pi bonds
‘The property of carbon chain formation is called
(a) catenation (b) hybridization
(c) polymerization (@ solvation
Chemical properties of fist member of homologous series with respect to
other members are
(a) same { (b) different
{@) depends upon number of C atoms _(d) depends upon number of H atoms
The organic compounds having very high molecular weight are called
(@) carboxylic acids {b) ketones
(0) aldehydes (@) polymers )
Kise 235 17.
18.
19.
21.
22.
25.
26.
27.
28.
Re ence rae
Compounds having same molecular formula but differ in str
formula are called
(@) polymer (b) monomer
(©) isomer (@) allotropes
Rate of reactions of most organic compounds are
{@) very slow (b) very fast
(©) slow (@) no regular character present
Organic compounds are soluble in
(a) polar solvent (b) non-polar solvent
(©) alkalies (@) water
Coal is produced after a long time decay of
(a) animals (b) fossils
{c) wood (@) all of the above
Methane is used in power generation in chemical industries being a
(a) natural gas (6) good caloric value
‘o) cheaper @ Al
Crude oil is blackish coloured liquid produced after the decay of orga
matter present between
(@) earth layer (6) mountains
() sedimentary rocks (@) rocks,
The process in which larger molecule with higher molecular weight bre
down into smaller molecules with lower molecular weight
(a) polymerization (b) Cracking
(6) isomerism {d) no such process occurs
At low temperature and pressure, cracking can be done in presence
catalyst
{a) AlLOs (0) Fez02
(c) Al:Og and SiO, (@) FesOs and SiO,
The metallic sound produced by engine due to the pre-ignition of
called
(a) knocking (b) reforming
(©) cracking (@) aandc
Which one of the following compounds shows intense knocking?
(a) n-pentane (b) iso-heptane
(6) tso-octane (@) n-heptane
Which of the following can be used as anti-knocking agent.
(a) PbCh (b) (CoHs}ePb
(©) (CaHs)2Pb (@) All of the above
Ether functional group can be represented as
(a)-O# ()RCOR
(ROR (@) R-COOH
Isomerism which is present only in alkene is
(a) structural isomerism (b) metamerism
(0) cls-trans isomerism (@) both b and c
A single atom or group of atoms which gives, characteristic properties
compound is called
(@) radical (b) hydrocarbon
(© functional group @) ion
xs (cae Pree at ede
npound containing benzene ring in their structure are
(b) aromatic
3) carboxylic acid (@) carbohydrates
‘2-propanol and 1-propanol show the isomerism
‘@) metamerism (6) functional group isomerism
(©) geometric isomerism (@) position isomerism
Which of the following is an amide
fa) R-NHL (b) RCONH,
fc) R-NH-R (@) CoHsNHe
Im sp* hybridization, the expected geometry of molecules will be
fa) square planar {(b) trigonal pyramidal
(c) tetrahedral (@) near
‘Only sigma bonds are present in
{a) propene
{c) butanal
In cyano group the carbon atom sl
fa) sp?
{c) sp°
The structure of ethyne is
(@) angular (b) trigonal
(©) linear (@) trigonal planar
the fractional distillation of petroleum produces gasoline up to
{2} 10% (b) 15%
(a) 30%
{b) butanoie acid
(d) ethoxy ethane
shows which kind of hybridization.
(0) sp
(d) none of the above
{c) 20%
The general formula of cycloalkene is
(@) CoHan (b) CaHfaova
{c) Cuban: (€) CoHan2
Which is not heterocyclic compound
(a) Furan (©) Thiophene
(©) Aniline (@ Pyridine
CcHi2has the number of isomers
(a) one (b) two
(© three (@) four
xsi [237 Alkanes containing a methyl group on main chain at 2=¢ carbon are called
(a) iso-alkane (b) normal-alkane
(c) neo-alkane (a) branched-alkane
When one hydrogen atom of alkane is removed, then it is called
(a) alkene (b) alkyl
(o) aldehyde (a) saturated hydrocarbon
‘Alkanes are also known as
{a) saturated hydrocarbon (b) unsaturated hydrocarbon
(c) paraffins (@) both a and ec
Sabatier Sendern’s reaction involve in presence of Ni
(a) alkene and Ha (0) alkene and O;
() alkene and Na {(@) alkyne ana Cl
Hydrogenolysis results in the formation of,
(@) alkane (b) alkene
(c) alkyne @ aldehydes
Clemmensen's reduction involves the reduction of
{@) ketone (6) aldehyde
(©) alkane (@) all of the above
Removal of COs is called
(@) carboxylation (b) decarboxylation
(c) esterification (@) hydroxylation
Soda lime is a mixture of
(@) CaO and KOH (b) CaO and NaOH
(©) NaOH and Na,O (a) NazO and KOH
Molozonide is unstable and changes into ozonide on
(@) reduction (b) oxidation
(0) hydrolysis (a) rearrangement
Dehalogenation of ethyl te*rahalide will give
(@) ethene (b) ethyne
(©) ethyl halide (d) all of the al-ove are possible
R-Mg-Br is called
(@) Grignard reagent (b} Metallic alkyl hatide
{o) Both a and b (@) Ally] halide
Upto C atoms, alkanes are gases
fa) 2 )3
4 @6
Which of the following is the most reactive
(@) ethane (6) ethyne
(c) ethene (@) benzene
Incomplete oxidation of methane in the limited supply of air forms.
(a) CO. and HO (b). CHO
(c) CO++C (a) CO+H:0+C
Introduction of nitro group in a moiecule is called
(a) nitration (b) halogenation
(¢) sulphonation (@ amination
Order of ease of halogeaction in alkane is,
(a) L>Ch>Brok (0) F-Chob>Br
{) FeeCh>Bnaly @ CpFeBrsk oS ee ier
17. The gas used in manufacturing of urea fertilizer
{a) CoH (&) GH:
(o) CB (@ CH
18. General formula of alkyne is
(2) Calan +2 {(b) CoHan-2
(0) CoH (@) CaFlan +1
19. Which of the following will be acidic
(a) propyne (b) L-butyne
(6) ethyne (a) all of the above
20. Removal of halogen and hydrogen atom is
(a) halogenation (b) dehalogenation
(©) dehydrohalogenation © (@) hydrohalogenation
21. Alkenes are produced from dehalogenation of
{a) dihalo alkane (0) trihalo alkane
(© vicinal-dihalo alkane {(d) vicinal trihalo alkane
22. Reactivity. due to ni- electrons is present in
(a) alkane (b) alkene
(¢) alkyne (@) both b and c
23. In unsaturated hydro carbons, x-electrons favour
{a) less reactivity (6) addition reactions
(c) substitution reactions (@) none
24, Raney nickel is prepared from by treating with caustic soda
(@) Ni-Cu alloy (b) Ni-Fe alloy .
(Nil alloy (@) Ni-Mg alloy
25. Which one is Chloroform
(a) CHaCh (b) CHCl
(¢) CHCl, (a cc
26. Vinylacetylene combines with HCI to form
(a) polyacetylene (b) benzene
{c) chloroprene (@) divinyl acetylene
27." B,8’-dichloroethy; sulphide is commonly known as
(a) laughing gas () bio-gas
(c) mustard gas (@) phosgene gas
28, Which is ased for arti‘ cial ripening of fruit?
(a) ethane (b) ethene
(© ethyne (@) methane
29. Preparation of “egetable ghee involves
(a) halogenation (0) hydroxylation
(c) hydrogenation (@) hydration
30. Which is methyl cyanide
(@) CHSNE, 3 (b) CHsNO2
() CHoCN ‘ (@) CHa= CH - CN
Kips ee ‘The molecular formula of toluene is
fa) CFs (b) CHs
(c} CaF (a) Cal
2, Im benzene sulphonic acid, the sulphonic group 1s attached with benzene
ring through
(a) Hydrogen o (b) Oxygen
(c) Sulpnur (@ -O8
3. Phenanthrene is a fused polycyclic compound contains ‘benzene
rings
fa) Two (0) Three
(Q) Four (@) Five
4. Aniline is a derivative of benzene which contains
(a) Imino group (b) Amino group
(@) Nitro group
{o) Amide group
5. ‘How many x electrons are there in benzene to form delocalized electronic cloud.
fa)3 b)4
{)6 @s
6. __ Nitration of chlorobenzene gives.
(a) o- chloronitrobenzene (b) p - chloronitrobenzene
{c) m- chloronitrobenzene (@)aand b
(a two or more different substituents are attached with & benzene ting,
weno? tuber 1 position in the ring is given to a high priority group. Which
one of the following groups has highest-priority?
(a) -NHe (b) CHO
(c)-COOH (a) -cN
substituted by halogens only, which one of the followihg
When benzene is 51
halogens is given the number one position $m the ring while writing the
name of compound?
(a) Bromine (b) Chlorine
{c) Fluorine (@) lodine
Which one of the following is not a meta directing group?
{a)-CN (b) -OH ‘
(q -COOH {q) -CHO.
Which pair of groups contains both ortho and para directing groups.
(a) OH, -RCO (b) -NRs, -CN
{c) -OCHs, -CHO (@) -N (CHa, NF
o chacl Faraday discovered benzene in the gas which was produced by
sesteuctive distillation of vegetable oil that is done in
(a) The presence of Oxygen (b) The presence of Hydrogen
(c) The absence of Oxygen - {d) The presence of excessive Oxygen
By which method, the molecular mass of ‘benzene was determined as
78.108?
(a) Specific gravity method
(Q X-ray diffraction method
(9) Vapour density method
{@) Distillation method
is heated with
oe wany reales’ of Haare added. up :whed DESeens,
hydrogen in the presence of platinum?
(b) Three
@ sx
(a) Two
(c) Four lela) ONE torts
Chlorination of toluene in the presence of sunlight produces
(a) Benzyl chloride (b) 0 - chlorotoluene
(©) p~chlorotoluene (@) benzoic acid
‘The heat of hydrogenation of cyclohexene is
(a) -239 kJ mol (©) -208 kJ mot!
()-119.5 kJ/mole (@) -119.5 keal/mole
‘The resonance energy of benzene is
(@) 150.5 kJ/mol (b) 250.5 kJ/mol
(6) 150.5 Cal/mol (@) 250.5 Cal/mot
‘The different resonance structures are represented by
a<— eS
fc) __ @=
What catalyst is employed when benzene is prepared from acetyl
70°C?
(a) CraO3 + AtzOs + SiOz (0) Raney nickel
{c) Organo-nickel (@) Ni 250 - 300°C
‘Mixture of catalysts Cr20s + AfaOs +'Si0z at 500°C are used when
ds prepared from
{a) acetylene (0) n-hexane
(c) Benzene sulphonic acid (@) Sodium benzoate
Which one of the following methods will not give benzene?
{a) Heating sod. Salt of Benzoic acid with soda lime
(b) Distilling phenol with Zn dust
(c) Chiorobenzene with NaOH at 360:C and 150atm.
(a) Hydrolysis of benzene sulphonic acid with super heated steam.
Which is fused cyclic aromatic compound
(a) diphenyl amine (0) diphenyl methane
(©) naphthalene (@) bipheny!
In Friedel Craft Alkylation, AfCG is used to generate
(a) Strong nucleophile (b) Weak nucleophile
(o) Strong electrophile (@) Weak electrophile
Acylation of benzene is the introduction of on benzene.
°
Wes I
/@R-C-0 wet—c—
li . I
@R—C— @H— c—
Acetophenone is a
{a) Ether (b) Ketone
(©) Aldehyde : (@) Ester
Reacting bromine with benzene in the presence of sunlight will result in
(a) The rupturing of benzene ring (b) Substitution reaction
{c) Addition reaction (@) No-reaction
Benzene does not undergo
{a) Substitution reaction (b) Addition reaction.
{c) Polymerization reactions {d) Oxidation reactions
During sulphonation of benzene, HaSO, generates the electrophile ©
(@) HSO, (b) SOx
(0) SOs, (d)
en 2c 2 oC) ECT seed
Nitronium ion is
(a) NOs “ {b) NO
(c) NOx: (@ No.
Which compound will readily undergo sulphonation?
{a) Benzene (b) Nitro benzene
(c) Toluene (a) Chioroberizene =
Benzene is heated in air with V20; at 450°C it undergoes
(a) Substitution reaction (b) Addition reaction
(c} Elimination reaction (@) Oxidation reaction
Which one of the following statement is not correct about benzene?
{a) On hydrogenation, 208 kJ/mole is liberated
(b) C-H bond length in benzene is 1.09 Av
{c) Molecular mass of benzene is 78.108
{d) Resonance energy of benzene is 150.5 kcal/mole
‘The preparation of benzene from acetylene can also be said as
{a) Oxidation (b) Polymerization
(c) Dehydration (d) Condensation
What is required other than anhydrous AfCfs, when toluene is prepared by
Friedal craft reaction?
(a) Celle (0) Cole + CHsCE
(c) CeHsC2Hs (d) CeHyCt and CHsCl
Replacement of hydrogen of benzene by alkyl group in the presence of
alkyl halide and aluminum chloride is known as
{a) Dow's process (b) Friedel and Craft acylation
(c) Friedel and Craft alkylation {d) Clemmenson reduction
Which one of the following radical is called benzyl radical?
(aCe H, ()C.H.-C
CH,-CH (@) C.H,-CH,
Which compound form benzoic acid on oxidation with acidified KMnO, or
K.Cr0;
{a) Toluene {b) Ethyl benzene
(c) n-propyl benzene (@) Al
Ozonolysis of benzene produces
(a) Glycol (b) Glyoxal
(c) Vicinal diot (@) Both b and ¢
Which one of the following is benzal chloride?
(a) Cotfp—CH2Ct (b) CoFfs —CHCts
(c) CeHs-CH = CHCE (d) None of the above 4
What is the molecular formula of Benzenetriozonide?
{a) CHO» (b) CoFlsOn
(c) CclHsOo (@) Calle
The hydrolysis of Benzenetrizonide will yield three moles of
{a) Glyoxime (b) Benzaldehyde
{c) Glycol (d) Glyoxal
Peres an toss ‘What will be the products when reactants are alcohol and thionyl chloride
in the presence of pyridine?
{a) RCU+SHHCE (b) REUSOn+ HCE
[c) RCL+SO24F20 (@) RCUSHLO
Which C-X bond has the highest bond energy per mole?
@cF (by C-CE
(9 C-Br @cr
Which alkyl halide has the highest reactivity for a particular ally! group?
@RF () RCE :
(j R-Br Ra
Ethyl chloride with nascent hydrogen produces
(b) ethane
(a) methane
{© propane (q) butane
Which one is not a nucleophile? S
(a) Cakis SCN”
(9) NH (a) HaC*
part in the rate determining steP is called
(b) Rate of reaction
{@) Extent of a reaction
of hybridization a5
‘The number of molecules taking
(a) Order of reaction
(q) Molecularity of a reaction
During Sx2 mechanism, carbon atom changes its state
fa) sp>sP? (b) sp>>sP*
(2) ssp (@) sptosp?
What will be the order of reaction of a rea
expressed as R = K [Al [)
ction whose rate can be
(a) Zero (b) One
() Two (@) Three
Which one among the following 1s not good leaving group?
(a) HSOs wce
(on (@) Br
What is the odes of kinetics im the Sx¥ mechanism?
(a) Zero (b) First
(c) Second (a) Third
‘which alkyl halide out ‘of the following my follow both Sxl and ‘Sx2
mechanism?
(a) CHe-X {b) (CH). C- CHa
(a) (CH C-%
{c) (CHs)2 CH-
halide, which site is more susceptible for
In elimination reactions of ally!
the attack of base
{a) a-carbon.
© (0) a-hydrogen (qd) G-hydrogen.
(b) B-carbon 13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
When two moles of
