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XI Assignment CH 2

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11 views

XI Assignment CH 2

Uploaded by

taashi2008
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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AMITY INTERNATIONAL SCHOOL, NOIDA

Class XI

Chemistry

Unit: 2 (Structure of atom)

LEVEL 1

1.Give one point of similarity and dissimilarity between 1s and 2s orbital. (1)

(similarity: same shape, dissimilarity: different energy.)

2. If the radius of 1 st Bohr orbit is ao, then what is the radius of the 3 rd Bohr orbit. (1)

(As cathode ray are made up of electron.)

3. What is the value of angular momentum for an electron in 5th orbit (1)
according to Bohr’s theory. (5h/2π)

4. Differentiate between (a) Orbit and orbital


(b) Radial node and planar(angular) node (2)
5. Show giving an example that Heisenberg’s uncertainity principle has no significance

in everyday life. (Since mass is very high so wavelength is negligible.)

(2)

LEVEL 2

6. How many unpaired electrons are present in the following :


Cu (Z= 29) , Br‒ (Z= 35) (2)
(Both have zero unpaired electron.)
7.How many angular and radial nodes are present in 3p orbital ? (2)
(angular and radial nodes is 1)
8. Define Hund’s rule of maximum multiplicity. Why is it called so? (2)
(total spin value is maximum.)
9. Which one of the two, an electron or a proton would show shorter de Broglie
wavelength when moving with the same velocity? Justify your answer. (2)
(Proton wavelength indirectly directly proportional to mass)
10. The line spectrum of which of the following species can be explained by Bohr’s theory
and why? He2+, Li+ or Li2+ (2)
2+
(Li no. of electron is same as H)
11. What is the difference between energies of different subshells and orbitals in case of hydrogen
and other multielectron atoms. (2)
(hydrogen depends on principle quantum no. n
other multielectron atoms. principle quantum no. n + azimuthal quantum no. l)

12. Draw the shapes of the following orbitals:


(a) px (b) dx2-y2 (c) dxy (3)

13. Write the electronic configuration of Chromium (z=24) and predict in it


(a) number of subshells (b) number of electrons in subshell having l = 0
(c) number of electrons having n+ l value equal to 3
(d) number of electrons in highest value of n. (5)
(a) 7 (b) 7 (c) 8 (d) 1

14. In which atom, the outermost electron can have the following set of quantum numbers?

n=3, l=0, ml=0, ms= -1/2 (Mg) (1)

LEVEL 3

15. Give the quantum numbers for the electron with the highest energy in Potassium atom. (2)
(4S1 n= 4 l= 0 m= 0 s = +1/2 )

17. The ionization energy of He+ is 8.72 x 10-18 J/atom. Calculate the energy of the first stationary
state of Li+. (-1.96 x 10-17 J/mol) (2)

18. Which one is more stable: Ferrous or Ferric salts and why? (Ferric half filled) (2)

19. Name the following: (3)


(a) Orbital which does not have directional characteristics. (spin)
(b) Quantum number which tends to specify the orientation in space for an
orbital.(magnetic)
(c) Quantum number which does not follow from the solution of Schrődinger wave.
(spin)

20. a) Define Pauli’s exclusion principle . (1+1+3)


b) Identify degenerate orbitals from the following:
3dxy , 3dzx , 4dxy

c) An electron has a speed of 600 m/s with uncertainity of 0.005 %. What is uncertainity in
locating its position. (1.92X10-3m )

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