Solution Lesson Work Sheets
Solution Lesson Work Sheets
1. A mixture contains 1 mole of volatile liquid A (P0A= 100 mm Hg) and 3 moles of volatile liquid B
(P0B= 100 mm Hg). If solution behave ideally. The total vapour pressure of the distillate is
a) 85mm Hg b ) 85.88 mm Hg c) 90 mm Hg d) 92 mm Hg
2. Which of the following represents correctly the changes in thermodynamic properties during the
formation of 1 mole of an ideal binary solution?
3. The vapour pressure of pure liquid A is 10 Torr and at the same temperature when 1 g of B solid is
dissolved in 20 g of A., its vapour pressure is reduced to 9.0 torr. If the molecular mass of A is 200
amu. Then the molecular mass of B is :
a) 100 amu b) 90 amu c) 75 amu d) 120 amu
4. The correct relationship between the boiling points of very dilute solutions of AlCl 3(T1 K) and CaCl2(T2
K) having the same molar concentration is
a) T1 = T2 b) T1 > T2 c) T2 >T1 d) T2 ≤ T1
5. Define the term azeotrope. Give one example of a minimum boiling azeotrope.
6. Why is the liquid ammonia bottle cooled in ice before being opened?
7. In thermogravimetric analysis, a sample of 25 mg hydrated compound ( molecular weight =
250g/mol) yields 16 mg of dehydrated compound. The number of water molecules lost per hydrated
compound molecule is ___________.( water has a molecular weight of 18 g/mol)
8. An aqueous solution containing m moles of non-volatile solute freezes at -0.1860C. Calculate the
elevation in the boiling point of the same aqueous solution.(Kf =1.86, K b =0.512)
9. What effect does pressure have on the solubility of solids and liquids?
10 In the following pairs, identify the most important type of intermolecular attractive interaction?
a) n-hexane and n-heptane b) I2 and CCl4 c) NaClO4 and water
11. What is the nature of molecular interactions in solutions with positive deviations? How does the
vapour pressure of such solutions vary?
12. Which of the following will form a non-ideal solution?
a) C2H5OH + Water b) HNO3 + Water c) CHCl3 + CH3COCH3 d) C6H6 + C6H6CH3
13. Which of the following pairs of solutions does not have the same van’t Hoff factor value?
a) 0.10 M FeSO4 and 0.05 M K 4 [Fe
14. A plot of osmotic pressure against concentration(gL-1) of a polymer is constructed. The slope of the
plot
a) increases with increase in temperature b) increases with increase in molar mass of polymer
15. Calculate the freezing point (in 0C) of 0.1 g of K3[Fe(CN)6] (mol.Wt.329) in 100 g of water (K
17. Given an example of a compound where hydrogen bonding results in dimer formation.
19. Which colligative property is preferred for determining the molar mass of macromolecules?
20. According to Reema, a class XII chemistry student, normal saline solution containing 0.9 percent
(mass/ volume) NaCl is isotonic with the fluid inside the cell. As a result, injecting normal saline
solution intravenously is risk free.
a) Define isotonic solutions. What happens if the saline solution concentration is (i) greater (ii) loss
than 0.9 percent (mass/ volume) NaCl?