ACETYLENE, DISSOLVED

Ïðîåêò

ËÈÑÒ ÄÀÍÍÛÕ ÁÅÇÎÏÀÑÍÎÑÒÈ

1 Ìàðêèðîâêà âåùåñòâà (èëè ïðåïàðàòà) è ïîñòàâùèêà

Íàçâàíèå ïðîäóêòà: ACETYLENE, DISSOLVED
¹ ëèñòêà òåõíè÷åñêèõ äàííûõ: C2H2 1. 0. 0
Èñïîëüçîâàíèå âåùåñòâà/ïðåïàðàòà: Gas for welding and cutting
Íàçâàíèå ïîñòàâùèêà: Unitor ASA
Àäðåñ ïîñòàâùèêà: Willem Barentszstraat 50
3165 AB Rotterdam-Albrandswaard, The Netherlands

Òåëåôîí: +31 10 4877 777

Ôàêñ: +31 10 4877 888
Îòâåòñòâåííîå ëèöî: Leen de Visser, Corporate Product Safety Manager, Tel.: +31 6 538 63736
Íàçâàíèå ïðîèçâîäèòåëÿ: UNITOR ASA, Business Group Repair & Maintenance
Àäðåñ ïðîèçâîäèòåëÿ: P.O.Box 300, Skøyen, N-0212 Oslo, Norway
Òåëåôîí: +47 22 13 14 15
Òåëåôîí ýêñòðåííîé ïîìîùè: NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
CMA +1 703 527 3887, Greece +30 210 7793777

2 Ñîñòàâ/äàííûå î êîìïîíåíòàõ
Õèìè÷åñêîå íàçâàíèå Êîíöåíòðàöèÿ ¹ ïî CAS ¹ ÅÑ Ôàêòîðû îïàñíîñòè Îáîçíà÷åíèÿ
Acetylene, dissolved in
acetone, in porous mass >98 % 74-86-2 200-816-9 5, 6, 12 F+

3 Îïðåäåëåíèå èñòî÷íèêîâ îïàñíîñòè

- Çàïàõ: Ñèëüíûé çàïàõ ÷åñíîêà
- Âíåøíèé âèä: Ðàñòâîðåííûé ïîä äàâëåíèåì ãàç
- Ïîïàäàíèå â ãëàçà: Ìîæåò âûçâàòü ðàçäðàæåíèå, Íåïðàâèëüíàÿ èëè íåäîñòàòî÷íàÿ
çàùèòà ãëàç âî âðåìÿ ñâàðêè/ïàéêè ìîæåò ïðèâåñòè ê ïîâðåæäåíèþ ãëàç.
- Ïîïàäàíèå íà êîæó: Ìîæåò âûçâàòü ðàçäðàæåíèå
- Âäûõàíèå: Âäûõàíèå ïàðîâ îáðàçîâàííûõ âî âðåìÿ ñâàðêè è/èëè ðåçêè ìîæåò áûòü îïàñíûì.
- Ïðîãëàòûâàíèå: Not regarded as a potential route of exposure.
- Íàãðåâàíèå ìîæåò ïðèâåñòè ê âçðûâó (R5)
- Âçðûâîîïàñíî ïðè íàëè÷èè èëè îòñóòñòâèè êîíòàêòà ñ âîçäóõîì (R6)
- ×ðåçâû÷àéíî îãíåîïàñåí (R12)

×ðåçâû÷àéíî îãíåîïàñíûé

4 Ìåðû ïî îêàçàíèþ íåîòëîæíîé ïîìîùè

Ïîïàäàíèå íà êîæó
- Íå ðàññìàòðèâàåòñÿ â êà÷åñòâå ïîòåíöèàëüíîãî ïóòè ïðîÿâëåíèÿ.
Ïîïàäàíèå â ãëàçà
- Åñëè ó âàñ âîçíèêëè ñîìíåíèÿ èëè ñèìïòîìû íå ïðîõîäÿò, îáðàòèòåñü ê âðà÷ó

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Ïðîåêò

4 Ìåðû ïî îêàçàíèþ íåîòëîæíîé ïîìîùè (....)

Ïðîãàëàòûâàíèå
- Íå ðàññìàòðèâàåòñÿ â êà÷åñòâå ïîòåíöèàëüíîãî ïóòè ïðîÿâëåíèÿ.
Âäûõàíèå
- Âûíåñèòå ïîñòðàäàâøåãî íà ñâåæèé âîçäóõ
- Åñëè ó âàñ âîçíèêëè ñîìíåíèÿ èëè ñèìïòîìû íå ïðîõîäÿò, îáðàòèòåñü ê âðà÷ó
Îáùåå
- Ïðè íåñ÷àñòíîì ñëó÷àå èëè åñëè âû ïî÷óâñòâîâàëè íåäîìîãàíèå, íåìåäëåííî
îáðàòèòåñü ê âðà÷ó (ïîêàæèòå ýòèêåòêó, åñëè âîçìîæíî) (S45)

5 Ìåðû ïðîòèâîïîæàðíîé áåçîïàñíîñòè

- Òåìïåðàòóðà ñàìîâîçãîðàíèÿ 305 °C ïðè 760 ìì ðò. ñò.
- ×ðåçâû÷àéíî îãíåîïàñåí (R12)
- Ìîæåò îáðàçîâûâàòü âçðûâîîïàñíûå ïàðû/âîçäóøíûå ñìåñè
- Íå òóøèòü ïëàìÿ ãàçà ïðè óòå÷êå, åñëè â ýòîì íåò îñòðîé íåîáõîäèìîñòè.
Ñóùåñòâóåò îïàñíîñòü ïîâòîðíîãî âçðûâíîãî âîçãîðàíèÿ.
- Ïîñòîÿííî îõëàæäàéòå ãîðÿùèé êîíòåéíåð (êîíòåéíåðû), îáëèâàÿ åãî âîäîé
-  ñëó÷àå ñìåæíîãî âîçãîðàíèÿ îõëàæäàòü òàðó âîäÿíûì ðàñïûëåíèåì
- Ïî âîçìîæíîñòè ïåðåäâèæíóþ òàðó ñëåäóåò ïåðåìåñòèòü áåç ðèñêà
- Èíôîðìèðîâàòü áðèãàäó î ïîòåíöèàëüíîé îïàñíîñòè âçðûâà è âûëåòà áàëëîíîâ

6 Ìåðû ïî ïðåäîòâðàùåíèþ ñëó÷àéíîãî âûáðîñà

Èíäèâèäóàëüíûå ìåðû ïðåäîñòîðîæíîñòè
- Îòêëþ÷èòü âñå èñòî÷íèêè âîñïëàìåíåíèÿ
- Íå êóðèòü!
- Ìîæåò îáðàçîâûâàòü âçðûâîîïàñíûå ïàðû/âîçäóøíûå ñìåñè
- Ýâàêóèðîâàòü ïåðñîíàë èç çîíû
- Èçîëèðîâàòü èñòî÷íèê óòå÷êè, åñëè ýòî áåçîïàñíî
- Â çàìêíóòûõ ïðîñòðàíñòâàõ, êàíàëèçàöèè è ò.ï., èñïàðåíèÿ ìîãóò íàêàïëèâàòüñÿ,
îáðàçóÿ âçðûâîîïàñíûå ñîåäèíåíèÿ ñ âîçäóõîì
Ýêîëîãè÷åñêèå ìåðû ïðåäîñòîðîæíîñòè
- Ïðè îáðàùåíèè ñ äàííûì ïðîäóêòîì íå òðåáóåòñÿ ñîáëþäåíèÿ ñïåöèàëüíûõ
ìåð ïðåäîñòîðîæíîñòè
Ìåðû ïî î÷èñòêå
- Èçîëèðîâàòü èñòî÷íèê óòå÷êè, åñëè ýòî áåçîïàñíî
- Ïðîâåòðèòü ðàáî÷óþ çîíó

7 Ïîãðóçêà è õðàíåíèå
Ïîãðóçêà
- Èñïîëüçîâàòü òîëüêî â õîðîøî ïðîâåòðèâàåìûõ ïîìåùåíèÿõ (S51)
- Use proper hoisting equipment
- Õðàíèòü âäàëè îò èñòî÷íèêîâ âîçãîðàíèÿ - Íå êóðèòü! (S16)
- Ïðåäîõðàíÿòü îò óäàðîâ è òðåíèÿ (S34)
- Ñì. ïðåäîñòàâëåííóþ ïðîèçâîäèòåëåì èíôîðìàöèþ
- (Unitor welding handbook)
Õðàíåíèå
- Õðàíèòü â ïðîõëàäíîì, ñóõîì, õîðîøî ïðîâåòðèâàåìîì ìåñòå
- Òàðà ïîä äàâëåíèåì: ïðåäîõðàíÿòü îò ïîïàäàíèÿ ñîëíå÷íîãî ñâåòà, íå
íàãðåâàòü äî òåìïåðàòóðû âûøå 50°Ñ
- Äåðæàòü â ñòîðîíå îò îòêðûòîãî îãíÿ, ãîðÿ÷èõ ïîâåðõíîñòåé è èñòî÷íèêîâ âîñïëàìåíåíèÿ.

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Ïðîåêò

8 Ìåðû çàùèòû îò âîçäåéñòâèÿ, èíäèâèäóàëüíàÿ çàùèòà

Ïðåäåëû âîçäåéñòâèÿ
- TLV (TWA) 5 mg/m3 (Ïàðû âûäåëÿåìûå ïðè ñâàðêå)
Ìåðû çàùèòû îò âîçäåéñòâèÿ
- Îñîáûõ òðåáîâàíèé íåò
Ìåðû ïî çàùèòå îò âîçäåéñòâèÿ íà ðàáî÷åì ìåñòå
-  óñëîâèÿõ íåäîñòàòî÷íîé âåíòèëÿöèè âûñîêîé êîíöåíòðàöèè çàãðÿçíåíèÿ â âîçäóõå
íàäåòü ñîîòâåòñòâóþùèå ñðåäñòâà çàùèòû îðãàíîâ äûõàíèÿ ñ ïîëîæèòåëüíûì äàâëåíèåì
- Ïðè ðàáîòå ñ áàëëîíàìè îäåâàéòå áåçîïàñíóþ îáóâü.
- Ïðè ñâàðêå/ðåçêå îäåâàéòå î÷êè ñ ñîîòâåòñòâóþùèìè ñâåòîôèëüòðàìè.
- Íàäåòü êîæàíûå ïåð÷àòêè, áîòèíêè è ïåðåäíèê

9 Ôèçè÷åñêèå è õèìè÷åñêèå ñâîéñòâà

- Çàïàõ: Ñèëüíûé çàïàõ ÷åñíîêà
- Âíåøíèé âèä: Ðàñòâîðåííûé ïîä äàâëåíèåì ãàç
- pH - íå îòíîñèòñÿ
- Òåìïåðàòóðà êèïåíèÿ îò - 84 °C ïðè 760 ìì ðò. ñò.
- Ïëîòíîñòü ïàðà (âîçäóõ = 1) 0.9
- Òåìïåðàòóðà çàìåðçàíèÿ îò -84 °C ïðè 760 ìì ðò. ñò.
- Òåìïåðàòóðà ïëàâëåíèÿ îò - 81 °C ïðè 760 ìì ðò. ñò.
- Ðàñòâîðèìîñòü â âîäå 1.2 ã/ë
- ×ðåçâû÷àéíî îãíåîïàñåí (R12)
- Òåìïåðàòóðà ñàìîâîçãîðàíèÿ 305 °C ïðè 760 ìì ðò. ñò.
- Íèæíèé ïðåäåë âçðûâàåìîñòè 2.2 % (â âîçäóõå)
Âåðõíèé ïðåäåë âçðûâàåìîñòè >85 % (â âîçäóõå)

10 Ñòàáèëüíîñòü è ðåàêòèâíîñòü
- Decomposition, generation of heat and increased pressure may be caused by external heating,
flashback in burner or by ignition of a leak from a valve or regulator.
- Íå äîïóñêàòü ïåðåãðåâà
- Incompatible with silver, mercury, copper and their alloys containing more than 67% copper.

11 Òîêñèêîëîãè÷åñêàÿ èíôîðìàöèÿ
Òîêñèêîëîãè÷åñêàÿ èíôîðìàöèÿ
- Íåòîêñè÷åí
Âäûõàíèå
- Âäûõàíèå ïàðîâ îáðàçîâàííûõ âî âðåìÿ ñâàðêè è/èëè ðåçêè ìîæåò áûòü îïàñíûì.
-  ñëó÷àÿõ èíòåíñèâíîãî âîçäåéñòâèÿ ìîæåò ðàçâèâàòüñÿ çàòðóäíåíèå äûõàíèÿ
- Óäóøàþùèé ãàç
Ïîïàäàíèå íà êîæó
- Ìîæåò âûçâàòü ðàçäðàæåíèå
Ïîïàäàíèå â ãëàçà
- Ìîæåò âûçâàòü ðàçäðàæåíèå

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Ïðîåêò

11 Òîêñèêîëîãè÷åñêàÿ èíôîðìàöèÿ (....)

Ïðîãàëàòûâàíèå
- Íå ðàññìàòðèâàåòñÿ â êà÷åñòâå ïîòåíöèàëüíîãî ïóòè ïðîÿâëåíèÿ.
Êàíöåðîãåííîñòü
- Ïðèçíàêîâ êàíöåðîãåííîãî ýôôåêòà íå îáíàðóæåíî

12 Ýêîëîãè÷åñêàÿ èíôîðìàöèÿ
Ýêîòîêñè÷íîñòü
- Ñîãëàñíî èìåþùèìñÿ äàííûì âåùåñòâî íå íàíîñèò âðåäà âîäíîé ñðåäå
Ïîäâèæíîñòü
- Äàííîå âåùåñòâî ëåãêî èñïàðÿåòñÿ
Ñòîéêîñòü è ñïîñîáíîñòü ê áèîëîãè÷åñêîìó ðàçëîæåíèþ
- Íå îòíîñèòñÿ
Ñïîñîáíîñòü ê áèîàêêóìóëÿöèè
- Íå îòíîñèòñÿ
Äðóãèå íåáëàãîïðèÿòíûå ýôôåêòû
- Íå ïðåäñòàâëÿåò îïàñíîñòè äëÿ îêðóæàþùåé ñðåäû

13 Ðåêîìåíäàöèè ïî óòèëèçàöèè
Ðåêîìåíäàöèè ïî óòèëèçàöèè
- Îáðàòèòåñü ê ïîñòàâùèêó çà áîëåå ïîäðîáíîé èíôîðìàöèåé

14 Èíôîðìàöèÿ î òðàíñïîðòèðîâêå

Flammable Gas

UN
Ïîëíîå íàèìåíîâàíèå ãðóçà: Acetylene, dissolved
¹ UN: 1001

Êëàññ îïàñíîñòè: 2.1 Ãðóïïà óïàêîâêè: N/A

Íàçåìíûé/æåëåçíîäîðîæíûé (ADR/RID)
Ïîëíîå íàèìåíîâàíèå ãðóçà: Acetylene, dissolved
¹ ADR UN: 1001

Êëàññ îïàñíîñòè ADR: 2 Tremcard: 20S1001

Ìîðñêîé (IMDG)
Ïîëíîå íàèìåíîâàíèå ãðóçà: Acetylene, dissolved
¹ IMDG UN: 1001

Êëàññ îïàñíîñòè IMDG: 2.1 Ãðóïïà óïàêîâêè IMDG: N/A

IMDG EmS (àâàðèéíûå ãðàôèêè): F-D, S-U

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14 Èíôîðìàöèÿ î òðàíñïîðòèðîâêå (....)

IMDG subrisk: N/A

IMDG labels: 2.1 IMDG Flashpoint: N/A

Âîçäóøíûé (ICAO/IATA)
Ïîëíîå íàèìåíîâàíèå ãðóçà: Acetylene, dissolved
¹ ICAO Un: 1001

Êëàññ îïàñíîñòè ICAO: 2.1 Ãðóïïà óïàêîâêè ICAO: N/A

ICAO subrisk: N/A ICAO Labels: 2.1

ICAO Flashpoint: N/A

DOT / CFR (US Department of Transportation
DOT Proper Shipping Name: Acetylene, dissolved
Hazardous Material: Acetylene

Hazard Class: 2.1 Identification Number: UN 1001

Product RQ (lbs): N/A DOT subrisk: N/A

DOT labels: 2.1 DOT Flashpoint: N/A

- Ãàçîâûå áàëëîíû ïðè òðàíñïîðòèðîâêå äîëæíû áûòü ñíàáæåíû çàùèòíûì êîëïàêîì êëàïàíà.

15 Íîðìàòèâíàÿ èíôîðìàöèÿ

×ðåçâû÷àéíî îãíåîïàñíûé

Ôàêòîðû îïàñíîñòè
- Íàãðåâàíèå ìîæåò ïðèâåñòè ê âçðûâó (R5)
- Âçðûâîîïàñíî ïðè íàëè÷èè èëè îòñóòñòâèè êîíòàêòà ñ âîçäóõîì (R6)
- ×ðåçâû÷àéíî îãíåîïàñåí (R12)
Ôàêòîðû áåçîïàñíîñòè
- Õðàíèòü òàðó â õîðîøî ïðîâåòðèâàåìîì ïîìåùåíèè (S9)
- Õðàíèòü âäàëè îò èñòî÷íèêîâ âîçãîðàíèÿ - Íå êóðèòü! (S16)
- Ïðèíÿòü ìåðû ïî çàùèòå îò ñòàòè÷åñêîãî ýëåêòðè÷åñòâà (S33)

16 Äðóãàÿ èíôîðìàöèÿ
(R12: ×ðåçâû÷àéíî îãíåîïàñåí. R5: Íàãðåâàíèå ìîæåò ïðèâåñòè ê âçðûâó. R6:
Âçðûâîîïàñíî ïðè íàëè÷èè èëè îòñóòñòâèè êîíòàêòà ñ âîçäóõîì.)

Èíôîðìàöèÿ, ïðåäîñòàâëåííàÿ î ïðîäóêòå â äàííîì ëèñòå äàííûõ áåçîïàñíîñòè, îñíîâàíà

íà çíàíèè ñâîéñòâ îòäåëüíûõ êîìïîíåíòîâ
Ïðåäñòàâëåííûå çäåñü äàííûå îñíîâàíû íà òåêóùèõ çíàíèÿõ è îïûòå. Â ýòîì ëèñòå
äàííûõ áåçîïàñíîñòè îïèñàí ïðîäóêò ñ òî÷êè çðåíèÿ òðåáîâàíèé áåçîïàñíîñòè, ëèñò
äàííûõ áåçîïàñíîñòè íå äàåò íèêàêèõ ãàðàíòèé îòíîñèòåëüíî ñâîéñòâ ïðîäóêòà.
Ïðåäñòàâëåííûå çäåñü äàííûå âåðíû òîëüêî â ñëó÷àå ñîîòâåòñòâóþùåãî
èñïîëüçîâàíèÿ ïðîäóêòà. Ïðîäóêò íå ïðîäàåòñÿ â êà÷åñòâå ïîäõîäÿùåãî äëÿ äðóãèõ öåëåé
- òàêîå èñïîëüçîâàíèå ìîæåò ïðèâåñòè ê ðèñêàì, íå óêàçàííûì â äàííîì ëèñòå.
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Ïðîåêò

16 Äðóãàÿ èíôîðìàöèÿ (....)

Çàïðåùàåòñÿ èñïîëüçîâàíèå â äðóãèõ öåëÿõ áåç êîíñóëüòàöèè ñ ïðîèçâîäèòåëåì.
Ýòîò ëèñò äàííûõ áåçîïàñíîñòè ïðåäîñòàâëåí â ñîîòâåòñòâèè ñ Äèðåêòèâîé
îòíîñèòåëüíî îáðàùåíèÿ ñ îïàñíûìè âåùåñòâàìè (67/548/EEC) (The Dangerous
Substances Directive (67/548/EEC))
Ýòîò ëèñò äàííûõ áåçîïàñíîñòè ïðåäîñòàâëåí â ñîîòâåòñòâèè ñ Äèðåêòèâîé
îòíîñèòåëüíî îáðàùåíèÿ ñ îïàñíûìè ïðåïàðàòàìè (88/379/EEC) (The Dangerous
Preparations Directive (88/379/EEC))
Ýòîò ëèñò äàííûõ áåçîïàñíîñòè ïðåäîñòàâëåí â ñîîòâåòñòâèè ñ Äèðåêòèâîé
îòíîñèòåëüíî ëèñòîâ äàííûõ áåçîïàñíîñòè (2001/58EC)

Äàòà ïîñëåäíåãî èçìåíåíèÿ 23-03-05 6