CHE434 Assignment 2
CHE434 Assignment 2
Semester: 20234
Assignment 2
(CO1, CO3, PO1, PO2)
Table 4: Differences in Stages and Ea for Reactions With and Without a Catalyst
Ea
Reaction Descriptio St (kJ/
n ep mol)
2NO(g) + O2(g) Without 2NO(g) + O2(g) =2NO2(g) 245
=
2NO2(g) Catalyst
With (i) NO(g) + O2(g) =2NO3(g)
(ii)2NO3(g) + NO(g) = 121
Au 2NO2(g)
Catalyst
(solid)
With (i) NO(g) + O2(g) = 2NO3(g)
(ii)2NO3(g) + NO(g) = 134
Pt 2NO2(g)
Catalyst
(solid)
Source: Atkins & Paula, 2006
List of claims:
2. The presence of a catalyst in a reaction does not lower the activation energy (Ea), but the
response takes a new reaction mechanism (stages) where the total Ea is smaller.
3. The presence of a catalyst in a reaction, in this case, a solid catalyst of gold (Au) or
platinum (Pt), increases the reaction steps. There are additional new reaction pathways to change
the reactants (reactants) into reaction products (products).
4. The addition of reaction steps, the addition of new reaction pathways to change the
catalyzed substances (reactants) into reaction products (products), makes the total value of Ea
(activation energy) smaller.