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DPP For Jee Daily Practice Problems CH 2: Structure of Atom: Part-I (Single Correct MCQS) 1

This document provides 25 practice problems related to atomic structure and quantum mechanics. The problems cover topics like electron configurations, ionization energies, atomic spectra, de Broglie wavelength, and photon energy. Multiple choice and numeric response questions are included to test conceptual understanding and calculations.

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143 views8 pages

DPP For Jee Daily Practice Problems CH 2: Structure of Atom: Part-I (Single Correct MCQS) 1

This document provides 25 practice problems related to atomic structure and quantum mechanics. The problems cover topics like electron configurations, ionization energies, atomic spectra, de Broglie wavelength, and photon energy. Multiple choice and numeric response questions are included to test conceptual understanding and calculations.

Uploaded by

hcvy7zbjs6
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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DPP FOR JEE

DAILY PRACTICE PROBLEMS


CH 2: STRUCTURE OF ATOM

PART-I (Single Correct MCQs)

1. Among the following groupings which represents the collection of


isoelectronic species?
(a)
(b)
(c)
(d)
2. The compound in which cation is isoelectronic with anion is :
(a) NaCl
(b) CsF
(c) NaI
(d) K2S
3. The frequency of light emitted for the transition n = 4 to n = 2 of the
He+ is equal to the transition in H atom corresponding to which of the
following ?
(a) n = 2 to n = 1
(b) n = 3 to n = 2
(c) n = 4 to n = 3
(d) n = 3 to n = 1
4. In hydrogen atomic spectrum, a series limit is found at 12186.3 cm–1.
Then it belong to
(a) Lyman series
(b) Balmer series
(c) Paschen series
(d) Brackett series
5. Two fast moving particles X and Y are associated with de Broglie
wavelengths 1 nm and 4 nm respectively. If mass of X is nine times the
mass of Y, the ratio of kinetic energies of X and Y would be
(a) 3 : 1
(b) 9 : 1
(c) 5 : 12
(d) 16 : 9
6. The ratio of magnetic moments of Fe(III) and Co(II) is
(a) 7 : 3
(b) 3 : 7
(c) :
(d) :
7. The values of Planck’s constant is 6.63 × 10–34 Js. The velocity of light
is 3.0 × 108 m s–1. Which value is closest to the wavelength in
nanometres of a quantum of light with frequency of 8 × 1015 s–1?
(a) 5 × 10–18
(b) 4 × 101
(c) 3 × 107
(d) 2 × 10–25
8. Li and a proton are accelerated by the same potential, their de Broglie
wavelengths λLi and λp have the ratio (assume mLi = 9mp)
(a) 1 : 2
(b) 1 : 4
(c) 1 : 1
(d)
9. If uncertainty in position and momentum are equal, then uncertainty in
velocity is :

(a)

(b)

(c)

(d)

10. Ionisation energy of He+ is 19.6 × 10–18 J atom–1. The energy of the first
stationary state (n = 1) of Li2+ is
(a) 4.41 × 10–16 J atom–1
(b) –4.41 × 10–17 J atom–1
(c) –2.2 × 10–15 J atom–1
(d) 8.82 × 10–17 J atom–1
11. The kinetic energy of an electron in the second Bohr orbit of a
hydrogen atom is [a0 is Bohr radius] :

(a)

(b)

(c)

(d)

12. If the nitrogen atom had electronic configuration 1s7 it would have
energy lower than that of the normal ground state configuration 1s2 2s2
2p3 because the electrons would be closer to the nucleus. Yet 1s7 is not
observed. It violates
(a) Heisenberg’s uncertainty principle
(b) Hund’s rule
(c) Pauli exclusion principle
(d) Bohr postulate of stationary orbits
13. In a hydrogen atom, if energy of an electron in ground state is 13.6. ev,
then that in the 2nd excited state is
(a) 1.51 eV
(b) 3.4 eV
(c) 6.04 eV
(d) 13.6 eV.
14. The limiting line in Balmer series will have a frequency of
(Rydberg constant, R∞ = 3.29 × 1015 cycles/s)
(a) 8.22 × 1014 s–1
(b) 3.29 × 1015 s–1
(c) 3.65 × 1014 s–1
(d) 5.26 × 1013 s–1
15. If the radius of first orbit of H atom is a0, the de-Broglie wavelength of
an electron in the third orbit is
(a) 4πa0
(b) 8πa0
(c) 6πa0
(d) 2πa0
16. Which of the following radial distribution graphs correspond to l = 2
for the H atom ?

(a)

(b)

(c)
(d)

17. If the kinetic energy of an electron is increased four times, the


wavelength of the de-Broglie wave associated with it would become
(a) one fourth
(b) half
(c) four times
(d) two times
18. The correct set of four quantum numbers for the valence electrons of
rubidium atom (Z = 37) is:
(a)

(b)

(c)

(d)

19. If λo and λ be threshold wavelength and wavelength of incident light,


the velocity of photoelectron ejected from the metal surface is:

(a)

(b)

(c)
(d)

20. If m and e are the mass and charge of the revolving electron in the orbit
of radius r for hydrogen atom, the total energy of the revolving electron
will be:

(a)

(b)

(c)

(d)

PART-II (Numeric / Integer Type Questions)

21. The ionization enthalpy of hydrogen atom is 1.312 × 106 J mol–1. What
is the energy (in kJ mol–1) required to excite the electron in the atom
from n = 1 to n = 2?

22. Energy of an electron is given by E = – 2.178 ×

What is the wavelength (in Å unit) of light required to excite an electron in an


–34
hydrogen atom from level n = 1 to n = 2 will be : (h = 6.62 × 10 Js
and c = 3.0 × 108 ms–1)
23. The dissociation energy of H2 is 430.53 KJ mol–1. If hydrogen is
dissociated by illumination with radiation of wavelength 253.7 nm, then
calculate the percentage fraction of the radiant energy which will be
converted into kinetic energy.
24. What is the de-Broglie wavelength (in nm) of an electron in the ground
state of hydrogen atom is ?
[K.E. = 13.6 eV; 1eV = 1.602 J]
25. The energy required to break one mole of Cl – Cl bonds in Cl2 is 242 kJ
mol–1. What is the longest wavelength of light capable of breaking a
single Cl – Cl bond ?
(c = 3 × 108 ms–1 and NA = 6.02 × 1023 mol–1).

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