All India Test Series (JEE–2024)

AVJLA2/20 Test- 20 Lakshya JEE

DURATION ::180
DURATION Minutes
90 Minutes DATE : 12/05/2024 M. MARKS : 180

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (5) 37. (4)
19. (4)
2. (7) 38. (1)
20. (6)
3. (3) 39. (3)
21. (9)
4. (3) 40. (6)
22. (2)
5. (8) 41. (4)
23. (3)
6. (2) 42. (8)
24. (2)
7. (3) 43. (1)
25. (2)
8. (4) 44. (5)
26. (8)
9. (B, D) 45. (A, B, C)
27. (A, B, C, D)
10. (A, B, D) 46. (C, D)
28. (A, B, D)
11. (A, C) 47. (B, C)
29. (B, D)
12. (B, D) 48. (B, C)
30. (A, B, C)
13. (A, B, C) 49. (C, D)
31. (A, B, D)
14. (A, B) 50. (A, C, D)
32. (A, B)
15. (D) 51. (C)
33. (D)
16. (C) 52. (D)
34. (D)
17. (D) 53. (D)
35. (B)
18. (B) 54. (B)
36. (D)

[1]
 PART-I (PHYSICS)
1. (5) k2x + mg – T = ma
h
2
1 Adding the equations gives the acceleration of the
E = 3.33 +    = 6.675 blocks as
   2me e
a = (k1 + k2)x/(2m)
  However, subtracting the equations gives
 
2 1 1  1 T = mg – (k1 – k2)x/2
E = 13.6 Z  2 − 
= 13.6 1 − 
2   2 for maximum value of k1, T will be zero.
 n ( n + 2)   2
 1 +   k −k 
  Z   mg =  1 2  x ; k1 = 300.
 2 
 
 
1  1  1 1 5. (8)
 1− =
2   2  
2
2
2
2
 1 +   1 + 
  Z   Z
2
1+ = 2
Z
2 2 …(1)
 = 0.41  Z = 5. Impulse I = m(Vcm + V0)
Z 0.41   m
2
Angular Impulse l  cos   =  …(2)
2. (7) 2  12
For process AB TA = 300 K, TB = 600 K e =1
W = nRT = nR(TB – TA) = 300 nR = 600R.  V0 = Vcm +  cos  …(3)
5 2
Q = n CpT = 2  R(300) = 1500 R. From equation (1) and (2)
2
For process BC m 2
m(Vcm + 2) cos  = 
vf p 2 12
W = nRT ln = nRT ln i nRT ln 2 = 1200 R ln 2
vc pf 3
(Vcm + 2) =  …(4)
Q = W = 1200R ln 2
For process CA From equation (3) and (4)
7
W  P dV = 
300 K 2nRT
dT . 2= −2
600 T K 12
= –2nR(300 = –1200R.   = 8.
Q = nCV  T + W
3 6. (2)
= 2  R(−300) − 1200 R. a
 r2 
2
= –900R – 1200R = –2100R
 dQ = 0 2 rdr V0 1 − 2 
 a 
600 R + 1200 R ln 2 − 1200 R V a 2
= = 0
1500 R + 1200 R ln 2 2
21
=1−  x = 7.
12ln 2 + 15 7. (3)
3 1  2 − 1 3 −  2
3. (3) − = +
v u R1 R2
T = 2T
T=0 2 1.2 1.5 − 12 2 − 1.5
− = +
 aA = aB = g −(80 − d ) −40 20 −20
2 1.2 0.3  −0.5 
4. (3)  + = + 
(−80 − d ) 40 20  20 
Let T be the tension in the ideal string and ‘a’ be
the acceleration of the blocks at the instant of 1.2 0.2 2
+ =
release. For the block on the left, the upward 40 20 (80 − d )
acceleration may be found from 1.6 2
T + k1x – mg = ma +
40 (80 − d )
For the block on the right, the downward
acceleration may be found from 80 – d = 50
d = 30 cm
[2]
8. (4)
After collision balls exchange their velocities
i.e. VA = 2 gh
and VB = 2 g ( 4h ) = 2 2 gh
V 2A
height attained by A will be hA = =h
2g
3
But path of B will be first straight line and then R
parabolic as shown in figure   −   2 
After calculation, we can show that = AB +   (−iˆ)
30 3
 0  3 R 
2
13  
hB = h  2 
4
− ˆ −R ˆ
hA 4
= = i+ i
hB 13 30 540
17R ˆ
= (−i )
540

11. (A, C)
When parallel light falls from left side
3 (3 −  2 ) (2 − 1 )
= +
f R R
4 / 3 (4 / 3 − 2) (2 − 1)
= +  f1 = 80cm
9. (B, D) f1 R R
When paralel light falls from right side
1 (1 − 2) (2 − 4 / 3)
= +  f 2 = 60cm
f2 −R −R

12. (B, D)
 ( u − u sin ) dt = D (horizontal)
As we know that,
Along the line joining hC 12400
=+ K  =  + vs , where  is in
 ( u − u sin  ) dt = d − D  
d electron volt and  is in Å
So, d – D = D  D = When light of wavelength  = 6000 Å is used
2
12400
=  + eV
4000
 eV = (3.1 – 1.77) e volt = 1.33 eV
 V = 1.33 Volt

so,  ( u − u sin ) dt = D ….(1) 13. (A, B, C)

x x q
also,  ( u − u sin  ) dt = 2d − D 2 + d 2 …(2) + − 10 + + x − 18 = 0
R 2 2
 3d  x − 0 x − 20 + q x − 18
on solving 1 and 2 we have D =   + + =0
 4  R 2 1
3 1 q
x  +  + = 28
10. (A, B, D) 2 R 2
Using superposition method, we can assume that q
system consists of whole sphere with density (+ρ) 28 −
x= 2
and the cavity portion is having an additional 3 1
negative density (–ρ). So overall there is no +
2 R
charge density in the cavity
20 − q − ( x)
Now E A = E+ + E− Current in AP = = 3A
2
− R ˆ R ˆ x
o+ (−i ) = i Current in R = = 7 A + R = 2.
30 2 60 R
and EB = E+ + E−

[3]
 m 1 E
= = Er =
mR 54 54

16. (C)
V2
Resistance of 1st bulb = R1 =
P1
V2
Resistance of 2nd bulb = R2 =
P2
When both bulbs are connected in series,
14. (A, B)  1 1  V 2 ( P1 + P2 )
Req. = V 2  +  =
Balancing torque about hinge when tension
 P1 P2  P1P2
becomes zero
Hence, power consumed
l
mg = il 2 B V2 V2 PP
2 P= = = 1 2
mg R  P + P  P1 + P2
 i= V2 1 2 
2 Bl  P1 P2 
If direction of current is reversed, then
mgl 17. (D)
Tl = + il 2 B
2 Relative acceleration 2g
mgl mgl
 Tl = +
2 2
 T = mg

15. (D)
The - particle emitting radioactive gas, thoron-
220, decays to radium-216 an emits an - particle. 18. (B)
The reaction can be represented by R to be maximum.
90 Th → 2 He + 66 Ra
220 4 216
3H Total height
Y= = .
By conservation of momentum, we have 2 2
momentum of - particle = momentum of
recoiling nucleus Ra
v m 4 1
 m v = mR vR  R =  = =
v mR 216 54
The kinetic energy of Ra, ER, is related to the
kinetic energy of alpha particle E by
1
m v2 2 2
ER 2 R R  mR  vR   mg  m 
=   =  
E 1 m v 2  m  m   m   mR 
 
2
PART-II (CHEMISTRY)
19. (4) [H ]2 [CO32 ]
Ka
H2CO3 H+ + HCO 3 Ka1 = 4.0 × 10–7 [H 2CO3 ]
HCO 3 H+ + CO 32 Ka2 = 5 × 10–11 17 [H ]2 2 10 11
2 10
On adding above two equilibria 0.01
H2CO3 2H+ + CO 32 Ka = 2.0 × 10–17  [H+] = 10–4
pH = 4
Ksp = [M+2][CO 32 ]
K sp 2 10 12 11 20. (6)
[CO3]2–minimum = 2
2 10
[M ] 0.1 A, B, C, D, E, G are correct
For equation (1)

[4]
 24. (2)
Compounds I and II are incorrectly represented

25. (2)
The configuration of migratory group remains
TD unchanged
SCD = 4 ln 16 = nCv ln
TC
TD p'
16
TC p/2
p ' 8p
1
TB PA
TA PB
1 1
TB
8 3 =
TA 2
 TB = 150 K
TD = 150× 16 = 2400 K

21. (9)
CH3CH2COONa → Na+ + CH3CH2COO–
H2O H+ + OH– 26. (8)
1
Cathode H+ + e → H2 Ph – CH2 – C  C – CHO (i)NaBH 4
(ii)PBr3
2 (i)Mg/ether
(ii)CO 2
Anode CH3CH2COO– → CH3CH2CO O + e Ph – CH 2 – C C – CH 2 Br (iii)H3O

(P)
CH3CH2CO O → CH3 C H2 + CO2 Ph – CH 2 – C C – CH 2 – COOH SOCl2

1 (Q)
CH3 C H2 → CH3CH2CH2CH3
2 Ph – CH 2 – CH CH – CH 2 – COCl
(Q)
2.5 38.6 60 0.6
Charge 0.036 F (i)H 2 (g)
96500 (ii)Pd/BaSO 4 /quinoline
36 Ph − CH 2 − CH = CH − CH 2CHO
m mole of H2 produced at cathode = =18
2 M wt. = 72 + 5 + 14 + 26 + 14 + 29 = 160
m mole of CO2 produced at anode = 36 M
=8
m mole of C4H10 produced at anode = 18 20
Total no. of m mole of all the gases evolved = 72
27. (A, B, C, D)
22. (2) Salt has equal moles of Na2CO3 and NaHCO3
when phenol phthalein indicator is used, only
H4P2O8 and H2SO5 have peroxy linkage
reaction occur till end point is
Na 2 CO3 + HCl → NaHCO3 + NaCl
23. (3)
40 mL 40 mL
SOF4 is sp3d hybrid but contains no lone pair.
0.05 M 0.05 M
SeF 3 & SeOCl2 contains lone pairs in sp3
 x = 40 mL
orbitals (no d - character) When methyl orange is used in an independent
XeF 5 is square pyramidal with one lone pair. titration, 2x mL of HCl would be required for
Na2CO3 and x mL for original NaHCO3.
BrF 6 is perfectly octahedral containing lone pair  y = 3x = 3 × 40 = 120 mL
in pure s-orbital Hence y – x = 80 and y + x = 160
If methyl orange is added subsequently at phenol
TeF5− & ICl 4 are sp3d2 hybrid with one & two
phthalein end point, x mL of HCl would be
lone pairs respectively. required for NaHCO3 produced from Na2CO3 and

[5]
 x mL for original NaHCO3 i.e. a total of 2x mL H2S 2H+ + S–2 in left direction.
of HCl would be required further. Turnbull’s blue and Prussian blue are the same
NaOH + NaHCO3 → Na2CO3 + H2O compound.
2 m mol 2 m mol
31. (A, B, D)
Volume of NaOH required
Those species which are more acidic than H2CO3
2 x
20 mL mL give effervescence of CO2 and CO2 comes from
0.10 2 NaHCO3. But Ph-OH is not as much acidic that
gives CO2 with NaHCO3. Therefore (C) is
28. (A, B, D) incorrect.

32. (A, B)

33. (D)
Coordination number of oxide ion is 8.
Therefore, it is present in cubical void formed by
eight Na+ ions.
Degree of unsaturation of K is 12
Y does not give 2, 4 – DNP test 34. (D)
Ln+3 ions have unpaired e– in f orbital
Most of the Ln+3 ions are coloured both in the
solid state and in the aqueous solutions.

35. (B)
[IrBr(en)(H2O)3]+  G.I = 2, O.A = 0
29. (B, D) [CoBr2(en)2]+  G.I = 2, O.A = 2
AlCl3.6H2O has no vacant orbital so it will not [PtBr(NO2)(SCN)(NH3)3]  G.I= 4,O.A= 2
behave as a Lewis acid.
Boric acid consists of B(OH)3 units which are 36. (D)
interlinked by H-bonds. 9.36 10 3 22400
Mol.wt = 117
VSTP
30. (A, B, C)
egH = –Ae –5/2RT
The amount of [S–2] required to precipitate group
II cation is less, due to lower value of Ksp. In
presence of dil. HCl, the equation

PART-III (MATHEMATICS)
37. (4) (a 2 − 1)2 + 1  1 & a + 1  1
(a 2 − 1)2  0 & a  0  a = −1

39. (3)
f '(x) > 2x f (x)
f ' ( x )  e− x − 2 xe − x  f ( x )  0
2 2

 − x + 1 , x 1 d  − x2 
f −1 (x) =    f ( x)e   0
1 + − x , x  0 dx  
f ( x )  e− x is strictly increasing function
2
Solutions are –1, 1, 0, 2 
Now, x  1
38. (1)
f ( x ) e− x  f (1)  e −1
2
sin x cos 2 y (or) cos x sin 2 y  1 

[6]
 45. (A, B, C)
f ( x ) e− x  1
2

Let f (x) = x3 – 6x2 + 9x + a
f ( x )  e x x  1,  ) f ' (x) = 3 (x2 – 4x + 3) = 3 (x – 1) (x – 3)
2

for three real and distinct roots
f (1) f (3) < 0
40. (6)
 a  (–4, 0)
Here P(x) = Q(x) (x2 + 1) + x2 – x + 1
Now, f (0) = a < 0
  P (  ) =  2 −   + 4 f (1) = a + 4 > 0
= (   ) − 2  −   + 4 = 1 + 2 − 1 + 4 = 6
2 f (2) = a + 2 may be positive or negative.
f (3) = a < 0
f (4) = a + 4 > 0
41. (4)  [α] + [β] + [γ] = 0 + 1 + 3 or 0 + 2 + 3
Clearly α is solution of the equation x11 = 1 so that = 4 or 5
1 +  + ..... + 10 = 0 .
46. (C, D)
( ) ( ) ( )
10
 f r = f (  ) + f 2 + ..... + f 10 Let P be the point (x1, y1, z1) on the given plane
r =1 then x1 + my1 + nz1 = p ….(i)
(α + α 2 + ... + α 10) + (α 2 + α 4 + ... + α 20) + (α 3 + α
Let Q be (α, β, γ) O, P, Q are collinear so
6
+ ... + α 30) + .... (α60 + α120 + α180 + …. + α600)
= 5 × 10 – 1 × 55 = –5 x1 y1 z1
= = = k (say) ….(ii)
  
42. (8) Now OP  OQ = p2
2  x12 + y12 + z12  2 + 2 +  2 = p 2
Replacing x by we get,
x
10 r
 k (α2 + β2 + γ2) = p2 ….(iii)
 8 6  20
2
 2 + x + 4 =  ar   Also from (i) and (ii), k (α + mβ + nγ) = p
x  r =0  x (iv), from (iii) and (iv)

( )
20
10 p(α + mβ + nγ) = (α2 + β2 + γ2)
 210 2 x 2 + 3 x + 4 =  ar 2r x 20−r
r =0  Locus of Q = (α, β, γ) is
20 20 p(x + my + nz) = x2 + y2 + z2
  ar xr =  ar 2r −10 x20−r
r =0 r =0
Comparing coefficient x7 both sides, we get 47. (B, C)
a7 = a13  23 . f (x) = 
1 − x,
x − 3,
0 x 2
2 x 4
43. (1)
As
 20 

 3 
 and   
N
 (1, 2)
g (x) = 
2 + x,
2 − x,
−1  x  0
0 x3
 (x) , 0  g (x)  2
( fog) (x) = 1 −( g)
6 111 4 4 11 3 3
 g x − 3, 2  g (x)  4
44. (5)
= 
−1 − x,
−1 + x,
−1 x  0
0 x 2

48. (B, C)
 1
x if 0  x 
f (x) =  2
1
1 − x if  x 1
 2
Let F1 (9, 20) and F2 (49, 55) be the foci. For So ‘f’ periodic with period 1
every point ' Q ' outside the ellipse. 1
1 1
QF1 + QF2  k (where ‘k’ is the length of the Also, Required Area = 4 f (x) dx = 4  +  = 1
0 8 8
major axis). So, we have to find P ( x, 0) on the x
axis so that PF1 + PF2 is minimum. Clearly ‘k’ 49. (C, D)
then will be PF1 + PF2 where F2 ' is the mirror There is only one point in A  B C which is say,
image of F2 in the x axis and ‘P’ is the point of ‘P’ with affix z.
tangency. Least value of PF1 + PF2 is F1F2 ' = 85

[7]
 ‘C’ is the straight line x + y = 2 which meets 52. (D)
Let mid point of AB is P (h, k ) & C be centre of
the y axis at Q (0, 2 ) .
given circle.
 −r r 
Then P =  , 2 +  where r = QP  0 and AB subtends 90 at Q (2, 3)
 2 2
‘P’ lies on the circle
B : x 2 + y 2 − 4 x − 2 y − 4 = 0.
 r 2 + (2 + 2 ) r − 2 ( 2 + 1) = 0 gives the
positive value of
− (2 + 2) + 14 + 12 2 In  ABQ, AP = PB = PQ
r= .
2 PC 2 + PB 2 = BC 2
1 (h − 2)2 + (k − 2)2 + (h − 2)2 + (k − 3)2 = 4
This implies that 0  r  2 − .
2
17
So,  x2 + y 2 − 4 x − 5 y + = 0
2
1 1
| z |= OP  OQ + QP  2 + 2 − = 2+
3
2 2 53. (D)
 | z | − |  || z | 3. Also, '  ' lies inside the A B  
circle B and so, In given ABC , both &   0, 
2 2  2
z −   z − 6  −6 z −  3  
sin x is increasing in  0,  & cos x is
 2
50. (A, C, D)  
decreasing in  0,  .
M (x0 , y0 ) is a point on the locus  2
− y0 2 y0 (x0 + 1) If 
A B A
 sin  sin
B
 x1  x2
 =  3x02 − y02 = 3 2 2 2 2
x0 − 2 (x0 + 1)2 − y02
A B
cos  cos  x3  x4
 Locus of ‘M’ is the hyperbola 3 x 2 − y 2 = 3 2 2
 x1  2010  x3  2009
51. (C)      
x
 2  x4 
f ( x − y) = f (x) g ( y) − f ( y) g (x) ...(1)
A B
Similarly, for 
Put x = y in (1)  f (0) = 0 2 2
Put y = 0 in (1) A B 1 1
 =  x1 = x2 & =
 f (x) = f (x) g (0) − f (0) g (x)  g (0) = 1 2 2 x3 x 4
f (0 + h) − f (0)  BC = AC = 1
Now, f ' (0+ ) = lim
h →0 h
f (0) g (−h) − f (−h) g (0) 54. (B)
= lim
h →0 h ( )
log 2 1 + 6 x − x 2 − 8  0  x [2, 4]
f (−h) |  −  |=| f (2) − f (4) |
= lim = f ' (0− )
h →0 −h

PW Web/App - https://smart.link/7wwosivoicgd4

Library- https://smart.link/sdfez8ejd80if

[8]