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Cheat Sheet

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Harshit Misra
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113 views

Cheat Sheet

Uploaded by

Harshit Misra
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Exp 1

Burette : 0.1 N NaOH

10ml 0.1 N Oxalic Acid (H2C2O4) from pipette

2 drops of Phenolphthalein

Colorless to Pink

Reactions
B H2C2O4 + 2 NaOH→ Na2C2O4 + 2H2O

Std NaOH

10 ml HCL from pipette

2 drops of Phenolphthalein

Colorless to pink

Reactions 2 NaOH + HCl → NaCl + H2O

Exp 2 Mohr method to find chlorides in water sample

AgNO3 (sol) (unknown concentration)

0.01 N KCl (10 ml)

K2CrO4

Color Change
Yellow Brick red

Reactions : Standardization of AgNO3

AgNO3 + Cl- AgCl + NO3-


(White precipitate)

K2CrO4 + 2AgNO3 Ag2CrO4 + 2KNO3

(Brick Red precipitate)


B
AgNO3 (sol) (Standardized)

Sample of water (10 ml)

K2CrO4

Color Change Yellow Brick red

Reactions : Standardization of AgNO3

AgNO3 + Cl- AgCl + NO3-


(White precipitate)
K2CrO4 + 2AgNO3 Ag2CrO4 + 2KNO3

(Brick Red precipitate)

Exp 3 Complexometric titration with EDTA (determining hardness


of water’)
A

0.01 M ethylene diamine tetra acetic acid (EDTA)

10 ml water sample + 3 ml buffer solution

1-2 drops of Erichrome Black T (EBT)

Wine red to navy/peacock blue

Reactions M2+ + CBT [M-CBT] [M-EDTA] + [M-EBT]


(dye) (wine red) EDTA (Metal Ligand Complex)

[M-EDTA] + [M-EBT] [M-EDTA] [EBT]


(Metal Ligand Complex) EDTA (navy blue complex)

metal ligand complex jo intermediate banta hai usko stability milne ke kiye 10 pH ki jaroorat hoti hai

Uske liye pH 10 wala buffer use karte hai jo 1 mol NH4OH aur 1 mol NH4Cl ka mixture hota hai jisko
1 L water me add karte
B
0.01 M ethylene diamine tetra acetic acid (EDTA)

10 ml boiled water sample + 3 ml buffer solution

Indicator : 1-2 drops of Erichrome Black T (EBT)

Wine red to navy/peacock blue

Reactions M2+ + CBT [M-CBT] [M-EDTA] + [M-EBT]


(dye) (wine red) EDTA (Metal Ligand Complex)

[M-EDTA] + [M-EBT] [M-EDTA] [EBT]


(Metal Ligand Complex) EDTA (navy blue complex)

Exp 4 Determination of total alkalinity in water

(ml) (ml) (ml)

IN PIPETTE : 10 ml sample of given water

0.1 N HCl

Phenolphthalein and Methyl Orange


End Point : Colorless Pink (addition of phenolphthalein)

Pink Colorless (addition of HCl) [P end-point]

Colorless Yellow (Addition of Methyl Orange)

Yellow Orange (addition of HCl) [M end-point]


Reactions
1. OH-- + H+ H2O 2. CO32-- + H+ HCO3—

3. HCO3— + H+ H2CO3 4. H2CO3 CO2 + H2O

PART 2.
BURETTE
0.1 N HCl
50 ml sample of Tap water

Phenolphthalein and Methyl Orange

End-point : Colorless (addition of phenolphthalein)

Colorless Yellow (Addition of Methyl Orange)

Reactions Yellow Orange (addition of HCl) [M end-point]


2. OH-- + H+ H2O 2. CO32-- + H+ HCO3—

3. HCO3— + H+ H2CO3 4. H2CO3 CO2 + H2O

Exp 5 pH metric titration

0.5 N NaOH solution

10 ml HCl unknown concentration


Indicator :
2 drops of phenolphthalein
End point :
Colorless to Pink
Chemical reactions :
Observation:

i) In burette: 0.5 N NaOH

ii) In beaker: 50 ml HCl

iii) Chemical reaction: NaOH + HCl NaCl + H2O

Exp 6 colorimetry

Slope of graph = tan θ


Tanθ = opposite / adjacent
Tanθ = absorbance / concentration (molarity)
Tanθ = 0.28 / 0.00067
Slope = tan θ = 417.91 = 418

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