CHEMICAL SCIENCES

Paper - II
1. Which ofthefollowing atoms has highest 6. The correct order of acidic strength is
electron affinity ? (A) CI,0, >S0,> P,0,io
(A) F (B) CI (B) CO, > N,0,> SO,
(C) Br (D) I (C) Na,O >MgO >Al,0,
(D) K,O > CaO > MgO
2. Among the following compounds that has
the lowest degree of ionic character is 7. Which of the following silver halide ion
has the maximum thermal stability ?
(A) NaCI (B) MgCl,
(A) AgF, (B) AgCi,
(C) AICI, (D) CaCi, (C) AgBr, (D) Agl,
3. Match List -I(Compounds) with 8. The correct statement about Borazine is
List ||(Structures) and select the 1. lIt is not isoelectronic with benzene.
correct answer.
2. It undergoes addition reaction with
List -I List - I| HCI.
1. XeO, i. square planar 3. Electrophilic substitution reaction on
borazine is much faster than that of
2. BrF, ii. tetrahedral
benzene.
3. SeCi, ii. distortedtetrahedral 4. Borazine polymerizes at 90°C.
(A) 1-i, 2- i, 3-i (A) 1and 2 (B) Only 2
(C) 2and 3 (D) 1and 4
(B) 1- i, 2-i, 3- ii
(C) 1-i, 2-i, 3- ii
9. The total number of steps involved and
(D) 1-i, 2- i, 3- i the number of beta particles emitted in
the spontaneous decay of
4. The compound with planar geometry is Ues8Pb06 respectively, are
(A) 8and 6 (B) 14 and 6
(A) N(t-Bu), (B) NPh,
(C) 6 and 8 (D) 14 and 8
(C) NE, (D) N(SiH),
10. Inphotosynthesis, the predominant
5. Among the following molecules, the metal present in the reaction centre of
shortest bond length is found in photosystem Il is
(A) C, (B) N, (A) Zn (B) Mn
(C) O, (D) F2 (C) Cu (D) Fe
3 J-03-02
 11. Thenumberofinorganicsulphur (orsulphide) 16. The cluster having arachno type
atoms present inthe metalloprotein active structure is
sites of rubredoxin, 2 iron ferredoxin and (B) (0s,(CO),)
4 iron ferredoxin, respectively, are (A) (Os (C0),J
(A) 0, 2 and 4 (B) 2, 4 and 3 (C) [Ir,(Co),J (D) (Rh,(CO),J
(C) 0, 4 and 2 (D) 0, 2 and 3
17. Consider the following statements :
12. The correct option for the metal ion I. AsCI, is thermally less stable than
present in the active site of myoglobin,
hemocyarnin and vitamin B, respectively,
PCl_
II. Size of As is more than that ofP.
are

(A) iron, iron and zinc Choose correct answer from the
(B) molybdenum, iron and copper following:
(C) iron, copper and cobalt (A) Statements Iand Il are true and Il is
the correct explanation of I
(D) molybdenum, copper and cobalt
(B) Statements l and ll are true but |l is
13. The molecule which is IR inactive, Raman not the correct explanation of |
active, is (C) Statement lis true and statement I|
(A) HCI is false
(B) N,
(C) SO, (D) HF (D) Both the statements land Il are
false
14. Polarographic method of analysis to
obtain individual amount of Cu²* and 18. The geometries of the anmonia complexes
Cd2+ in a given mixture of two ions of Ni2, Pt²and Zn*² respectively, are
(Cu and Cd²:) is achieved by measuring (A) Octahedral, square planar and
their
tetrahedral
(A) Half-wave potential
(B) Migration current
(B) Square planar, octahedral and
tetrahedral
(C) Decomposition potential
(D) Diffusion current (C) Tetrahedral, square planar and
octahedral

15. The Mossbauer spectra of K,(Fe(CN)J (D) Octahedral, tetrahedral and square
gives a single peak indicate that iron planar
exists as
(A) Spin free iron (lI) 19. The crystal field splitting energy )
(B) Spin free iron (I) for CoCl is 18000 cm-, The Afor the
(C) Spin paired iron (|) CoCI;² would be
(A) 18000 cm-! (B) 16000 cm-!
(D) Spin paired iron (1)
(C) 8000 cm (D) 2000 cm
4
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20. The compound which exhibit Jahn-Teller 25. Consider the following reactions :
distortion is
1. [Cr(H,0)]2 + [CoCI(NH,)]"2 ’
(A) [Mn(H,0),]:2 (B) [Mn(H,0),J-3 [Co(NH,),(H,0)}² + (CrCi(H,0),J2
(C) [Cr(H,0)J-3 (D) [Fe(CN)J4 2. [Fe(CN)J-4 + [Mo(CN)J-3 ’
21. The number of manganese ions in
[Fe(CN)J+ [Mo(CN)J
tetrahedral and octahedral sites, Which of the following is the correct
statement ?
respectively in Mn,o,
(A) One Mn² and two Mn+3 (A) Both involve an inner sphere
mechanism
(B) One Mn* and two Mn+2
(C) Two Mn and one Mn+2 (B) Both involve an outer sphere
mechanism
(D) Two Mn*² and one Mn+3
(C) Reaction 1 follows inner sphere
22. Aligand in metal complex behaves as and reaction 2 follows outer sphere
mechanism
1. Electron pair donar
(D) Reaction 1 follows outer sphere
2. Lewis base and reaction 2 follows inner sphere
3. Nucleophile mechanism
4. Electrophile
(A) 1and 2 only 26. Consider the following statements :
(B) 1and 3 only 1. The size of lanthanides M+3 jon
(C) 1,2 and 3 only decreases as the atomic number
increases.
(D) All 1, 2, 3 and 4
2. Electronic spectra of lanthanides
23. Which of the following compounds is show very broad band.
optically active ? 3. La(OH), is less basic than Lu(OH),
(A) P(NH,),CI, 4. La(acac),.2H,0 is approximately
Square anti prismatic, La is in +3
(B) Ni(CO),(PPh,), xidation state.
(C) trans-Co(en),Cl, Which of the statements given above
(D) cis-Co(en),Cl, is/are correct ?
(A) 1 and 4 (B) 2 and 3
24. Intense blue colour of Prussian blue is a
result of (C) Only1 (D) All the above
(A) Electron transfer from Fe+2 to Fe+
(B) Electron transfer from Fe+2 to Fe+3
27. The common hapticity observed for
CO-ordinationof Can to a metal centre is
(C) d-d transition (A) 2 (B) 4
(D) Paramagnetic nature of Fet2 and (C) 5 (D) 6
Fe+3
5 J-03-02
28. The HOMO of CO is 32. Match Column -A(Coupling reactions)
(A) G- bonding with Column - B(Reagents).
(B) o-anti bonding Column-B
Column -A
(C) n- bonding
(D) T- anti bonding 1. Suzuki I. CH, =CHCO,CH,
29. On oxidative addition of O, to Vaska's coupling
complex Ir(CO)ci(PPh,),, the oxidation 2. Heck I. RB(OH),
state and the co-ordination of Ir changes coupling
respectively by
(A) 1and 3 (B) 2 and 2
3. Sonagashira lI. PhCO(CH),Znl
(C) 3and 1 (D) 2 and 3 coupling
4. Negeshi IV, CH=CR
30. The catalyst involved in carrying out the
metathesis of two molecules of butene coupling
to give ethylene and 3-hexene is V. SnR,
(A) Na,PdCI, The correct match is
(B) Co,(CO), (A) 1-1, 2-1, 3-1V, 4-|||
(C) Grubb'scatalyst
(D) RhCI(PPh,), (B) 1-1, 2-V, 3-|||, 4 -IV
(C) 1-IV, 2-I, 3-11, 4-|
31. Consider the following statements
regarding the carbene: (D) 1-I, 2-1I1, 3-IV, 4-V
1. The carbon of Fischer carbene is
nucleophile.
2. Fischer carbene, generally, follows 33. 31P NMR of H,PO, has
18e-rule. (A) Singlet
3. Schrock carbene behaves like a
(B) Doublet
phosphorus ylide in some extent.
4. InFischer carbene, the M-C bond has (C) Triplet
a relatively low rotational barrier. (D) Quintet
5. A carbene is a 2 e-donar in neutral
atom method.
6. Fischer carbene contains at least one 34. Which of the following exhibit quadrupole
hetero atom and/or a phenyl group. splitting ?
The true combination is
(A) K,[Fe (CN)J
(A) All are true
(B) 2, 3, 4,5 and 6 only (B) K, (Fe (CN)]
(C) 3,4, 5 and 6 only (C) (Fe (H,0),) Cl,
(D) 1,2, 3 and 4only (D) Fe(CO),
6 J-03-02
35. Which of the following statements 37. Forareaction AH° = 9.08 kJ mof' and
are correct with respect to Raman AS=35.7 JK- mot!, which of the
spectroscopy ? followingstatements is correct for the
i. Raman spectroscopy is generally reaction ?
carried out in visible region. (A) Reversible and lsothermal
ii. Polarisability decreases as the
(B) Reversible and Exothermic
electron density increases or as the
length of the band increases. (C) Spontaneous and Endothermic
iii. If Raman lines are to be sharp, (D) Spontaneous and Exothermic
the excitation radiation must be
monochromatic. 38. According to Le-Chatelier principle, if
iv. Stokes lines are more intense than heat is given to solid-liquid equilibrium
antistokes lines. system, then
(A) i, ii and iv (A) Quantity of solid will reduce
(B) i, ii and ii (B) Quantity of liquid willreduce
(C) ii, ii and iv (C) Increase in temperature
(D) i, ii, iiand iv (D) Decrease in temperature

36. Which of the followingstatements 39. Given standard electrode potentials

are correct with respect to rotational
Fe2+ + 2e -’ Fe: E° =-0.440 V
andvibrational spectra of diatomic
molecules ? Fe +3e ’ Fe; E0=0.036 V
i. HCI, HBr, NO, CO are microwave The standard electrode potential (E) for
active. Fet + e ’ Fe?+ is
ii. H,, N,, O,,Br, are microwave (A) -0.476 V
inactive.
(B) 0.404 V
ii. Fundamental vibrations involve no
(C) +0.404 V
change in the centre of gravity of
the molecule. (D) +0.771 V
iv. Transitions which strictly obey
selection rule are called allowed 40. If equivalent conductance of 1 M
transitions and the transitions benzoic acid is 12.8 ohm- cm² and if
which do not obey selection rules the conductance of benzoate ion and
are called forbidden transitions. H+ ions are 42 and 288.42 ohm cm²
(A) i, ii and iv respectively. The degree of dissociation
of benzoic acid is
(B) i, ii and iii
(A) 39% (B) 3.9%
(C) ii, i and iv
(C) 0.35% (D) 0.039%
(D) Allare correct
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 41. For the electrochemical cell 45. The gold number of A, B, Cand D are
MIM*l|X-|X,
E°(M|M) = 0.44 V;E° (X|X) = 0.33 V 0.04, 0.002,10 and 25 respectively. The
From this data one can deduce that protective power of A, B, C and Dare in
(A) M+X’ M+X, spontaneous order
reaction
(A) A> B>C> D
(B) M + X-’ M+ X, spontaneous
reaction (B) B> A>C> D
(C) Ere = 0.77 V (C) D>C> B> A
(D) Ere =-0.77 V (D) C>A>B> D

42. In the Bragg's equation for diffraction of

X-rays, n represents for 46. Which of the folowing wave functions can
(A) Quantum number be solutions of Schrodinger's equation
(B) An integer for allvalues of x (x> 0) ?
(C) Avogadro's number (A) y= Asec x
(D) Moles (B) r= Atan x
(C) r = Aex
43. Example of unit cell with crystallographic
dimensions a #b÷C;a=y= 90°; B90° (D) r=Ae-x
is
(A) Calcite 47. In which set of diatomic molecules, the
(B) Graphite bond order is 2.5?
(C) Rhombic sulphur (A) NO, CN, CN
(D) Monoclinic sulphur
(B) O;, N,, CN
44. Which one of the following statements is (C) O;, CN, NO
incorrect in the case of heterogeneous (D) CN, NO, N;
catalysis ?
(A) Catalyst lowers the activation 48. Para dichlorobenzene and naphthalene
energy
belongs towhich point groups ?
(B) Catalyst actually forms a compound
with the reactant (A) Dap D respectively
(C) Surface of the catalyst plays a very (B) D,, D¡, respectively
important role
(C) Both D,
(D) There is no change in the activation
energy (D) Both Dan
8 J-03-02
49. Which statement is true about the change 52. Which of the followingis true about
Michaelis-Menten kinetics ?
in symmetry on going from BF, to [BFJ ?
defined
(A) Point group changes from Dan to T (A) K,theMichaelis constant,is at
as that concentration of substrate
(B) Point group changes from D., to T, which enzyme is working at maximum
(C) Point group changes from D.,, to D, 4
velocity
(D) Point group changes from D, to Cay (B) K is defined as the dissociation
m

constant of the enzyme substrate

complex
50. The thermodynamical relation expressing (C) K_m is defined as the concentration of
substrate at which enzyme is working
Tds equation is
at half of maximum velocity
(D) It assumes covalent binding Occurs
(A) Tds =C,dT-T OT dV
between enzyme and substrate

OP
(B) Tds =CydT+Tv 53. For nth order reaction dx
=k[A| graph
dt
between log(rate), vs log[AJ, is of the
(c) Tds -C,dT-T oV type
P

(D) Tds =C,dT +T

R
51. Anapproximate equation of state of areal
gas at moderate pressure is P(V-b)= RT,
where R and b are constants. The partition log (rate),
function, Z is given by
1/P
(A) Z = 1+ bP/RT
log [Al,
P
(B) Z= Lines P, Q, R, Sare for the order
1+bT
PQ R S
p2 (A) 0 1 2 3
(C) Z= 1-bT (B) 3 2 1

P (C) 1 2 3 0
(D) Z= (D) 0 3 2 1
1-bT
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 54. The kinetic salt effect for the reactions is 57. Aset of measurement of anexperimental
represented in the graph data shows the values 28.7, 28.9 and
28.8 while the true value is 24.4, thus the
experimental data shows
(A) Good accuracy and poor precision
(B) Good accuracy and good precision
R
(C) Poor accuracy and p0or precision
(D) Poor accuracy and good precision
58. The equation of straight line is y=ax +b.
Toobtain the regression line y on x,the
slope of the line (a) is estimated by

Match the following : nEx,y,- x,2y,

(A) 2
System Reaction Symbol for
the Reaction
nEx, -(x,)
I. S,o+T (B)
n2x,y,- 2x,9, 2

I. NO,NCo,C,H, + nEx-(Ex,)
II. CH,COOC,H, + OH P
nEx,y,- x,3y,
V. H,O, + H+ + Br R (C)
(A) |-P, I|Q, l R, IV-S nx, -nEy,
(B) |-S, I|Q, IllP, IV-R
(D)
n2x,y,- 2x,y,
2
(C) |- P, I| - R, IIlQ, IV -S nEx, - nEy,
(D) |-S, I| P, II -R, IV- Q
59. Match the Column |with Column II.
55. According to band theory of bonding, Column -I ColumnI|
conduction occurs in very good
conductors because P. S, ’ S,+ hv 1. Heat internal
(A) Valence band is full Conversion

(B) Band gap is appreciable Q. S, ’ S, 2. Phosphorescence

(C) Valence band and conduction band R. S, ’ T, 3. Fluorescence
overlap S. T, ’ S,+ hv 4. Intersystem
(D) Band gap is small crossing
P R
56. Which of the following, when doped into
a crystal of ultrapurified germanium, will (A) 2 1 4 3
convert it into a P-type semiconductor ? (B) 3 1 4 2
(A) In (B) P (C) 2 4 1 3
(C) As (D) C (D) 3 4 1 2

10 J-03-02
 64. Match Column (Molecules) with
60. The Hermitian conjugate of operator d
d dx Column -Il(Modes of vibrations).
called is actually equal to Column -I|
dx Column -I
p. 7
I. HCI
(A) (B)
dx dx q. 4
II. SO,
d r. 3
(C) (D) i II. CO,
dx
S. 1
IV. C,H,
61. Molecular recognition is made through IV

(A) Host and guest molecular (A) s

complementarities
(B) Non-covalent interactions (B) p r

(C) Inter and intramolecular (C) s

phenomena (D) s
(D) All above three

62. Formation of photochemical smog is 65. Match Column I with Column -I.
made by Column -I Column -II
(A) O, Hydrocarbons
(Term) (Related property)
(B) NO, Hydrocarbons
(C) CO,, Hydrocarbons I. Coagulation p. Scattering of
(D) N,O, Hydrocarbons light
I. Lyophilization q. Washing of
63. Match Column I with Column I1. precipitate
Column-1 Column-1| r. Purification of
I. Peptisation
I. Osmometry p. Ma
colloids
I. Light scattering q. Mw
III. Sedimentation r. M,
IV. Tyndalleffect s. Electrolyte
s. M, IV
IV. Viscosity
IV (A) s r p

(A) p (B) s p
(B) p (C) r
r
(C) q (D) r
r
(D) q
11 J-03-02
66. Match Column -Iwith Column ll. 68. The products obtained in the following
transformation are
Column -I Column - Il
(System) (Energy level)
2n-1 hv
1. Harmonic p. En = Products
Oscillator
2
II. Hydrogen atom q. E, =n
III. Particle in a box r. E is (A) and
continuous
IV. Free particle in s. E, an?
motion
IV (B) and

(A) q r

(B) q
(C) p (C) and
(D) p S OH

67. Match Column I with Column I|.

(D)
Column-1 Column -11
I. WsW1s dT =1 p. Orthogonal

I. VisV2s dT =0 q. Normalization
69. The following inter conversion involves
III. AB=BA r. Hermitian
H H D
CD, CH2
IV. viAV2 dT = s. Commutation H.

CD2 cH2
III IV (A) Sigmatropic shift
(A) q S r
(B) D/H-Shift
(B) p q r S

(C) 4 p
(C) Electrocyclization-ring opening
(D) p (D) Cycloaddition-cycloreversion

12
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70. The product obtained in the following 72. The product obtained and reaction name
transformation is
in the following reaction is
RCHO + NH, Product
R R
Zn/AcOH
(A) NH, Product
R
4
EtO,C RT
R Ri
R R
R
(B)
R COEt

(A) R It is Knorr synthesis

R
-R1
(C)

(D)
R COEt
R (B) Ri R2 It is Knorr synthesis
H
71. The correct statement(s) for following
conversion

HCI
R COZEt
H It is Pall-Knorr
(C) R2 IN "R1
Statement-1: Fisher Indole synthesis synthesis
Statement- 2: Aza- Cope
rearrangement
followed by
deamination
Statement -3: Boulton - Katritzky
reaction
Statement 4: Borshe- Drechsel R2 R

cyclization (D) EtO,C It is Pall-Knorr

(A) Statements 1and 2are correct R1
synthesis
(B) Statements 1 and 3 are correct
(C) Statements 1,2, 3and 4 are correct
(D) Statements 1,2 and 3 are correct
13 J-03-02
73. The product obtained in the following 75. The correct example of 1, 2-Wittig (or)
reaction is 1, 2-Sigmatropic rearrangement is
(DHQD),-PHAL
H (A)
R
R

OH
OH H
(A) Rs R
(B) RoR
R, R R.

OH
OH H
(B) R R1
RLi
Rs (C) Ro-R1 R OH

OH
(C) Rs R,
H
(D) R-NH2
R NH2
H

(D) R OH
OH
76. The formation ofBromocyclohexa-2-ene
from cyclohexene by treating with NBS,
74. The following conversion involves
AIBN inCCI, reflux is belongs to
R´ OAg ROR +CO, + Agl
NBS, AIBN
-Br
(A) S,2 Reaction, Heterolytic cleavage, CCI,, reflux
Decarboxylation followed by S,2
(B) S2 Reaction, Homolytic cleavage, (A) Wohl-Ziegler reaction
Decarboxylation followed by S,1
(C) S,2 Reaction, Homolytic cleavage, (B) Hell-Volhard-Zelinsky reaction
Decarboxylation followed by S,2 (C) Angeli-Rimini reaction
(D) S,,1 Reaction, Homolytic cleavage,
Decarboxylation followed by S2 (D) Conrad reaction

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 77. The correct order of relative rate of 79. Which of the following stereo isomeric
reactivity in the solvolysis of following
molecules with acetic acid is pairs will not give the same corresponding
Aroco ArOco product(s) ?
H
OTs
Acetolysis ’ Product(s)
(a)

() (I1) Acetolysis
OTs ’ Product(s)
H (b)
OCOAr
Me
H -Br
Br-H E reaction ’ Product(s)
Me
(X)
(I)
(A) () > (I) > (0) Me
Br -H
(B) () > (I1) > (1) H-Br ’ Product(s)
E reaction
Me
(C) () >(I) >() (Y)
(D)(1) >() >(0)
78. In which of the following molecules I, I| NaBH4
and IlI, the observed max value is lower Hg0t
’ Product(s)
Me
than calculated ? (K)

NaBH4
Me
Product(s)
(1)
Hg0t
() (11) (L)

(A) Molecule -| (A) Pair Xand YIsomers

(B) Molecule -| (B) Pair a and b lsomers
(C) Molecule -IlI (C) Pair Kand L Isomers
(D) Allthe above (D) Pair a, b and Pair X, Y
15 J-03-02
80. Which of the following is observed when 82. The most stable conformation of

UV-Visible spectrum of a-B unsaturated optically active 2, 3-Butanediol and

Meso 2, 3-Dibromo butane are
Compound is recorded in polar solvent ?
respectively
(A) The (n ’ T*) band moves to longer Me

and (n ’ )band moves to OH

shorter 2
OH

(B) The (T’ ) band moves to longer Me

Aand (n ’T) band mnoves to

longer B

Me
(C) The ( ’ r*) band moves to
shorter and (n ’ T)band moves M H

to shorter 2 B

(D) The ( ’ T*) band moves to

Me

shorter and ( n ’ ) band moves Me

to longer
H
HO

OH

81. In alinear synthesis like A’B’ C

Br
’D with yield of each step being Ato Me
H.

B= 80%, Bto C=50% and Cto D =50%,

the overallyield of A’ D is Me

Br

(A) 75% IV

(B) 40% (A) land IV

(C) 50% (B) Illand ||
(D) 20% (C) lland IV
(D) l and I|
16 J-03-02
83. The product of the
following reaction 84. Choose the correct statement for
following molecules.
Ph
COOH
OTMS HOH H
Br
OTMS HO-H -Br
+Product
TMSOTf
-78/DCM HgC
Ph
() (U)

GS

(4)
G
(111)

CH,
R, S refers configurations

(B)
(A) () Dissymmetric,
(I1) Asymmetric,
(1) Symmetric

(B) () Asymmetric,
(11) Symmetric,
(C) (111) Dissymmetric

(C) () Dissymmetric,
(11) Symmetric,
(I) Asymmetric
(D) (D) () Asymmetric,
(I) Dissymmetric,
(I) Symmetric
17
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 85. The major and minor product(s)obtained 87. Lipinski's rule states that, in general, an
in following conversion orally active drug has no more than one
violation of the following criteria
Hoc-CHO
OL
THF
(A) No more than 5 hydrogen bond donors
-78°C
Major Product + Minor Product and 10 hydrogen bond acceptors
(B) No more than 5 hydrogen bond
acceptors and 10 hydrogen bond
donors
(A) HyC
ÖH Þ and (C) Nomore than1Ohydrogen bonddonors
and10 hydrogen bond acceptors
(Major) (Minor)
(D) Nomore than5 hydrogen bonddonors
and 5 hydrogen bond acceptors
(B) H,C HgC.
88. Arrange the correct order of rate of
OH O and OH O reactivity difference i.e. AE,, AE, and AE.,
(Major) (Minor) for followingdiastereomeric pairs.

MeO,C

(C) H,C Hydrolysis a-Product

and ÖH O aE,
(Minor) (Major) Hydrolysis -e-Product
co,Me

co,Et
OH
Hydrolysis a-Product

(D) H3C HgC Hydrolysis e-Product

OH O and co,Et
(Minor) (Major) OCOPh
Hydrolysis a-Product

AE,
86. Which of the following molecule is inert Hydrolysis -e-Product
OcOPh
towards oxidation with alkaline KMnO, ?
(A) p- Nitro Toluene
(A) AE,>AE, >AE,
(B) ter-Butyl benzene
(B) AE, >AE, > AE,
(C) n-Butyl benzene
(C) AE, > AE,>AE,
(D) None of the above
(D) AE, > AE,>AE,
18 J-03-02
 89. Whichof the following molecules produce 91. The structure of the final major product
5, 5 - dimethyl-cyclohexa-1, 3-dione ?
obtained in the following conversions
(A) Cyclohexanone and methyl bromide
(B) Cyclohexanone 1,3-dione
(C) Acetone and ethyl acetoacetate
CHO 1) But AlH 1)(-)1PC,BH
(D) Acetone and diethyl melanoate 2) CH,C(Me)OMel
+Intermediate 2) NaOH/M0, Major product

TsOH 3) dl. H,S0,

90. The stereo heterotopic relationship of
specified H, andH, inthefollowing
molecules
Ha
OH
(A)
OH
(0)
Me
-Me

OH
(B)
Ha HO
Hp
(1)

Ha H
OH

(1) (C) HO
(A) In molecule Ihomotopic; In
molecule ll homotopic; In molecule
Il diastereotopic
(B) In molecule Ihomotopic; In
molecule Il enantiotopic; In
molecule ll diastereotopic OH
(D)
(C) In molecule I diastereotopic;
In molecule ll enantiotopic; In OH
molecule ll homotopic
(D) In molecule Ienantiotopic; In
molecule ll homotopic; In molecule
IlIldiastereotopic
19 J-03-02
 93. The starting material for formation of
92. ChO0se a correctstatement from the following target molecule (TM)
following options. Me

(A) Cyclopentenyl anion,

Cyclopentadienyl cationand
Cyclopropenyl cation are aromatic.
Cyclopentenyl cation,
Cyclopentadienyl anionand (TM) Ph
Cycloheptatrienyl cation are
antiaromatic.

(B) Cyclopentenyl anion, (A)

Cyclopentadienyl cation and
Cycloheptatrienylcation are Ph
antiaromatic.
Cyclopentenyl cation,
Cyclopentadienylanion and (B)
Cyclopropenyl cation are aromatic.
Me
(C) Cyclopentenyl anion,
(C) Styrene
Cyclopentadienyl cation and
Cycloheptatrienyl anion are (D) Ethyl benzene
antiaromatic.
Cyclopentenyl cation, 94. Which of the following bicyclic ketone does
Cyclopentadienyl anion and not undergo Aldol self-condensation ?
Cycloheptatrienyl cation are
aromatic.

(D) Cyclopentenyl anion,

Cyclopentadienyl anion and (A) (B)
Cyclopropenyl cation are
antiaromatic.
Cyclopentenylcation,
Cyclopentadienylcation and
Cycloheptatrienylcation are (C) (D)
aromatic.

20 J-03-02
95. Among the following forms of the 98. The IUPACname of the following
carbon, the thermodynamically most molecule
stable one is Br

(A) Cartbon nanotube

Br Br
(B) Diamond (A) 2-E, 4-Z, 6(R)-3, 4, 6-tribromo hepta
(C) Graphite 2, 4-diene

(D) Fullerene (B) 2-Z,4-Z, 6(R)-3, 4, 6-tribromo hepta

2, 4-diene
(C) 2-Z,4-E, 6(S)-3, 4, 6-tribromo hepta
96. The equation for measuring the partition 2,4-diene
coefficient (p) of a drug (D) 2-Z, 4-Z, 6(S)-3, 4, 6-tribromo hepta
(A) Con. of drugin 1-Octonol/Con.of 2, 4-diene
drug in aq. solution
99. Predict how many signals are possible
(B) Con. of drug in 2-Octono/Con. of for 1-Chloro-2, 4-dimethyl pentane in
drug in ag. solution 'H-NMR and 13C-NMR spectroscopy
(C) Con. of drug in ag. solution/Con. of respectively ?
drug in 1-Octonol
(A) In 'H-NMR 06 and 19C-NMR 06
(B) In 'H-NMR 06 and 13C-NMR 07
(D) Con. of drug in ag. solution/Con. of (C) In H-NMR07 and 13C-NMR O6
drug in2-Octonol (D) In 'H-NMR 07 and 13C-NMR 07
97. The atom economy formula 100. Presence of these ions/elements and
Total types of atoms in desired product
their quantities are the International
x 100
(A) Total mass of atoms in all products Standards for drinking water
Mol. wt. of desired product
(A) Fluoride 1ppm; Lead 30 ppb;
(B) x 100 Nitrate 90 ppm; Sulphate 500 ppm
Mol. wt. of all reactants
(B) Fluoride 2 ppm; Lead 20ppb;
Mass of atoms in main reactant
x 100
Nitrate 80 ppm; Sulphate 500ppm
(C) Mass of atoms in desired product (C) Fluoride 1 ppm; Lead 20 ppb;
Total mass of atoms in all products X 100
Nitrate 50 ppm; Sulphate 500 ppm
(D) Total number of atoms in desired product (D) Fluoride 1ppm; Lead 40 ppb;
Nitrate 90 ppm; Sulphate 600 ppm

21 J-03-02