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17.03.24 - SR - Star Co-Sc - Jee-Adv - 2016 - P1 - Gta-1 (P1) - QP

The document describes a test for JEE Advanced containing questions in Mathematics, Physics, and Chemistry. It provides the marking scheme and sections for each subject. The test has a total duration of 3 hours and contains multiple choice and integer answer type questions.

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0% found this document useful (0 votes)
105 views16 pages

17.03.24 - SR - Star Co-Sc - Jee-Adv - 2016 - P1 - Gta-1 (P1) - QP

The document describes a test for JEE Advanced containing questions in Mathematics, Physics, and Chemistry. It provides the marking scheme and sections for each subject. The test has a total duration of 3 hours and contains multiple choice and integer answer type questions.

Uploaded by

ipsita lahiri
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 16

Sec: SR.

IIT_*CO-SC Date: 17-03-24


Time: 3HRS Max. Marks: 198

Name of the Student: ___________________ H.T. NO:

17-03-24_SR.STAR CO-SUPER CHAINA_JEE-ADV_GTA-1(P1)_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEMATICS: TOTAL SYLLABUS


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 23) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 24 – 31) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 32 – 36) Questions with Integer Answer Type 3 0 5 15
Total 18 62

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 41) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 42 – 49) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 50 – 54) Questions with Integer Answer Type 3 0 5 15
Total 18 62

OSR.IIT_*CO-SC Page. No. 2


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. The incircle of ABC touches the sides BC, CA, AB at D, E, F respectively and let 1, 2,

3 be the lengths of portions of tangents, inside the ABC, drawn to the incircle parallel

to BC, CA, AB respectively. If AF = 3, BD = 5, CE = 4, then [1 + 2 + 3] is equal to

(Where [.] denotes greatest integer function)


A) 6 B) 7 C) 8 D) 5
2. Let g: R  R be a differentiable function (g(0)  0), and f : R  R be a function, such
that g(x + y) = g(x) + g(y) + 1  x, y  R and g(f2(x) + 2) + g(x2f2(x)) – g(x2f(x)) –
g(3f(x)) = 0,  x  R.
 1
If f is continuous on R and f(2023) = f(2024)  f(0), then f    f  2   ______
2

13 8
A) 2 B) 3 C) D)
5 5

3. If A  aij  , B  bij 
22 22
such that 
aij  f x 2i j2  and 
bij  f x 2i j1  and
 2  1   1 
  x f  x  f 1   1  f   1x
  x4   x2 
A  BT  
 f  1   1  1   1
 1  f 1  

, then  f  t  dt is always equal to
f
 x  
x
  x  x2  x2
  

A) f 1 B) f 1  1 C) f 1  1 D) None of these


4. If f  x   cos x  ˆi   sin x  ˆj   cos 2x  kˆ , g  x    tan x  ˆi   sin 3x  ˆj   cos 4x  kˆ and

h  x    cos 3x  ˆi   sin 5x  ˆj   cos 6x  kˆ are three variable vectors given, then   f  x  g  x  h  x   dx ,
0

where [.] denotes scalar triple product, is belonging to


A)  1, 0  B)  0, 1 C)  ,  1  1,   D) (–1, 1)
     
1  a1.a1 1  a1.a2 1  a1.a3
        
5. If a1  aiˆ  bjˆ , 
a2  a1  2iˆ  5ˆj  and a 3


 a1  2iˆ  5ˆj  , then 1  a2 .a1 1  a2 .a2 1  a2 .a3 is equal
     
1  a3 .a1 1  a3 .a2 1  a3 .a3

to
A) 0 B) 20 C) 40 D) 80

OSR.IIT_*CO-SC Page. No. 3


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases
6. Let f(x) = x3  x  1 , suppose g(x) is a cubic polynomial such that g(0) = -1 and the roots
of g(x) are the square of the roots of f(x), then
A) g  x 2    f  x    
g x2    f  x  C) g 1  3 D) g  4   99
2 2
B)

7. Consider the following statement about the equation x x  px  q  0 ,  p,q  R  then

A) it has at most 3 real roots B) it has at least one real root


C) it has real roots only if p2  4q  0 D) it has 3 real roots if p<0 and q>0
A A
8. In a ABC ,if sec  tan  1
2 2
B B
sec  tan   2
2 2
C C
sec  tan  3 , then
2 2

A) 1 2  23  3 1 =1 B) 12   22   3 2 <1

C) 12  23  3 1  1 D) 12   22   3 2  1

 n
k   k  
n

9. If k is an integer such that lim   cos    cos    0 then which of the following
n  4 6
     

is/are possible
A) k is divisible neither by 4 nor by 6
B) k must be divisible by 12, but not necessarily by 24
C) k must be divisible by exactly one of 4 or 6 but not by both together
D) either k is divisible by 24 or k is divisible neither by 4 nor by 6
10. Let f: [2, 4]  R is a continuous positive function, differentiable on (2, 4), then
2f (  )
f(4)
A) there exists   (2, 4) such that e f ()

f(2)

f() f()
B) there exists   (2, 4) such that f() = 
2 4 

C) there exists   (2, 4) such that f() = 0


D) there exists   (2, 4) such that f() = 2f()

OSR.IIT_*CO-SC Page. No. 4


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
f x
11. If f 3  x   3x2 f  x   x 3  0, then  x
dx is equal to

A) f  x   c B) f  x   c C) 2f  x   c D) xf '  x   c

2 2
 x 1  x p 2  1 
12. If  2x dx  ln    cos1    , p,q  I , HCF (p, q) = 1, then
1 1  x 
3 q
  3 m 6

A) p  m2  1 B) p  m2 C) q  m 1 D) pq  4m2

13. Consider the circle z  5i  3 and two points z1 and z2 on it such that

z1  z2 , arg  z1   arg  z2   . A tangent is drawn at z2 which cuts the real axis at z3 then
3

 5i  z3  
A) arg   B) z3  z2  3 3 C) z3  5i  6 D) z3  11
 z2  z3  6
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
14. The least natural number p for which the equation
3x  x  
cos2   p  x   2 cos   p  x   cos cos     2 =0 has a root is ____________.
2p  2p 3 

Let  be the bigger root of the equation f x   ax 2  4  2a x  8  0 where a   ,2  and


4
15.
3 
cot  
if the value of cot 1 2 tan    tan 1 
6L
  2 L then the value of is ____________.
 2  

16. Let ABC be an acute angled triangle with circumradius and inradius 3 and 1
respectively. Let PA, QA be the points in which the line AI meets the circumcircles of
ABC and IBC respectively. Similarly, PB, QB; PC, QC are also observed. (I is the
PA B.PA C PB C.PB A PC A.PCB
incentre of ABC) then    ______
PA QA  PBQB  PCQC 
2 2 2

17. Let f: R  R be a function defined as f(x + y) = f(x) + f(y) – 3xy(x + y) – 1  x, y  R,


f(0) = –1. Find the least positive integer value of x which satisfies the inequality 1 – f(x)
– f3(x) > f(1 – 5x).

Let n > m, and f(n, m) =    K r  Cr  nr  Cm  and if f(100, 50) = C51 – C51, then the
n n m
18.
k 0  r 0 

number of odd integral divisors of  +  + 3 is ______

OSR.IIT_*CO-SC Page. No. 5


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. A ball is thrown from point A making an angle 600 with line OAS as shown in the
R
figure, where OA  [O is the centre of fixed hemispherical smooth surface of PQS].
3

If after striking the hemi-spherical surface, the ball rebounds in direction parallel to AO.
The coefficient of restitution between the ball and the surface is [Neglect the effect of
gravity and any type of frictional force]

A) 0.50 B) 0.75 C) 0.25 D) 1


20. A parallel plate capacitor is filled by a dielectric whose permittivity varies with the
applied voltage according to the law   U , where   1V 1 . The same (but containing
no dielectric) capacitor charge to a voltage U 0  156 V is connected in parallel to the first
“nonlinear” uncharged capacitor. Determine the final voltage U across the capacitors.
(nearly)
A) 25 V B) 12 V C) 100 V D) 50 V
21. You measure the period of a physical pendulum about one pivot point to be T. Then you
find another pivot point on the opposite side of the center of mass that gives the same
period. The two points are separated by a distance L. Then mark the correct option
2 2 L
A) g = 2
T

4 2 L
B) g =
T2
C) The two points must be equidistant from CM
D) The two points must be at a distance of k from CM where k is radius of gyration
about CM.

OSR.IIT_*CO-SC Page. No. 6


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
22. The potentiometer wire AB in the figure has length ‘L’ and resistance ‘9r’. The cells
have emfs V and V/2 and internal resistance ‘r’ and ‘2r’ as marked. Mark the
INCORRECT options

10 L
A) The Galvanometer ‘G’ will show zero deflection, when the length of AJ equal to
18
B) The Galvanometer ‘G’ will show zero deflection, when 5r is in series to emf of ‘V’
15 L
then AJ 
18
C) The Galvanometer ‘G’ will show non zero deflection, when the length AJ is equal to
L
if 2r is in series with V/2 emf
18
D) Balancing length remains unchanged if any finite resistance is connected in series
with V/2
23. A tube of uniform cross section ‘a’ and length L is rotating with a constant angular speed
 in the vertical plane. End A is open to atmosphere. What is the angular speed required
just to stop water coming out from a very small opening present at the closed end B
when the hole is at the top most position. Atmospheric pressure is P0 (pascal)
B

h
L

=constant
A

2g 2(hg  p0 ) 2gh 2(hg  p0 )


A) B) C) D)
(2L  h) h(2L  h) 2
L h 2
(L2  h2 )

OSR.IIT_*CO-SC Page. No. 7


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases
24. A planet is moving around the sun in a circular orbit of radius R and with a time period
T. If the planet is suddenly stopped in its orbit then
A) the mechanical energy will decrease
B) the mechanical energy after the stopping will become twice the initial
C) Its angular momentum about the centre of the sun will become zero
T
D) It will fall onto the sun after a time if released thereafter
4 2
25. In the given diagram three concentric conducting charged spherical shells are indicated.
Initially both the switches are open. Select the correct alternative(s).

A) If only switch S2 is closed then the charge transferred through this switch
Q
will be
2
B) If only switch S2 is closed then the charge transferred through this switch
Q
will be
3
C) If only switch S1 is closed then the charge transferred through this switch
will be Q/3
D)If only switch S1 is closed then the charge transferred through this switch
Q
will be
2
26. A ring of mass M, radius R, cross section area ‘a’ and Young’s modulus Y is kept on a
smooth cone of base radius 2R and semi vertex angle 450, as shown in figure. Assume
that the extension in the ring is small. Pick the correct alternative(S)

45°

Ring

2R

OSR.IIT_*CO-SC Page. No. 8


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
Mg
A) The tension in the ring is
2
MgR
B) The extension in the ring will be
aY
M 2g 2R
C) Elastic potential energy stored in the ring will be
4 Ya
M 2g 2R
D) Elastic potential energy stored in the ring will be
8 Ya
27. A wooden cubical block ABCDEFGO of mass m and side ‘a’ is wrapped by a square
wire loop of perimeter 4a at z = a/2 as shown. The current in the wire I such that current
in wire branch lying in yz plane is parallel to positive y-axis. The whole system is placed

on frictionless horizontal surface in a uniform magnetic field B  B0ˆj . In this situation ,
normal force between horizontal surface and block passes through a point at a distance x
from centre. Select the correct statement(s)

G F B
C
B
a
O

E y
A D
x
mg
A) The block must not topple if I 
aB0
mg
B) The block must not topple if I 
2aB0
a mg
C) x  if I 
4 2aB0
a mg
D) x  if I 
4 4aB0
28. A uniform disc of mass m and radius R starts with velocity v0 on a rough horizontal
floor with a purely sliding motion at time t=0. At time t  t0 , disc starts rolling without
sliding :
m gt
A) work done by frictional force upto time t  t0 is given by  3 gt  2v0 
2
m gt
B) work done by frictional force upto time t  t0 is given by  2 gt  3v0 
2
C) work done by frictional force upto time t  2t0 is given by m gt  3 gt  2v0 
mv02
D) work done by frictional force upto time t  2t0 is given by 
6

OSR.IIT_*CO-SC Page. No. 9


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
29. Choose the correct statement(s):
A) In a reversible adiabatic expansion, the product of pressure and volume decrease.
B) The rms translational speed for all ideal gases at the same temperature is not the same
but it depends on the molecular mass.
C) If temperature of an ideal gas is doubled from 100C to 200C , the average kinetic
energy of each particle is also doubled.
D) The magnitude of momentum of a Helium atom in a sample of Helium gas at 200K
will be less than the magnitude of momentum of a Hydrogen molecule in a sample of
Hydrogen gas at 400K
30. In the arrangement shown, the small spherical object of mass m is at rest on a smooth
R
floor at x   and it is connected to a spring of force constant k. At t = 0, it was given
2
 R kˆ
a velocity v  i . Then
4 m

concave mirror of R
radius of curvature

ˆj
x=0

R/2

3 m
A) At t  , the velocity of object is towards the concave mirror
4 k
3 m R k
B) At t  , the speed of object is
4 k 4 2m
3 m 2k
C) At t  , the speed of image of this object is R
4 k m

3 m
D) At t  , the image is virtual, erect & magnified
4 k

31. X ray from a tube with a target A of atomic number Z shows strong K lines for target A
and weak K lines for impurities. The wavelength of K  is  z for target A and,  1 and  2
for two impurities.
z  1
 4 and z  . Consider screening constant of K  lines to be unity. Select the correct
1 2 4

statement(s)

OSR.IIT_*CO-SC Page. No. 10


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
A) The atomic number of first impurity is 2Z-1
B) The atomic number of first impurity is 2Z+1
(Z  1)
C) The atomic number of second impurity is
2
Z
D) The atomic number of second impurity is 1
2
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32. A neutron is scattered through (=deviation from its old direction)  degree in an elastic
2
collision with an initially stationary deuteron. If the neutron loses of its initial K.E,
3

to the deuteron then find the value of ( In atomic mass unit , the mass of a neutron is
10
lu and mass of a deuteron is 2u)

33. The heat capacity in a process of 0.5 moles of a diatomic gas, if it does work of Q/4
10
when a heat of Q is supplied to it ,is R . The value of x is
x

34. A radioactive material consists of nuclides of 3 isotopes which decay by   emission ,


  emission and deuteron emission respectively. Their half-lives are

T1  400sec,T2  800sec and T3  1600sec respectively. At t=0, probability of getting ,  and

deuteron from radio nuclide are equal. If the probability of  emission at t=1600
seconds is n 13 , then find the value of ‘n’

35. The values of two resistors are (5.0  0.2)k  and (10.0  0.1)k  . What is percentage error in
the equivalent resistance when they are connected in parallel?

36. In a car race sound signals emitted by the two cars are detected by the detector on the
straight track at the end point of the race. Frequency observed are 330 Hz & 360 Hz and
the original frequency is 300 Hz of both cars. Race ends with the separation of 100 m
between the cars. Assume both cars move with constant velocity and velocity of sound is
330 m/s. Find the time taken by winning car (in sec)

OSR.IIT_*CO-SC Page. No. 11


Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
37. Which of the following is NOT correct about hydrides?
I. Saline hydrides are stoichiometric and metallic hydrides are non – stoichiometric
II. BeH 2 is monomeric whereas MgH 2 is polymeric.
III. Hydrides of the elements of group 13 are electron deficient.
IV. NaH reacts with water and liberates H 2 whereas B2 H 6 does not react with water.
A) IV only B) I and III C) III only D) II and IV
38. The solubility product of AgCl is 1.0 1010 . The equilibrium constant of the reaction
AgCl  s   Br   AgBr  s   Cl  is 200 and that of the reaction
2 AgBr  s   S 2  Ag 2 S  s   2 Br  is 1.6 1024 . What is the K sp of Ag 2 S ?
A) 3.2 1016 B) 1.56  1049 C) 3.95 1025 D) 3.13  1017
39. Step – I: A moles of NaOH, B moles of Na2CO3 and C moles of NaHCO3 are takes in a
container. On dry heating 224 ml of gases are evolved at STP
Step–II: A, B and C moles of the same compounds are taken again in another container
and by dilution volume made up to 100 ml, excess of BaCl2 solution is added to this
solution and filtered. Step–III: The filtrate is titrated with 1M HCl solution using
phenolphthalein indicator and 50 ml of HCl solution is required to reach end point.
Step–IV: The precipitate of Step–2 is separated and treated with excess of Na2CrO4
solution and again filtered. To new precipitate excess of KI sol is added in the presence
of HCl and now this solution is treated with 1M Hypo solution. 500 ml of hypo is
required to reach end point.
Based on above experimental analysis, original solution of step–2 contains?
A) CO32 ,HCO3 and OH– ions B) CO32 and OH  ions
OH  ions

C) HCO3 and CO32 ions D) HCO3 and
40. In which of the following, a new C – C bond is formed without breaking any existing C
– C bonds
I. NBS
CH2 CH2 CH2
AlBr3

II. O O _
OH
C C

III. OH-
OHC CHO

A) I and II B) II and III C) I and III D) I, II and III

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P
41. The emf of the given cell is -0.46 V

1atm  


 
Pt  H 2  H 2 PO4  0.4 M  , HPO4 6.4  103 M M 2  0.81M  M  s 

1L solution

If E 0 M 2 M  0.76V  log 3  0.477, log 2  0.3010   and temperature is 250 C .

pK a for reaction H 2 PO4  HPO42  H  is?

A) 5.9 B) 4.57 C) 7.9 D) 6.84


SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases
42. Incorrect matching(s) is/are:

A) don't neutralize dil.HNO3 : SiO 2 , CO

B) reacts with HF : SiO 2 ,SnO

C) Solid at room temperature: LiHCO3 , NaCl

D) act as reducing agent: CO, SnO


43. Identify the incorrect statement(s)

A) Combustion of methane in an adiabatic rigid container will cause no change in


temperature of the system.

B) Dimerization of acetic acid causes an increase in entropy of the system

C) It is possible to have both adiabatic reversible and adiabatic irreversible processes


between two states.

D) P – V work is always non – zero when there is a change in volume

44. Which of the following statement(s) is/are correct?

A) Tetracyanocuprate (I) is a tetrahedral complex

B) Tetracyanonickelate (II) is a square planar complex

C) Tetrachloridopatinate (II) is a tetrahedral complex

D) Tetraamminecopper (II) sulphate is a square planar complex

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45. CaC2  N 2  
X  Y , X contains Calcium, then identify correct statement(s) regarding
'X' & ‘Y’?
A) Anion of 'X' is isoelectronic and isostructural with CO2
B) Hydrolysis of X gives melamine
C) both of the hydrolysis products of X formed are highly water soluble
D) Y is amorphous form of carbon
46. Which of the following reaction is not an example of redox reaction?
A) Hydrolysis of XeF2 B) Hydrolysis of XeF6
C) Reaction of XeF4 with O 2 F2 D) Reaction of XeF2 with PF5
47. Observe the following reaction:
H3C

NBS
CH2

Pick the correct statement (s)


A) 6 optically active products are formed

B) All products formed in the reaction show geometrical isomerism

C) 4 chiral and 2 achiral products are formed

D) 4 Fractions are obtained on fractional distillation


48. The time required for an electron to make one complete revolution around nucleus of H-
atom in a higher orbit n2 is 8 times to that of a lower orbit n1 . Therefore n1 and n2 are
A) 1 and 2 B) 2 and 3 C) 2 and 4 D) 3 and 6
49.

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P1)_Q’P

SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
50. The Vander wall’s constant ‘b’ of a gas is 3.42 102 L mol 1 . How near can be centers of
the two molecules approach each other with respect to their nuclei (in A0)?

51. Matching

List- I List- II

Reactant/Product gives
P) 1)
Molisch test

NO 2
i) Sn + HCl
ii) NaNO2/HCl, <5 oC Reaction proceeds via
Q) 2)
(iii) napthol/OH-
SE pathway

Lassaigne's extract of

R) glu cos e 


polymerisation
starch 3) product gives blue colour
solution with FeSO4 &
conc.H2SO4
Reactant/Product gives
S) a min oacid mixture 
polymerisation
 protein 4)
Biuret test
If P matches with 1 and Q matches with both 1 and 3 and R with 4 and S with 2
Then sum of these numbers is, 1 + 1 + 3 + 4 + 2 =11. after this, keep adding digits till
you get single digit & report it? In this case we got 11, 1+1 =2, so, you would report 2.

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52. How many of the following amino acids when fused with sodium followed by addition
of aq. Sodium nitroprusside give purple colour solution?

Arginine, Lysine, Serine, Aspargine, isoleucine, Tyrosine

53. Identify the number of correct statements out of the given?

1. Cl2 and SO2 both are bleaching agents. Bleaching of flowers by Cl2 is permanent
while by SO2 is temporary

2. We have PCl3 and PH3 but there is no PH5 though we have PCl5

3. HNO3 releases NO2 gas when reacted with metals like Zn, Fe etc under concentrated
conditions but HNO3 with same metals releases N2O under diluted conditions.

4. Ability to form negative oxidation states decreases down in the group VA.

5. For titrating boric acid with NaOH in presence of phenolphthalein, we add catechol.

6. Nitric acid is only oxidising agent but Nitrous acid is both oxidising as well as
reducing.

7. Dipole moment of NF3 is less than NH3 though F is more electronegative than H.

8. Na2CO3 is stable while Li2CO3 and MgCO3 are less stable and decompose on heating
while Al2CO3 doesn’t even exist.

9. Cl forms only HOCl, HClO3 and HClO4 while Br forms HOBr, HBrO2, HBrO3 and
HBrO4

10. In permanganometry titrations we use H2SO4 to provide acidic conditions but not
HNO3 or HCl

54. If 4 atoms of same radius are placed at the alternate corners of a cube touching each
other, and if the length of body diagonal of the cube is equal to x  R , where R is the
radius of atom. Find the value of x ?

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