Note 3 C
Note 3 C
A metal contains a large number of free electrons which are free to move about in entire
volume of the metal like the molecules of a gas in a container.
The fre electrons move in random directions and collide with either positive ions fixed in
the lattice or other free electrons. All the electrons are elastic and there is no loss of energy.
The velocity and the energy distribution of free electrons obey the classical Maxwell
Boltzmann statistics.
The free electrons are moving in a completely uniform potential field due to the ions fixed
in the lattice.
In the absence of electric field the random motion of free electrons is equally probable in all
directions so that the current density vector is zero.
When the external electric field is applied across the ends of a metal, the electrons drift
slowly with some average velocity known as drift velocity in the direction opposite to that
of electric field. This drift velocity is superimposed over the random velocity. This drift
velocity is responsible for the flow of electric current in a metal.
Drift velocity
The average velocity of the free electrons with which they move towards the positive terminal
under the influence of the electrical field.
Mobility
It is defined as the drift velocity of the charge carrier per unit applied electric field.
1
Collision time
The average time taken by a free electron between two successive collisions is called collision time.
The average distance travelled by a free electron between two successive collisions is called mean
free path.
Relaxation time
It is defined as the time taken by a free electron to reach its equilibrium position from the disturbed
position in the presence of an electric field.
Electrical conductivity.
Electrical conductivity is defined as the rate of charge flow across unit area in a conductor
per unit potential (voltage) gradient.
J
= . Its unit is -1m-1 or Sm-1.
E
Expression for the electrical conductivity.
When an electrical field (E) is applied to an electron of charge ‘e’ of a metallic rod, the electron
moves in opposite direction to the applied field with a velocity vd. This velocity is known as drift
velocity.
Lorentz force acting on the electron F = eE……..(1)
d a ......(4)
Substituting equation (3) in (4)
2
e
d E .........( 5 )
m
The Ohms’ law states that current density (J) is expressed as
J
J Eor .....(6)
E
Where is the electrical conductivity of the electron.
But, the current density in terms of drift velocity is given as
J = nevd ……. (7)
Substituting equation (5) in equation (7), we have
e
J ne E
m
J ne 2
or .....(8)
E m
On comparing the equation (6) and (8) , we have
ne 2
Electrical conductivity .....(9)
m
Thermal conductivity
Thermal conductivity K is defined as the amount of heat flowing per unit time through the
dT
material having unit area of cross-section per unit temperature gradient. Q = K .
dx
Expression for Thermal Conductivity of a Metal
Consider two cross-sections A and B in a uniform metallic rod AB separated by a distance
λ. Let A at a high temperature (T) and B at low temperature (T-dT). Now heat conduction takes
place from A and B by the electrons.The conduction electron per unit volume is n and average
velocity of these electrons is v. During the movement of electrons in the rod, collision takes place.
Hence, the electrons near A lose their kinetic energy while electrons near B gain kinetic energy.
3
At A, average kinetic energy of an electron = kT ....(1)
2
3
At B, average kinetic energy of the electron = k (T dT )....(2)
2
3
The excess of kinetic energy carried by the electron from A to B is,
3
kdT .......(3)
2
Number of electrons crossing per unit area per time from A and B is,
1
n
6
1
The excess of energy carried form (A to B) per unit area in unit time is = nkdT ....(4)
4
Similarly, the deficient of energy carried from B to A per unit area per unit time is
1
= nkdT .....(5)
4
Hence, the net amount of energy transferred from A to B per unit area per unit time is,
1
Q= nkdT .....(6)
2
But from the basic definition of thermal conductivity, the amount of heat conducted per unit area
per unit time is,
dT 1 dT 1
Q= K i.e., nvkdT K ; K nk.....(7)
2 2
We know that for the metals i.e. c ......(8)
Substituting the equation (8) in equation (7), we have
1 2
K= n k .....(9)
2
We know that,
ne 2
......(1) and
m
1
K= n 2 k .....( 2 )
2
4
1
n 2 k
Thermal .conductivi ty K 2 k 1 m 2 k
; ......( 3 )
Electrical .conductivi ty ne 2 2 e2
m
We know that the kinetic energy of an electron,
1 3
m 2 kT ......(4)
2 2
Substituting the equation (4) in the equation (3). We have
2
k 3 kT k 3 k 2T K 3 k K
2
2
, or T , or LT .....(5)
2 e 2 e 2 e
2
3 k
Where L = is a constant and it is known as Lorentz number.
2 e
K
∝T ….(6)
Hence, it is proved that the ratio of thermal conductivity of a metal is directly proportional to the
absolute temperature of the metal.
5
Thus at T = 0K, there is 100 % chance for the electrons to occupy the energy levels below
the Fermi level.
At ordinary temperature, the value of probability starts reducing from 1 for values of E slightly less
than EF. With the increase of temperature, i.e., T> 0K, Fermi function F (E) varies with E.
At any temperature other than 0K and E = EF’
1 1 1
F ( E) 0
50%
1 e 11 2
Hence, there is 50 % chance for the electrons to occupy Fermi level. Further, for E > EF the
probability value falls off rapidly to zero.
When kT >> EF, the electrons lose their quantum mechanical character and Fermi distribution
function reduces to classical Boltzmann distribution.
6
Density of energy states.
1 4 1 4 3 1 4
N (E) dE = 8 3
3
( n dn)
8 3
n
8 3
3
( n dn) n
3
7
N ( E ) dE n 3 dn 3 3n 2 dn 3ndn 2 n 3
6
Since dn is very small, higher powers of dn terms dn2 and dn3 can be neglected.
2
N (E) dE = 3n dn N ( E ) dE n 2 dn N ( E ) dE n( ndn)......(4)
6 2 2
We know that the energy of an electron in a cubical metal piece of sides ‘a’ is given by
1/ 2
n 2h 2 2 8ma 2 E 8ma 2 E
E ...(5) or ; ; n .....(6) or ; ; n .....(7 )
8ma 2 h2 h
2
Differentiating the equation (6), we get
8ma 2 dE 8ma 2 dE
2ndn = or ; ndn .....(8)
h2 h2
Substituting equations (7) and (8) in equation (4), we have
1/ 2 1/ 2
8ma2 E 8ma2 dE 1 8ma2 E 8ma2 dE
N (E)dE
2 h 2 2h 2 2 2 2h 2 h 2
1/ 2 3/2
8ma 2 1/ 2 8ma 2 8ma 2
2 E 2 dE N ( E ) dE 2 E 1 / 2 dE ....(10)
4 h h 4 h
Pauli’s exclusion states principle states that two electrons of opposite spins can occupy each state
and hence the number of energy states available for electron occupancy is given by
3/2 3/ 2
8ma 2 1/ 2 8m
N ( E )dE 2 2 E dE 2 a 3 E 1 / 2 dE
4 h 2h
3
a3 a
(8m) 3 / 2 3 E 1 / 2 dE N ( E )dE (8m) 3 / 2 E 1 / 2 dE
2 h 2 h
3
a 3 / 2 1/ 2 4 3 / 2 3 1/ 2
N ( E )dE 8(2m) E dE 3 (2m) a E dE
2 h h
Density of states is given by the number of energy states per unit volume,
N ( E ) dE
Z ( E ) dE
V
4
3 ( 2m ) 3 / 2 a 3 E 1 / 2 dE
i.e., Density.of .states.Z ( E ) dE h 3
; ; [Volume.V a 3 ]
a
4
Z ( E ) dE 3 ( 2m) 3 / 2 E 1 / 2 dE.......(11)
h
This is the expression for the density of charge carriers in the energy interval E and E + dE.
8
Carrier Concentration: Carrier Concentration, i.e., the number of electrons per unit volume
in a given energy interval is calculated by assuming the product of the density of states Z (E)
and the occupancy probability F (E).
i.e. nc = Z ( E ) F ( E )dE
Substituting the expressions for Z (E) and F (E), we have
4 1
nc 3
( 2 m) 3 / 2 E 1 / 2 ( E E F ) / kT
dE......(12)
h 1 e