MATERIAL SAFETY DATA SHEET

Trade Name CHIMEC 1036

Product Code 100/1

1. Identification of the substance & the company

Identification of the substance
Trade name : CHIMEC 1036
Chemical family : blend of aliphatic amine in high boiling
point aromatic solvent.
Type of product and use : corrosion inhibitor - neutralizing
product.
Company identification
Responsible for placing on the market : CHIMEC S.p.A.
Address and telephone nr : CHIMEC S.p.A., Via Ardeatina, Km 22,5
00040 S. Palomba di Pomezia - ROMA
Tel. 06.918251
Fax 06.91825260

2. Composition / information on ingredients

Hazardous component(s) : diethylamine.

Highly flammable (F), Corrosive (C).
R:11,20/21/22,35.
DL50 oral: 540 mg/Kg (rats). DL50 dermal:
820 mg/Kg (rabbits).
CL50 inhal.: 13.4 mg/l /4 h.(rats).
CAS Nr.109-89-7 Conc.
: 40 - 50 %
: 1 methyl naphtalene.
Harmful(Xn). R:20/21,43.
CAS Nr.90-12-0 Conc.
: 2-5%
: 2 methyl naphtalene.
Harmful(Xn). R:20/21,43.
CAS Nr.91-57-6 Conc.
: 5 - 10 %
: quinoline.
Harmful(Xn). R:21/22.
CAS Nr.91-22-5 Conc.
: 2-5%
: aromatic solvent.(high boiling point).
Harmful (Xn), Dangerous for environment
(N).R:51/53,65.
TLV (OEL): 100 ppm.

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CAS Nr. 64742-94-5 Conc.

: 20 - 30 %
: ethylene diamine. Corrosive(C). R:10,21/
22,34,42/43.
LD50 oral: 1200 mg/Kg (rats).
LD50 dermal: 730 mg/Kg (rabbit).
CAS Nr.107-15-3 Conc.
: 5 - 10 %

3. Hazards identification

Important hazards : the product is flammable and harmful if

inhalated, ingested or on contact with
skin: the most important hazard is
exposure to high vapour concentration,
which may produce central nervous system
depression.
: the product is corrosive: the
concentrated solution produces serious
damage on contact with skin and eyes. If
swallowed, it may cause internal and
mouth burns.
: the product is harmful if inhalated,
ingested or on contact with skin: the
most important hazard is endo-tracheal
aspiration which may cause pulmonary
edema and hemorrhage.
: repeated skin contact may cause
sensitization.

4. First-aid measures

First aid
- Inhalation : remove the exposed person from
contaminated area; keep warm and in
fresh air.
: if victim has trouble breathing,
transport to medical care and give
supplemental oxygen.
: in case of loss of consciousness, give
artificial respiration.
- Skin contact : take off immediately all contaminated
clothing.
: wash thoroughly with soapy water.

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: if irritation persists, seek medical

advice.
- Eye contact : wash with plenty of water,for at least 15
minutes, keeping the lids well open.
: seek medical advice.
- Ingestion : rinse the mouth with clean water; give
plenty of water, seek medical advice.
: do not give anything by mouth to an
unconscious or convulsing person.

5. Fire - fighting measures

Extinguishing media
- Suitable : carbon dioxide, dry chemicals, foam,
water spray ( or fog).
- Not suitable : none.
Fire/explosion hazards : keep away from sources of ignition - no
smoking.
: avoid breathing the fumes.
: avoid static build up; must be earthed.
: avoid vapours contact with sources of
flame (open flames, sparks, very hot
surface).
Fire-fighting procedures : fire fighters and others who may be
exposed to the products of combustion,
should be equipped with NIOSH approved
positive pressure self-contained
breathing apparatus and full protective
clothing.
: when exposed to flames or high
temperatures encountered during fire
conditions, sealed containers may rupture
because of the build up of internal
pressure: cool containers with water and
remove.
: the contaminated water used for
extinguishing must be disposed of in
accordance with local legislation.

6. Accidental release measures

After spillage / leakage

- on soil : limit contaminated area until risk of

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dangerous concentration in the air has

been eliminated.
: isolate the dangerous area, wear
protective clothing. Remove all sources
of ignition and contain the spill with
inert materials.
: vapours heavier than air propagate at
ground level and may cause risks of
explosion and poisoning in basements and
pits.
: then collect in suitable containers and
dispose of or burn at approved site.
: avoid dispersion of large quantities of
product in sewers or waterways.
- on water : if spilled product is going into water
courses or drain and soil or vegetation
are contaminated, advise legal authority
and take measures to minimize effects on
the aquatic environment.

7. Handling and storage

Handling : avoid contact with skin and eyes.

: handle this product near emergency
showers, emergency eye-wash and with
independent breathing protection.
: protect eyes from vapour/spray.
: do not breathe vapour/spray.
: take precautionary measures against
static discharge during blending and
transfer operations.
: wear suitable respiratory equipment.
: a localized aspiration is necessary if
the warmed product forms vapours.
Storage : store in well closed boxes.
: store in a fresh and well-ventilated
place, away from incompatible
substances.
: keep containers in store rooms with
security electric plants and protection
from atmospheric discharge.
: store away from all sources of ignition
(heat sources, sparks and open flames).
: store away from heat source. Avoid static
build up. Must be earthed.

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: do not store at a temperature exceeding

: 50°C
Suitable storage materials : stainless steel, teflon and fluorinated
polymers, high density polyethylene,
phenolic resins, Viton.
Not suitable storage materials : copper and its alloys, natural or butylic
rubber, polyacetalic resins,
polycarbonates, polyurethanes, nylon and
poly-methyl methacrylates

8. Exposure controls / personal protection

Occupational exposure limits : this product is a complex mixture and

contains following substances with
recommended or approved OEL limits:
TLV (mg/m3) : ----
TLV (ppm) : ----
TLV (ref. to solvent) (mg/m3) : ----
Personal protection
- Respiratory protection : a localized aspiration is necessary if
the warmed product forms vapours.
: protective mask in case of exposure to
vapours formed by warmed product.
- Skin protection : protective gloves in neoprene or latex,
approved for protection against chemical
substances (EC seal - Directives 89/686
and 93/68).
- Eye protection : goggles or face shield with safety
glasses.
- Others : appropriated protective clothing.
: eyewash bottle with clean water.
Industrial hygiene : ventilate thoroughly the working place.
: do not eat or drink when handling this
product.
: remove all contaminated clothing and
remove protective clothing when the work
is completed.
: handle in accordance with good industrial
hygiene and safety procedures.

9. Physical and chemical properties

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Appearance
Physical state at 20°C : liquid.
Colour : brown.
Odour : ammonia odour.
Change in physical state -760 mm Hg
- Freezing point (°C) : n.d.
- Boiling point (°C) : n.d.
- Pour point (ASTM D97) (°C) : n.d.
Density at 20°C (gr/cm3) : 0.87 ± 0.02
Viscosity at 20°C (cP) : < 50
Solubility in water (% weight) : not very soluble.
Soluble in : aromatic and aliphatic hydrocarbons.
pH value in distilled water : N.D.
Flash point (ASTM D 93) (°C) : <0
Auto-ignition temperature (°C) : n.d.
Explosion limits
- Lower (% vol) : n.d.
- Upper (% vol) : n.d.
Thermal decomposition (°C) : stable if utilized under normal
conditions.

10. Stability and reactivity

Conditions to avoid : caution must be used when mixing the

product with strong acids and bases.
: extremely high temperatures.
Substances to avoid : corrosive for aluminum, zinc, copper and
its alloy.
On combustion forms : this product may release smoke, toxic
fumes (carbon dioxide e carbon monoxide,
NOx) and irritating gases (amines).
Hazardous decomposition products : no hazardous decomposition products.
Hazardous reactions : avoid contact with acids, acid chlorides,
acid anhydrides and oxidizing agents.
: under special conditions nitrosamines may
be formed with nitrites and/or nitrous
acid; nitrosamines have proved to be
carcinogenic in animal experiments.

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11. Toxicological information

Rat oral LD50 (mg/kg) : ----

Rabbit dermal LD50 (mg/kg) : ----
Rat inhalation LC50 (ppm) : ----
Inhalation : vapour overexposure: extreme irritation
of respiratory tract, pulmonary
inflammation, congestion, with potential
for pulmonary edema.
: vapours or fog inhalation at high
temperature may produce irritation of
respiratory tract.
Dermal toxicity : may produce dermatitis and burns.
Ingestion : may cause gastro-intestinal troubles,
with nausea and vomiting.
Corrosivity / Irritating capacity
- skin : corrosive.
- eyes : corrosive.
Sensitization : repeated skin contact may cause
sensitization.
Carcinogenicity : no evidence of this effect is shown.
Mutagenicity : no evidence of this effect is shown.
Teragenicity : no evidence of this effect is shown.

12. Ecological information

Information on ecological effects : utilize in accordance with good working

practice and avoid to disperse the
product in the environment.
: this product is strongly basic and, if
not diluted or neutralized, may be
dangerous limitedly to areas involving
great spills.
: the product is toxic to aquatic
organisms, may cause long-term adverse
effects in the aquatic environment.
Mobility : with a correct disposal in biological
treatment system, are not expected
problems for the degradation activity of
activated sludge.
96 Hour-LC50-fish (mg/l) : ----

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Persistence and degradability : readly biodegradable.

Biodegradation (%) : the product is rapidly and irreversibly
adsorbed onto suspended matter and soil.
: because of its very low solubility in
water, this product may be easily
separated by mechanical means in
biological wastewater treatment plants.
Bioaccumulative potential : the product has been shown to present no
bioaccumulation hazard in aquatic plants
or fish.
WGK class (Germany) : 2 - hazardous.
AOX : the product do not contains organic
halons.

13. Disposal considerations

Disposal : dispose in a safe manner in accordance

with local/national regulations.
: do not dispose in a sink, drain or in the
immediate environment.
: of the methods of disposal currently
available, it is recommended that an
alternative be selected according to the
following order of preference, based upon
environmental acceptability:
: 1 - recycle or rework if at all
feasible;
2 - incinerate at an authorized
facility;
3 - treat at an acceptable waste
treatment facility.
Disposal of packaging : dirty containers of product must be
recycled or disposed by an authorized
facility.
: empty containers can retain product
residues and may be hazardous: do not use
heat, sparks, open flames, or cigarettes
on near empty container.

14. Transportation information

- RID/ADR - Transport by road

Proper shipping name : Flammable liquids, corrosive, n.o.s.
ADR Class : 3 - Flammable liquids.

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Packaging group : II
Risk Label(s) : 3 - Flammable.
Subsidiary Risk Label(s) : 8 - Corrosive.
Danger identification number (upper) : 338
Substance identification number (lower) : 2924
Tremcard type : F1
UN Number. : 2924
- IMO-IMDG code - Transport by sea
IMO class : 3.2 - Flammable liquids.
Intermediate flashpoint group (up to -
18°C but not including 23°C).
Risk Label : 3 - Flammable.
Subsidiary Risk Label : 8 - Corrosive.
: Marine pollutant (P).
Proper shipping name : Flammable liquids, corrosive, n.o.s.
Contains : diethylamine.
: heavy aromatic solvent
: ethylene diamine.
Packaging group : II
Page : 3126
Medical First Aid Guide (MFAG) : 320

15. Regulatory information

UE
- Symbol(s) : Highly flammable:F
: Corrosive:C
- Contains : diethylamine.
: ethylene diamine.
: heavy aromatic solvent
- R Phrase(s) : R 11 :Highly flammable.
: R 20/21/22 :Harmful by inhalation, in
contact with skin and if swallowed.
: R 35 : Causes severe burns.
: R 42/43 :May cause sensitization by
inhalation and skin contact.
: R 51/53: Toxic to aquatic organisms, may
cause long-term adverse effects in the

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aquatic environment.
- S Phrase(s) : S 26 :In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
: S 36/37/39 :Wear suitable protective
clothing, gloves and eye/face
protection.
: S 41: In case of fire and/or explosion do
not breathe fumes.
: S 16 :Keep away from sources of ignition
- No smoking.

16. Other information

Further information
Sources of key data used : N.Irving SAX - Dangerous properties of
Industrial Materials ( Sixth edition) -
Edited by Van Nostrand Reinhold Company -
1984
: TLV - Threshold Limit Values for Chemical
Substances in Work Environment - Adopted
by ACGIH - 2000
: A.D.R. - European Agreement concerning the international
carriage of Dangerous Goods by Road - United Nation
Publication
: Karel VERSCHUEREN - Handbook of
Environmental data on organic chemicals -
1977
Information for medical staff
Revised chapters

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Data di Revisione: 06/11/2003 Sostituisce:

MATERIAL SAFETY DATA SHEET ST1 - 100/1 03/07/2003 - 1

Preparata da: C.SCALAMANDRE

This MSDS complies with Directives 91/155/EC, 93/112/EC, 2001/58/EC, 2001/59/EC, 2001/60/EC and their amendments.

Laboratorio CHIMEC
Via Ardeatina KM.22.500 - Loc. S.Palomba
Pomezia(ROMA)
Tel.(06)- 918251 - Fax n.(06)-91825260

Le informazioni contenute in questo documento sono date in buona fede, e costituiscono la nostra migliore conoscenza in m

Tuttavia non possono costituire in alcun caso responsabilità a nostro carico quando il prodotto è impiegato impropriamente.

The information reported on this MSDS results from our present state of knowledge on safety regulations and is not to be co
guarantee of any specific product property.
CHIMEC cannot be held responsible for any injury or damage deriving from the improper application of the product.

Les informations incluses dans cette fiche de sécurité dérivent de nos connaissances actuelles en matière de sécurité. Elles n
en aucun cas une garantie des propriétés spécifiques du produit.
Aucun dommage résultant d`une application impropre du produit ne peut être imputé à CHIMEC.

Alle Angaben stützen sich auf den heutigen Stand unserer Kenntnisse. Das Sicherheitsdatenblatt ist dazu bestimmt, die beim
chemischen Stoffen und Zubereitungen wesentlichen physikalischen,
sicherheitstechnischen, toxikologischen und ökologischen Daten zu vermitteln und Empfehlungen für den sicheren Umgang
Verwendung und Transport zu geben.

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