Omega Competitive Classes

(AN IDEAL PAD FOR DEDICATED STUDENTS PREPARING FOR +1, +2, NCERT, JEE & NEET)

DURATION: 60 Minutes DATE: 08/04/2024 M.MARKS: 720

Code-A
Topic Covered

Chemistry : GOC

GENERAL INSTRUCTION
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 1 hours duration.
3. The test booklet consists of 200 questions. The maximum marks are 180.
4. There is only one correct response for each question.
5. Each correct answer will give 4 marks while 1 Mark will be deducted for a wrong MCQ response.
6. No student is allowed to carry and textual material, printed or written, bits of papers, pager, mobile phone,
any electronic device, etc. inside the examination room/hall.
7. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
 SECTION-II (CHEMISTRY)
SECTION – A 56. Most stable carbocation is:
 
51. Wrong statement regarding methyl carbonium ion CH2 CH2

(CH3) is :
(1) It is sp2 hybridised (1) (2)
(2) Vacant orbital is sp2 hybridised
(3) Vacant orbital is perpendicular to molecular
Cl NO2
planar and in pure p-orbital  
(4) It is electrophile with sextet of electron CH2 CH2

52. Most stable carbanion is: (3) (4)

 
(1) HC  C (2) H2C = CH
CH3 OCH3
 
(3) H3 C – C – CH2 (4) CH3 – C = CH 57. In which σ bond, the inductive effect is minimum?
C – C – C – C – Cl
CH3 CH3 (d) (c) (b) (a)
(1) a (2) b
(3) c (4) d
53. Which of the following has maximum pKa ?
(1) CH2FCOOH (2) CH3C1COOH 58. Arrange in decreasing order of basic strength:
NH2
(3) CH3COOH (4) HCOOH
NH2
54. Which of the following show + I-effect? I. II.
(l) –OH (2) –OCH3
(3) –CH3 (4) –Cl NO2
NH2 NH2
55. Which of the following acids is stronger than
acetic acid?
III. IV.
(1) Propanoic acid
(2) Formic acid
(3) Butyric acid CHO CH3
(4) Iso butyric acid (1) I > II > III > IV (2) II > III > I > IV
(3) IV > I > III > II (4) IV > I > II > III
Space for Rough Work

[8]
59. Which is incorrect stability order? 62. Select the correct option for stability of following
  carbanions:
(1) CH2 = CH – CH2 > CH3 – CH – CH3
 
  I. CH3 II. C6H5CH2
(2) CH2 = CH < CH3 – CH2
  CH3
(3) CH3 – CH2 – CH2 > CH3 – CH – CH3

  III. CH3 – C
(4) CH3 – CH2 > CH3O – CH2
CH3
60. The most stable carbanion among the following is:
 (1) I > II > III (2) II > I > III
CH2 – CH2 (3) III > II > I (4) II > III > I
(1)
63. Four structure are given in options (a) to (d).

Examine them the select the aromatic structures.
CH2
(2)
(a)  (b)

CH2
(c) (d) 

(3) (1) a and d (2) b and c

(3) a and b (4) a and c

OCH3 64. Phenol is less acidic than

 (1) Ethanol (2) o-Nitrophenol
CH2
(3) o-Methylphenol (4) o-Methoxyphenol

(4) 65. Which of the following is least stable?


(1) CH3 – CH – CH3

NO2 (2) CH3 – CH2 – CH2

(3) CH3 – C – CH3
61. Among the following the aromatic compound is:

(1) (2) CH3

CH3

 
(4) CH3 – C – CH – CH
6 5
(3) (4)
CH3

Space for Rough Work

[9]
66. Which of the following is most stable alkene? 69. Which of the given compounds can exhibit
H H tautomerism?
(1) C=C H3 C CH3
H H CH3
CH3 H I. II. CH3
(2) C=C
H H
H5C2 H O O
(3) C=C
H H III. CH3
CH3 CH3
CH H
(4) CH3 C=C O
H H (1) I and III
(2) II and III
67. Tautomerism is not observed in: (3) I, II and III
(1) (4) I and II

70. Correct order of Kb is:

(2) Ph – CH = CH – OH CH2NH2
(3) CH3 – NO2
CH3 I.
(4) CH3 – C – CHO NH2

CH3
II.
68. Stability of carbanions in the following.
III. CH3CH2 – NH2

 IV. H3C – C – NH2
(a) RC  C (b)

 
O
(c) R2C = CH (d) R3C – CH2 (1) IV > III > II > I
is in the order of: (2) III > I > II > IV
(1) (d) > (b) > (c) > (a) (2) (a) > (c) > (b) > (d) (3) I > II > III > IV
(3) (a) > (b) > (c) > (d) (4) (b) > (c) > (d) > (a) (4) II > III > IV > I

Space for Rough Work

[10]
71. The correct statement regarding the basicity of 73. Which of the following carbon has most acidic
arylamines is:
hydrogen?
(1) Arylamines are generally less basic than
alkylamines because the nitrogen lone-pair O
electrons are delocalized by interaction with CH3 – CH2 – CH2 – C – H
4 3 2 1
the aromatic ring π electron system.
(2) Arylamines are generally more basic than (1) C1 – H
alkylamines because the nitrogen lone-pair
(2) C2 – H
electrons are not delocalized by interaction
with the aromatic ring π electron system. (3) C3 – H
(3) Arylamines are generally more basic than
alkylamines because of aryl group. (4) C4 – H

(4) Arylamines are generally more basic than

alkylamines, because the nitrongen atom in
arylamines is sp-hybridized. 74. Which is an example of +E effect?

H 
(1) C =C C –C
72. Statement-I : The acidic strength of
monosubstituted nitrophenol is higher than phenol H
because of electron withdrawing nitro group. 
CN
Statement II : o-nitrophenol, m-nitrophenol and (2) C =O C – O
p-nitrophenol will have same acidic strength as
they have one nitro group attached to the phenolic CN
ring. 

OH
(1) Both Statement I and Statement II are (3) CCl3 – CH = CH2 CCl3 – CH – CH2
incorrect. OH
(2) Statement I is correct but Statement II is
Cl Cl
incorrect.
OH
(3) Statement I is incorrect but Statement II is 

OH
correct (4)
(4) Both Statement I and Statement II are correct

Space for Rough Work

[11]
75. Arrange the following derivatives of carboxylic 76. In which delocalisation of positive charge is
possible?

acid in their increasing order of their acidity. NH3
H H
N

COOH COOH COOH (1) (2)

 
(1) < < OH2 O


OCH3 NO2 (3) (4)

COOH COOH COOH 77. The correct stability order of given resonating
structures is:
(2) > >
I.

OCH3 NO2
II.
COOH COOH COOH
III.
(3) > <

IV.
OCH3 NO2
(1) I > II > III > IV (2) IV > III > II > I
COOH COOH COOH (3) I = II = III = IV (4) II = III > I = IV


(4) = < 78. H3C – CH – CH = CH2 does not involve:
(1) -p overlap (2) -* overlap
(3) p-p overlap (4) p-d overlap
OCH3 NO2

Space for Rough Work

[12]
79. If the given compound is planar. Select the correct 81. Observe the following compound and write the
statement. number of hydrogen atom involved in
hyperconjugation?

B – CH3

(1) The boron is sp2 hybridized and the p-orbital

contains an unshared pair of electron (1) 6 (2) 3
(2) The boron is sp2 hybridized and a hybrid (3) 9 (4) 8
orbital contains an unshared pair of electron.
(3) The boron is sp2 hybridized and a hybrid 82. Find the total number of positions where positive
charge can be delocalized by true resonance
orbital is vacant
CH2
(4) The boron is sp2 hybridized and the p-orbital 
CH3 – CH – CH = CH – C –
is vacant
(Excluding the given position)
(1) 2 (2) 3
80. How many groups (attached with benzene ring)
(3) 6 (4) 5
can show +M effect?
O
83. Which of the following is incorrect?
NH2 SH C–H
(1) is nonaromatic
, , ,

  (2) is aromatic
NH3 F O

, ,
(3) is aromatic

(1) 4 (2) 5
(3) 6 (4) 3 (4) is aromatic

Space for Rough Work

[13]
84. The correct orders for bond length is: 88. Urea molecule exhibits
CH3 CH3
a a’

(1) (a’ > a) (isomerism):

(1) Chain (2) Position
b
(2) CH3–C–NH2 (b’<b) (3) Geometrical (4) Tautomerism
b’
NH2


c 89. Consider the following free radicals.

(3) CH3–C–ONa (c < c’) CH3
c’
O I. CH3 – C – CH
(4) d d’ (d = d’)
CH3
85. Which of the following species is an electrophile? Ph
(1) RNH2 (2) SO3
(3) NO3 (4) ROH II. Ph – C – Ph

SECTION – B III.
86. The non-aromatic compound among the following CH3
is: Hyperconjugation occurs in:
(1) (2) (1) II only (2) III only
S (3) I and III (4) I only

(3) (4)
90. The correct order of strengths of the carboxylic
 acids
COOH COOH
87. Which statement is incorrect?
I. II.
(1) The energy of actual structure of the molecule
is lower than that of any canonical structure. O
(2) The energy difference between actual COOH
structure and least energy resonance structure III.
is called as resonance energy. O
(3) More number of resonating structure, more is:
resonance.
(1) III > II > I (2) II > I > III
(4) In equivalent resonance structure of acetate
ion the (C–O) bond lengths are unequal. (3) I > II > III (4) II > III > I

Space for Rough Work

[14]
91. Incorrect statement with respect to P and Q is: 94. Which bond is more polar in following pair?
NH2 (a) CH3 – Br > CH3 – H
(b) CH3 – NH2 < CH3 – OH
(c) CH3 – F > CH3 – Cl
(P) (1) a, c only (2) a, b, c
H5 C2 C2 H5 (3) a, b only (4) b, c only
NO2
95. The most unlikely representation of resonance
NH2
structures of p-nitrophenoxide ion is:
–
H5 C2 C2 H5 O +
O
(Q) N

(1)
NO2
(1) –NO2 in (P) has inductive effect
–
(2) –NO2 in (Q) has stronger (–M) effect group O
–
O O–
(3) –NO2 in (P) has stronger (–M) effect group +
N
(4) –NO2 in (Q) has (–I) effect
(2)
92. Which of the following is the most stable
carbocation?
 O
(1) (2) O +
O
 N

(3) (4) (3)


–
93. Which cation have no resonance with lone pair? O
–
  O +
O
N
(1) (2)
OCH3 O (4)
  
(3) (4)
NH N
O
Space for Rough Work

[15]
96. Decreasing order of potential energy of the 99. The correct order of +M effect of ‘N’ containing
following cation is: functional group on benzene ring, amongst the
 given compound is:
OH
CH3 I. NH2
I. CH3 – C – N
CH3 CH3
OH II. N
CH3 CH3
II. CH3 – C – N H
 CH3 III. N CH3
OH C

CH3
III. CH3 – C = N O
CH3 O
(1) II > I > III (2) I > II > III
(3) III > II > I (4) II > III > I C – CH3
IV. N
97. Stability order of the following species? C – CH3
 
NH NH NH
O
(1) I > II > IV > III (2) II > I > III > IV
C C C (3) I > II > III > IV (4) IV > III > II > I

O S O S 
O S
100. Select the correct order of heat of hydrogenation?
I II III
(1) I > II > III (2) III > I > II
(3) III > II > I (4) I > III > II I.
98. Which of the following is correct about
 
O O
II.
dianion?
O O
(1) In the dianion all the C – C bonds are of same III.
length but all C – O bonds are different length
(2) In the dianion all C – C bonds are of same
length and also all C – O bonds are of same
lengths IV.
(3) In the dianion all C – C bonds are of not a
same length (1) I > II > III > IV (2) IV > III > II > I
(4) None of the above (3) II > III > IV > I (4) II > III > I > IV

Space for Rough Work

[16]