Unit 2 Introduction To Thermal Engineering
Unit 2 Introduction To Thermal Engineering
Mechanical
Engineering 202041
Mr. K. B. Bansode
Course Objectives:
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Course Outcomes
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Unit II Introduction to Thermal
Engineering
Laws of thermodynamics, heat engine, heat pump, refrigerator (simple
numerical)
Modes of heat transfer Conduction, convection , Radiation, Fourier’s law,
Newton’s law of cooling , Stefan Boltzmans law (simple Numerical)
Two stroke and Four stroke engines (Petrol, Diesel and CNG engines). Steam
generators.
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Thermodynamics can be defined as the science of energy.
The name thermodynamics stems from the Greek words therme (heat)
and dynamis (power), which is most descriptive of the early efforts to
convert heat into power.
One of the most fundamental laws of nature is the conservation of
energy principle. It simply states that during an interaction, energy can
change from one form to another but the total amount of energy remains
constant.
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Classical Statistical
Thermodynamics Thermodynamics
(Macroscopic (Microscopic
approach) approach)
Thermodynamics
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Classical Thermodynamics & Statistical
Thermodynamics
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Application Areas of Thermodynamics
The heart is constantly pumping blood to all parts of the human body,
various energy conversions occur in trillions of body cells, and the
body heat generated is constantly rejected to the environment. The
human comfort is closely tied to the rate of this metabolic heat
rejection. We try to control this heat transfer rate by adjusting our
clothing to the environmental conditions
Some other applications are
The heating and air-conditioning systems,
The refrigerator
The humidifier
The pressure cooker
The water heater
Automotive engines, rockets,jet engines
Power plants, solar collectors
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Some application areas of thermodynamics
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DIMENSIONS AND UNITS
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SYSTEMS
The mass or region outside the system is called the Surroundings. The
real or imaginary surface that separates the system from its
surroundings is called the Boundary. The boundary of a system can be
fixed or movable. Note that the boundary is the contact surface shared
by both the system and the surroundings. Mathematically speaking, the
boundary has zero thickness, and thus it can neither contain any mass
nor occupy any volume in space.
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Types of systems
Open
System
Closed Isolated
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Open System(Control Volume)
Both mass and energy can cross the boundary of a control volume
Eg. compressor, turbine, nozzle
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Closed System
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Isolated system
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State of a System
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Properties of a System
Any characteristic of a
system is called a
property. Some familiar
properties are Pressure P,
Temperature T, Volume V,
and Mass m.
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INTENSIVE EXTENSIVE
PROPERTY
Intensive properties are those that
are independent of the mass of a
system, such as temperature,
pressure, and density
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Equilibrium
Mechanical equilibrium
Thermal equilibrium
Chemical equilibrium
Phase equilibrium
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• There is no • Temperature is
unbalanced force same throughout
acting on the the entire
system system
MECHANICAL THERMAL
EQUILIBRIUM EQUILIBRIUM
PHASE CHEMICAL
EQUILIBRIUM EQUILIBRIUM
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In reversible process, two states Irreversible process is usually
can be shown by a continuous represented by a dotted line
line joining the end states
Reversible process is an ideal In a real process, the
process intermediate state points
cannot be located
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Friction
Heat transfer
across a finite Chemical
temperature reactions
difference
Inelastic
Unrestrained
expansion deformation
of solids
Electric
resistance
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PATH
To describe a process completely, one should specify the initial and final
states of the process, as well as the path it follows, and the interactions
with the surroundings
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Path and Point Functions
Path Functions
If the value of the thermodynamic variable depends upon the path
followed in going from one state to another
Path functions are not properties of the system
Path functions have inexact differentials designated by the symbol ‘δ’
Eg. Work(W), Heat(Q)
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POINT FUNCTIONS
Properties does not depend on the path followed in reaching the state,
but only on the equilibrium state itself
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CYCLE
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Temperature and The Zeroth
Law of Thermodynamics
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Zeroth Law of Thermodynamics
The zeroth law was first formulated and labelled by R. H. Fowler in1931
If two systems (say A and B) are in thermal equilibrium with a third
system (say C) separately (that is A and C are in thermal equilibrium; B
and C are in thermal equilibrium) then they are in thermal equilibrium
themselves (that is A and B will be in thermal equilibrium)
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Temperature Scales
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Pressure
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Boyle’s Law
V α 1/P, T = constant
PV = constant, T = constant
P1V1 = P2V2 = P3V3 = PV = constant, T = constant
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Charle’s Law
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Gay Lussac’s Law
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Characteristic Gas Equation
Combining the 3 gas laws obtain a relationship between Pressure,
Volume & Temperature
A perfect or ideal gas is the gas which strictly obeys all the gas laws
under all conditions of pressure and temperature. Also, a theoretical
gas composed of a set of randomly moving non- interacting point
particles
PV/T = constant
P1V1/T1 = P2V2/T2 = P3V3/T3 = PV/T = constant
PV = mRT (Characteristic gas equation )
; m-mass, R-characteristic gas constant
For air R = 287 J/KgK
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Universal Gas Constant
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Real Gas And Real Gas Equations
Real gas behaves more like an ideal gas when it is under high
temperature and low pressure
The deviation from ideal-gas behavior at certain ranges of temperature
and pressure can accurately be accounted for by the introduction of a
correction factor called the compressibility factor, Z
Z = PV/mRT
Mathematical equations of state for analyzing the real gas behavior are
Van der-Waals Equation
Berthelot Equation
Dieterici Equation
Redlich-Kwong Equation
Beattie-Bridgeman Equation
Martin-Hou Equation
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Van der-Waals Equation
Real gas conform more closely with the van der Waals equation of
state than the ideal gas equation of state, particularly at higher
pressures
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HEAT
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WORK
Positive work is done by a system when the sole effect external to the
system could be reduced to the rise of a weight
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Sign Conventions
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Similarities Between Heat and Work
Both are path functions (i.e., their magnitudes depend on the path
followed during a process as well as the end states)
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SPECIFIC HEATS
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Heat Capacity, C = Q/dT
cp = Q/ [m(T2-T1)]
cv = Q/ [m(T2-T1)]
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Material J/kgC cal/gC
Water 4186 1
Ice 2090 0.50
Steam 2010 0.48
Silver 234 0.056
Aluminum 900 0.215
Copper 387 0.0924
Gold 129 0.0308
Iron 448 0.107
Lead 128 0.0305
Brass 380 0.092
Glass 837 0.200
Wood 1700 0.41
Ethyl Alcohol 2400 0.58
Beryllium 1830 0.436
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Work
First Law of
Thermodynamics
Internal
Heat
Energy
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The First Law of Thermodynamics
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Net heat transfer = Net work transfer
∑Q = ∑W ; Q1 – Q2 = W2 – W1
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First Law Applied to a Process
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Since A and B are arbitrarily chosen, the conclusion is, as far as a
process is concerned (A or B) the difference (δQ – δW) remains a
constant as long as the initial and the final states are the same.
The difference depends only on the end points of the process. Note
that Q and W themselves depend on the path followed. But their
difference does not.
This implies that the difference between the heat and work
interactions during a process is a property of the system
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Forms of Energy
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The macroscopic forms of energy are those a system possesses as a
whole with respect to some outside reference frame, such as kinetic
and potential energies
The microscopic forms of energy are those related to the molecular
structure of a system and the degree of the molecular activity, and
they are independent of outside reference frames. The sum of all the
microscopic forms of energy is called the Internal energy of a
system and is denoted by U
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Hence,δQ – δW = dU/∆U
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Nuclear
energy
Vibrational
kinetic Translational
energy energy
Internal
energy(U)
Rotational
latent energy kinetic
energy
Chemical
Spin energy
energy
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δQ – δW = dU or Q1-2 = W1-2 + dU
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Mechanisms of Energy Transfer
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Work Transfer, (W) An energy interaction that is not caused by a
temperature difference between a system and its surroundings is work.
A rising piston, a rotating shaft, and an electrical wire crossing the
system boundaries are all associated with work interactions. Work
transfer to a system (i.e., work done on a system) increases the energy
of the system, and work transfer from a system (i.e., work done by the
system) decreases it since the energy transferred out as work comes
from the energy contained in the system.
Mass Flow, (m) Mass flow in and out of the system serves as an
additional mechanism of energy transfer. When mass enters a system,
the energy of the system increases because mass carries energy with it
(in fact, mass is energy). Likewise, when some mass leaves the
system, the energy contained within the system decreases because the
leaving mass takes out some energy with it.
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Perpetual Motion Machine of First Kind (PMM-1)
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ENTHALPY
Measure of the total energy of a thermodynamic system
Sum of the internal energy and pressure volume product
H = U + PV
Enthalpy is also a property of the system
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Ratio of Specific Heats
cp/ cv = γ
H = U + PV ; PV = mRT
H = U + mRT
dH = dU + mRdT
dH/dT = dU/dT + mR
m cp = m cv + mR
cp – cv = R
cp = γR/(γ-1) ; cv = R/(γ-1)
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Refrigerators
Second Law of
Thermodynamics
Introduction to the Second Law of
Thermodynamics
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Thermal Reservoirs
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Thermal Efficiency
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The Second Law of Thermodynamics
1.Kelvin–Planck Statement
It is impossible for any device that
operates on a cycle to receive heat
from a single reservoir and produce
a net amount of work
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Violation of Kelvin - Planck statement
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Refrigerators
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2.Clausius Statement
It is impossible to construct a device that operates in a cycle and
produces no effect other than the transfer of heat from a lower-
temperature body to a higher-temperature body
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Violation of Clausius statement
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Equivalence of Kelvin-Planck and Clausius
Statements
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Violation of the Clausius statement leads to the violation of the
Kelvin–Planck statement
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Perpetual-Motion Machine of The Second Kind
(PMM2)
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Modes of Heat Transfer
1. Conduction
2. Convection
3. Radiation
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Modes of Heat Transfer
4. Constant conductivity, k
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Thermal Conductivities
Iron 75
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Thermal Conductivities
Substance Thermal
Conductivity:
Insulators have
low conductivity. k (W/mK)
Air is a good Glass 0.84
insulator, except
that large air Water 0.60
spaces allow
heat flow by Wood 0.10
convection
Air 0.023
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Variation of Thermal Conductivity
1. It is the property of material; defined as ability
of material to conduct heat through it.
2. Thermal conductivity in decreasing order :
Metals » Non-metallic Solids » Liquids » Gases
3. Higher conductivity in metals due to free
electrons in their outer orbits
4. k depends on grain structure. When k is different
in different directions (kx , ky , kz ), material is
known as anisotropic. When k is constant in all
directions, it is called Isotropic.
5. k is strongly dependent on temp; k=ko(1+αT) 103
Isotropic & Anisotropic Materials
• Some materials exhibit same conductivity in all
directions. These are called ISOTROPIC materials
(kx = ky = kz = k)
• While some materials have different conductivity
in different directions(kx , ky , kz ), such materials
are known as anisotropic.
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HEAT CONVECTION
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Heat Convection
When a fluid flows over a solid body or surface and
temp of the fluid and solid surface are different, heat
transfer between the solid surface and fluid takes
place due to motion of fluid relative to the surface.
Mathematically;
Q = hA(Ts - T∞); Watt
h is not a property of fluid or surface, but it depends
on properties of the fluid and vital dimensions of the
surface 108
Convection Ts > T∞
T∞
Fluid
A h
Ts
Q = hA(Ts - T∞); Watt
Q
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HEAT RADIATION
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Heat Radiation
All bodies continuously emit energy if their temp is
above zero absolute (0K) and energy thus emitted
is called thermal radiation.
Thermal radiations are electromagnetic waves and
do not require any medium for propagation.
Mathematically;
q ∞ T4 W/m2;
Q = σAT4 W; where σ is Stefan Boltzmann’s
constant (5.67 x 10-8 W/m2K4 )
Q=Qc+Qr
2cm
Qc=hA(T1 – Ta) h=25
Q=kA(ΔT/Δx)
T1 =250°C
=kA(T2-T1)/(Δx) 50cm
k=43
T2 = ? 75cm
Q=2456W; T2=253°C Q 113
Electrical Analogy
Electrical Heat Energy
Energy
What flows? Electrons Heat energy through
electrons
Driving Voltage Diff, ΔV Temp Diff, ΔT
Potential
Flow Current, I Heat Transfer Rate, Q
Resistance ρ, A, L of R, Thermal
to flow conductor Resistance
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Carnot Cycle
Probably the best known reversible cycle is the Carnot cycle, first
proposed in 1824 by French engineer Sadi Carnot. The theoretical
heat engine that operates on the Carnot cycle is called the Carnot heat
engine. The Carnot cycle is composed of four reversible processes—
two isothermal and two adiabatic
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Process 1-2, Isothermal expansion process
Process 2-3, Isentropic expansion process
Process 3-4, Isothermal compression
process
Process 4-1, Isentropic compression
process
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Area under curve 1-2-3 is the work done by the gas during the
expansion part of the cycle, and the area under curve 3-4-1 is the work
done on the gas during the compression part of the cycle.
The area enclosed by the path of the cycle (area 1-2-3-4-1) is the
difference between these two and represents the net work done during
the cycle
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QL /TL = QH /TH or Q/T- Independent of path, called entropy
Q/T = dS
The area enclosed by the path of the cycle (area 1-2-3-4-1)
represents the net work done during the cycle
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Carnot cycle is not a practical cycle
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Otto Cycle
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Process 1-2, Isentropic compression
Process 2-3, Constant volume heat addition
Process 3-4, Isentropic expansion(Power Stroke)
Process 4-1, Constant volume heat rejection
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Thermal efficiency is a function of the compression ratio ‘r’ and the
ratio of specific heats ‘γ’
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Diesel Cycle
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Process 1-2, Isentropic compression
Process 2-3, Constant pressure heat addition
Process 3-4, Isentropic expansion(Power Stroke)
Process 4-1, Constant volume heat rejection
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Thermal Efficiency, η = 1- (Qout/Qin)
= 1 – [mcv(T4-T1)/ mcp(T3-T2)]
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Comparison of Otto and Diesel Cycle
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Cycle 1-2-3-4-1 shows Otto cycle
Cycle 1-2-5-4-1 shows Diesel cycle
For the Otto cycle heat supply(area under 2-3 in T-S diagram) is
greater than that for the Diesel cycle(area under 2-5 in T-S diagram)
For the Otto cycle work done(area under 3-4 in P-V diagram) is
greater than that for the Diesel cycle(area under 5-4 in P-V diagram)
Otto cycle will have a higher thermal efficiency for the same
Compression Ratio
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2. On the basis of maximum Pressure and Temperature
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Cycle 1-2-5-4-1 shows Otto cycle
Cycle 1-2-3-5-4-1 shows Diesel cycle
Heat supply for the Diesel cycle(area under 3-5 in T-S diagram) is
greater than that for Otto cycle(area under 2-5 in T-S diagram).
Since Otto cycle receives less heat for the same heat rejection, its
efficiency will be lower than that of diesel
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THANK YOU
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