EEE487 - 1 - Basics
EEE487 - 1 - Basics
(Basics)
Lectures prepared
by
Prof. S. Shahnawaz Ahmed
REFERENCES
For subsequent materials assistance mainly taken from the following references.
1.Raymond L. Murray and Keith E. Holbert, Nuclear Energy : An Introduction to the
Concepts, Systems, and Applications of Nuclear Processes; Elsevier, NY, 2020 (Eighth
Edition).
2. https://courses.lumenlearning.com/boundless-chemistry/chapter/nuclear-fission/
https://www.statista.com/statistics/267358/world-installed-power-capacity/
Total : around 7800 GW : Fossil: 4436 GW+ Nuc: 375 GW +Hydro and non-hydro
renewable: 3026 GW
Distribution of electricity generation worldwide in 2022, by energy source
[in % of total TWh energy generated;
•Though hydro and non-hydro 2022 World electricity generation (28,520 TWh)
renewables have a share of
respectively about 15% and 23%
of the total installed capacity their
contribution to the annual energy
production is respectively about
15% and 18% while
approximately 67 % is
contributed by fossil fuel and
nuclear power plants. This is
because of the intermittency of
renewable sources.
Letting the mass when the object is stationary be m0, the rest mass;
letting m be the mass when it is at speed v; and noting that the speed of light in a
vacuum is c, then the relativistic mass is
For motion at low speed (e.g., 500 m/s), the relativistic mass is almost identical
to the rest mass, because v/c and its square are very small.
The relation shows that a material object can have a speed not higher than c.
The implication of Einstein’s formula
is that any object has a rest mass energy
when motionless,
•Thus we see that matter and energy are equivalent, with the factor c2 relating the
amounts of each.
•This suggests that matter can be converted into energy and that energy can be
converted into matter.
Although Einstein’s relationship is completely general, it is especially important in
calculating the energy released by nuclear means where particle (at atomic/nucleus level)
motion at high speed ( in the order of several percent of light speed) is involved.
•We find that the energy yield from a kilogram of nuclear fuel is more than a million
times that from chemical fuel.
•To prove this startling statement, we first find the result of the complete transformation
of 1 kilogram of matter into energy, namely,
•However, the nuclear fission process, as a method of converting mass into energy, yields
approximately 7.8x1013 J/kg of the uranium consumed which means only 0.87 g of matter
is converted into energy compared with 9x1016 J/kg of uranium i.e. theoretical complete
transformation. [In fact, typical fission of 3.9 kg U235 per day yields 3000 MWt i.e. 4.51
x10-5 kg U 235 provides in 1 second 3x109 J so that fission of 1 kg of U 235 provides in 1
second (3x109/4.51x10-5 ) ≈ 6.65 x 1013 J/kg.]
•Still, the enormous magnitude of this energy release (7.8x1013 J/kg by fission process)
can be appreciated only by comparison with the energy of combustion of a familiar fuel
such as gasoline (i.e. octane), 5x107 J/kg.
•The ratio of these numbers (7.8x1013 J/kg uranium and 5x107 J/kg gasoline), 1.5x106,
reveals the tremendous difference between nuclear and chemical energies.
Atoms and nuclei:
There are more than 100 known elements. Most are found in nature; some are artificially
produced.
Each is given a specific number in the periodic table of the elements; examples are
hydrogen (H) 1, helium (He) 2, oxygen (O) 8, and uranium (U) 92.
•The symbol Z is assigned to the atomic number, which is the number of negatively
charged electrons in the atom and determines its chemical properties. Z is also equal to
the number of positively charged protons in the nucleus so that an atom is charge
neutral. Protons are heavier than electrons but carry same amount of positive charge.
Generally, the farther an element is in the periodic table, the heavier are its atoms.
•The atomic weight M is the weight in grams of a definite number of atoms, 6.02x1023,
which is Avogadro’s number, NA i.e. M is expressed in grams/mole when one mole
contains NA number of atoms.
•Besides gm/mole atomic weight may also be expressed using ‘atomic mass units ‘ (amu
denoted by u), while atomic mass is always quantified using atomic mass units (u).
•Although we often use the terms atomic weight and atomic mass interchangeably,
atomic mass describes the mass of a single atom of a particular isotope, whereas
atomic weight provides a weighted average mass for an element based on the
abundance of its constituent isotopes.
For the elements hydrogen (H) 1, helium (He) 2, oxygen (O) 8, and uranium (U) 92, the
values of M in atomic mass unit are approximately H, 1.008; He, 4.003; O, 16.00; and U,
238.0.
•Isotopes of an element have same chemical properties but they differ in number of neutrons.
•A neutron is charge neutral having a mass close to that of a proton. Protons and neutrons are together
named as nucleons because both reside in the nucleus.
•Atomic mass number A is used to denote the total number of nucleons. The atomic weight, a real
number, is approximated by the atomic mass number, which is an integer, i.e. M≈ A. Then the mass of 1
mole of an element in grams is equal to its atomic mass number. e.g. 1 mole of U-235 weighs 235
grams.
•The complete shorthand notation for an isotope is given by the
chemical symbol X with leading superscript A and subscript Z values,
that is, ZAX. e.g.
•In addition to the atomic number Z and the atomic mass number A, we often
need to write the neutron number N, which is, of course, N=A – Z. For the set of
hydrogen isotopes listed, N is 0, 1, 2 respectively.
•The vast majority of all nuclear power reactors require 'enriched' uranium fuel in
which the proportion of the uranium-235 isotope is raised from the natural level of
0.7% to about 3.5% to 5%.
The atomic mass of the proton is 1.007276, of the neutron 1.008665, the difference being
only about 0.1%. The mass of the electron on this scale is 0.000549.
*
[*Note: 1 mole of pure C weighs 12 grams. So 12 gm carbon contain Avogadro’s number of atoms.
• Then in terms of C, 1 amu=1/12 th of the mass of a carbon atom =1/12x(12/6.022x1023 ) gm.
• In terms of H, 1 amu = mass of 1 H atom =1/6.022x1023 gm.
Both definition will give 1 amu=1.660539x10-24 gm.]
BINDING ENERGY
To disrupt a nucleus and separate it into its component nucleons, energy must be
supplied from the outside. Recalling Einstein’s relation between mass and energy, this is
the same as saying that a given nucleus is lighter than the sum of its separate nucleons,
the difference being the mass defect.
Let the mass of an atom including nucleus and external electrons be M, and let mn and
MH be the respective masses of the neutron and the proton plus matching electron.
Then the mass defect is
Fission is most widely used in NPP. The materials fissionable by thermal or slow neutrons
are U-235, Pu-239.
•The three most relevant
fissile isotopes are
Uranium-233, Uranium-
235 and Plutonium-239.
When the unstable
nuclei of these atoms
are hit by a slow-moving
neutron, they split,
creating two daughter
nuclei plus two or three
more neutrons. These
neutrons then go on to
split more nuclei of the
fissile atoms. This
creates a self-sustaining
chain reaction that is
controlled in a nuclear
reactor, or uncontrolled
in a nuclear weapon.
•Many naturally occurring and man-made isotopes with small binding energy per
nucleon and Z>81, have the property of radioactivity, which is the spontaneous
transformation (decay) of the nucleus into another nucleus plus the emission of a
particle.
The process takes place in minerals of the ground, in fibers of plants, in tissues of
animals, and in the air and water, all of which contain traces of radioactive elements.
•Generally, nuclei with an even number of protons and/or neutrons tend to have a
higher degree of stability.
Many heavy elements and a few light elements (e.g. K-40, C-14, H-3) are radioactive.
An example is the decay of the most abundant isotope of uranium, in the reaction
(uranium-238 has a half-life of 4.4683×109 years)
The particle released is the α (alpha) particle, which is merely the helium-4 nucleus. The
new isotope of thorium is also radioactive, as shown in following reaction.
antineutrino and electron released
A free neutron has a half-life of 10.3 min. The conversion of a neutron into a proton can be
regarded as the origin of beta emission in radioactive nuclei.
•In addition to the radioisotopes that decay with beta or alpha emission, there is a
large group of artificial isotopes that decay with the emission of a positron β+, which
has the same mass as the electron and an equal but positive charge.
An example is sodium-22, which decays with 2.6 y half-life into a neon isotope as
Neutrino (v) is a subatomic particle having no electrical
charge (but other properties are similar to an electron), very
neutrino and positron released little mass and it is very abundant in universe.
It should be noted that electrons are normal particles that form matters while positrons
only occur due to nuclear process and are termed antiparticle forming antimatter
•The preceding Na-22 reaction can be regarded as involving the conversion of a proton
into a neutron with the release of a positron and a neutrino by use of excess energy in
the parent nucleus.
This is an example of the conversion of energy into mass. Usually, the mass appears in
the form of pairs of particles of opposite charge. The positron–electron pair is one
example. An electron and a positron will combine, and both will be annihilated to form
two γ (gamma) rays.
•A nucleus can get rid of excess internal energy by the emission of a gamma ray, but in
an alternate process, called internal conversion (IC), the energy is imparted directly to
one of the atomic electrons, thereby ejecting it from the atom.
•In an inverse process, called electron capture, the nucleus spontaneously absorbs one
of its own orbital electrons.
•Each of these two processes (IC and EC) is followed by the production of X-rays as the
inner shell vacancy is filled.
Decay constant, half life, activity, units
•Nuclear reactions are much more energetic than chemical reactions, but they
obey the same physical laws: conservation of momentum, energy, number of
particles, and charge.
•The number of possible nuclear reactions is extremely large, because there are
approximately 2000 known isotopes and many particles that can either be
projectiles or products: photons, electrons, protons, neutrons, alpha particles,
deuterons (nucleus of deuterium), and heavy charged particles.
•The nuclear reactions that are induced by projectiles and that involve neutrons
are important for NP generation.
TRANSMUTATION OF ELEMENTS
We note that on both sides of the equation the A values sum to 18 and the Z values
total 9. It is difficult for the positively charged α particle to enter the nitrogen nucleus
because of the force of electrical repulsion between charged particles. The α particle
thus must have several MeV of energy.
yields a gamma ray and an isotope of nitrogen. The latter decays with a half-life of
10 min, releasing a positron, the positive counterpart of the electron.
•Because the neutron is a neutral particle, it does not experience electrostatic
repulsion and can readily penetrate a target nucleus. Neutrons are thus especially
useful as projectiles to induce reactions.
Several examples are chosen on the basis of interest or usefulness. The conversion
of mercury into gold, the alchemist’s dream, is described by
A reaction that produces tritium, which may be a fuel for controlled fusion reactors of the
future, is
Fission
•Out of the many nuclear reactions known, the reaction that results in fission has, at
present, the greatest practical significance. (fission involves production of daughter nuclei)
•The absorption of a neutron by most isotopes involves radiative capture, with the
excitation energy appearing as a gamma ray. (non-fission or rdaiative capture produces
gamma emission)
In order to initiate most fission reactions, an atom (specially those with higher atomic masses) is
bombarded by a neutron to produce an unstable isotope, which undergoes fission. When neutrons
are released during the fission process, they can initiate a chain reaction of continuous fission which
sustains itself.
The first neutron can come from a primary neutron source (e.g. Californium, Cf-252)
(spontaneous fission) or from Plutonium-238 and beryllium (α,n) reaction*. The startup sources are
typically inserted in regularly spaced positions inside the reactor core, in place of some of the fuel
rods. The primary sources are removed from the reactor after the first fuel campaign, usually after
few months.
*The requisite alpha (α) particles for the (α, n) reaction are generated from the radioactive decay of Pu isotopes. The
interaction of these alpha particles with proximate light atomic number beryllium (Be) atoms produces the regular
flux of (α, n) neutrons.
•The fission of one atom of uranium-235 releases 202.5 MeV
(3.24×10−11 J) inside the reactor. That corresponds to 19.54 TJ/mol, or
83.14 TJ/kg. Another 8.8 MeV escapes the reactor as anti-neutrinos.
When 23592U nuclides are bombarded with neutrons, one of the many
fission reactions that it can undergo is as follows (shown in the
adjacent image):
•Heavy water reactors, and some graphite moderated reactors, can use
natural uranium, but light water reactors must use at least low
enriched uranium because of the higher neutron absorption of light Nuclear fission of U-235: If U-235 is
water. Heavy water's extra neutron decreases its ability to absorb bombarded with a neutron (light blue small
excess neutrons, resulting in a better neutron economy. In other words circle in diagram above), the resulting U-236
the heavy water moderator does not absorb as many neutrons as the produced is unstable and undergoes fission.
commonly used light water does. The resulting elements (shown here as Kr-92
and Ba-141) do not contain as many
•Uranium enrichment removes some of the uranium-238 and increases nucleons as U-236, with the remaining three
the proportion of uranium-235. Highly enriched uranium (HEU), which neutrons being released as high-energy
contains an even greater proportion of uranium-235, is sometimes particles, able to bombard another U-235
used in the reactors of nuclear submarines, research reactors and atom and maintain a chain reaction.
nuclear weapons.
•In Stage A, the neutron hits the U-235 nucleus.
Variation of U-235 fission
•In Stage B, the U-236 compound nucleus has been formed in
an excited state. The excess energy in some cases may be
released as a gamma ray, but more frequently the energy
causes distortions of the nucleus into a dumbbell shape, as in
Stage C.
where the asterisk (*) signifies the excited state. The mass of (U-236)* in atomic
mass units is
Each fission yields about w =190 MeV (not exactly 200 MeV) of useful energy, that is,
recoverable energy.
Thus the number of fissions required to obtain 1 W-sec i.e. 1 Joule of energy is
Each fission requires one fuel atom to be ‘burned’. In one day’s operation of a reactor
per megawatt of thermal power (MWt), the number of U-235 nuclei burned by fission is
1 day = 86400 s
the average number of neutrons (n) emitted in fission is termed v ( which is between 2 and 3)
(thermal)
•In fact due to poor fuel efficiency of reactors, reproduction factor (much depends upon
radiative capture of neutrons i.e. non-fission) and due to requirement of enriching natural
uranium, a typical thermal reactor (3000 MWt) contains about 100 tons of natural
uranium (U-238) with an average enrichment of 2%. Only about 0.01% of the potential of
natural uranium is extracted i.e. converted into heat through enrichment and chain
reaction. Due to 2% enrichment this 100 MTU (metric tons of uranium) usually lasts for
about 2 years.
•The higher the enrichment less mass of uranium will be required to be loaded into the
reactor but more mass of natural uranium will be required to be processed to achieve
that enrichment.
•Spent fuel is degraded enough that even though it is still wicked radioactive, it is no
longer efficient for doing what nuclear power plants are supposed to do i.e. generating a
lot of heat, boiling water, making steam that spins turbine and generator set to produce
electricity. The spent fuel is still incredibly hot, like touching the stove hot. These hot and
radioactive fuel rods are put under water in pools. The size of the pools, in the case of the
Japanese reactors , is about 40 feet by 45 feet.
•Why is the fuel made up of rods rather than being a solid single piece of fuel?
To maximize efficiency, the moderator needs to be interspersed between the fuel which is
possible if the fuel is in the form of a large number of rods. Neutrons need to pass through
a moderator to slow them in order to cause further fissions or prevent U-238 absorbing
them. If a neutron passes out of a fuel rod it is unlikely to re-enter it, but there is a
possibility that it may enter another one. Fuel in rod form also makes it easier to replace
the fuel in stages.
•Typically, reactor operators change about one-third of the fuel rods in reactor core (i.e.
40 to 90 fuel assemblies) every 12 to 24 months.
Fusion
•Only by giving one or both of the particles a high speed can they be brought close
enough to each other for the strong nuclear force to dominate the electrical
force. This behavior is in sharp contrast to the ease with which neutrons interact
with nuclei.
•There are two consequences of the fact that the Coulomb force between two
charges of atomic numbers Z1 and Z2 varies with separation R according to
•A medium in which high particle energies are obtained is the plasma. It consists
of a highly ionized gas as in an electrical discharge created by the acceleration of
electrons. Equal numbers of electrons and positively charged ions are present,
making the medium electrically neutral.
•The plasma is often called the fourth state of matter. Through the injection of
enough energy into the plasma, its temperature can be increased, and particles
such as deuterons reach the speed for fusion to be favorable.