[Si] MARANDA HIGH SCHOOL by. Kenya Certificate of Secondary Education ¥ PRE-MOCK EXAMINATIONS 2022 A 233/2 CHEMISTRY Paper 2 JUNE 2022 TIME: 2Hours Candidate's Signature: ...... Date: «.../6/2022. ‘Instructions to candidates (@ Write your name and index number in the spaces provided above, (b) Answer ALL the questions in the spaces provided end show ALL working (4) KNEC mathematical tables & silent non-programmable electric calculators may be used, (9 This paper consists of 13 printed pages (g) Candidates should check the question paper ty ascertain that all the pages are printed as indicated and that no questions are missing FOR EXAMINER'S USE ONLY.Water 1A In anexperiment to determine the percentage of oxygen in ir, the apparatus below were se up, Study the set up and the infomation provided wo answer the questions tat follow. ‘Copper turnings = B a ask (500m?) ‘A SODem? measuring cylinder K was filed with water and assembled for gas collestion, Copper tumings were heated ed hot and water was slowly pased into SOQcm ask H unt itreached the SODem? mark. A colourless gas was collected in K. (What was the purpose of passing water into Mesk H? (many i) What observations were made in the tube I? (man) (iy Name one ofthe gases thet is key tobe found in J (many (0) What was the volume of the gas collected in the measuring cylinder atthe ond of the experiment? many (¥) Calculate the percentage of oxygen in ir using the above results @ mar)'B. Sty the diagram below and answer the questions that follow ‘Copy oxide oe cold water Hap @Z : E CColourtess id ¥ Heat ae (@) Give one observation made inthe combustion tube after some time, (1 mark) (0) Write an equation fr the formation of the colorless liguidY. (mark) (©) What was the aim of the above experiment as emonstrated inthe combustion tube? Explain (@ marks) 2, Usethe information Below fo answer the questions that follow. The laters are not the set symbols ofthe elements. {emeat™ | AtomieNo [SUC BC [Tonic rages om) P i 38 wo, 0.085] 12 650) 116 0.065 (er 13 560 2470 10,080 fees 1 1410, 2360 ‘001 | T 15 28 90_[ 280 ‘ose vu, 16 Tei | s To. Vv 17 2 a OT Ww 1s 188 186 —@ o o @ (Write the electronic configuration ofthe toms represented by Iter T and W. (i mark) (Gi) State the nature ofthe oxides ofthe elements represented by Q and U, marks) ‘Why does the elements represented by the letors T and U have wo values of melting poins? (1 mark) Explain tho following observations in terms of stucture and bonding. There san increase in boiling point from P 10 R. marks) Element S has «high boiling point. marks) (li) There isa decrease in boiling points from U to W. marks) © Compare the stomic radius of U and V. Explain (1 marky(Gi) Why is there no joni dius for W reported in the table? (CL mark) (8) The solubilities of potassium nate and potassium bromide at fee temperature was eteemined, The following data was obtained, (ampeniure*c To [30 [0750 foo fro Fao Supiity [KNOs[s—[is— [2543 _(61_[as [wos fas fies wid, Ho [KBr [50155 |60 os 70177 [xs [90 [9s Draw solubility cures for both sls on the same axis marks) Ty(Gi) From your graph, determine the solubility @Feschsaltat 65°C? (mark) (Gi) 100g oF saturated solution of potassium nitrate at 70°C was cooled 1 20°. ‘What mass of the erystals wil be crystallized? (Qmarks) (6) Study the how chart below and answer the questions that follow. rice heat soli] piticr [Solution carbonate ‘ 2 Gab A few drops of Nie Desp blue | Excess of. solution je — Ri Sora (Write an equation forthe formation of solid A and gts B mark) i) Name: Soltion C- oe (mark) Solid D- Stoo (mark) (2) Write te formula ofthe complex ion in solution B, (mark)4 Study the flow chart below and answer the questions that follow m1 cagoone | 08 fen} [ea Theo Proce cH,coo# | 1+ (CH COOCH,CH,CH, | nso w oS femenson coo cco x z ems) x. al. 2 (Wie own aren rte eon epee ys mn (eat condin ad apn eed or ep? © tReet Conta - ems)()WeReagent- . Condon marks) (Name the proses repented by (maria) 3 mn - wv - v 1. Study the scheme below and answer the questions that follow, Keen ea oven Ammonia gas = Colourless | +} Brown gas sep Les Water ite”) (@) entity substances (©) State the catalyst necessary for; Sep - ‘Step 1- (©) Write an equation forthe reaction tking place in step TL (@ marks) (mark)Powdered DINOS): © 0 © (@) Write two balanced chemical equations for the reaction between chlorine ‘gasand; ( Hotand concentrated sodium hydroxide. (mark) (ii) Dilute and cold sodium hydroxide. (mark “The dlagram below shows an experiment in which the Lead (Il) nitrate erystals are heated Did? Names * (2 marks) © Liguia? Gay \Writea balanced chemical equation forthe decomposition of Lead (I sate. (mark) Explain how you can dstngish between nitrogen (I) oxide and nog (0) oxide marks)4) ip State Hess’ Law (mark) Use the equations given below to answer the questions tht follow: Calla +7/, O24) > 2COr y+ 3120 9 ‘AH = 1560 csmole Cw+ Ory > COrwy AH =-394 br/mole Ha + 40269 HO AN =-286 b/mole 1). Draw an encrgy cycle diagram that inks the enthlpy of formation of ethane to combustion of carbon hydrogen and ethane. (mark) 1 Determine the enthalpy of formation of ethane marks) ») The diagram below shows the set-up of the apparatus used by a student to detarmine the enthalpy change of combustion of ethanol. The heat produced by burning fuel warms: ‘a known mass of water. ‘Thormometer Metal calorimeter Clamp ‘Water Draught shield ——f} Spirit burner Liquid fuel,Resul ‘Volume of water inthe besker= 500em* Initial temperature of wate 129C Final temperature of water= 315% Mass of ethanol burnt = 1.508 Density of water giom* ‘Specific heat capacity = 423g" {oecalealate the heat required to rage he tmperature ofthe wate fom 12°C 31.S8C, marks) (i) Find the molar enthalpy of combustion of ethanol. @ marks) (C= 12.4 =3,0=16) (Gi) An accurate value for AHe of ethanol s 1368 Kimo, Sate rwo sores of ears forthe low Figure obtained. (@ marks) iv) Draw an energy level diagram for she combustion of ethan marks)(Calculate the heating value of ethanol from the sbove experiment (mark) (C= 12.4 = 1,0 = 16) 7.4) The diagram below represents a setin oF apraratus sed inthe electrolysis of led I bromide = 1) Name electrodes C and D (mari © D li) State and explain the observation mede a electrode D @ marks) Til) Write the ionic equation forthe reaction at electrode C (1 marig |v) State two applications of electrolysis. marks)»b) The table below gives some properties of substances A, B, C, and D. Study it and answer the questions that follow. [swowane [Een Consus ‘Melting Point | Boiling Point Solid ‘Molien ©) ¢O [A [Does nat conde | Conduct 50 130 8 | conus ‘Conducts 630 Hor f Does nat conduc_| Does not conduct | 1700 200- [Dest cnet {Dosen | 1} |) Which particles are responsible for eonductivity in substances 2 marks) a ii) Which substance is likely to be silicon (1V) oxide? Explain, @ marie)