Chemical Reaction and Equation - Class 10th
Chemical Reaction and Equation - Class 10th
• REACTION:
A change due to some reason or cause.
2) Chemical change
PHYSICAL CHANGE:
A change in which a substance changes from one physical state to another,but no substances with
different composition are formed.
Examples of physical changes are boiling, melting, freezing.
CHEMICAL CHANGE OR CHEMICAL REACTION:
It is a process in which new substance with new properties are formed. During chemical reaction
rearrangement of atoms takes place between reacting substance and a form a new substance having
entirely different properties.
Examples of chemical changes are burning, cooking, rusting
2Mg(s)+O2(g)→2MgO(s)
(i) Word equations: A word equation links together the names of the reactants with those of the
products. For example, the word equation, when magnesium ribbon burns in oxygen to form a white powder
of magnesium oxide, may be written as follows-
Similarly, the word equation for the chemical reaction between granulated zinc and hydrochloric acid may
be written as -
Zinc + Sulphuric acid → Zinc sulphate + Hydrogen
In a word equation
● The reactants are written on the left hand side with a plus sign (+) between them.
● The products are written on the right hand side with a plus sign (+) between them.
Although word equations are quite useful, yet they don’t give the true picture of the
chemical reactions.
(ii) Symbol equation: A brief representation of a chemical reaction in terms of symbols and
formulae of the substance involved is known as a symbol equation.
In a symbol equation, the symbols and formulae of the elements and compounds are written instead of their
word names.
For e.g. Burning of magnesium in oxygen to form magnesium oxide may be written as
follows:
Mg + O2 ⎯⎯→ MgO
(i) Evolution of gas: Some chemical reactions are characterized by evolution of a gas.
• When zinc metal is treated with dilute sulphuric acid, hydrogen gas is evolved. The hydrogen gas
burns with a pop sound.
Zn (s) + H2SO4 (dilute) → ZnSO4 (aq) + H2(g)
• When washing soda is treated with hydrochloric acid, it gives off colourless gas with lots of
effervescence.
Na2CO3(s) + 2HCI → 2NaCI(aq) + H2O(I) + CO2(g)
(ii) Change of colour: Certain chemical reactions are characterized by the change in colour of
reacting substance.
• When red lead oxide is heated strongly it forms yellow coloured lead monoxide and gives off
oxygen gas.
2Pb3O4 (s) ⎯⎯ ⎯→
he at
6PbO(s) + O2(g)
Lead oxide Lead monoxide
(Red) (Yellow)
• When copper carbonate (green) is heated strongly it leaves behind a black residue.
heat
CuCO3 (s) ⎯⎯ ⎯→ CuO(s) + CO2 (g)
Copper
carbonate Copper oxide Carbon dioxide
(Green) (Black)
• 2Pb(NO3)2(s) ⎯⎯ ⎯→
he at 2 PbO(s) + 4NO2 (g) + O2 (g)
Lead (II) nitrate Lead (II) oxide Nitrogen dioxide
(White) (Yellow) (Brown)
• C12H22O11 (s) ⎯⎯ ⎯→
he at
12C(s) + 11H2O
White sugar Carbon Black Water
(iii) Formation of precipitate : Some chemical reactions are characterized by the formation of
Precipitate (an insoluble substance), when the solutions of the
soluble chemical compounds are mixed together.
(iv) Energy changes: all chemical reactions proceed either with the absorption or release of energy.
● Light energy is essential for biochemical reaction, photosynthesis, by which green plants prepare
their food from carbon dioxide & water.
(B) Exothermic reaction : A chemical reaction which is accompanied by the release of heat
energy is called exothermic reaction.
When magnesium wire is heated from its tip in a bunsen flame, it catches fire and burns with a
dazzling white flame with release of heat and light energy.
Heat
2Mg (s) + O2 (g) ⎯⎯⎯→ 2MgO (s) + Energy
● When quick lie (calcium oxide) is placed in water, the water becomes very hot and sometimes
starts boiling. It is because of release of heat energy during the reaction.
(v) Change of state: Some chemical reactions are characterized by a change in state i.e. solid, liquid
or gas.
●Two volumes of hydrogen gas react with one volume of oxygen gas to from water.
2H2 (g) + O2 (g) → 2H2O (l)
or when electric current is passed through water it splits into its elements.
Synthesis reaction : It is a type of addition reaction in which a new substance is formed by the union of its
component elements.
All synthesis reaction are addition reactions but all addition reactions are not
synthesis reactions.
Other Example of synthesis reactions are -
● 2H2 + O2 ⎯⎯→ 2H2O
● 2Mg + O2⎯⎯→2MgO
● 2Na + CI2 ⎯⎯→ 2NaCI
CH2 − Br
● CH2 = CH2 + Br2 ⎯⎯→ |
CH2 − Br
(iii) When and element and a compound combine to from a new compound.
For eg.
● 2CO + O2⎯⎯→ 2CO2
● 2CO2 + O2 ⎯⎯→ 2CO3
2AI2O3 ⎯⎯ ⎯⎯ ⎯→
Electricity
4 AI + 3O2
(iv) Decomposition reaction in which a compound decomposes into its elements is known
as analysis reaction.
For eg.
● 2HgO ⎯⎯→ 2Hg + O2
● 2HI ⎯⎯→ H2 + I2
All analysis reactions are decomposition reactions, but all decomposition reactions are not analysis
reactions.
For eg.
Acid base neutralization reactions and ppt reactions are double displacement
reactions.
OBJECTIVE
Column A Column B
Types of chemical reaction Chemical equations
(a) Combination reaction (i) CaCO3 ⎯⎯→ CaO + CO2
10. The reaction in which two compounds exchange their ions to form two new compounds is-
(A) a displacement reaction (B) a decomposition reaction
(C) an addition reaction (D) a double displacement reaction
OXIDATION NUMBER OR OXIDATION STATE
The charge present on an atom in a given compound is called its oxidation no. or state.
Or
the charge produced on atom due to difference is electronegativity with surrounding atom.
Eg; O2, H2, N2, Na, Fe, P4, S8, diamond, graphite.
(iv) The ON of IA [Li, Na,K,Rb,Cs ] elements is always +1 and IIA [Be,Mg,Ca,Sr,Ba ] is always +2.
H2O2
H
Peroxide bond
O
H2O2
O
H KO2 ----
OF2 O2F2
(vii) For complex ions the algebric sum of ON of all the atoms Is equal to the net charge on the ion.
Eg . [Fe(CN)6]–3 x–6=–3
x=+3
.
(viii) Radicals are considered as single unit and the charge present on them are considered as their
Oxidation number (ON).
− − − −2 −2
Eg. OH , CN , NC , CO3 , C2O4 → Oxalate
(ix) In case of neutral molecule the algebric sum of the oxidation number of all the atoms is zero.
Eg. CO, NO
ON OF Cr in CrO5 is +6.
CaOCl2
Average ON of Cl is zero.
ON of Cl in bleaching powder is +1 & -1.
H2SO5 (Caro’s acid).
Average ON of S is 2.5.
ON of S in Na2S4O6 is 5,0,0 & 5.
Brown Ring Complex
3) One mole of A2H3 gives n mole electron and form new compound in which new oxidation of A is –1/2, find
the value of n.
(a) 3, (b) 2 (c) 4 (d) 1
A2 H 3 + Ne − → ( A2 H 3 )
+n
1
2x − + 3 = n
2
n=2
3.1 OXIDATION AND REDUCTION:
(a) Oxidation:
Oxidation is a chemical reaction in which a substance gains oxygen or loses hydrogen. Since oxygen is an
electronegative element and hydrogen is an electropositive element, so, oxidation is defined as a reaction in
which a substance gains and electronegative radical or loses and electropositive radical.
For eg.
● S + O2 ⎯⎯→ SO4
For eg.
● 2HCI ⎯⎯→ CI2 + H2
For e.g.
2Na → 2Na+ + 2e-
( b) Reduction:
It is a chemical reaction in which there is a gain of hydrogen or any electropositive radical or a loss of
oxygen or electronegative radical.
● CuO + H2 ⎯⎯→ Cu + H2 O
● ZnO + C ⎯⎯→ Zn + CO
REDOX REACTIONS :
reactions in which oxidation and reduction take place simultaneously are known as redox reactions.
Reduction
CuO + H2 Cu + H2O
Oxidation
(d) To convert acidic medium into basic medium equal no of OH– as that of
H+ are added on both sides.
+8H + C2 O4 → 2CO2 + 2e −
+5e– ………………..(i) ….(ii)
(i)×2+(ii)×5
(i) Calculate the change in oxidation no. and cross multiply in reactants
Side only.
(b) Respiration:
Fish takes up oxygen dissolved in water through their gills while plants take
up air through small pores (stomata) present in their leaves.
Prevention of rusting
(j) Coating of metal with oil, grase and paint
(iii) Electroplating
(v) Alloying
Rancidity : The condition produced by aerial oxidation of fats and oils in foods marked
by unpleasant smell and taste is called rancidity.
Prevention of rancidity
2. When the gases sulphur dioxide and hydrogen sulphide react, the reaction is
SO2 + 2H2S → 2H2O + 3S
Here hydrogen sulphide is acting as -
(A) an oxidising agent (B) a reducing agent
(C) a dehydrating agent (D) a catalyst