FIITJEE

ALL INDIA TEST SERIES

JEE (Advanced)-2022
FULL TEST – X
PAPER –1
TEST DATE: 21-08-2022

ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A

1. D
Sol. E = Bv
 A
q  0 Ed
d
q  0 R2Bv
dq dv
I  0 R2B
dt dt
dv
m  mg  BId
dt
dv dv
m  mg  0 R2B2 d
dt dt
dv
(m  0 R2B2 d)  mg
dt
dv mg
a 
dt (m  0 R2B 2 d)

2. A
Sol. When the nail B is removed Ny
 3m 2
3mg  IA    /2
2 2 A B
  = g/ …(i) Nx 30
 g  g G
Also, a      Removed
3  3 3 nail
Nx = 3ma cos 60
a C
3
 Nx  mg
2
3mg  Ny = 3ma sin 60

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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22 2

3mg
 Ny 
2
N  N2X  N2Y  3mg

3. C
Sol. V1 = 3sin t; V2 = 5sin (t + 1) and V3 = 5sin(t  2) 5
2
5 3  2
30
Vmax     (1.5)  21 3
 2
 
37
Vmax 21 21 3
Imax     3A 5
R 7/3 7

4. B
C kC
Sol. Ceq  and Ceq   Ceq  Ceq
2 k 1
 Q > Q

5. A
KA(1  2 )
Sol. i …(i)

Thermodynamics process in both the vessels are isochoric
d i i
 1   …(ii)
dt 5R 5R
2
2
d 2 i i
  …(iii)
dt 3R 6R
4
2
Addding (ii) and (iii), we get
d(1  2 ) 11i
 
dt 30R
d(1  2 ) 11KA(1  2 )
  
dt 30R
25 t
d kA  11
 
50


30R
dt 
0
(where, 1  2 = )

0.693  30  242  10 2  8.3  7

t = 3 sec
693  7  22  8.3  10 4  11

6. A, D
12
Sol. Ex   Ex  3 V/m
4
8
Ey   Ey  4 V/m
2

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 3 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22

7. A, D
Sol. 2T = dhg
2T 2  7  102
h  3  14  10 2 m  14cm h
gd 10  10  1 10 4
Force of mutual attraction between the plates is
h
gh2
F   gydy 
0
2 d
103  10  0.10  (14  10 2 )2

2
= 19.6/2= 9.8 N

8. B, D
 C
Sol. D2  4d2  D 
2
45
 1 4d2  
 D 1   2  1  B A
 2 D  2
4d2

D
Resulting intensity at point P is I = I0

9. A, B
1 1
Sol. v , r  n2 ; E  2
n n

10. A, C
dU d k
Sol. F   (k nr)  
dr dr r
mv 2 k nh k
 ; mvr  ;v
r r 2 m
k nh nh
 m r ;r 
m 2 2 mk
1 k k
Again: E = U + k = knr + m   knr
2 m 2
1  nh  
E  k   n  
2  2 mk  

Section – B
11. 40
Sol. Potential across each capacitor is 10 V
Charge = 20 C
Charge on plate C = 40 C (both sides included)

12. 4
qE0
Sol. aE  (along negative z-direction)
m
Electric field will make z-component of velocity zero. At that time speed of the particle will be
minimum and that minimum speed is the other component, i.e. v 0.

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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22 4

This is minimum when,

v z  uz  a z t
qE0
Or 0  v 0  t
m
mv 0
Or t  = 4 sec
qE 0

13. 90
2mg 2  0.4  1 10
Sol. The maximum displacement on each side decreases by   8 cm
k 100
mg
It stops completely if comes to rest between   4 cm
k
 S = 27 + (19 + 19) + (11 + 11) + 3 = 90 cm

Section – C

14. 02.00

15. 01.00
Sol. (for Q.14-15):
2mv 0 1  qE0  2
  t
qB0 2 m 
4m2 v 0
 t2
q2E0B0
2m v0
x  v0  t  x  v0
q E0B0

16. 01.00

17. 01.00
Sol. (for Q. 16-17):
For solid sphere to just start rolling without slipping.
tan  2
  tan 
mR 2 7
1
I
gsin  5
asphere  = gsin 
I 7
1
mR2
5
acylinder  g(sin    cos ) = gsin 
7
5
aring  g(sin    cos ) = gsin 
7
Ring, solid cylinder and solid sphere have same acceleration.

18. 01.00

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 5 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22

19. 03.00
Sol. (for Q. 18-19):
During the first crossing,
d d
tv
v t
X= 1
During the second crossing,
v d
sin   and  3t  cos  = 1/3
u v cos 
v 3 d
u 
sin  2 2 t
Y=3

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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22 6

Chemistry PART – II
Section – A

20. A
Sol. O O O O
H3C C C Ph OH 
  H3C C C OH
(EDG)
Ph

OH O O O
Acid  base
H3C C C O H3C C C OH
reaction
Ph Ph

H / H2 O

OH O

H3C C C OH
Ph

21. B
Sol. Beryl is cyclic silicate, two oxygen atoms per tetrahedron are shared to form closed ring.

22. D
Sol. (A) CH2OH

CHOH  2HIO4  2HCHO  HCOOH  2HI  H2 O

CH2OH
(B) CH2OH CH2 CH2
CHOH Conc. H SO
2 4 Tautomerises

or
 C   CH
P2 O5  Heat 
CH2OH Dehydrating agent  CHOH CHO
H2O

Unstable Acrolein
 unpleasant smell
(C) CH2OH COOH

CHOH Conc. HNO3

 CHOH
O
CH2OH CH2OH
Glyceric acid

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 7 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22

(D) CH2OH CH2

CHOH  3HI 

 CH  I2

CH2OH CH2I
Allyl iodide
Allyl iodide formed further reacts with HI.
CH2 CH3 CH3
CH3
CH  HI   CHI 
I2
 CH Hi
  CHI
CH2I CH2I CH3
CH2
Unstable Propene Isopropyl iodide

23. B
Sol. Amine oxide on heating follows syn-elimination thus producing alkene
O
CH3
N
CH3 CH3

  HO N
H
H CH3
CH3
CH3

24. B, C, D
M2 
0.059   right
Sol. Ecell  log
2 2 
M 
 left
0.059 0.01
0.236  log
2 M2 
  left
M2    1  10 10 M
 left
 Solubility of MX2 in 0.2 M X   1  1010 M
2 2
K SP of MX 2  M2   X    1  10 10   0.2   4  1012 M3
1/3 1/3
K   4.0  10 12 
Solubility of MX2 in water   SP     1.0  104 M
 4   4 

25. A, B, C, D
Sol. Cellulose, a polymer of D-glucose, has   1, 4  glycosidic linkage .

26. A, C
Sol. Haematite  Fe2 O3 Bauxite  Al2 O3 .2H2 O 
 Oxide ores of same metal
Magnetite  Fe3 O 4 Corundum  Al2 O3 
Anglesite  PbSO4 Cuprite  Cu2 O
Cerrusite  PbCO3 Cassiterite  SnO2

Oxide ores of different metals

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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22 8

27. B, C, D
Sol. Kjeldahl’s method is not applicable to compounds in which nitrogen atom is present in ring and to
compounds containing nitro and azo groups.

28. B, D
Sol. Ice cube of D2 O has greater density than H2 O (liquid) and hence will sink.
Ice cube H2 O has smaller density than D2 O (liquid) and hence will float on it.

29. C, D
Sol. H3C
H3C OH OH 2 CH3 CH3 CH3

H H O 
 2
 
 H
  

H H

Section – B

30. 7
Sol. All statements except (F) are true.
Insulin is a harmone and not co-enzyme.

31. 9
Sol. eg

K 3 Fe  CN 6  : Fe3   3d5

t 2g P 1

t2

2
FeCl4  : Fe2   3d6

e Q3

eg

Fe H2 O   Cl3 : Fe3   3d5

 6

t 2g R3

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 9 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22

eg

4
FeF6  : Fe2   3d6

t 2g S2
P  Q  R  S  1 3  3  2  9

32. 17
Sol. the process involved are
q1 q2 q3 q4 q5
H2 O  s   H2 O  s   H2 O     H2 O     H2 O  g  H2 O  g 

 10 C
o
0o C 0o C 100o C 100o C 205.56o C
Q  q1  q2  q3  q4  q5
 5  2  10  333  4.18  100  2439  1.8  105.56 
= 17000 J

Section – C

33. 44.80

34. 67.20
Sol. (for Q. 33 and 34):

NH4 2 Cr2 O7   N2  Cr2 O3  4H2 O

NH4 NO3   N2 O  2H2 O

Hg NO3 2   Hg  2NO2  O2
Total number of moles of diatomic gases (X)  N2 1 mole   O 2 1 mole 
= 2 moles
 Volume  2  22.4  44.8 litres
Total number of moles of triatomic gases  N2 O 1 mole   NO2  2 moles 
= 3 moles
 Volume  3  22.4  67.2 litres

35. 272.87
(272.86 – 272.88)

36. 00.09
Sol. (for Q. 35 and 36):
1.66  1000
Molality of KI solution   0.1
166  100
Effective molality  i  0.1  2  0.1  0.2
Tf  KI  K f  m  1.86  0.2  0.372
‘X’ freezing point of KI solution = 273.15 – 0.372 = 272.778 = 272.78 K
In KI solution saturated with solid HgI2 we get K 2 HgI4 
2
2K   2I  HgI2  s   2K   HgI4 
Now, effective molality  1.5  0.1  0.15

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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22 10

‘Y’ (Freezing point of saturated solution) = 273.15 – (1.86 × 0.15)

= 273.15 – 0.279
= 272.87 K
 Y  X  272.87  272.78
= 0.09 K

37. 03.00

38. 30.60
Sol. (for Q. 37 and 38):
1 1 
E  3.4 eV  13.6Z 2  2  2 
n  
2
Z
3.4  13.6 2 … (1)
n
Energy emitted in the transition from excited state to the IInd excited state (n = 3)
 1 1
E  4.25  5.95  13.6Z2  2  2 
 3 n 
2
 n  9 
10.20  13.6 Z 2  2 
… (2)
 9n 
From (1) and (2), we get
10.20 n2  9

3.4 9
2
n 9
3 n6
9
3.40  n2
From Eq. (1) Z2  Z3
13.6
1 1 
Ionization energy of first excited state (n = 2) of the atomic species E  13.6  32  2  2 
2  
1
 13.6  9 
4
= 30.6 eV

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 11 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22

Mathematics PART – III

Section – A

39. D
Sol. y 2  4  y  x  y  1, 4   y   1
y=4
 y2 = 4x similarly x  1, 4   x   1
x2 = 4y
2 4
 x2  11
1
 
Required area  2 x  1 dx    2 x   dx =
2
4  3
y=4

x=1 x=4

40. A
x
4
Sol.   x  t  1 g  t  dt  x  x 2 ; differentiating with respect to x
0
x
2
g  x    g  t  dt  4x 3  2x ; differentiating again g(x) + g(x) = 12x + 2
0
So, g(x) = 12x2 – 24x + 26 – 26e–x

41. A
Sol. The desired region consists of 12 boxes, whose lower left corners are integers solution of x 2 + y2
= 25, i.e. (5, 0), (0, 5), (3, 4), (4, 3)
 1 1
Since, the points them self are symmetric about (0, 0) the boxes are symmetric about  ,  ,
 2 2
 1 1
then distance from  ,  to the fullest point on a box that lays on the axis
 2 2
130
So, minimum values r 
2

42. B
2 2 2 2 2
Sol. 2010 = 2  3  5  67
4 4 4
Total divisors = 3  3  3  3 = 3 i.e. (2 + 1) and (1 + 1) of which are squares
26
So, required probability =
81

43. A, C
Sol. Let the centre of base is (0) E D
  1 
P 4iˆ  2ˆj  2 3 kˆ 
AB  2ˆj  AB  2  OAB =  4 3
4 F G C
 Base area = 6 3
Let height of pyramid = h
1
 6 3h  6 3  h = 3
A ˆi  
B ˆi  2jˆ 
3
    
AP  3iˆ  2ˆj  2 3 kˆ  AP  5  AG  4 . Now AG and AO are collinear
    
 AG   AO  AG    AO   = 2  G  ˆi  2  ˆj  3 ˆi 
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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22 12


 G = ˆi  2ˆj  2 3 kˆ or ˆi  2ˆj  2 3 kˆ

44. A, B, C, D
Sol. Since, 1  sin2x  1  sin 2x  2  x  [0, 2]
  3 
Now, if cos x  0  2 cos x  1  sin2x  1  sin 2x  x   , 
2 2 
2
If cos x > 0, then 4 cos x  1 + sin 2x + 1 – sin 2x – 2 1  sin2 2x  cos 2x  0
  3   5  7    7 
x ,   ,   x ,  so, x = 1, 2, 3, 4
4 4   4 4  4 4 

45. B, C
2  1
Sol. 4sec A
x 2  2x   B2  B    0 have real roots
 2
2  1 2 1 1
 D  0  4sec A  B 2  B    1 but 4sec A  4, B2  B  
 2 2 4
2 1 1
 Equation will satisfy when 4sec A  4 and B2  B  
2 4
2
 1 1
 sec A = 1 and  B    0  cos2 A = 1 and B 
2

 2 2
1  
 A = n and B   cos A  cos 1 B   1 ;  1
2 3 3

46. A, C  
  
Sol. Let p and q be the pv of P and Q r  a  
      
Let p  a  t1 ; q  b  s1 P A a
      
 p  q  a  b  t1  s1
 

B b
Taking dot product of this equation with  and  , we have Q   
       r  b  
 
O  a  b    t1       s1    and  
        
     
O  a  b    t1     s1    solving for t1 and t2, we get p and q

47. A, C
Sol. Since, x3 + ax + b = 0 ; x 3 + cx2 + d = 0 have complex root so it appears in conjugate pairs
Let z  m  n i ; z  m  n i ; So z  z  2m ; zz  m2  n
For the equation x3 + ax + bn = 0  –20 + z + z = 0 ; z  z  20  m = 10
and for equation x3 + cx2 + d = 0  –21z – 21z + zz  0  n = 320

48. C, D
Sol. Clearly f(x) is not define at x = 1 if a < 0 and if a > 0, then all the conditions of Rolle’s theorem
holds on f(x)

Section – B

49. 1
Sol. Since, g(0) = 0 and f(g(x)) = x
5 2 4

 g  x   3 f   g  x     f   g  x      f   g  x     f   g  x    g(0) = 1

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 13 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22

50. 13
Area of ADC C
Sol. E, F exist if and only if 2
Area of ADB
Since, AD is the angle bisector, and the ratio of area of triangles with F
equal height is the ratio of their bases E D
AC DC Area ADC
   2  AC = 2AB
AB DB Area ADB
Let BC = d so, by triangle inequality d + 7 > 14 ; 7 + 14 > d A B
7
 7 < d < 21
So, there are 13 possible integral values of BC

51. 5
1 1 1
 
1 p   1  3  1 3  1 3 
Sol. Put t   lim t   1    1  2  
x t 0  t  t  t 
 
1
p   1 1
 1
t t2 1
t t2
 lim t 3
 1  t  3  1  t  3  2
 use expansion  1  t  3  1  ;  1  t  3  1 
t 0
  3 9 3 9
1 1 5
p 
3
 2t 2  2 p  2  3 2 p 5
 lim t     t    t 3 so, p   3p = 5
t 0
 9  9 9 3

Section – C

52. 04.00

53. 06.00
Sol. (for Q. 52 to 53):
f(x + 2y) = f(x) + f(2y) + ex + 2y (x + 2y) – x ex – 2y e2y + 4xy
Replace x, y = 0  f(0) = 0
Put 2y = –x, we have f(0) = f(x) + f(–x) – xex + xe–x – 2x2
f  x  h  f  x 
 –f(x) = f(–x) – x ex + xe–x – 2x2. Now, f(x) = lim
h 0 h
x x 2
f  x  h   f  x   xe  xe  2x
= lim
h 0 h
f  h   ehh   x  h  e x h  xe x  2  x  h  x  xe x  xe x  2x 2
= lim
h 0 h
h x h
f  h   e h  xe e  2hx  xe x
 f  h   f  0    eh h  e x  1  xe x  eh  1  2hx
lim = lim
h 0 h h 0 h
2 x 2
 f  x   x  xe  f  2   4  2e

54. 84.00

55. 25.00
Sol. (for Q. 54 to 55):
Let P1(u, v) be any point of C1 and P2(x, y) be the C1
corresponding point on C2
Since, P1P2 (line joining) is perpendicular to y = 2x so, y = 2x
1 P1 (u, v)
C2
its slope = 
2
yv 1 P2(x, y)
 ….. (1)
2x  u 2

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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/22 14

and midpoint of P1P2 lies on y = 2x

yv  x u
 2  ….. (2)
2  2 
Solving equation (1) and (2), we get 12x2 – 7xy – 12y2 + 25 = 0

56. 401.00

57. 10.00
Sol. (for Q. 56 to 57):
f(2 + x) = f(2 – x)  f(4 – x) = f(x) ..... (1)
From f(7 + x) = f(7 – x)  f(14 – x) = f(x) ..... (2)
From equation (1) and (2), we get f(x + 10) = f(x) so period is 10
Now, replacing x by x + 10 and then x – 10 is equation (3) continuity in this ways
f(x + 10n) = f(x) ..... (4)
for n = 1, 2, 3 .....
Since, f(0) = 0 equation (4)
f(10) = f(20) ..... = f(1000) = 0. so total 201
Now, x = 0, in equation (1) f(x) = f(0) = 0 from equation (1), we have 200 more roots

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