0% found this document useful (0 votes)
18 views

7

The document discusses several chemical reactions involving the formation of sulfate compounds from sulfur dioxide and other reactants. Key reactions discussed include the formation of sulfur trioxide from sulfur dioxide and oxygen, and the reaction of zinc with sulfuric acid to form zinc sulfate and hydrogen.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
18 views

7

The document discusses several chemical reactions involving the formation of sulfate compounds from sulfur dioxide and other reactants. Key reactions discussed include the formation of sulfur trioxide from sulfur dioxide and oxygen, and the reaction of zinc with sulfuric acid to form zinc sulfate and hydrogen.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 13

(i)

2SO2 (g) + O2(g)  2SO3 ; H = 197/mole


(i) 2SO2(g) + O2(g) 2SO3(g); H = 197kJ/mole;
(ii) Zn + H2SO4 = ZnSO4 + H2

(ii)

(i)
(i) H
DËi
11 (Cu) (Ag)
(Au)

SO2 O2

SO3
(i) 3 2

(ii)
c om SO2
(i)
O2

(i) NaOH(aq) + HCl(aq)  NaCl(aq) + H2O(l);


a.

(ii) Zn H2SO4 (ii) 2Mg(s) + O2(g) 2MgO(s);


(iii) N2(g) + 3H2(g) 2NH3(g); H = 92 kJ.
on

Zn + H2SO4  ZnSO4 + H2
m

(i) (ii)
Zn + H+  Zn2+ + H2
.it

Zn (0)
ZnSO4 Zn- +2 Zn
w

ZnSO4-
DËi
w

Zn  2e Zn2+ 
H2SO4 OH +1 H
w

(0) H2SO4
OH

2H+ + 2e  H2
(CaO)
H2SO4 Zn

(i) (ii) (ii)


Zn + H2SO4 ZnSO4 + H2

(ii)

www.itmona.com 1
DËi
(i)
(HCl)
(NaOH) (NaCl)
(H2O)
(H+)

(OH )
(Na+) (Cl)
(Na+)

(Cl )
HCl(aq) + NaOH(aq)  Na+(aq) + Cl(aq) + H2O(l)
L
+  +  + 
H (aq) + Cl (aq) + Na (aq) + OH (aq)  Na (aq) + Cl (aq) +
H2O(l) ZnSO4
H+(aq) + OH(aq)  H2O(l)

(ii)  2Mg O2  2MgO(l)


2Mg  4e  2Mg2+
2
O2 + 4e  O x
2
+2
2Mg  4e + O2 + 4e  2Mg2+O2
2

(i) (ii) (ii) om


ZnSO4-
2(+2) + x + 4(2) = 0
4+x8=0
x4=0
(ii)
x=+4
c
 ZnSO4- +4
a.

(iii) N2(g) + 3H2(g)


2NH3(g); H =  92kJ;
on

Zn + H2SO4  ZnSO4 + H2
m
.it

N2
H2 (NH3)
DËi
w


w
w

(NH3)

Zn + H2SO4 ZnSO4 + H2.


ZnSO4


ZnSO4- S- x

www.itmona.com 2
(Zn)- 2 Fe3+ + e  Fe2+
Fe3+ Fe2+
(O)- 2
∵ ZnSO4 2Fe3+ + 2e  2Fe2+

(+2) + x + (2)  4 = 0
x6=0

∴ x=+6
 ZnSO4 +6
Sn2+ + 2Fe3+ Sn4+ + 2Fe2+

+2e
5| (i) 2FeCl2 + SnCl4  2FeCl3 + SnCl2
(ii) 2Na + Cl2  2NaCl

(ii)
(i)

DËi om
c
a.
on

DËi
m
.it
w

(ii)
2Na + Cl2  NaCl
w

Na Na+
Na  e  Na+
w

2Na  2e  2Na+


Cl
100C
Cl2 + 2e  2Cl
Na Cl2
100C
Cl2 Na

(i)
2FeCl2 + SnCl4  2FeCl3 + SnCl2 H2O(s) J H2O(l) J H2O(g)

Sn2+  2e  Sn4+


Fe3+ Fe2+

www.itmona.com 3
i
Zn + CuSO4 = ZnSO4 + Cu...... (ii)
Zn + Cu2+ + SO42- = Zn2+ + SO42- + Cu
Zn + Cu2+ = Zn2+ + Cu...... (iii)
Zn - 2e = Zn2+ ...... (iv)
Cu2+ + 2e = Cu ...... (v)
iv v iii ii

CxHy + (x + 4y) O 
2
 y
xCO + H O +
2 2 2
ii

Fe + H2SO4 = FeSO4 + H2...... (ii)


+
Fe + 2H + SO42- = Fe2+ + SO42- + H2
+
x 2 Fe + 2H = Fe2+ + H2...... (vi)
y x y Fe  2e = Fe2+ ...... (vii)
+
CO2 H2O(g) 2H + 2e = 2H2 ...... (viii)
vii viii vi ii
xy=a
a

i.
ii.
Zn + CuSO4 = ZnSO4 + Cu
Fe + H2SO4 = FeSO4 + H2
i.
ii.
om
NaOH + HCl  NaCl + H2O
Zn + CuSO4  ZnSO4 + Cu
H
c
a.

i ii 
on

DËi DËi
m
.it

H
w

H
H
w

H
w

Na + Cl2  NaCl.
i. Zn + CuSO4 = ZnSO4 + Cu
ii. Fe + H2SO4 = FeSO4 + H2
Cu Zn, Cu
CaO + CO2  CaCO3
(i) Zn, Cu
Cu Zn, Cu i
(i) NaOH + HCl  NaCl + H2O
Cu + ZnSO4 = No reaction
H Fe Fe, H +1
(ii) H H +1
Fe Fe- Fe +1 +1
H i ii 1
1

www.itmona.com 4
NaOH) (HCl) (NaCl) PCl5
(H2O) +5 -1 +3 -1 0
i P Cl5 = P Cl3 + Cl 2
+5 - 3+ - 0
P + 5Cl = P + 3Cl + Cl 2
(ii) +5 - 3+ 0
P + 2Cl = P + Cl
- 5+ 3+
2
 P + 2e = P ( )
(ii)  
2Cl - 2e = Cl2 ( )
PCl5 = PCl3 + Cl2
ii 3Fe + 2O2 = Fe3O4
Zn + CuSO4  ZnSO4 + Cu 3Fe + 2O2 = FeO, Fe2O3
2+
CuSO4  Cu + SO42 Fe  2e = Fe2+ 2Fe - 3e = Fe3+
2+
ZnSO4  Zn + SO24 O2 + 4e = 2O
2

2+
Zn  2e  Zn Fe  2e = Fe2+
2+ 3+
Cu + 2e  Cu 2Fe  6e = 2Fe
Zn 2O2 + 8e = 4O2-
3Fe + 2O2 = FeO.Fe2O3 -
Zn Cu ii
i ii -

(ii)

om
FeCl3 + SnCl2  FeCl2 + SnCl4
2Na + Cl2  2NaCl

i. PCl5(l) PCl3(l) + Cl2(g)
c
ii. 3Fe(s) + 2O2(g) Fe3O4(s) CaO + CO2 = CaCO3
a.
on

i
i ii

DËi
m

DËi
.it

CaO + CO2 = CaCO3


w

-
w

CaO CO2 CaCO3

FeCl3 + SnCl2  FeCl2 SnCl4 .....(i)


w

HCl + NaOH = NaCl + H2O ( )


+ - + -
H + Cl + Na + OH = Na + Cl + H2O
+ -
FeCl3 Fe3+ SnCl2 Sn2+
+ - Cl
H + OH = H2O. 2+ 4+ -
Sn  Sn + 2e ............. (ii)
Fe3+ + e- Fe2+ ............... (iii)
- (iii) 2
i (ii)
Sn2+ + 2Fe3+  Sn4+ + 2Fe2+ ........... (iv)
PCl5(l) PCl3(l) + Cl2(g) (iv) (i)
2

Cl5, Cl2

www.itmona.com 5
NaCl iv
2Na  2Na+ + 2e– ; Na C + O2  CO2
2Cl + 2e–  2Cl– ; Cl

ii
2Na + Cl2  2 (Na+ + Cl)  2NaCl

iii

HCl + MgO  MgCl2 + H2O


i. 2H2 + O2  2H2O
2(1 + 35.5) + (24 + 16)  (24 + 35.5  2) + (1  2 +
ii. Zn + H2SO4  ZnSO4+ H2
16)
iii. 2HCl + MgO  MgCl2 + H2O
73 + 40  95 + 18
iv. C + O2  CO2
113  113

i. 
DËi ii. 
iii.
iv.
c om 

a.
on

i) iii) ii)

DËi
m

i
.it

2 H2 + O2  2H2O
w

ii
w

Zn + H2SO4  ZnSO4 + H2 C6H12O6(s) + 6O2(g)  6CO2(g) + 6H2O(g) +


w

iii

i. C + O2  CO2
2HCl + MgO  MgCl2 + H2O
iv ii. CaCO3  CaO + CO2
iii. 2H2 + O2  2H2O
iv. Zn + H2SO4  ZnSO4 + H2
C + O2  CO2 i)
(ii) iv)

iv)

i i) iii) (ii)

www.itmona.com 6

Na+(aq) + Cl-(aq) + Ag+ (aq) + NO (aq)  Na+ (aq)
3

+ NO (aq) + AgCl 
3
Ag+ Cl-
i) iii) AgCl
-
Na+ NO3
ii) CaCO3 CaO CO2

(i) (iii) (ii)

CH4(g) + 2O2(g) L CO (g) + 2H O(g)


2 2

C  H, O = O, C = O, H  O 430 KJ/mole, 498


KJ/mole, 724 KJ/ mole, 462 KJ/mole
XCl + YNO3  XNO3 + YCl 

50g
X Na Y Ag

om DËi
DËi
c
a.
on
m

1 2
.it

XCl + YNO3  XNO3 + YCl 


1 2
YCl (H2O) = 1  2 + 16
w

= 2 + 16 = 18
 1 mole = 18 gm
w

X Na Y Ag  2 mole " = 18  2 gm
= 36 gm
w

H
NaCl + AgNO3  NaNO3 + AgCl 
|
H C H (g) + 2O = O  O=C=O + 2HOH
|
H
= (4430+2498) KJ/mole
= 2716 KJ/mole
NaCl + AgNO3  NaNO3 + AgCl  = [2  724 + 2 (462 + 462)]KJ/mole
= 3296 KJ/mole
 = (2716 – 3296) KJ/mole
= –580 KJ/mole
580 KJ
NaCl (aq) + AgNO3 (aq)  NaNO3 (aq) + AgCl  36g 580 KJ
580
1 " " " " " " = "
36

www.itmona.com 7
580  50 1 3
 50 " " " " " " = "
36
= 805.56 KJ
CH3COOCH2CH3 + H2O  CH3CH2OH + CH3COOH
805.56 KJ
+CH2CH3
CH3COO¯ H+ OH¯
CH3COOCH2CH3

CH4 O2

CO2 H2O

Mg HCl
H2

0 1 2 3 4 5 6 7

0 14 23 31 38 40 40 40
cm3

1, 2 3 CaCO3

Y X
1
CH3COOCH2CH3
2
NH4CNO
3
H2O
c om (cm3/min)

2
DËi
a.

1 3 CaCO3
on

CO2

DËi
m

CaCO3 CO2 CaO


CO2
.it

H2 Y H2
w

X
w
w

CH4(g) + 2O2(g)  CO2(g) + 2H2O(g)

2 NH4CNO NH4CNO

NH4CNO  H2N  CO  NH2


1 min H2

cm3/min

(ii)

www.itmona.com 8
N2, H2 NH3

H2 38cm3 40cm3 N2 + 3H2 2NH3; H =  92 kJmol


(40  38)cm3
=
(5  4)min
2 cm3
= 2 cm3/min
1 min
NH3
 2 cm3/min

DËi
¯1
N2O4(g) NO2(g); H = + 58kJ mol
1
H2(g) + CO2(g) CO(g) + H2O(g); H = + 40kJ mol¯
1
KCl(s) + H2O(l) K(OH)2 + HCl; H = + 19kJ mol¯ c om
a.
on

DËi
0
m
.it

4Fe(s) + 6H2O(l) + 3O2(g)  Fe2O3. nH2O(g)


Fe O2
w

1
N2O4(g) 2NO2(g) ; H = + 58 kJmol¯
w
w

1
H2(g) + CO2(g) CO(g) + H2O(g); H = + 40 kJmol¯
NH3

KCl(s) + H2O(l) K(OH)2 + HCl; H = + 19kJmol¯1

NH3

1 N2 3 H2
2 NH3

www.itmona.com 9
C D A B

200  250
NH3
Fe

NH3
NH3
NH3
i
ii
t=0

A+B C+D
A B 300

300

c om
H
a.

300 3A2(g) + B2(g) 2AB3(g); H =  92kJ/mol


on

DËi
m
.it

DËi
w

H
H
w

H H
w

H

A+B C+D

A, B, C D
C D A B 3A2(g) + B2(g) 2AB(g); H =  92kJ/mol
C D

A B

www.itmona.com 10
+2 2

AB ii)
A B N2 O2 NO

NH3
HNO3
N2 + 3H2 2NH3, H =  92kJ/mol
NH3
NO
HNO3

i. 2HCl + Na2CO3  2NaCl + H2O + CO2


ii. H2SO4 + Ca(OH)2  CaSO4 + 2H2O
NH3 Fe

i)
om 5 gm HCl Na2CO3
NH3
c
200  250 atm
ii)
AB NH3
a.
on

DËi
i. 2Mg + O2  2MgO
m

1
ii. N2(g) + O2(g)  2NO(g); H = 180 kJ mol¯
.it

i) Zn + Cu2+
w

ii)  Zn + Cu 2+
Zn2+
Cu2+
w

2+
Cu Cu
w

DËi 2HCl + Na2CO3  2NaCl + H2O + CO2


HCl 1+35.5
= 36.5 gm
 HCl (36.5  2) gm
= 73 gm
Na2CO3 (23  2 +12 +16  3) gm
= 106 gm
2 HCl
1 Na2CO3
 73 gm HCl 106 gm Na2CO3
106  5
 5 gm HCl gm 7.26 gm
2Mg(s) + O2(g)  2MgO(g) 73
 Na2CO3 7.26 gm

www.itmona.com 11
ii)
H2SO4 + Ca(OH)2  CaSO4 + 2H2O

2Al + 3O2  Al2O3


H2SO4(aq) + Ca(OH)2(aq)  CaSO4(aq) +
2H2O(1)

pH 7
pH 7
(H+)
2Al + 3O2  Al2O3
OH¯ H+(aq) +
OH¯(aq)  H2O(1)

2H+(aq) + SO42¯(aq) + Ca2+ + 2OH¯(aq)  Ca2+(aq) + SO42¯(aq) +


H2O(1)
Al2O3

om
i. CaO + CO2  CaCO3
ii. CaCO3  CaO + CO2
iii. Zn + H2SO4  ZnSO4 + H2
c
H2SO3
a.

(i)
on

DËi
m

DËi
.it

S x,
H +1
w

O 2
H2SO3
w

 (1)  2 + x + (2)  3 = 0 i. i.
,x=62
w

4
H2SO3 S = +4
ii. ii.

Fe2O3.nH2O (i)

n FeO(OH) (a) (II) (III)

4Fe(s) + 6H2O(l) + 3O2(g)  4Fe(OH)3(s) 2FeCl2(aq) + Cl2(g)  2FeCl3(aq)


H2O
2Fe(OH)2(s) Fe2O3.nH2O(s) (b) (H2) (Cl2)
(HCl)

www.itmona.com 12
H2(g) + O2(g)  2HCl(g) (iii)
(c) NH4HCO3 (NaCl) (NH4Cl)
2H2(g) + O2(g)  2H2O(l) NaHCO3
NH4HCO3 + NaCl  NaHCO3(C) + (NH4Cl)

i. CaCO3  CaO + CO2


ii. CO2 + NH3 + H2O  NH4HCO3
iii. NH4HCO3 + NaCl  NaHCO3 + NH4Cl
(Na) (Cl2) CaCO3
(NaCl) CaO CO2
2Na + Cl2  Nacl
CaO CO2
CaCO3 CaO + CO2 — CaCO3 NH4HCO3

+ +
NaCl Na NH4HCO3 NH4
CaCO3 Cl HCO3


25| (i) 

(iii) B +
+ A(g)
(ii) A(g) + NH3 + H2O  B
C
om
c
C
a.
on

DËi
m
.it
w
w
w

(i), (ii) (iii) C

(i)
(CaCO3) (CaO) CO2


(CaCO3)  CaO + CO2(g)
(A)
(ii)
CO2 H2O NH4HCO3

CO2(g) + NH3 + H2O  NH4HCO3


(A) (B)

www.itmona.com 13

You might also like