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Poc Iii MCQ

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76 views

Poc Iii MCQ

Uploaded by

rakshitha43disha
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Compounds with same molecular formlula but different structural formula are called

(a) Alkoxides
(b) Iso Compounds
(c) Isomers
(d) Ortho Compounds
C

Ethanol (CH3CH2OH) and dimethyl ether (CH3OCH3) are best considered


(a) Structural isomers
(b) stereoisomers
(c) enamtiomers
(d)diastereomers

The compounds CH3CH2O CH2CH3 and CH3OCH2CH2CH3 _are


(a) enantiomers
(b) conformational isomers
(c) metamers
(d) optical isomers

How many isomers are possible for the compound with molecular formula C4H8
(a) 2
(b) 4
(c) 6
(d) 8

How many structural isomers are possible for C4H9Br


(a) 2
(b) 3
(c) 4
(d) 5

How many isomeric aromatic hydrocarbons are possible for C8H10


(a) 2
(b) 4
(c) 6
(d) 8

Which of the following is not an isomer of the other three


(a) n-pentane
(b) 2,2-dimethylpropane
(c) 2-methylbutane
(d) 2,3dimethylbutane

Geometric isomerism is shown by


(a) lactic acid
(b) maleic acid
(c) 1-butene
(d) 1,1-dichloroethane
What is the correct term for a 50:50 mixture of two enantiomers?
(a) cis/trans mixture
(b) mirror image mixture
(c) chiral mixture
(d) racemic mixture

Which of the following groups has the highest priority according to the Cahn-Ingold-Prelog
sequence rules?
a) CH3
b) CH2Cl
c) CH2OH
d) CHO

Cis-trans isomers are:


a. Diastereomers.
b. Enantiomers.
c. Geometric isomers.
d. Constitutional isomers

A mixture of equal amounts of two enantiomers __________.


a. is called a racemic mixture
b. is optically inactive
c. implies that the enantiomers are meso forms
d. both A and B

__________ is the use of an optically active reagent or catalyst to convert an optically


inactive starting material into an optically active product.
a. Asymmetric induction
b. Racemization
c. Optical reduction
d. Meso effection

What term describes the structural relationship between (E)- and (Z)-2-pentene?
a. Constitutional isomers
b. Enantiomers
c. Geometric isomers
d. Conformers

Compounds which have different arrangements of atoms in space while having same
atoms bonded to each other are said to have
a. position isomerism
b. functional group isomerism
c. chain isomerism
d. stereoisomerism

Which of the following can make difference in optical isomers?


a. heat
b. temperature
c. polarized light
d. pressure

Which of the following is true of any (S)-enantiomer?


a. It rotates plane-polarized light to the right.
b. It rotates plane-polarized light to the left.
c. It is a racemic form.
d. It is the mirror image of the corresponding (R)-enantiomer.

Those stereoisomers which can be interconverted only by breaking and remaking of


covalent bonds are called as____
a. Chain isomers
b. Positional isomers
c. Configurational isomers
d. Conformational isomers

Those stereoisomers which can be interconverted by simple rotation about sigma bonds
are called as____
a. Conformational isomers
b. Functional isomers
c. Geometric isomers
d. Tautomers

A beam of light having a particular wavelength and having vibrations only in one plane
is____
a. Ordinary light
b. Plane polarized light
c. Monochromatic light
d. None of above

Optically active compound can rotate_____


a. Ordinary light
b. Plane polarized light
c. Monochromatic light
d. None of above

Which instrument is used to measure angle of rotation?


a. Polarimeter
b. UV spectrometer
c. pH meter
d. Conductometer

For being chiral compound, chemical compound should not possess following
characteristic
a. Plane of symmetry
b. Centre of symmetry
c. Axis of symmetry
d. All of the above

Ratio of dextro and levo isomers (d:l) of compound present in raceme mixture is__
a. 50:50
b. 40:60
c. 30:70
d. 20:80

The process of separation of a racemic mixture into optically active d and l isomers
is___
a. Racemization
b. Resolution
c. Both (a) and (b)
d. None of the above

Absolute configuration of stereoisomer is denoted by__


a. R and S isomers
b. D and L isomers
c. d and l isomers
d. cis and trans isomers

Relative configuration of stereoisomer is denoted by__


a. R and S isomers
b. D and L isomers
c. d and l isomers
d. cis and trans isomers

By studying which physical property, configuration of geometric isomers can be


determined
a. Melting point
b. Solubility
c. Dipole moment
d. All of the above

Most stable conformation of cyclohexane is___


a. Chair conformation
b. Boat conformation
c. Twist boat conformation
d. Half chair conformation

The hydrogens lying in the plane of the cyclohexane ring are called____
a. Axial hydrogens
b. Chiral hydrogens
c. Equatorial hydrogens
d. None of the above
The hydrogens lying above or below the plane of the cyclohexane ring are called____
a. Axial hydrogens
b. Chiral hydrogens
c. Equatorial hydrogens
d. None of the above

Which of the following is a not a five membered ring?


a. Pyridine
b. Pyrrole
c. Furan
d. Thiophene

Which is the most reactive five membered heterocyclic compound?


a. Pyrrole
b. Furan
c. Thiophene
d. Pyridine

Which heteroatom present in pyrrole?


a. Oxygen
b. Nitrogen
c. Silicon
d. Sulphur

Which heteroatom present in Furan?


a. Oxygen
b. Nitrogen
c. Silicon
d. Sulphur

Which heteroatom present in thiophene?


a. Nitrogen
b. Silicon
c. Oxygen
d. Sulphur

Which compound is most basic?


a. Pyridine
b. Pyrrole
c. Imidazole
d. Pyrrolidine

Which is least basic compound?


a. Pyridine
b. Pyrrole
c. Imidazole
d. Pyrrolidine
Oxidation of pyrrole in presence of chromium oxide (Cr2O3) and acetic acid
produce_______.
a. Maleinimide
b. Maleic acid
c. Pyrrole N-oxide
d. None of the above

Atorvastatin, drug useful in CVS disease, contain heterocyclic ring______.


a. Pyrazole
b. Pyrrole
c. Imidazole
d. Purine

Which of these is a comparatively insignificant factor affecting the magnitude of specific


optical
rotation.
a. Concentration of substance of interest
b. Temperature of measurement
c. Length of the sample tube
d. All of the above

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