ORGANIC CHEMISTRY | S.

3 Holiday Notes | ==> Copy into your books

Organic chemistry is a branch of chemistry dealing with carbon and its compounds except
Ecolebooks.com
oxides of carbon, carbonates, hydrogen carbonates and carbides of metals.
These organic compounds contain carbon as the basic framework and other
elements like hydrogen, nitrogen and chlorine are attached to it.
Carbon has a unique behaviour because:
1. It can form a very long chain of carbon atoms, which can be up to 2000 atoms.

These compounds consisting of chains of carbon atoms are called aliphaticcompounds.

These compounds can be saturated (if all the carbon atoms are joined to each other
by a single covalent bond e.g. ethane, ) or unsaturated (if it contains multiple
covalent bonds i.e. either double or triple e.g. ethene, CH 2 =CH 2 and ethyne,

2. It can form a ring of carbon atoms. The compounds that form rings of carbon atoms
are alicyclic compounds.

Because of these two unique behaviours, carbon can form very many and complex
compounds which has made it necessary for its study under a separate branch called
organic chemistry. However, for historical and conventional reasons some simpler
compounds such as carbon dioxide (CO2 ) and sodium carbonate (Na2CO3 ) are usually studied
under non-carbon compound in inorganic chemistry.

Classification of organic compounds

Organic compounds can be classified into several groups. The simplest of the organic
compounds are hydrocarbons. Other groups include alcohols, esters, carboxylic acids,
amines, ketones, alcohols and ethers.
These groups are differentiated from each other by functional groups.

Functional groups are groups of atoms that are common to a given homologous series and
are responsible for chemical reactions. Examples of functional groups include:

-OH for alcohols e.g. ethanol, CH 3 CH 2OH; methanol, CH 3 OH.

-COOH for carboxylic acids e.g. Ethanoic acid, CH 3 COOH; methanoic acid HCOOH.
-NH 2 for amines e.g. amino ethane, CH 3 CH 2NH 2, amino propane, CH 3 CH2 CH 2NH2

Homologous series
This is a series of organic compounds related to each other by the same functional group.
Characteristics of homologous series include:
i) All members conform to a general molecular formula e.g.
CnH 2n+2 for alkanes. If n=2, C2 H 6 (ethane); if n=4, C4 H 10 (butane)

CnH 2n for alkenes. If n=2, C2 H 4 (ethene); if n=3, C3 H 6 (propene)

ii) Members of the same homologous series have the same chemical properties (though
DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM
varying in vigour/speed)

1
 iii) The physical properties of the members change gradually with increase in molecular
Ecolebooks.com
mass. E.g. boiling point, melting point and density increase with increase in molecular mass;
there is a gradual change in state down the group (methane is a gas, pentane is a liquid and
decane is a solid); solubility decreases down the group as molecular mass increases.
iv) Members in each homologous series differ from the next by –CH 2 group (methylene
group).
v) Members have the same general method of preparation

Hydrocarbons
These are compounds consisting of only hydrogen and carbon atoms. They have a general
formula of CxH y where x and y can be any numerical whole numbers.

Hydrocarbons are classified into three main groups as alkanes, alkenes and alkynes.
These three are differentiated by the following functional groups.

Alkanes, Alkenes, Alkynes,

Alkanes
These are saturated hydrocarbons with the general formula of CnH 2n+2 . Where n is the
number of carbon atoms. Alkane members are referred to as the paraffin i.e. they have little
affinity to react.

Sources of alkanes
The main sources of alkanes include:
i) Natural gas. This contains mainly methane with small amounts of other gases like propane
and butane. Methane is formed by anaerobic decomposition of organic matter and it is
found in swamps, stagnant ponds and marshes.
ii) Petroleum. This contains a wide range of alkanes ranging from molecular gases to high
molecular waxy solids (C2 -C40 ). Petroleum is formed by anaerobic decomposition of sea
plants and animals. The components of petroleum are separated by fractional distillation, a
process known as refining.

Nomenclature of alkanes
According to IUPAC (International Union of Pure and Applied Chemistry), all members of
alkanes have their names ending with the suffix –ane.
Value of n Formula Name
1 CH 4 Methane
2 C2 H 6 Ethane
3 C3 H 8 Propane
4 C4 H 10 Butane
5 C5 H 12 Pentane

Straight chain alkanes have a prefix n before the normal name e.g.
CH 3 CH 2 CH2CH3 n-butane

In branched
DOWNLOAD chains,
MORE the branch
RESOURCES LIKE may
THISbe
ONa hydrocarbon or other atoms like chlorine, and
ECOLEBOOKS.COM
bromine.

2
 Ecolebooks.com
The hydrocarbon side chains have one hydrogen less the parent alkanes and are generally
referred to as alkyl groups. The alkyl groups derive their names from respective parent
alkanes e.g.-CH 3 (methyl); -CH 2 CH 3 (ethyl); -CH 2CH2 CH 3 (propyl); - CH 2 CH 2 CH2CH3 (butyl).

For branched alkanes e.g.

i) Name the longest unbranched carbon chain .i.e. the longest carbon chain consists of
5-carbon atoms, it is therefore a derivative of pentane
ii) Give the number showing position of the branch. Count from the side that will give
the branch the lowest possible number. E.g. the branch is on the 2nd carbon atom
(the branch replaces hydrogen on the 2nd carbon)

iii) Name the branch (substituent group) i.e. methyl group

So, write the name of the alkane starting with the carbon position on which the branch is
located (2); put a dash (-); write the name of the branch/substituent group (methyl)
followed by the name of the longest straight carbon chain.

The above compound is therefore 2-methylpentane.

iv) If the branches of side chains are more than one and are similar, di, tri, etc are used.

CH 3 CHCH 2CHCH2CH3 2,4-dimethylhexane

CH 3 CH 3

2,2-dimethylpentane

3,3-dimethyl hexane

v)If the side chains are different, naming follows alphabetical order

DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM

3
 Ecolebooks.com
Note: the longest unbranched chain has 6-C
atoms;it istherefore a derivative of hexane.

3-chloro, 3-methylhexane

Molecular and structural formulae

Molecular formula shows the number of each kind of atoms present in one molecule of a
compound. It does not show the arrangement of atoms in the molecule.

Structural formula (graphical formula) shows the arrangement of atoms in one molecule of
a compound.

Alkanes like other hydrocarbons and other organic compounds have covalent bonds
between the atoms. In alkanes, the carbon atoms use all the four outer most electrons to
form covalent bonds by sharing with other carbon atoms and hydrogen atoms. Because all
the electrons are used up in the formation of covalent bonds, they are called saturated
hydrocarbons.

Compound Molecular formula Structural formula

Methane CH 4

Ethane C2 H 6

Propane C3 H 8

Butane C4 H 10

Isomerism
This is the existence of a compound with the same molecular formula but different
structural formulae.

Isomers are compounds with the same molecular formula but different structural
formulae.

All hydrocarbons with four or more carbon atoms per molecule possess isomers. E.g.
DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM
butane (C4 H 10 )

4
 Ecolebooks.com

2-methyl
propane
n-butane

Hexane (C6 H 14)

2-methylpentane
n-hexane

3-methylpentane
2,2 -dimethyl butane

Properties of alkanes
Alkanes are not so reactive and undergo combustion and chlorination reactions only.
1. Combustion
Alkanes undergo complete combustion in plenty of oxygen to form carbon dioxide and
water vapour. For example, methane explodes in air/ oxygen on application of flame

CH 4 (g) + 2O2 (g) CO2 (g) + 2H 2 O (g) + Heat.

Incomplete combustion of alkanes in limited supply of oxygen produces carbon monoxide,
and sometimes carbon and water vapour.

2CH 4 (g) + 3O2 (g) 2CO (g) + 4H 2 O (g) + Heat.

Or
CH 4 (g) + O2 (g) C(s) + 2H 2 O (g) + Heat.

The combustion of alkanes produces considerable amount of heat. This explains why they
are used as fuel for domestic and industrial uses.

The in complete combustion of carbon occurs in cylinders of petrol engines that results in
DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM
to release of poisonous carbon monoxide and sometimes even carbon. It is therefore
dangerous to run a car engine in a garage where there is no free air circulation.

5
2. Chlorination

Ecolebooks.com
Alkanes undergo substitution reaction with halogens. A substitution reaction is reaction in
which an atom or a group of atoms in a compound is/are replaced by other atoms.

For the case of alkanes, this is only possible with halogens, e.g. when sunlight shines on a
mixture of methane and chlorine, the chlorine replaces hydrogen in a chain reaction i.e.
substitution reaction occurs as follows:

CH 4 (g) + Cl2 (g) CH 3 Cl (g) + HCl (g)

(Chloromethane)
CH 3 Cl (g) + Cl2 (g) CH 2 Cl2 (g) + HCl (g)
(Dichloromethane)

CH 2 Cl2 (g) + Cl2 (g) CHCl3 (g) + HCl (g)

(Trichloromethane)

CHCl3 (g) + Cl2 (g) CCl4 (g) + HCl (g)

(Tetra chloromethane)
This reaction occurs rapidly in bright sunlight and when chlorine is in excess.

Petroleum (Crude oil)

Petroleum is formed by anaerobic decomposition of sea plants and animals. It is oil
consisting of different alkanes normally ranging from C5 H 12 to C43 H 88. The oil deposits are
usually found with sand and brine.

Refining fuel
The different alkanes that make up petrol can be separated by fractional distillation.
This is based on the boiling points of the different components.

After the removal of impurities mainly sulphur compounds, it is heated until when most of
it vaporizes. The vapour is passed into the bottom of a tall fractionating tower. The
fractionating tower is divided into several compartments each cooler than the one below it.

During fractional distillation, the fraction of petroleum that is most volatile settles at the
top, the non-volatile heavy oil runs out, and the bottom of the column.

DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM

6
 Ecolebooks.com
Fractionating tower

Crude oil is separated into the following fractions

Fraction Distilling Number of uses
temperature carbon
atoms
Natural gas e.g Below 40 C C1-C4 Fuel for lighting and heating
methane,ethane,propane purposes
Petrol + naphthalene 40 C to 175 C C5 -C10 Fuel; solvent for grease,
paints and stain;vanish,dry
cleaning
Paraffin 175 C to 275 C C10 -C14 Fuel
Diesel + gas oil 275 C to 350 C C14 -C18 Fuel
Lubricating oil+paraffin Above 350 C C18 -C40 and Lubrication, making candle,
Wax+vaseline above making Vaseline.

The gas oil fraction is cracked to yield more petrol.

Cracking of gas oil

Fractional distillation of crude oil above only yields 20% of the petrol. The cracking
process produces more petrol.

Cracking is the breaking down of large complex hydrocarbons into smaller molecules (of
short carbon chain) by use of heat or catalyst. Heavy alkanes are cracked to produce
useful alkenes and fuel of high quality (relatively smaller alkanes). E.g.

C10 H 22 C7 H 16 + C3 H 6
Cracking can be classified in to:
i)
DOWNLOAD Thermal cracking: this
MORE RESOURCES LIKEinvolves
THIS ONheating of large hydrocarbons at highpressures to
ECOLEBOOKS.COM
break them into smaller molecules.

7
 Ecolebooks.com
ii) Catalytic cracking: this involves the use of a catalyst to break down large
andcomplex hydrocarbons in to simpler ones. Catalysts commonly used are silicon
(IV) oxide and aluminium oxide. Catalytic cracking takes place at a relatively low
temperature and pressure.

ALKENES
Alkenes are unsaturated hydrocarbons with a general formula of CnH 2n. where n=2 or more.
They are characterized by possession of a double bond between carbon atoms.

Nomenclature and structure

Alkenes are named as alkanes except that their names end with suffix –ene. Consider the
table below.
n Molecular formula Name Structural formula
2 C2 H 4 Ethene
or CH 2 =CH 2
3 C3 H 6 Propene

or CH 2 =CHCH3
4 C4 H 8 Butene

or CH 2 =CHCH2CH 3

Isomerism
Isomerism in alkenes begins when n=4i.e from butene. Isomers of butane are:

But-1-ene But-2-ene 2-methylpropene

Ethene
This is the simplest alkene with molecular formula, C2 H 4.

Laboratory preparation
Ethene is prepared by dehydration of ethanol using excess concentrated sulphuric acid.
Set up

DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM

8
 Ecolebooks.com

Procedure
- To 50cm3 of ethanol, add 100cm3 of concentrated Sulphuric acid slowly while shaking
under a tap
- The apparatus is set as above and the mixture heated with care to 180˚C. Ethene is
evolved and is collected over water.

NB. The wash bottle of alkali solution removes sulphur dioxide produced in small quantity as
ethanol reduces sulphuric acid slightly. The alkali also removes fumes of the acid.

Excess Conc. H2 SO4

CH 3 CH 2 OH(l) C2 H 4 (g) + H 2 O(g)
170˚C-180˚C

Sometimes aluminium sulphate is added to the reaction to reduce frothing.

Ethene can also be prepared by catalytic dehydration of ethanol. Here, ethanol vapour is
passed over a heated catalyst to produce ethane.

Properties of ethene
Physical properties
- Is a colorless gas with a faint sweet smell
- It is insoluble in water but soluble in organic solvents eg benzene and methylbenzene
- It is slightly less dense than air

Chemical properties
Alkenes are generally more reactive than corresponding alkanes. They undergo the
following reactions
a) Combustion
Ethene burns in excess oxygen with a smoky flame since it contains a relatively high
percentage of carbon forming carbon dioxide and water vapour
C2 H4 (g) + 3O2 (g) 2CO2 (g) +2H2 O (g) ( ()

b) Addition reaction of ethene

Ethene and other
DOWNLOAD unsaturated
MORE RESOURCEScompounds ON ECOLEBOOKS.COM
LIKE THIS undergo addition reactions an addition
reaction is one in which a molecule adds to an unsaturated compound by breaking the

9
double bond or triple bond
Examples;
Ecolebooks.com
i)When ethene gas is bubbled through bromine water, bromine water changes from red
brown to colourless i.e. the red brown color of bromine is discharged

CH 2 =CH 2 (g) + Br2 (l) CH 2 BrCH 2 Br (l)

This is the common test for unsaturation.

ii) Acidified potassium manganate (VII) solution (purple) turns to colourless if ethene is
bubbled through the solution

The above is alternative test for unsaturation.

When chlorine gas is mixed with ethane and the mixture left in sunlight, the two combine
forming a colorless oily liquid called 1,2-dichloroethane

c) Hydrogenation (addition of hydrogen)

When hydrogen and ethane mixture is passed over a finely divided nickel catalyst, which is
heated to about 2000 C ethane is formed

CH 2 =CH 2 (g) + H 2 (g) CH 3 CH 3 (g)

d) Reaction with sulphuric acid

Ethene undergoes an addition reaction with fuming concentrated sulphuric acid to form an
oily liquid called ethyl hydrogen sulphate

CH 2 =CH 2 (g) + H 2 SO4 (l) CH 3 CH 2 HSO4 (l)

When the liquid formed above is boiled with water, ethanol is produced

CH 3 CH 2 HSO4 (l) +H 2 O (l) CH 3 CH 2 OH(l) + H 2 SO4 (l)

e) Polymerization
Ethene under a very high pressure becomes a liquid. When this liquid is strongly heated to
about 200°C in the presences of a little oxygen catalyst, a white waxy solid (Polyethene) is
obtained.

nCH 2 =CH 2 - CH 2 CH 2 n

DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM

10
 Ecolebooks.com
Uses of ethene
- it is used in the manufacture of ethanol
- it is used in the ripening of fruits
- it is used in the manufacture of plastics (synthetic polymers e.g. polythene)
- it is also used in preparing other solvents

Polymerization
Is the combination of many molecules of the same compound with relatively small
molecular masses to form one complex molecule with very large molecular mass.

The complex molecule with a large molecular mass formed by the combination of many
molecules of relatively small molecular masses is called the polymer. The small molecules
from which a polymer is built are called monomers

Types of polymerization
These are mainly two i.e. addition and condensation

Addition polymerization
This is a combination of many small but unsaturated molecules to form a large molecule
without any other product. In this case, the polymer possess the same empirical formula
as the monomer. E.g. in the formation of Polyethene
nCH 2 =CH 2 -(CH2 -CH 2 ) n -
(Monomer-ethene) (Polymer-Polyethene)

Condensation polymerization
In the condensation polymerization, two different molecules combine to form one large
molecule with consequent loss of simple molecules like water, hydrogen chloride etc. so
the empirical formula of the monomer and the polymer are not the same e.g. formation of
starch from glucose and formation nylon 6,6

Types of polymers
Polymers can broadly be divided into two groups namely natural polymers and synthetic
polymers

Natural polymers

Polymer Monomer Use

Starch Glucose Source of energy
Proteins Amino acids Repair of worn out tissues
Cellulose Glucose Cell walls
Glycogen Glucose Source of energy
Lipids (fats and oil) Fatty acids and glycerol Source of energy,
Natural rubber Isoprene Making foot wears
DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM
Synthetic (artificial) polymers

11
 Polymer Monomer Use

Ecolebooks.com
Polyethene ethene -Making containers, eg plastics bowls
and dust bins
-used as wrapping materials

Polyvinyl chloride (PVC) Chloro ethene -Making rain coats

-Electrical insulation
-making pipes and films
Polystyrene styrene -making packing materials
- making house hold items such as
combs, plastic cups and a common
lining in refrigerators

Classes of addition polymers

There are two main classes of addition polymers i.e. plastics and rubber.

Plastics
A plastic is a substance, which when soft can be formed into different shapes
Plastics are minor products formed by cracking of crude oil eg poly ethene. Polyvinyl
chloride. Melamine
All synthetic polymers are plastics in nature

Advantages of plastics
-They are good thermal and electrical insulators
- They can easily be shaped and molded (they are ductile)
- They resistant to acids and alkalis and they do not rust
-plastics can be coloured when they are being manufactured and they do not need
repainting
- They are light and therefore
portable -They are cheap

Disadvantages
- Produce poisonous fumes when they are burnt
- They are non-biodegradablei.e they do not decay naturally
- Where serious fire hazards occur, molten plastics can inflict very severe burn

Types of plastics
Plastics can be put into two types depending on their behavior upon heating i.e thermo-
softening plastics and thermo-setting plastics

a) Thermo- softening plastics (Thermo-plastics)

These are plastics that soften or melt when heated and can be therefore be moulded
into any shape while they are still soft. The plastics only harden when they cool.
DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM
Structure of thermo-plastics

12
 The long polymer chains in thermoplastics lie alongside each other. They may be entwined
on each other but the polymer chains are not linked (not bonded to each other). When
Ecolebooks.com
heated, the chains slide over each other making them soft and runny.

Examples of thermoplastics
1. Polythene
Polythene is a polymer of ethene. There are two types of polythene i.e. low-
densityPolyethene and high-density polythene.
i) Low density polythene
This is made by polymerizing ethene at a high pressure of 1000-2000 atmospheres and
temperature of 200˚C. Oxygen is used as a catalyst. It has a lower softening temperature
of 105˚C-120˚C. The low density is due to poor packing of the branched polymer chains.
The low-density polythene is soft, light and flexible

Uses:
For making polythene bags; insulation of electric cables because they can withstand bad
weather conditions; making of squeeze bottles such as wash bottles; making plastic bags.
Disadvantage:
At boiling water temperature, they become soft so much that they become flappy and lose
shape.

ii) High density polythene

It is made by polymerizing ethene at low pressure (5-25 atmospheres) and low
temperature (20-50˚C) in the presence of a Ziegler catalyst. It has a higher softening
temperature of about 140˚C. The high density is due top the close packing of the
unbranched polymer chains. Very few of these polymers may be branched.
They are much harder, stiff, and do not lose shape at boiling water temperature.

Uses
For making crates e.g. of beer and sodas, bowls, toys, buckets, food boxes, etc.

2. Polyvinyl chloride (PVC)/Polychloroethene

PVC is made by polymerization of vinyl chloride (chloroethene).

nCH 2 =CHCl -(CH 2 CHCl)n-

(Monomer-chloroethene) (Polymer-polychloroethene)

PVC are more rigid than Polyethene and are used for making water pipes, light switches
and sockets, insulation for electric cables,, carpets, plastic rain coats etc.

3. Polypropene
This is made by polymerizing propene at a high pressure in the presence of a Ziegler
DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM
catalyst.

13
Ecolebooks.com

It is used for making ropes and for

packaging.
b) Thermosetting plastics
These are plastics, which do not soften or melt on heating and therefore cannot
be remoulded into different shapesonce they are set. They simply decompose
upon heating. Thermosetting plastics have polymer chains, which are bonded/
linked to each other. This is called cross-linking.
Structure

Examples of thermosetting plastics include: Bakelite (used for making electric

plugs,
saucepan handler, switches); melamine (used for making cups and children dishes).
Natural
rubber
Natural rubber is obtained from a rubber tree as a milky liquid called latex. Latex
can be coagulated by addition of a little ethanoic acid to form a solid of high
molecular weight.
The monomer of rubber is isoprene (2-methylbuta-1,3-
diene)
Vulcanization of
rubber
Rubber in its natural state is not strong or elastic enough and it is made more
strong and useful by vulcanization, which involves heating the rubber with sulphur.
The sulphur combines with rubber forming cross linkages between natural rubber
chains.

Vulcanized rubber is stronger, more elastic and more

durable.
Uses of vulcanized
rubber
- It is used in the manufacture of
- tyres
Used in the manufacture of foot
Condensation
wears
polymers
Fibres
These are polymers, which can be drawn into threads. This is because, the forces
of attraction between the linear molecules are weak but those between individual
atoms are strong.
Classification of
fibres
DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM
14
Ecolebooks.com

Advantages of synthetic/artificial
polymers
- Relatively low production cost compared to the cost of extracting
natural
- polymers
.
- They are usually stronger and more resistant to corrosive substances like
acids compared to natural polymers.
They can easily be modified depending on the purpose for which the polymer
is required unlike natural polymers, which are hard to modify. As well, their
Disadvantages of synthetic
quality can easily be improved in terms of appearance, strength etc.
polymers
- Many are non-biodegradable causing pollution to the environment.
- When burnt, they produce toxic gases like hydrogen cyanide (from
polypropenenitrile) thus endangering lives of the people working in the
factories.
Alcohols/Alkanols
These are organic compounds with hydroxyl (-OH) group attached to the
hydrocarbon. Alcohols have a general formula of CnH2n+1OH.

Members of the
series
n Molecular formula Structural formula Name
1 Methanol

2 Ethanol

3 Propanol

Alcohols are named by placing –ol in the place of –e in the corresponding

alkane
members.
Ethanol
DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM
15
Ecolebooks.com
Physical
properties
- It is a colourless liquid with a strong characteristic
- smell
- It is a volatile liquid and boils at
78˚C It is very soluble in water
Chemical properties
1. Combustion
Ethanol burns completely in air with a blue non-luminous flame producing carbon
dioxide and water vapour.

C2H5OH (l) + 3O2 2CO2 (g) + 3H2O

(g) (l)
2.
WhenDehydration
a little concentrated sulphuric acid is added to ethanol, an oily liquid called
ethyl
hydrogensulphate is produced and the reaction is exothermic.
C2H5OH (l) + H2SO4 C2H5HSO4 (l) + H2O (l) +
(l) Heat
When concentrated sulphuric acid is heated with ethanol, it produces
ethene.
CH3CH2OH (l) Conc. H2SO 4 C2H4 (g) + H2O
170˚C-180˚C (g)
Preparation of ethanol
Ethanol is manufactured/ prepared by the process of fermentation of
carbohydrates such as starch and sugars.

Fermentatio
n
This is a process in which carbohydrates like starch and sugars are converted
to alcohol by enzymes. The enzymatic break down of glucose yields simple compounds
like ethanol and carbon dioxide. Some heat is as well generated. Fermentation takes
place in the absence of oxygen (anaerobic process).
Preparation from starch
Starch is heated with malt at a temperature of 60˚C. Malt contains an
enzyme diastase, which hydrolyses starch to maltose.

2C6H10O5 (aq) + H2O C12H22O11 (aq)

(l) (Maltose)
Yeast is added at room temperature to the mixture and left to ferment for 2-3
(Starch)
days.
Yeast contains two enzymes, maltase and zymase. Maltase catalyses the hydrolysis
of maltose to glucose as below.
C12H22O11 (aq) + H2O 2C6H12O6
(l) (Glucose)
(Maltose) breakdown of glucose into ethanol, carbon dioxide,
Zymase catalyses producing
the heat in the
C 6H 12O6 (aq)
process. 2C2H5OH (l) + 2CO2 (g) +
DOWNLOAD MORE RESOURCES Heat
LIKE THIS ON ECOLEBOOKS.COM
16
Ecolebooks.com
(Glucose) (Ethanol)

The crude ethanol produced can then be concentrated or purified by

fractional
distillation.
Preparation of ethanol from
millet
- Millet flour is mixed with little water to form paste. The mixture is then put
under
- ground for about 8 days.
It is then removed, roasted and dried under the sun.The dried material is
- then mixed with germinated millet flour (yeast).
Water is added and the mixture allowed to ferment for about 3 days in a
warm place. This forms a local drink known as ―Malwa.
Preparation of ethanol from ripe
bananas
- Ripe bananas are squeezed to obtain the
- juice.
- The juice is filtered to remove the solid
particle.
The juice is mixed with roasted sorghum flour and the mixture allowed to ferment
for 1-3 days in a warm place. A crude form of ethanol locally known as ―Tonto
Beeris is made by the fermentation of the starch in barley; wine by the fermentation
obtained.
of
sugars in grapes. Spirits are obtained by distillation of dilute produced by
solutions
fermentation and therefore have an increased alcoholic content.
Uses of
ethanol
- It is used as an alcoholic beverage e.g. beers, wines and spirits
- It is used as a solvent for paints, varnishes
- etc. It is used as a fuel
- It is used as a preservative and for sterilization
- It is used as a thermometric liquid especially in minimum and
maximum thermometers.

DOWNLOAD MORE RESOURCES LIKE THIS ON ECOLEBOOKS.COM

17