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harinath.rao124
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CHAPTER 1

Chemical Reactions and Equations

followi11g n·ne·tion:
~ - - - ONE MARK QUESTIONS
Sodium hydroxide + Sulphuric ncid - -•
Ans : IC'DSE 20 1:11
1. In electrolysis of water. why is the volume of gas
collcctccl o,·er o uc electrode double that of gas 2N11O H + H,so , - ~11,SO, + 2H,O
rnllccl c,I over lhe u~hcr d L't'l.rodc.
9. Nn mr 1111d stnr o t ho lnw which is kt!pt i11 111inrl wlwn
Ans : [COSE S.11 2018, COSE 2lJO!J, 2012. 201:jj ,,·e balru1cc cl1omic1t l equations .
\~'nt •·r c·m1111i11s hydrog<'II 11ml oxyg,·11 i11 1Ji,, ral iu uf Ans : [C'fiSE 20 12]
2 : I . that is why volume of II, is <louhlc tlurn that of
Law uf cunscrvutiou uf 111a.ss. It stutcs Matter can
ox_,·gcn.
neither be creut.ed nor be destroyed. T Iil' to111I 11111.-..~
2. \~'!1111 t'IIII l1t· St'l!II 11'11<'11 II SI rip of copper 1111'1111 is uf n·11C·l11111 s 1u11sl he• <'fllllll 1.o Iola! 11111.~s of prucl11t'ts.
pln<·1•d in II sol111'io11 of sil w r 11i1rntp'/
10. What is meant by o cbcmicnl rcuction'!
AnR : [CDSE 20 15j A ns : !COSE 20 11 [
T he sol11tio11 will bcco111c blue. shiny silver 111c111I will
C'll<'mirnl n·m:1lu11. 11 pron·s.~ i11 wltid1 11111• ur 11111rc:
µ;1•1 d,·1,,~~i11·d.
suhs1111u·1·1<, th,• r1111e·t11111s. 11r1· o:1111v1·1·t.,~11u 01u· or 111orc•
('11(:-) 1- 2AgNO,.(11q) - <.'11(NO,.), (aq ) ➔ :lAg(s) <lifferout s uhs1 1111c<•s, 1he products. S11bsw11ccs 1u1•
either cl1c111icul clcu1c11ts or co111µot111<ls. A chc111irnJ
3. St11tf' om• i11rl11sl.l'i11I applir11tin11 nf rr d11d ,i1111 proc<•ss.
l'l'lll"lio11 l'l)lll'l'llllgt~~ I Ire l'Unsl,it lll'III 11tu111s of tire
Aus: [CDSE 20 1!'i[ n ·11rt1111t.s lo n,·1111' d iffn1·111 s 11hsl.11111·1·s 11.-i prud11 cls
It L5 used in the eidn1dion of metals e.g ..
ZnO(s) + C'(s) ____!.!!!!..... Zn(s) + CO,(g) 11. A~NO_,(nq) + N11Cl(11q) - All.Cl ! + XnNO..(1
F('S + H,,SO I - F'1'SO I + H,S i
4. Which one of t he following is n chemica l clumge'! Give Co11sid1•r thl' ahovP 111c111ionerl two chemiC"al eq1111t.i1
rcn.,011 nlso. with two diffcrc111 ki11c.l~ of arrows ( 1 nnd ! ) olon
(11) 8 11rni11µ; uf WIIX (I,) ~ldt.inJ.!, or \\'IIX wit h LIil' prudnet.. \\'11111 do l,hcs1· two diffcn:ut 111Tuws
Aus : [COSE 2014[ i11dk111 c'(
Arni : [COSE 20 1lj
D11rui11g of gas is II d ll'lllin,1 d11111g,· ht·<·1111s,· ll<'W
prod uns with new properties will be funned 011 i shows e•voh11io11 of g1L~. rnpn•sc•11ts II prc,cipil atr.
buruiug.
12. H.n lruµ;c11 bci11g II highly i11n11mu111hlc gas 1111d
5. Whid1 unr is II dlt'111irnl d11111g<': oxygen I ,dug 11 "11ppurt.t:r 1>J' c·11111h11s1ion, yl'I. wn.11·r. 11
Rusting of iron or melt ing of iron'! compound made up of hyd rogen Ellld oxygen is ui;ed to
Ans: [CDSE 20 1·IJ ext ing;ui:;h lire. \\'h_v'(
Ans : [COSE 20 11'
Hu:itini of iron is 11 cbc111irnl chungc.
H,0 i:; 11, t·o111pu1111d co11Hti111kd of hydrogc11 uf oxygen
6 S1.11t<- 0111• l>Hsic di fft·r,·m·•· hl't.Wcc11 11 physirul i:h1111g,· l'lt·11111111 s 1111d hd11g II e·1>111p111111tl it has diffc·n·n1.
aurl 11 rlw111iral e·haugl'. properties AR compared t,o its constit11ti11g clement,-.
Aus : IcnsE 2n1 ,1. 20 1JI
13. N,(g) + :l H,(g) - 2NH,(g) . 111111111 1h1° 1.1•111· of
ln a physical clmngc. no new s ubst.t1uce is Conned . rn11d.io11.
111 u d1c111iwl d1a 11ic, 11cw ~1.ilJtilu11re(s) with 11cw
Aus : [CBSE 20 11]
proper, i,~ is/an· formrd.
Combinnt ion renction.
7. Nnmc the oxidising and reducing agent in t he following
rc11ctio11: 14. If rnppcr t11t•111I is hcnl l'd ov1·r a n111111· ii. cl1·,·c-Iups
11 coat;i11g. \\11n1 is t ht• colour 1111<1 co111posilio11 of
C110 + 11.J - C11 + II}) c:onting'!
AnH: 1cnsi:: 20 1:lj Ame: [COSE 20 1I]
C u O is oxidising ngcnt 11, is re<l ncing ngcnt.
131uck culo11rctl cuuLing is furrucd. It is II d11e tu
8. \\'rite 11 1·u111plcl 1· lml1111n,'fl c:l1c111irnl e·q11111ion fur l he for111alio11 of ropper oxide·.
15. \Vritc u bultmccd chc111icuJ cquutiou tu rcprcscut IL is phutochcu1icul dccu111pusitiu11 reuct io11.
the followiug rei\C'tiou: ciu-hou 111011oxid1· rnwts with
hyd rogen j!;IIS at :1.IO attn to form methyl alcohol. 25. \\'ri t1e II lmh111l·e,.I d1t·111k11I eq11111 io11 for tit,· r1•11d iou
bctwccu sudimu chloride uud sih·cr 11-itrntc i11dicatin~
Ans: [C'llSP.20 11 ]
tlll' plt,vsirnl ~Ink of 1,111' n :111·t1111t.~ 111111 t,111' prrnhwl h.
('JI ,011(1) Aus : [CIJSE 2010]
16. \,\' ldd1 •JIit" i:< 11 d11·111iml d11111g,·: ft ·ruu·ut 111 iuu of fruit A i:N0,.(11q) + NnC'I {Mt) ~ . AgCl (s) + NaNO, (nq)
1"411~.,, "'•ll-w111<11k,rl,~·) l"iih"'f '111,11111"1 (So,lhuu S l u a1◄1l
juic<' or dilu l iu~ frnit j11il'P'! .S111 11I\• )

Ans: [C'IJS820 11 ] 26. Co111 plPtP nn<I halnn<·f• t.hP fo llowi11g e-q11atio11:
Fcrn1cut nt iou of fruit juice is u chemical c:huup;c. fo,0, + Al - -
A us: ICJJSE 2010]
17. ls l111mi11i; of II n 111dl,· \\'11.x II phy~ic-111 or II dl('11ii1:11l
rhnn g<''! F'c.,O, + 2Al - 2f',· + Al,O,
Aus : [C'BSE 2111 I] 27 IJa lnuc·c I he followiug C'he111ir11l rq1111tio11:
Durning nf a candle wax is n. r·hemintl chauge. Pb(NO,), - PbO + NO,+ 0 ,
Ans : ICDSE 2lJO!J]
18. Write· 11 lml11111·t'd 1·1p1at.iu11 for tlw die111in1I rc:11l'tio11
t hnt r a.n b<· characterised as pn'<'ipitntinu rear-tiou . 2Ph(NO ,), ~ 2PIJO + .1i\O, + 0 .,
Ans: [CBSE 201 I] 28. Identity the type of react ion in the following example:
J\g~O,(nq) + NnCl(aq) - AgCl(s) + NaNO,(nq) Ntt.,SO,(oq) + UaCl,(u,q ) - BuSO, (s) + 2NuCl(nl?. )
It is a prcdpitulivu rc11l'livn. Ans : ICIJSE 2008(C)]
19. St.ntr· I he main rl iff<'rf'llC'<' hetwN·u r·n<luthermic Double displm:cmcut rcudiuu.
rcn.ction and un exothermic rcnct iou.
29. lclt>11t ify t ht' 1.ypc• of l'l'►lf'I io11 i11 t lw fnblowi11g <'Xn111pli·:
AuH: [C13SP. 20 11] Fc(s) + CuSO ,(nq) - foSO,(uq} + Cu(s)
111 e11dothcr111ic rcuct.iou. hcuL is nb~orbcd . Ju Aus : ICDSE 2008(C)]
t·xotlwnuic l'l'11t'lio11, h,·u.t. is 1·1·ul\'t ~I.
Displacc111c111 rcuct.iou.
What happcus chouaicully whcu quick lime is added to
30. lcl1•11t ify t lw l.ypP uf r<•11ct io11 iu t ill' fotl owi11i; cxa111 plt·
wat(•r filll'd iu II h1wkl'I '!
2H.,(I?.) + 0 ,(1;() - 2H,0(1)
Aus: [C'13SE WIO. WOii] Ans : [CDSE 2008
C:11.ki11111 hytlruxidl' (Sl11kl'd li111l') is funt 1l·tl with
Cu1111Ji1111tiu11 rc11ct.iu11.
f'\'0l11tiu11 o f heal nucl hil;siug sound.
CaO(s) + 11 10 (1) - C'a(Oll ),(aq ) 31. IJ11l n11c•p t hr givc~11 dw111irnl Pq11111.io11:
Al(t;) + CuC:l,(nq) - , AICl.,(aq) + Cu(s)
21. D1·1i111• uxi, lat ion and rnhlt't iou.
Aus : [COSE 2008(C)]
Aus: [C'USB 2011. 2010]
2Al(s) + :1C11Cl,(11q) - 2AIC1_1(11q) + :_!C11(s)
Oxitlnt i,m is II proc·t•ss in whid1 oxyi.:rn1 is 111ltl1~l or
los.~ uf ck•ctruns tnkc pluce. lk~luction is u proccSli iu 32. IJul nnce t he given chemical e<111ntio11:
whid1 hytlro14e11 is 11dd,~I or 1411i11 of oltx:t rou,- 111kcs FcS0,(8) ~ Fc,0.,(,i) + SO,(g ) + SO ,(g)
pllll'(',
Ans : [CDSE 2008]
22. Gin • nn cx1u11plc of clo11bk• displncc111cnt reaction 2FeSO,(s) ~ Fc,0 ,(s) + SO, (g) + SO. (g) 1
(u11 l.v with rnmp lult• bnl1111cccl cq1111tiun).
Aus : [CUS E 21111. 20IO] 33. IJnlance t he followi ng chemical eq1111ti.011:
Fe(s) + 11,0(p;) - Fc,0,(i;) + Ui g)
IlnC'l,(1111) + H., SO ,(tlil.) - ll11S0 1(s) + 2HC'l(nq )
It is n do11hl1· displ n1·t•1111•111 rf'11rl io11. Ans :
3f'l'(s) + -IH,O(g) - Fc,O ,(s) + -IH,(g)
23. 011 wl111t basis h1 a d w111ical rcnctiu11 h11l1111n·d'!
Aus: [( ' USE 2010. 2008] 34. On add i11g dilut e hydrochloric acid to copper oxirlf'
powder , t he solution formed is blue green. l'nxlict the
Ch1·111i1·11I •~111111 in11 Is h11l1111r1·d 011 I Ill' l111s is of lnw of
uc,,· cumpou11d former! which imparts II l,l111· gn·1·11
C'OIISt' t'\'111 irrn nf mnss. n1lu11r I c, t.lu: sol111iou,
24. What d11111gl' 111 rnlo11r is obSl'rl'Cd wll('II whill' silver Aus : 1cnsE 20011]
d1lorid1• i~ lt'ft.1·x post•tl tu s1111 ~ligltl't S111t1· 1111' typt• of CuO + 21ICI - · CuCl1 + 211,Q
che111irnl r(•art ion iu I his du111g11. Copper chloride solutiou imparts blue i.:rccn colunr lo
Ans: 1cmm 2010. 2000[ the solut.iuu.
Grey coloured ~ilver tuetu l is formed aud pungent 35 \\l1y is respirat ion consid<>red as exor hcr111ic procC'ss·t
s111clli11~ d1luri11c ~IL~ is evoh·cd.
11 Aus : ICDSE 2008]
2AgCl(s) '"'' •1<1 • 2Ag(s) + C:l, (g)
lkspiration is an cxolhcnnic process becatL5e energy is coUected by the method as shown in figure.
is gi,·1·11 0111 i11 n·spirnt io11.

TWO MARKS QUESTIONS

36. Wriw the l"'-~culinl rnu<li tiu11 for the followiup, rcuctiou
Io Ink<" pl111·1·:
2A~Dr • 2Ag + Ur..
Wrilc npplicntiu11 of t his rci,1ction.
Ans : [C'DSE 20 1Gj
The rcuctiuu will tukc plucc in presence of ,;1111li~h1.
Thi,; r<·1wlio11 i,; 11sod i11 l1l1u·k nwl whitl' photo~rnph_v.
Awmw I he folluwinJ!. qut'81iou,;:
37. (a) Complete the folluwin~ L-c1uutio11 fur the d1emicul 11. '.11,rnw tlt1• i;ns lihernt<-d.
rl'11r1 io11: h. :--111111' tlti: 11101hod 11:wcl for C'ol11:C'l,io11 of i;us.
r. SC u,,,., "' c·. Is 1hr );\IIS sol11hlt- or i11sol11hlo i11 wnl f•r'!
rt· ) ,(:<) - -• rc•,o, + --- + ---
d. I:, the J!.l1S liJ?.hter or header 1111111 11.ir'f
(b) What ha ppens when water is added to quicklime
(C'nO? Wrill· t he d1cmirnl cf1u11Liu11. Aus: [CBSE 2015. C'IJSE 20 10]
Ans : [COSE 20 16) 11. T he 11.11s libcrul cd is H,·
1,. h is f'ollc•etcd hy dowuwunl di,;pl11ee111t·11 t of wute r.
(11 ) 2F,·SO,(s) ~ Fl',0,(s) + S0, (1:) + SO ,(~)
c. The J!.US is insoluble in wnter.
(Ii ) Sl11k1~l li1111· C:11 (01 1). i,- fur11wd . llh1,1i11g; so1111d 111111
d. Hydro~i:11 µ,1c~ is liv.h11•r t h1111 11ir.
lot of hl'n t is a lso pr~d Uet' d :
CnO(s) + 1-1,0(1) - C11(0 l l)~(11q) 43. Gh·inf:!; m1 nxn mplr- list 1wo impnrtnnl infnrmn tion
whid1 mnkcs u d1c111icnl cq11at i1m more useful
38. Writr hnlnnr<"<I rhrmirnl c·q1111t ion for t lw following (infur11111ti v,·).
n ·net io11s: Anii : [C'USE 201 r1]
11. Hydrogen 1-11lphid1· h11 nL, in nlr tu ~iVl' ,,·11t1·r 1111d
s11lph11r dioxirk 11. h :<honlcl ill('l11d,· physirnl st111,,...; of rrnf'l1111l s 111111
b. D11ri111n chloride reacts in aqueous solution ,,·ith prnd11cts.
zim.: :;ulplmle l,u )!;i\'e zim: cl1luride an<l buri11111 b. It :;houkl specify condition:, under whicl1 reuct·
s11lpl111tt·. t11kt·s pl111·1· e.g,.,
Aus : [CBSE 201Gj 2Na(s) + 2H,O(l) - , 2Nu0ll (aq) + 111(g)
(( 'oli:I) ..

II . 2l 1JS(g) + :10,(g} 211,0(1) + 2SO,(g) ,unu,111


2HC'l(g)
b. t:lr1Cl(nq) + Z11S0 (11q) - t:l11S0 1 (s) + Z11Cl,( nq)
44. C'o11sid,·r i h<' followi11g dw111ic11l cq1111t ion:
39. I.isl lwo olt,;1• rvnl. i1111s 1h111 11n · 11111.Ir,·d wlw11 1111 iro11
nail is put inside c·oppcr snlphntc solution. \\'ri te t he
X + Utu·iun1 d1luridc - Y + Sodium chloride
(Wl1il,· 111>11
t:hl'micnl 1·q111Ll,io11 for Ihe n·nc·lio11 Lhnt OlTUl'h. ldl'nti (y (11) X 111111 Y (11) T Iii' t-.l'J>l' of n ·111·1iun.
Aus : [C'DSE 20Hi[ Aus : [C'USE 2111:ij
TIii' lilue r uluurcd soh11 io11 wi ll lic1:u1111· p11l1• ~n·c11. (11) X is silv,w 11i1 rn t.- , Y iKsil VPr rl1l11ridP.
fl e<ldii;h hrown nwt.al will get deposited . 2AgNO ,{nq ) + BnCl,(nq } - 2AgCI I+ Un (:JNO,J,( nq)
Fc (s) + CuSO ,(aq) - FcSO 1(aq) + C u (s) l\\"h11r ppr

lllhw) Cl1,Jt.• (lrw11) !HuM~h lotuv.uJ (1,) Tlw l'l'ad io11 is 1111 exan1plt- of cl u11hll- clispl11cc111e111
40. i'/111111• t hr rrd11rl11i,; 11gl'111 in 1.110 foll owi11g l't'11ctio11: (prcc:ipi t 111ion) n ·11.cl ion.
:n. 11102 + IA I • :Jl\ l11 + Al,0 .,
Stute which is 111ore rcncti ve, l\ 111 or Al aud \\'hy'f 45. (11) Wri te u bnlann .~.I chc111i<:ul t.'C111atiuu fur the proccs,;
of' photusy nlhl'sii..
Ans : [C'USE 1016. 2lll 5j
(Ii) Wlt1·11 do ,lt-s,·rl pla11I, tnkc· 11p rnrhon clioxicl,· 1111cl
Al is 1111' n :ch1c:i111; IIJ!.l'II I. Al is 111ore n•11t·tin· th1111 Mu. pPrform pho10;.ynthPsiN.
n, •1L'lllll: It is h1•1·a11s,· Al J,. cllsplill'illg; l\111 fro111 ~foO,. Ans : [CllSE 2015]
111mll1•11
41. "We need to btiluuce n skclctou chcmirnl cc1uat iou·•. a. <iCO,(g) + CiH.,O(1) c1,,,,"'r>h,-u ~•,,H/ )11(11q) + Ci07 (g)
Gh·c rca:;011 to just iry I he ,;luLc1uc11t. h. Deser1 pl nnL tn.kr· up rnrhon d1ux1dr- 1u1d pr rform
Ans : [CBSE 2015] photos~11thesis at nizht.
\\'C' 11111st h11l1111n: 11 ,-k,•lr t nl Pq1111I io11 so IL~ Io e11s11re 46. Two n•u1·liu11s urc· give11 hduw:
t hnt the rcnction follow,- ·Law of con~cr\'!lt ion or mnss·.
II . 21':t +Cl. __, 21\C'I + ' ·
uc
The tutnl 11111.::1s of rc11clu11t s 1111ttiL equal tu Lhe t.utal b. 21, + c 1: - 21\Cl •
111ns.~ or prod11rt.s. t,hnt is wh,v 1111 n·11c·1io11s ,; ho11lcl hi' ldc11t,ily t lw \\'pc of reurt ion. giving just ilirn tiu11 in
h11l1111ced. 1·11,·h l'IISI ~.
42. A llll'tal i,; l.rc11t.cd with dil111c H.,so,. The gm; evol vl'cl Aus : [C'BSE 20 I!i]
a. Displ11cement reaction hecause Cl, is displacing 12 n.nswer the questions which follow:
rro111 Kl sulutiuu. - (i) CuO + l:l2 ~ Cu + H,O
h. C'o111bi11111ion n·n.d ion lwc:1111so K rl'll<"ts with Cl, (ii) ZnO + C ~ Zn + C'()
to form potassium chloride. a. :'1/nme thr snhst.ances that nre oxidisecl and
reduced rcspocth·cl.v in each case.
47. On heating copper powder in uir. the surfocc or copper
b. ltleut.if~· t.hc rcduci11g agent i11 l'll<:h ens<!.
powd1·r h,-<·011ic ~s <·on.Ieel wil.h hl1wk Cu0 . Hm1· 1·1111 I his
black co11ting be converted into brown copper"! \\"rite Ans : [C'USE :m1:1)
d10111icul cc1u11t ion for I.la<: rcm:I ion thnt mT11rs clurin)?. 11.H, is i;t't I hag oxiclisc~I I•• Ii ,(). C'nO p;c-llin).!. r(·chwr cl
1ht: ,., 1lnur dmng,·. Cu .
to
Aus : (C'13SE 20l!i] b. II . is reduci11p; op;eut in (i) rc11ctio11 whcrcas C is
n·~l11d1tJ,!. IIJ.!.<·11L in St'C.'011d n ·11ct iuu.
2('11 + o,
54. Whal is 11 1'1'.<-lox reaction·! Identify the substances
Copper oxide 011 hcuLing with 11., will c:hm11,;c buck to
oxidist'd 11ud I he• sul,st nnce reduced in the follow iug
ruddish l1rm1·11 n1pp1•r 111ot11I. -
n·1u-l ious:
C:110(s) + H,(g) ~ . Cu(s) + H,O(1,;) n. ~l nO,+ •IIIC'l - • }.lnC'l, + Cl,+ 11.,0
48. What is ohscrn'Cl when a solu tiou or potnssi11111 iodide b. CuO + H, - Cu + Ii ,0
is 11dd1·d I•> 11 1<11lutio1111f Imel ui1rnh-"! X1111lt' till' 1yp1· Ans: IC'USE 20 121
of n•nc-tion. \\'ritP II hn ln11fc•cl d1m11irnl <·quation In R•~lux n·m·ti1111 is II n·1u·1iuu iu whid1 11xid11ti1111 a11d
represent t hc 11ho1·e chcmicnl rcnct io11. rc~hwtiuu takt•s pl11n: sin111h1111,•011sly.
Aus : [COSE 201,1. 201:l] c. IIC'I is the sub.,tnnre c,xidi,,cd . l\lnO, is the
~ul..st nncc gclti111,; reduced.
Yellow pn·dpit nlt· is fomavd du,· tu furu111tio11 uf lead
ti. 11, i~ t;<'I I ing oxidi:<c·<L C' u() L~ g,it ting; rc:d1w<'d.
iodid,·.
It is n prrc-i pit 111 inn 1~s wull ns rlouhlc rlisplnc-c•nwnt 55. \\'rile bulun<:l.'C.I d1e111icnl cc1untiuns for the fulluwi11Jl,
reaction. rc·1u·I ions :
Ph(NO 3 )(11q) + 21, 1(111!.)--. Pbh{s) + 2KNO3(11q) 11 . Sil\·,·r hru111idl' 0111·xposmc• lo snnlighl, d••c·t1111posus
Y1•Uuw 111,1
49. Writ.n a lml1111<·c'< l dwniicnl equation for the prnc·•-ss of
into sih·er nml hrominc.
h. Sodium metal rcacl,1! with wntcr lo form i;udiu111
pho1.nsynt lws is 1111<1 I 11(· rnmli t. iuns of rmcl ion 1,;ivi11J.!.
physirnl ,., alt• of all suhst,11111·1·1<. hydroxitl•· 1111<1 hydrogtm s as.
Aus: (CLISE 2014 )
A us : ICBSE 20
11
GCO, (g) + 011, O (I) -;-"'"-'
·•••-...'-_ C., 11 ,.,0,,(aq) + fiO , (g) n. 2J\gDr(s) '"" •h• 2Ag(s)+ Dr ,(g)
Jill,wpll) It
1,. 2Nn(s) f- 211,0 (1) - :.!NaOH(i) + 1-f:.!{1,;)
Giv,: 1111< 1 1·xn111pk of c11d1:
56 ldc11t,ify the t~'pc of rcnction from
11. C'lwmi<'nl re11c-1io11 showi111,1 PVolu tlon of a gn.s.
b. Chnnp;e in colour of u sub»tn11cc duri11p; cheniical equations:
rcncl io11. 11. c·H, + 20, - co,+ 2H,o
1,. Ph( l'\O,.); + 2KI - • Pltl., + 2K:'11O ,
A us : [CBSE ,!01 :lj c. C'nO + H,0 - C'n(O II),,
11. 21\(s) + 2H,O(I) - 21(011(nq) + H,(1:1) ti. C'uSO, + Z11 - Z11SO 1 + ( 'u
h. Ft·SO 1.7Ilp(11,1) ~ • FcSO,(.s) + 711,()(1) Aus : [CUSE 2111:.!j
lr.-ilt ~ • (ll1rty wh1tC'l
a. Oxidutiu11 rrnl<'t.i1111
51. ' l)·nnslale 1,he fol111wi11~ st,111l'1111;11I 1111.o d 1rn11ic11I h. Donltlt• disph1C·1•1111111t rPnction
equ1tl.iu11 uml tlwn lu•l11111·1• ii. ··A 1tlt'l.11I 111 li lt' l\ 1r111 of c. Co111bi11ntio11 reaction
ribbon hurni< wit h 11 <l11zzli11g whit<' 011.111<' 1111<I c-hnngPs ti. Oispl11ccn111·11I, n•nd.ion
i11to whi1 c• powd,•r:·
Aus : [COSE '..WlJj 57 \·Vrit.c baluucecl cquutio11 fur the rcnction between l\lg
1111d hydrochloric acid. Nu111e I ht· protlucl ul1tni11cd .
2l\lg(s) + O,(g)
011111111,i;
2l\ lgO(s) + Lighl. + H1:11I idcint ify t.hc t.ypt• of n ·111·t.i1111,
Ans : [C'ASE 20i2]
52. Jt hm, bcC'n fotwcl that mar hie of T11j it; getting corroded
dell' Iu dcvclop1ucut of i11d11~t ri11I UJ'cas uro11ml i1. l\lg(s) + 2IICl(rlil) - • l\IgCl/ nq ) + 11,(g)
Explain this fact gi,·ing a c-hnm irnl equation. Mllgne:,iu,n chloride and h~·clrogcn 1,;11s arc formed in
Aus : [CASP. 20 1:lj \,his n ·11t:1 iu11 . II, is II displ111·c1111·11t n·a<·t iuu.
Tn.j is made up of CnCO • wbich reacts wit.It acid 58. a.. Whnt. is colour of ferrous sulphate crystnls't flow
formed by pollutiou uf SO,(g) uud :'110, from ~luthtu·a dues this colour change 1iftcr heating"?
rnli1ic:rv 11ml other i11tlust rit·s. 1,. N11111<' the product~ fort11l~ I on st ro111?,ly hcul.ing;
CaCo ,; + 2Hlso . - · CaSO, + co, + 211,0 fcrrous s11Jplmte r rystols. \\' hnt type of chemical
CuCO., + 21:lNO., - Cn(NOJ)J + II}) + CO2 reaction occur~ in I his change'!
Aus : [CDSE 2012.20UDI
53 Consider tlw dwmirnl ecprn1 ious 1,1 ivc·11 l,plow 1111rl
n. FcSO 1· 7H 1 0 cr~·stul,; arc pnlc grccu i.n colour.
TlrP~• hPm111P dirty whit e 011 lwatiug,. 64. Trnnsla.1t• t l11' fullowi ug: st.111<!1111·111s into 1:lw111i rnl
IJ. Ferric oxide. sulpl1w· dioxide aud sulphur trioxide cquutious und then balance them:
,ire· fornlC'd : n. Hydrogen gas combines with uitrogcu to form
2FPS0 ,(s) ____!!:!!..... Fc}\(s) + SO,(g;) + SO ,(g; ) 11111111011 i11.
Jt is n dl'C0111positio11 rct1ction. b. Hydrogen sulphide gas burns in air to give water
uncl sulphUI dioxide.
59 rlc 11C't i1111 of c·o111po1111d X wit.It 11l11111ini11111 is 11sc·d 1u
0
c·. B11rit1111 d1lorid1• rcncl.s with 11h1111i11i11111 s11lphnt c
Joi n rnilw11~· t rnr ks 11r n 11ck1>d mnchirw pi11ts. to ~iYc 11l11mini1m1 chloride and a precipitnte of
u. ldcutify the co111pound. barium s11lphnlc. State the two types in which
1,. N1111u· I IIC' n•adicm. this r1·11c·I ion 1·1111 I11 , c-lussilic·cl.
c . \\'rilt' 11 lml111wc·cl du·111ir11I c•q11111.io11 for I IIC' cl. Pc,t 1L~sit1111 r,·m·ls wirh l\'11IN Ill givc- pot11s.,;i11111
rcm:tiou. hydroxi<ll" 1u1d hydro~nn ~as.
Aus: [CnSE 2012] A1111 : IC IJSE 20121
a. T ire co111po11nd X is Fc~O , (Ferric oxide) or Iron II. :1H, (1!,) + X, (J!.) __, 2NH ,(J!,)
(lll) oxide. I,. 2H..S(!!.) + :102(g) - 2H,0 (1) + 2SO,(g)
h. It is cnllcd Thcrmit.e n e11ction. <·. :10,;C'l,(m1) I Al,(SO, L, (m1 ) • ;JOuSO,(N) I 2A IC'I ,(m1)
c. 2Al(s) + Fc,0,(s) ~ Al,(),(s) + 2Fe(I) T his rl'llctio11 1·1111 hl· dassilicd IL~ 11 douhle
clisplm·e111l'll1 rc1wtin11 IL'! I h,· two rcm·tiug spl·<·i1!S
60. !;sing; l111l11nrc,I du,111irnl c·•11111t io11 cx pl11i11 I he (Oa.SO ,· AI,SO 1},, nnclc' rgocs m11t11n.l cxdmngc
difference between a displacement reaction and a of ions. It can also he classified as precipitation
do11hk disph11'c1uc111 1'('1u·1io11. reuct iou. ~im;c u white ppt. of 13uSO , is ohtuiucd.
Ans: [COSE 2012. 2011 ] cl. 21\(s) + 2H})(l) - • 2KOH(11q) + H,(g;)
Dillplncement rcnctiou: A reunio11 i11 whi ch a 111ure
65. Wlrl'II 11 1111'l1tl X is 1uld,,l 10 s11l1 sol11l.iu11 uf 111<'111I Y.
n ·1U"l.i\lc' c·l1·1111•111 clispl11c·c•,.; 11 lc·ss n·111·1 ivc· c•lcr1u•11I fn1111
1IIC' followi ug. d11·111ic·11I rc·111·t ion 1.11k1•:; pl1U"c 0
:

ili; snit solut io11 e.J.\,,


21':Br(nq ) + ('I,(,:;) - 21,C'l(nq ) + Br.,(11q) ~IC'tnl X + Snll suh1t io11 of Y
Douhlo dliiplnco111ont r1mction: A n•11c·l.ion i11 wlrid, S11II sul111 io11 of X I- ~-lc-1.n l Y
two compounds cxchnn,:;e their ions lo form two new l\l1·111 iu11 1111, i11f,·r,·11rc· you cll'llw rc·g;11rcli11g I IIC'
co111puu11ds c.,:;.. rPar th·ity nf 11101111 X 1111<1 Y a11d 11lsn thn 1ypc• nf
KOii + IIXO, _ , J.: :'JO, + 11,0 n·11rtio11. Stal 1· 1IIC' n ·1L,;u11 uf your 1·0111·l11sio11s.
Uin · 1111 cxm nplc cud1 for tlicr111ul clc(·o1111,v.~ilio11 Ans : [COSE 20
1111d photod11·11tintl cl1·1·cJ111 p1~~it io11 n·11c·I ious. \\'rill' X is 111111'1' rcnd.i\11' 1h,111 Y h1~·1111S<: . X clispl111:1'S Y f
lmlnmw l d1t·111ical eq1111lin11 also. its s11lt sol11tio11. 11,•ncP. this rc,;wtio11 is flit c•x11.111pl
Ans : [<'BSE 20121 displ11ce1111·11l rcm·1ion.
Thermal decomposition: 66 ldl'nt ify 1hr 1,vpc· 11f r11d1 of lhr- li,llowing l'l'J1c1ic111s:
Z11C0 1(s) ~ ZuO(s) + C O, (id n. A rcnction in which n sin~lc product is formed
Photochemical dccompositiou: frlllll lWll lll' IIIUl'l' l'l'IIC'LIIIII S,
:.!J\l,\I(,;) .....11.11, :.!Ag(s) + I ,(g) h. Tlw rc•11c:Lict11 111ixt 11n, h1·<·ct111cs w11r111.
r . Au i11sol11hlP snhst 11111·..- is for111P<I.
62. Why 11n• d1!1·0111poslLic111 rc•11rl ious C'll llc·cl 1h1· opposil.1· ti. Exl c·rnnl s11rf111·1· of I he c1111l.11i11l'I' in which rc11ct io11
of <·ot11hi1111tio11 rrn<'l'.ic,11,;! Giw ch1•111knl C'<pmt.ions for tnkl's plm·<· lwnl111es cold.
t hc!lc react ions. Aus : [CBSE 20l2J
Ans : [COSE :.!012]
11 .Co111bi111t1 io11 rnw1.io11
III d,~·0111 pn~i1 ion n·111·t i1111:,. 11 1·11111pu1111cl is hrok1·11 I,. Exothcnuic rcuctio11
clown into one or 111on• ele111e111s or <·orupo11nds e.g .. 1·. Prcdpi1111 io11 r<'11t'I io11 (Donhlc- displ11c·1·1111•11t
CuCO,(s) ~ CnO(s) _... CO2( :;) n •11cl.io11)
111 combi1mt ion rc11c:tio11s. two or 111111·1· l'il·1tw111:; cl. Endothermic renction
or 1·0111p01111cl,.; 1·c1111hi11,· 1o fon11 11 111'\V c·o111prn11ul.
Therefore· . dcco111position rc•11<·1ions n.rc opposih' to 67 A sol11ti1111 of pu111,-sit1111 dtloriclt· wh1·11 111ixl'cl wirlr
co111binulio11 rcm:tiotus e.g.. sih•c•r 11itrnl11 ,ml11tio11. a n i11 Rol11hle white subst ance is
:U,li,;H + N, (i;) ~ . ~lg;, N,(s) formed . WriLc the d1c111irnl reaction involved and ulso
1111m1.i1111 I he I ypc of react.ion.
63. Why docs the colour of copper sulphate solution Ans: ICBSE 2012, 201 I. 20101
d11111gl;, wlu:11 1111 iron piu is dipped i11 ii '!
Agl\O,(n.q ) + KCl(11q) - AgC'l(s)+ KN0 ,(11,1)
Ans : [CBSE 20121 (Whll" f'P .
It is a double displnccrncnt react ion.
1r<lll lwi11g; 111orc real'l.i\'<' tlisplnccs copper from 1·oppPr
sulphate (Dlue) solution to form iron (11 ) s11lphnk 68 l1si11g; n ,;11i1 11hl1• d w111 irnl c·q11111in11 j11,11if',1· th11t smm·
(Pale green) soluUou uud reddish brown copper 111ct.11 l d1c111icnl 1·cact io1L~ f11·e det:cr111 inecl by
gets deposited . 11 . Chm1ge i11 colom.
Fe(s) .... C'11S0 1 _,, FeSO,(nq} + C11(s) h. Cl11111g;P i11 lP1111,c•rat11rc.
Aas : [COSE 2011 ] fumes and n white residue i,- left hehi11d.
u. Ch ange in colour: Blue coloured cryst a lline n. Name the suit.
cop1wr s11lpl111tP n~•st11ls ch1111gp;; to \\'hite C11SO I h. \\'rite· I ht! c>q11al,io11 for t.lw dccm11p1~-;iU011 rend ion.
(11nh~·drous ) 011 hentin~. Aus : ICBSE 20 11]
C11S0 1 .r1H,O ~ C11S0 1 1- !iH,0 11. T.<•11,I 11ilrntc
W IIH') ( l.>U I) v.hH< )

I,. Chru1ge lu te111per11tur e: b. 2P b (~O ,), (s) ~ 2Pb0 (s) + 4NO, (g) + O, (g)
1\\uill•) ,n,~'-.tur> ( Hr"""'u l
C'110 (s) + II ,0(1) • 111(0 11) ,(nq ) + ll r11t 74. Wlwn 11 ,;0)11tio11 of pulnssin m iodidl' is ndtlcd to 11
1mh1 tiu11 of lf'nd 11i1r11.lc- in II tt-,,1 t11hc, a 1n1c1im1111k,--,..
69. (11) A sol11 t.i1111 or s11hst11m·1· X is use·cl l'or white· pince.
w11.,hi11g. \ Vhat is s11h~1,11w1• X'! Writ,. 1he d1<·111il'11I
11. \\"l1111 l_vpe· of' n·ae·t ion i,- 1his'{
rcnction of X wit,h \l'ntcr .
h. Writ1• tlw l111l11n,·c•cl d11•111irnl ,·,p111 t i1111111 r<•pn•~ •11t
(I,) Why tlut~ lite c:ulu11r of copper sulµIULll' w l11tiu11
d11111gcs w licm in111 1111il is dipp1·cl i11 it.'! t ht ubo,·c rcuctio11.
A111, : [C'RSE 201 1, 2010, 2008)
Aus : [C'BSE 20 1lj
a. X is C'aO. r·alci11111 oxi<l1· 11. It is pl'l'l'ipit 11Uu11 1111 wd l 11:-1 clu11lilo di:-1pl111·,·111l't1l
l'l'llt'I iun.
CnO(s) + II ,0(1) - Ca (O II) .(n.q )
h. Ph (NO,) (nq) + 21<1(aq) - • Phl, (s) + 21<1'-0 ,(11r1)
11. It is because Fe displnccs C u [roi11 CuSO , (blue}
o<ol11t i1111 to limn F't·SO 1 (p11lr gn :c:11) 1111d n , ldi~h 75. Dcli11c cu111hi1111tio11 rc11ct io11. Give 1mc 1·x11111pk of 11
brown Cu metnl ~ets deposited . ro111hi1111tio11 n,ae·t ion \\·hid1 is 11lso c:xot ll<'n11ie.
70. Il11l11111·,· t lw followi ng n ·111·t i1111s: Aus : [CBSE :2011 ]
11. OnC'I, + 11., SO , • 011SO, + IIC'I Comhiuation ronction: Thi" rea<'tion in wh ir h two
b. Cn(O II ), + II NO , - • Cn(~(J,), + 11,0 or more clc111cnl.s or cu111pou11di; combine to form
l ', Ph(~O ,), - PIJO + .'\01 + o, rn111po11ml(11) o.~..
,I. ~1110, + HCI - ~l11Cl, f Cl., + 11,0 C'(s) + O,(i;) - CO,(g) + ll,•111,
Aus : [CBSE 201 I, 200!1, 2(Kl8. 21Kli!C'j It is uu exot hermic. co111bi11uliun rcndio11.
a. OnCl, (aq) + 11, S0 ,(<lil) • D11S0 ,(8) + 211Cl(11<1) 76 \\'·1t111 l111ppc,111< wllt' II 1111 111 1111,1111;; :<111111 iu11 uf :<rnll11111
b. C'11 (0H ),(m1) I 2H1'0, - C'u(NO-,l,(u4) I 2H, O(I) s11lphn1r rc:nc· ts \\'ii h 1111 11q11eo11s solution uf hnri11111
1·. 2Ph(1'0,) 1 (s) ~ 2PhO (s) + -IN0 2 (g) + 0 2 (g) chlorido't Stnlc t he phyijicnl co11ditiou,; of rcaclnuls i
which tlu: r,·111·1iou I 1t·11,·1·1•11 l.lm111 will 1101 t 11k,· pl1
~l110-1+ <II ICI - hlnCb + Ch+21110
\\"ri te· LIil' hal11.1tl'<'d d1e111ir 11I 1:q111.tl io11 for I he rc11.<·
\ \:ri te I ht· h11l11111·cd cq1111I iu11 fur the fullowi11~ rc11dio11s und 1m111c t he 1~1>0 of rcuctio11.
11nd id,·111 ify I h,· t.ypc· of n ·11ction i11 i-nd1 nuw: Ans : !COSE 2016, 20
Pot11..,si11111 hro111iclf' + 0 11ri11111 iodide•
While preci pit at e of 1311~0 , ii; fon11cd .
U11rii.1111 bru111itlc + I 'olw;si11111 Iodide BnC:l2(11q) + J\11 2S0 1(11q) - 811S0 1(s) + 2N11Cl (11q)
I,. Hydroi,:,·11(i.:) + Chloriiw(~) Hyclro~•·11 It is n double displace111cnl reaction. If rcn('t1111t s arc
chloride(p;) l11ke11 iu Kolid st utl', pruducll! will 11ot bl' funned.
Aus: [C'RSE 20 1IJ
77 \\"h111 i,; rf'clux n•11r-1ioi1 't Whr 11 " 11111g111•,;i11111 ril1h1111
n. 21(1Jr(ac1) + Un..l, - • OalJr ,(nq ) + 2Kl(nq ) burns i11 ai r with II dnzzliup; Jlnme n11d for1111, n white
It is double di:;piacemcnt re1~ t io11. ash. is 111n)?;uc,;ium oxid ised or reduced . Why'!
""' • h• ► 211Cl(g)
11
h. 11,(g) +. Cl,(g) Awl: jCBSE :WW, 2UOUJ
It i:s combiuutiou react ion.
R1·clox n :11<·t,io11 is 11 r<·ac:t io11 i11 whid1 nxid11t.io11 1t11tl
72 A zi11,· plnit• wn;, put i11tu soh11 ion of 1·npp1•r s11lph11t.(• n~<lur.t ion 1itkrs placr. simultaneonsly.
kept i11 11 p;lnss cont ai ner. It. wu;, found t l1111 blue colom ~ I~ iHid.t in~ oxklist~I lm :aw;c it ii; ~u i11i11~ uxy~t·11
uf the :;olntiu11 g;cts fntlcr ullll futlcr wilh p11ss1.1~t• of lo l'urn1 n111~111-si11111 oxide:.
1i111e. Afll·r few days wlu·n zi11c pl11.h: WIL'> 1ukt' 11 1111!. of
t llC' w l11tio11, n number of holc•s W<'l'C' ohs<.'n '<'d on it. 78 Wri te 1111.v 1wo obsl'rvations i11 1111 nclivit,,r which 11111,r
11. Stale t lll' n ·1iso11 fur the clm11~cs observed u11 :due SIIJ,;!;CSI Lh111 11 d11.•111irnl n ·1tdiu11 h ,L., l11k,·11 plan·. Gil'I'
plnlt'. 1111 cxn.mplf' in ~ttpport of your 1111swor.
Ii. \\"rit .- t,ht• d1P111icnl •·<111a1 io11 for I hP rt·11rt.in11 Au8 : jC IJSE 2010J
involved.
a. Change in colour:
Ans: [COSE 2011] Ag NO a(uq ) + 1(1 (uq) - Agl (s) + l(~O a(nq )
(Y,.llo11,• pr,tl
11, Zinc displace:; t·opper from copper sttlphnt.c
~1h1tio11 I,1 fort11 t'ulu11rle·ss Z11SO,I 111111 1·op1>t·r I,. Evolution or gas:
111t•t1-1I is cl!'(IOl'ilc-<1. Zinc gl'ls rons11111ecl cl11 t' In Z11(s) + ll 0S0 1(11q) - Z11S0 1 (11q) + 11 ,(g)
which holes 11rc fonnt d . 79 \\'hell t hl' powder ol' c.:u111111011 metal is he11ll~I in op1·11
I,. Zn(s) + C'11S0 1(11q) - + Z11S0 1 (11q} + C11(s) r hi1111 dish its m lo11r lttrus hlnck. I luwf'wr. whc11
73. A wh.itt' suit on hcutiag decomposes lo givo brown hydro~ea is passed o,·er the hot blnck subst nnce so
funucd. it. rcgnius its origiu nJ culom . BtL%'tl 011 the
ahovr i11furumtion nn sw!'I' t hr following. 111u-,,1 ions: Oxiclatluu reaction: TIil' n·,wt ion i11 ll'hid1 0 ., is mlcl,·cl
a. \\:1t111 1_vpe uf dlt'111it·11l rcat:1 iu11 t11kcs place i11 ur II, is ri,muv1.-<l or luss uf clcdru11s t nkl...;
• pln,·i, is
c11ch of the twu 1-:ivt·11 sLCps·t calletl oxiil>1tio11 r,:,act io11. E.;;.,
b. '.\,m 1c the metal i11i1 iall.1· tak,:,11 in powd ered fun 11. 2Cu(s) + O, (l\) - 2C uO (s)
Write balllilced cquntious for both the reactions. It is au cxotheru1ic rend iou.
Aus : {C l3SE 2010]
O xicl111 inn n·1u·1iw1, Hi.l11x n ·url i1111
11 . THREE MARKS QUESTIONS
h. t'oppt·r 1111'1 111 \\'IL~ J>r<'S1·11t i11il i11lly
l h•
2Cu (s) + Ch(p;) - -• C'uO(N)
t lu.tlct 85, D1•c·rn11p«silio11 n·1u·t iu1111 require 1·111·ri;.1· f•it her in 1111'
C11O M + H1(i;) ~ C'11 (s ) + H, O (1) l'or111 11f hC'>tl . lii,:ht 11r d,·, ·I rici1.y fur I11'1°11ki11g dow11 1111'
flt.-t1h,b 111,1111 II ~ rt ·111·t 1111ts . \\'rit1• 1111 1·q1111I ion c:11.c-h fur cl,~·n111pnsil ion
80 \\' h_v du w,· ~ton· sil l'C'r d1luriclc· in clnrk 1·11l,,i1rrcl renctious w here cucrp;_v is su pplied i11 t he form of heat.
h11Ult•'( Explu.i 11 i11 hri1•f. li~ht Rnd cl<Xtricity.
Aus : ICDSE 20 IOJ Aus: [C DSE :?0 18. 211 1 I]
It is don<' so 1\$ t.u cut off the expo.~11r<' to sunli~ht. 11, C11CO 1(s) -
llm1
CnO(s) + C'O,(;;)
/\~Cl is photoS<'11sitiv<'. it will dtXomp OS<' to i\g nnd h. 2i\f:13r(s) ••nllcl,,- .. ~)A ~ (s) + r,(~ o· )
Cl., in t.lw prc·sc·11r1• of sunlight,
c. 211 ,0 ( I) f.w11• n•• 211,(g) + 0 ,(~•)
2Ai;CIM '""h~ . 2A;;(s) + ( 'l,( J,\)
86. In the electrolysis of wotcr:
81. "O xitl.11t.i1111 1111<1 ri•d11r t i1111 pn w,·ssc·s .,,.,.111· 11. N11111t• t Ill' gns 1·ollt-rl.1•cl 111 IIll' nit h,.cl,· 1111d 1111ud1·
s i111ultu111.-ou1:1 ly'' . .Justif~• t.his 11tute111cut with t he help rc,,;p,"<·t in ·l,1•.
ul' oxnmplc. h. \\'h,\• is 1•ul11111t· of µ;11~ 1·11ll1•d,1•cl 111 u1w 1•l1•1·l.r11d,·
A1111 : [C' IISE :.10 Hl] ,luuhlc t l11111 t h nl 111 t. hc 111 her? 1\111111· tlii~ µ;1L,;,
Oxid1t tio11 involves loss o f c-k<"t rorn, nr nd dit io11 nf c. ll uw \\'ill ~·uu test I his J.\Hll'!
11xygm1. VVhr•n·1L< n•d111't-im1 i11v11Jvi,s p;a111 .,r 1•l1•1·I r1111s Aus : [CDSE 20 12, C l3S E S11111plc P11pcr 20 181
ur ncldil io11 of hydrop;1·11 ,·.p;., 11. li _l'llrog,·11 is .-ol11'C··ln1I 11I t,hl' m t hocll'. 11xyg1111 is
Ox11l1\l lo11 1·, ,ll,·1·t c·d 111 t lw 1111od1•,
I,. It b lwn111s1· H,O 1·1111l11i11s hyclr11i;1·11 1111d IIX,l'J.\<'11
i11 the rntio 2: I.
n1'l.hwtin11 c. Orin~ 11 bnrninJ:: mntchHtick ucnr I he gu8,
H, i~ gd I i11g 11:ddis,·d Io H..0, < '110 is g,i:t.tiu;; rl'1 h11"1·cl J);ns hums with ·pop' sound. the _gas is 11,.
1, ; ('11 . .
I I s hows 11xid11t.irn1 11111 I 1nhll'l.irt1111<'l'llr s i1111dl 11111~111,il_v, 87. Deline tho term decomposition rcnctio n. C:i vc
our c•xn111.ple r 11d 1 o f thermal d c.'Co111positio11 11nd
\\' h,·11 11u,g11,•si11111 rilol,1111 111111111 in nii- 11r 11X,YJ,\t'II , 11 ,,kd rolyt ir tli'<·mnpnsit io n rt' nl'I i, 1111;.
pn11l111·L is ft1l'lllt'd, SL,dt• 1111' ly p,· or d1ui11irnl n•11t'l.io11 Ans : [C'BSE 2111 fi]
nnd n.n111c t he product formed i11 t ho re11ct io11. Write Dc.-composition reaction: Tlw r,•11c t ion iu which u
hnl1111cc<l che tnicn l rq1111tio11 for I hn r<·nd ion. cu111puu111 l i,, broken down i11Lu 1,i111plt,r e!cm,mt~ or
Aus : IC DSE 200!:J(C)] CUIU))Olllltls:
It is n n1111l,i1111tiu11 r<'11C'lic111. 'l'hr. prnd11r t ft1rnlt'd is 11. C'nCO ,(s) ~ ( 'nO (s) I ('() ,(g)
11
11111p;11t-,.i11111 oxid,•: Ii. :.! H,O( 1) •: " ""'f • :.11-l,(µ;) + 0 ,(~)
2~lg(s) ~ O,(J.\l 2l\ l!!,O(s )
88. N11111l' lll'<J snits t hut. 111'11 11srn l i11 hlnrk n 11tl whiti·
83 Dist iuAu isli between II tlii<pl111·c11ae11t reut.'tio11 1>holo~aphy. Gil'C cquntio n8 for the r<'a ct ions whc11
uud u double d isplacc111c11t rcat'Lillll. ldc11tify t lie these nr<' e xposed t.o sunliJ);ht.
dis pllLccmcllt nud the double dis plncou1cnt reaction Aus : [C'DSE 2016]
from the following r<'ncl io11.s:
11. HC'l(m1) ➔ N11OH(1u1 ) - N11C'l(11q) + H,O (1) i\ gll r (Silwr ilr11n1idc:) a nd Ag l (Siln:r irn lid,·) nrt·
h. F,·(s) + C'11S0,(11q ) - F,:SO,(aq ) + C',i(s ) 11,11~1 in blaek 1111d whit.c phot.uµ;rnphy,
-11uh~l11
A ns : [C BSE 2000] 2Agl3r(s) • 2A_g(s) + 13r,(_g)
2A g(s) + 1,(i;)
•1111Ut1.ht
:.!Ai;l(s)
Oisplacemeut Reaction: \\"heu a lllllrc n·,11·1iv,· 111,•tnl
dis places n less reactive mctnJ from it i- :<nit sol11t io n. 89. St ntl' our. r.xnmph: 1:11d1 d 1llra1.·t~·1-iM,I l,y l'ul lowi11g
D011hk cli~plnrc•mrnt rr 11c-tio11: \\'hr n two <"ompo1111rls aloug wit.Ii ,uit.ai>I,· d1m11irnl 1·q1111tio11.
l'Xdurngc· t l11·ir inns 111 for111 two 11r11· c11111po1111tls. a. CI.J,u1j:!,e iu st.ate,
11, l>u11hlt- d ispl11er1111"11t rrnrl io11. b. Evolutiou of p;1.~ ,
I,, l)ispl111•1•1111•11t. n·111·t iun. c. Chnni::;c i11 tcmpcrnturc.

84. What i~ nn oxidntion rr11rtio11? Giw 1111 1·x11111pl,· of A nM : rcmm 20W]


uxidatiou real·tiou. Is oxidntiuu a u exothermic or 1111 n. Ch1111ge 111 Mint.a:
cudot]1ermic rcnction'? J\ ~1\0,( HCJ) + HC l(uq ) - AgC' l(s} + HNO_,(1111 )
Ans : [C'IISI-: :.!IKJ!Jj h. Evolution of gas:
C'nC'O:I(• J+ 111<"1(<1il) - Cn<'l,(nqJ + 11 1 0( I )+ C<>2(1l:) 95. I1111 sd1C·n111t.i1· di11gr11111 for t l1r prc·p11rnt ion uf hyd mg,·n
e. Chango lu temperature: gas as shown in I he fi~tre. \\'hut wonltl huppen if the
cl. Cll,(l(J + 20,(g) - • ('0 ,(1\) + 21I,0(1) + l lc111 folluwiu,c; dmngcs are mad e

90. Nnn1c the t~·pc of rcnctious reprcscuic.'<I by the


following equal ious:
r,. CoO + 11,0 - • Ca(OII ),
b. :IIJoC'I, + Al,(SO,) - :mnSO, + 2AICI,

C'
•JJ.'
.. I '
·S() t ~ F' ( .J() I r-L •S():! + so
' I

Aus : [COSE 2015]


u. Combination reac tion.
b. Dou blc displncc111c·111 reaction.
c. Drc:omposition rcnction.

91. Write the d 10111ic11I equation of the ro11ction in whi ch


t he followi ng c-hnngcs tnkc plnrc with nn cxmnplc of II, 111 plan· uf' ;,,int· :,:r111111b;, SU.Ill(' IUllllllnl uf ii u,·
c·nd1. dust is taken in the t<:sl 1.11bu'!
IL, ('1111111,c iu C'olour. b. lustC'ad of dihtl c sulphuric, dil ut e hydruchlurl c
I,. Cl111111,c in te111-pl'rnlttr<·. acid is takc11'!
,·. Fur111atiu11 of J>l't'<·ipitnle. .-. S111li11111 hydroxid,· is 111k1·11 i11 pl111·,· uf dil11l.1·
An~ : [l' BSE :Wl f,[ s11lph11 ri1: ,wid 1111d the: llnsk is lw11t<"d'!
Aus : [COSE 201-1. 20 IOJ
IL. Chru1gc in colour:
Zn (s) + F,·S0 ,(11r1) - Z11S0 1(11q) + Fr(s) 11.Zi111· d11~L will n·111•1 fnsl.,·r. H ,(g) will 111· lil11•1·111.,•d
1'1.lfoa,..,..11 1 < '••lv1 11 lo••1< ►
nt o foster rntc. ·
It. Chango iu Tempol'ltture: b. Si\mc volume of 11,(,::) "~ll be formed.
2~1i; + 0 ,(1\) - 2:\ lgO(s) + llcnt c. On hcnt i1tl\ Zn with l\aO II. hyclrogcn l!;M wil l he
c. Formation of precipitate: funnNI nt II fu11tnr rn.tc.
Ph (~O ,),(uq) + 211('1(,Iii) - • Phf'I ,(~) + 211 N0, (11<1)
\\1111••1'11'1
96. (n) Why is it 1wrc•ssnry to hnl1111<·1· a d1c11dr 11I
Sl.n k tllf' l,\'Jl<' of rlw111ic:nl rrnrtions nncl rl11·111knl C~"Jllll tint t'!
eq11111 iuns tltnl t 11k1· pl,1n: in t hi' following: (h) \\'rile llw l1nl1111t"e1I d1P111intl C<J1t>1tio11 for till'
n. :\ln11111•si11111 win· is burnt i11 >1ir. fulluwi111-: rc111'1 iu11~:
I,_ Elt·c·t.rit· t·111·rl'11t is l'"--;,;ctl through wnt.t•r.
(i) K11tt1rnl j.\111< Imm" in ail' to form c11 rho
e. A111111u11i11 11ml hydrogen chloride J!.n,;ci, Mc tnixcd. diuxi<ll' 1111d wnt cr.
AnH: !<TISE :WI G[ (ii ) Durin.c; rcspirntion. ,c;lucoso combincij with
u. 2:-.li;(s) + O,(,c;) - n I,c;O(s): oxyg,·n 111111 f11rt11s mrho11 olioxid,· 11rnl wnlor
I,. Oxitl11ti, 111 n•,wt ion 11long wil Ji I he rl'l1•1L<I' or t' lll'I'!;.\',
1·. 2 H,0(1) - 2H,(;;) + O,(g): Ans : [C' BSE :201 :1]
D, ~·11nq11 ,sit.ion n•11d io11 11. Clll'1ni<"11l l'I Jll1tli1111 11111,t lui b1L)11n1·1•d so n~ lu
,I. NH,(:.:) + Jl('l(J?.) - Nll ,C'I(~): lullow thl' law of cunscrvnt ion of' 1nu,;s,
Co111lii1111t.iu11 react ion
h. (i) C'll ,(g) + 202(g) - CO,(g) + 211,0 (1)
93 \\'rill' t he b,tl,mn~ I dw111i<"nl t•qnnl iollb for t he (ii ) C.11.,0.(•) + GO,(~) • tlC0,(1d + GH,0(1) + lk111
followin,c; chcmicnl react.ions: 97. (i) Solid rnlri111 11 oxid<' wns 1.n.k<:11 ltt n rnnt.ni11N nnrl
11. I l.vciroJ?,rn + C hlorine - I lydrog<'n Chloridn
w11tc•r \\'!Ls nrlrlrn l slowly tu it.
It. Lrn11l + C'npper C'hloricl,, - t.<·nrl d tlorid11 I (11) Wri11· t 111: oliscrv111,i1111:<.
Copper ( b) Wri11· 1,11(! d111111iml f<>r11111l11 uf t Ill' prudt1<"t
,·. Ziur uxid,· + ('11rl111n - 7.i111: + C11 rl11111
J'urnted.
t. l011uxidc (ii) \\'lrnt lmppc11s when curbon dioxide is bubbled
Ans : [('BSE 201:jJ throur;;b lime 11·ot,<·r (n) in Rtnn ll nmount (b) in
a. 11,(g) + Cl,tg) - 211Cl(,c;) excess'/
b. Pb(s) + CuCl,(aq) _ , PbCl, (s) + Ctt (s) Aus : [COSE 2013. 2012. 20HIJ
,·. Z110(~) + CH - Z11(s) + C'O(g) (i) (11) T lw 1·1111L11i111·r l11~·rn111·s hot 11ml l1 L,,i11g so1111d
94. \Vr·it ,· r lw111i,·11I rq1111t ions fitr t lu• n•iwti1111s t11ki11i is prud11ced .
pl11('(' Whl'n (b) Ca{OH), is the fonuulu of thl' product furnwd .
n. Iron reacts with stc11111 (Ii ) (u) Litue waler tw·u milky when CO,(g) is passed
I,. :-.t11g11esiu1n react,- 1vith dil HCI t hrn11gh it : ·
c. Cuppc•r is hci1t 1..-. _J in ait· C'n(O H),( nq) -i C'O,(g) - C'nC'O ,(:<) + H,0(1)
(h) If ('X('c:iS or co, is pn..s., c·d 111ilki111,,;;, dis11pprnr~:
Aus : [CIJSE 201-1]
C'11C'O,(s) + CO,(;;) + H,O(s) - C11( HCO ,),(1u1)
n. :ffl'(s) + -IH,()(g) - Fc,O,(:<) + -IH, (g)
Ii. ;,.Jg(s) + 2HC'l(dil) - l'vlgC'l,(nq) 98. Wrill' I h,· lml11111·,:d d 11't11in 1l 1·1111111 i1111 forth,· followi11g
,·. 2C'n(s) + O,(g) - 2C'110(s)
reuct iou llllcl iclt:111 i[y tlte typ<' of rrn,·Lio11.
Thcr111it c rcncti ou. iron (III ) oxide reacts with
nl11111ini11m nnd gi,·c moltrn iron nnd aluminium ox:idc.
CuO(s)
All$ :
+ Z11(s) - 1......,
('u (s) + Z11O(s)
[C'l!SJ<~ 21l l l j
a. ln respiratiou. c11ergy is released, therefore, it is
Ans : [C13SE 201 2]
cousidcr<.'<I an cxothC'rm ic reaction.
f'c}},(s) + 2Al(s) - Al,0,(s) + 2Fr(I) h. Oxidnt ion in\'oh·cs nddit iou of 0 , or loss of
It is disph11·,·111,·111, 11s well ns n~ lox n ·nrt ion. dt:t·t runs. Hrrhwt in11 i11v11h'1':< nddiiion of H, or
gni ll o[ .-J1•cLn11ts.
99. Au 111111,•011" sol11Lio11 ur IIIC'tnl 11il r11tr •P' rencts with t·. Z11 is gc·t1.i11A oxicl b,·,I. ('110 is gl'ttittg n:1 lt11't<i.
t,:tuli111u l1r(.11uidc sol111.iou to fn1·11 1 _v,·lln\\' prt•t·i pil al t•
'Q' which is us,~I iu phutuv;rnphy. ·er
011 cx posun· 104. \\'riLt• l111li11lt'l'd dw111it-11l ,·q1111lions fur l11t• 1'11lluwing
tu stuilii:ht 1111d,,ri,:u,•s 1kco111positi,rn 1.o funu 111c•tal rcaC'1ion!'\:
prescut nlouv; with u R~ld ish brown ):\lls. ldcul i(v •P' 11. l l.l'< lrnw·11 snlphitlc gas hums in air 111 giv,· wat er
1111d •Q' writ<' tll<' lmhuu·c·rl chr 111in1l f'f(Ullt,iou for thr nnd sttlplmr diox:idc.
d1or11ic-nl 1·1•1u-tiu11. Li,..1 th<' two r11l1·gmi1·s i11 whic-h I,, IJnrinm d1loridc rencts with zinc snlphntc to gi,·c
n·111·1 iou t'llll ht: plnrt'tl. 1.inc d1lnridc nnrl h11ri11n1 snlpl11tt C'.
Aus : [COSE 20 12] ,·. ~nlnrnl gns l>11111s i11 11ir to fur111 c:i,rhon dioxidl'
1111tl wut.-r.
•p · is sil vrr ni trate· ( Ai;NO ,)
Ai;NO ,(aq ) + Nailr(nA) • Ai:Or(s) + l'\aXO ,(nq) Atts : [C' BSE 201 lj
II') • 1Ycll~••rrtl '
II. 211,S(i:) + 30, (g) • 211,0(1) + 2SO, (J:i)
Th is rNu-1,inu i" ,·nt<'guri>«·d 11., doulih: disph1C·<'rt11•111 11.,
b. lluCl,(nq) + Z11SU 1 (11c1) • lluSO,(s) + Z11Cl,(nq)
wd l 11.s pn•d pit11Lio11 r,·m·Lio11.
2Ag0r(s ) ,.,.1,.1,, • 2Ai:(s) + Dr ,(g)
c. Cil,(I!:) + 20, , C'O,(I!:) + 211,0(1)
Thr nbon' rrnctio11 i,- photochcrnicnl dccompo~ition
rrnrtio11. - - - FIVE
- - MARKS QUESTIONS
100 A v.;rccn culot rrt'<I h_vdrnt cd mctnllir snit on heat ini:
Jo:;r,.. wnlC'I' of 1T)'SL11ll isatio11 1110IN·11lco;, nml l?,i\'(':< n l(lll'I 105. Wril,t· lml11tlt'llci d11·111iml t•q1111Liu11 for I.lit' folluwi11g
with ,..111To1·11ti111; s111<'ll. ld,·11Lil'~• llu· s11 ll, 1111,I writ.<' I. lit' st.uh ·1111·ut s:
d 11·111inil 1•1111111 i1111 fur tlw n•11t l iu11. 11. :-luOH sulut iun is h, 111,,·d with zi rw /,\l'll llll ic•,-.
0

Am, : 1n1si-: :w1 I] I,. Exl'e.ss of l'llrl,011 diox id,· i,.. pus.sc•rl 1.hron/,\h li1111·
wntcr.
The sail ib F'eSO 1· 711 10 (11.n lrntcd ferrous st1lpl111tc)
r. Dilute s11lplmrk 11d1l is 1uldc•cl to sodium cnrbonnt
FeS0 1 • 71110 ~ . FcSO 1(s) + 711 20(1 ) cl. Egg ,;hdl i, dropp,·cl ilr hydrnd ilurir n<"i,i.
2F,·SO ,(s) ~ F1:~O,.(s) + S01 (g) + SO:r(g) C'. C'npptff (II ) rixicl,· rrnu:ts with cli l11l 1· hydmd1lorr
111'i1I.
( '1111 ,·ui11hi1111I ion r<'nl'I io11 J,., 1111 ox icl111irnr
1'<'111'1 i1111'! AnR:
I,. How will y1 111 tc":<1 wl11•Ilwr the g11.s 1·,·ul\'t·cl i11 IL 11. Zu(,) .,. 21'\aOII - • :-.a,Z11O, + II,
n ·1u·t i1111 is Irycl roi;t'II '/ b. Cu(O II ), + 2CO, - · Ca(IICO,),
c. \\'hy docs copper not evol\'c hydrogen on reacting c. N11 1C0 1 + 11,SO, • :-.n,SO, + 11,0 ... CO,
wit h dilut r Mtlphurir- nc-icl '! cl. C'nC'O ,(s) + 211C'l(dil) - C'nCI, + 11,0 + CO,
Aus : IC13SE 2011 ] ,•. CnO(s) + 2HCI - C'11C'l, + H,(>
11. Yes, ro111lii1111.t; i1111 n·nrt i1111 c·1111 hr c11 llrd 11 106. ldt'ltt ify tlu, t,vp,· of d wurirnl r.-111'1 i1111 in Liu· f111l11wi11g
11xid111 io11 nmc l iu11. sla1t·11tt·11t nml tlc·li11t· ,,,...Ji uf l,hrn11:
b. 13ri11v. u burni11A SJJliutcr 11ci.11· the i,:11.~. ii' it hurns 11. Dig1i, t iu11 of food in onr lwdy.
with 11op sou11d. it is hydro)!.Cll v.us. h. ll11s1i1111111'iron.
c, It i,, bcco u,;c• coJ>pcr is less reactive tlmu hydrogen. c. llcnting of mn111?:nncso dioxide \\it h alumin.inm
powdor.
102. \\'rite b11 lu11ccd cq1111tiu11s fur I.he followi11i.; rcact ious:
rl. Blur eolonr vf ropp!lr snl JlhntA' solut ion disnppcnrs
.i. J\lumi11itu11 + Druminc • Aluminium bromide
when im11 lili11gs ltl'l' nclclt~I 1o ii.
h. Cukim n rnrl1111111 l·1· ~ .. r. Dil ut.l' hydmd1lnri1· 11,cid is uclc )i,I l.u socl i11111
C11lciu111 oxide ... Carbu11 diuxidt• lry,l roxitl,· s11l111,iu11 l,o form sodin111 d 1lor id1, 111111
11
1·.Sil\'t'r drluri cl,: "" • h• Sil \'l'r + Chluriiu· \\'Ill.Cr.

Ans : [COSE 201 lj Aus : [C'HSE :WIG]


II. 2Al(s) + :mr,(g) - 2Alllr,(s) a. Decomposition reaction: It is a procc68 iII whk it n
b. CaCO,(s) ~ . CuO (s) + CO, (g) compound is broken do,,11 into si mple substnnca;.
c-. 2AgCl(s) "''""•"' 2Ag(,-) + C l,(g) Ii.Oxid11ti1111: '1'111' pro1·,~s., irr whiclr nx,vgc·u is mlcl,·d
ur dcl"l ru11s an, lu, I.
103. 11. \\' hy is l'<'S)l irnt inn consi<l <'rw l nn rxot,hnrmir. e. Displacement reaction; Tic<' rt•11t·t iu11 in whid1 11
wnrti1111 "! 111ure renclive element cull displace a le:ss wacLive
b. Defi11e the l.enus oxidal iu11 und rt·ducLiou. dt•111cnl l'ru111 its salt w lutiuu. Oxidt1tiun 1rnd
c ldeuti fy the st1IJSLtu1ce that is oxidised a uc.J red ucec.J n cd 11rt ion an· t 11ki11g 11l11n· sii1111lt.nn,·,n1~ly in
i11 Ihe followi11g reaction: rusting of iron.
d. Displacomont reaction: The rcnct ion in which n surface u f <'O ppc•r puwdcr t unL, ltl11ck.
more rr nc·1iv<' <'lr mcnt cn.n di~plnrC' n less react.iv(' c. On beotinl); green coloured ferrous sulphat('
c-i('lllf'n f. cn .,.t.nls, rnrl, lish bro\\11 solid is ld t a nd srn<'ll
('. Ncul1·111isation reaction: Tlw rr11c:1.ion in wldd1 ,ir' 11 J.\IIS hal' ing odour of burni ng ~nilph11r b
,wirl r,·1wts with lms1· lo form ,mh mul w11.l1!r, 1:x1111ri1·11c1•,I.
ti. lruu nnils whrn lrft ,lip1 wd in him· c:oppc•r s11lpl1111.,·
107, l>d11u- dw1nir11 l rl'ILc:liun. Stut r. r,mr 11hs1•rv11t ion~ s11l111,i1111 hl',·1111w rcal,li,-h l,ruwn i11 ,·ol1111r 1111d t hr
wh ich help.~ to dl'l1·n11iu,· whelher II d11'1nk11 l n·uct iou blue colour of copper ,; ulphate fade,; mrny.
has Lakl'II pl11e1• ur uut. \\·rill' Ulll' ,·x11111plc uf cncl1 c. Quick lime rcncLs vigorously with wate r rclcusing
obserl'aliou wi th a balauccd d1e11dc11I t!tjllatiou. n lar)?;<' nmo,mt of heat.
Aus: [CASE 211 1~,] Aus: [C'BSE S11111pl1· p,, pi-r 2110!))
Clw111inil reaction is II rc•nct ion which r('prr,;rul:< 11 11. D1111hl1· displ11c1·111t' III ri-11r1io11.
du-111ic11I d111 ngr. Ii. Oxi,lllt iou,
n. Change in colour: r. D,~·•1111po., i1 iuu n·1u:1.lo11,
C11 (s) + 2AgN0 :i(1u1) - Cu (N03) (m1) + 2Ag(s) d. l)i,.pl1&rc111c11l re11r liu11,
.. .. .. ••1tlo·- I IHtu, I
t', Cu111hi1111t iou l'CIH'I iuu.
b. Evolution of gas:
C11CO,(s) ~ C110 (s) + CO (g)
1·,.,,• • 1ll•o..ll'lt• 1(1"'
c, For111ntiou of precipitate:
P b ( NOl)i (nq) I 2KI • P b l,(s) r<NO~(nq )
l\"1•Jl11W1'JII)
d. Change in temperature:
C'uO(s) + II ,0(1) - C'n(OII),, + ll l'11L
108 a . D,•n un II lml111wnl d1c111ic11I 1•q1111I im1. \\'h_v should
r111 oqnnl ion be bnlauc:cd?
b. Wri k n hnln11ccd chcmirnl ('qunt ion for the
fullowi ng r(•11c1ions:
(i) Pho:,phurns hums i11 1lw prc'M'II<'<' of drloriur
tu form phuspborn,- p1•11111d1l11rid1•.
(ii ) Ou rnini; uf 1111111ml 1\11,..,
(iii ) The 111·ocess of res piration.
Aus: [f'BS E 20l i"i]
11. Diu,111c1o.·cl chcmim l ,:c11111tiou is u cquutiou in whkh
uumber of atoms of rnrious clements urc cqutil on
lwt.11 i;j,I,,,. 11f I lw 1·q111d i1111.
T iu, 1·1111111 i1111 sh1111ld 111· l11d11.11c:rn l d111· tu law of
C' CH1M •l'VH l i1H1 41r IIUL,:-1 ,
Ii. ( i) :ll'(s) + !iCl,(i.:) - 2PC'l,.(S)
(ii ) Cll ,(J.\) + O,(J.\) - C'O,(i;) + W ,0 (1)
(iii ) c . 11.,0 .(s) + (i0 ,(1?:) • 6CO,(~) - 611,0(1)
109 (n) \ \"rit e unc (•xtunpk- for ca.ch of decomposition
rcn<"f io11 c-arl'ied out. with the help or (i) Elect ricity.
(ii ) ll rat. (iii) Li~ht.
(Ii) W l1irl1 of lhc following ~tntcmcnt i~ cm rrd , 111111
why"!
C:11pp1·r run displn1·1· sil\'t•r frn111 si11•er nil rnl,t•
sol11tio11 1111cl silvl'r cn11 dlspl11ce copper fro111
euppn ,-ulphulc sulution.
AIIM: [C'BSE 1111-1]
n. (i) C'nC'O,(s) ~ CnO (s) + C O,(g)
11 1
(ii ) 2AgBr(s) '"" •" • 2Ag(s) + Br1(g)
(i'ii ) 211})(1} f l"""" > 211,(g) + 0 1(g )
h. Copper r.1u1 displ1w(' Ag from Agl\O,(nq ) solntio11
lwnu1s1· C'u is 1111,rp rr11rti v(· I h1111 Ag.
Cu(s) + 2A g~O ,(iut) - C'u (N0, ) , (,111) + 2Ag(s)

110. lck11lif~, tlw t~·p1· .,f rr111·1io11s taking plac-c• iu 1·11d1 of


t:lw fo llowing:
a. Oarium d ilorid1;: w l11l,io11 is 11dxud wltli copper
sulphate :;oiu Liou a ucl white preci pitute i,; formed.
b. On heating copper powder in cl.lim1 di8li, tlic

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