Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name

GAZELLE SG
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Plant protection product
Insecticide
Uses advised against
No data available.

1.3 Details of the supplier of the safety data sheet

Address
Certis Europe (GB)
Suite 5, 3 Riverside
Granta Park - Great Abington
Cambridgeshire CB21 6AD
United Kingdom
Telephone no. +44 (0) 1223 894 261
Fax no. +44 (0)1223 891210
e-mail [email protected] - www.certiseurope.co.uk
Advice on Safety Data Sheet
[email protected]

1.4 Emergency telephone number

Carechem 24 GB +44 870 190 6777

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification in accordance with Regulation (EC) No 1272/2008 (CLP)
Acute Tox. 4; H302
Aquatic Acute 1; H400
Aquatic Chronic 1; H410
Classification information
Classification and labelling are based on toxicological studies performed on the product (mixture).
Classification and labelling with respect to water pollution risks are based on ecotoxicological studies performed on the
product (mixture).
This product is assessed and classified using the methods and criteria below referred to in Article 9 of Regulation (EC)
n° 1272/2008:
Physical hazards: determined through assessment data based on the methods or standards referred to in part 2 of
Annex I to CLP
Health hazards and environmental hazards: determined through toxicological and ecotoxicological assessment data
based on the methods or standards referred to in Part 3, 4 and 5 of Annex I to CLP.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP Regulation)

Hazard pictograms

GHS07 GHS09
Signal word
Warning

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Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

Hazardous component(s) to be indicated on label:

acetamiprid
Hazard statement(s)
H302 Harmful if swallowed.
H410 Very toxic to aquatic life with long lasting effects.
Hazard statements (EU)
EUH401 To avoid risks to human health and the environment, comply with the instructions for use.
Precautionary statement(s)
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor/… if you feel unwell.
P501 Dispose of contents/ container to a licensed hazardous waste disposal contractor or
collection site except for triple rinsed empty clean containers which can be disposed of as
non-hazardous waste.

2.3 Other hazards

PBT assessment
The components of this product are not considered to be a PBT.
vPvB assessment
The components of this product are not considered to be a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
Not applicable. The product is not a substance.

3.2 Mixtures
Chemical characterization
solid plant protection formulation
Hazardous ingredients
No Substance name Additional information
CAS / EC / Index / Classification (EC) 1272/2008 (CLP) Concentration %
REACH no
1 acetamiprid
135410-20-7 Acute Tox. 4*; H302 >= 10.00 - < 25.00 %-b.w.
- Aquatic Chronic 3; H412
608-032-00-2
-
2 Benzenesulfonic acid, mono-C10-13-alkyl derivs., sodium salts
90194-45-9 Acute Tox. 4; H302 < 2.50 %-b.w.
290-656-6 Eye Dam. 1; H318
- Skin Irrit. 2; H315
-
Full Text for all H-phrases and EUH-phrases: pls. see section 16
(*,**,***,****) Detailed explanation pls. refer to CLP regulation No. 1272/2008, annex VI, 1.2

SECTION 4: First aid measures

4.1 Description of first aid measures
General information
In case of persisting adverse effects, consult a physician. Change contaminated, saturated clothing.
After inhalation
Remove affected person from the immediate area. Ensure supply of fresh air.
After skin contact
Wash immediately with plenty of water for several minutes.
After eye contact

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Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

Remove contact lenses. Rinse eye thoroughly under running water keeping eyelids wide open and protecting the
unaffected eye (at least 10 to 15 minutes).
After ingestion
Call a doctor immediately and show label or packaging. Rinse out mouth and give plenty of water to drink. Never give
anything by mouth to an unconscious person. Do not induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed
No data available.

4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media
Carbon dioxide; Extinguishing powder; Water spray jet; Foam
Unsuitable extinguishing media
High power water jet

5.2 Special hazards arising from the substance or mixture

In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO); chlorine compounds;
Nitrogen oxides (NOx)

5.3 Advice for firefighters

Fire-fighting operations, rescue and clearing work under effect of combustion and smoulder gases just may be done
with breathing apparatus. Run-off water from fire fighting must not be discharged into drains or enter surface water.
Wear protective clothing.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.

6.2 Environmental precautions

Do not discharge into the drains/surface waters/groundwater. Do not uncontrolled discharge into the subsoil/soil. Notify
authorities if product enters sewers or public waters.

6.3 Methods and material for containment and cleaning up

Take up mechanically. When picked up, treat material as prescribed under heading "Disposal considerations".

6.4 Reference to other sections

No data available.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
No special measures necessary if stored and handled as prescribed. Do not inhale dust. Provide good ventilation at
the work area (local exhaust ventilation, if necessary).
General protective and hygiene measures
Do not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Wash hands before breaks
and after work. Provide eye wash fountain in work area. Do not inhale dust/fumes/aerosols.
Advice on protection against fire and explosion
No special measures necessary.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions

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Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

Keep container tightly closed and dry in a cool, well-ventilated place.

Requirements for storage rooms and vessels
Store product in closed containers.
Incompatible products
Do not store together with foodstuffs. Keep away from water. Avoid direct contact with water, acids or base.

7.3 Specific end use(s)

Industry solution
Always read the label and product information before use.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No parameters available for monitoring.

8.2 Exposure controls

Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In
case of dust, vapour and mist formation, take appropriate measures for breathing protection in the event workplace
threshold values are not specified.
Eye / face protection
Safety glasses (EN 166)
Hand protection
In case of intensive contact, wear protective gloves (EN 374). Sufficient protection is given wearing suitable protective
gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product. Before use, the protective
gloves should be tested in any case for its specific work-station suitability (i.e. mechanical resistance, product
compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use,
storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically
damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
Discharge into the environment must be avoided. Do not contaminate surface and groundwater.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Form/Colour
solid; granules
11
blue
Lk.16727

Odour
70
weak
Odour threshold
No data available
pH value
Value 4 - 10
Source 4
Manufacturer 10

Boiling point / boiling range

No data available
Melting point / melting range
No data available
Decomposition point / decomposition range

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Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

No data available
Flash point
No data available
Auto-ignition temperature
No data available
Oxidising properties
not oxidizing
Lk.923

Explosive properties
Product does not present an explosion hazard.
Lk.3613

Flammability (solid, gas)

No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
Value 0.673 - 0.739
Source 0.673
Manufacturer 0.739

Density
No data available
Solubility in water
Source Manufacturer
Comments soluble
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No Substance name CAS no. EC no.
1 acetamiprid 135410-20-7 -
log Pow 0.79
Source Manufacturer 0.79

Viscosity
No data available

9.2 Other information

Other information
Surface Tension 32 mN/m at 20℃
Lk.34052

SECTION 10: Stability and reactivity

10.1 Reactivity
The product is stable under normal storage and handling conditions.

10.2 Chemical stability

Stable under recommended storage and handling conditions (See section 7).

10.3 Possibility of hazardous reactions

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Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

Hazardous polymerization will not occur under normal conditions.

10.4 Conditions to avoid

None, if handled according to intended use. High temperatures.

10.5 Incompatible materials

strong acids; strong bases; Oxidizing agents

10.6 Hazardous decomposition products

Combustion or thermal decomposition may generate toxic vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute oral toxicity
No Product Name
1 GAZELLE SG
LD50 1065 mg/kg
Species rat
Source 1065
Manufacturer 67

Acute dermal toxicity

No Product Name
1 GAZELLE SG
LD50 > 2000 mg/kg
Species rat
Source
3 50
Manufacturer
Acute inhalational toxicity
No Product Name
1 GAZELLE SG
LC50 > 3.5 mg/l
Duration of exposure 4 h
State of aggregation Dust/mist
Species rat
Source Manufacturer
Evaluation/classification Based on available data, the classification criteria are not met
50
(maximum achievable concentration, no mortality). Lk.30725

Skin corrosion/irritation
No Product Name
1 GAZELLE SG
Species rabbit
Source Manufacturer
Evaluation
10
non-irritant
Serious eye damage/irritation
No Product Name
1 GAZELLE SG
Species rabbit
Source Manufacturer
Evaluation
10
non-irritant
Respiratory or skin sensitisation
No Product Name
1 GAZELLE SG
Route of exposure Skin
Species guinea pig
Source Manufacturer
Evaluation
Lk.3647 20
non-sensitizing
Germ cell mutagenicity
No Substance name CAS no. EC no.
1 acetamiprid 135410-20-7 -

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Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

Source Manufacturer
Evaluation/classification Based on available data, the classification criteria are not met. Lk.3661

Reproduction toxicity
No Substance name CAS no. EC no.
1 acetamiprid 135410-20-7 -
Source Manufacturer
Evaluation/classification Based on available data, the classification criteria are not met. Lk.3661

Carcinogenicity
No Substance name CAS no. EC no.
1 acetamiprid 135410-20-7 -
Source Manufacturer
Evaluation/classification
Lk.3661
Based on available data, the classification criteria are not met.
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration hazard
No data available
Other information
Gazelle SG:
NOAEL (rat) 7,1 mg/kg/day - 2 years
Lk.34055
8,8 mg/kg/day - 2 years

SECTION 12: Ecological information

12.1 Toxicity
Toxicity to fish (acute)
No Product Name
1 GAZELLE SG
LC50 > 100 mg/l
Duration of exposure 96 h
Species Cyprinus sp.
Source
50
Manufacturer
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No Product Name
1 GAZELLE SG
EC50 > 159 mg/l
Duration of exposure 48 h
Species Daphnia magna
Source Manufacturer
EC50 0.0981 mg/l
Duration of exposure 48 h
Species Chironomus riparius
Source
U_900
Manufacturer
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No Product Name
1 GAZELLE SG
ErC50 > 97.8 mg/l
Duration of exposure 72 h
Species Scenedesmus subspicatus
Source
Lk.7001243
Manufacturer

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Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

Toxicity to algae (chronic)

No Product Name
1 GAZELLE SG
NOEC 97.8 mg/l
Duration of exposure 72 h
Source
NOEC
Manufacturer
Bacteria toxicity
No data available

12.2 Persistence and degradability

Biodegradability
No Substance name CAS no. EC no.
1 acetamiprid 135410-20-7 -
Source Manufacturer
Evaluation not readily biodegradable
Abiotic Degration
No Substance name CAS no. EC no.
1 acetamiprid 135410-20-7 -
Half-life 0,8-5,4 day(s)
with reference to soil
Source Manufacturer
Half-life 3,6-5,8
with reference to Water
Source Manufacturer

12.3 Bioaccumulative potential

Partition coefficient: n-octanol/water
No Substance name CAS no. EC no.
1 acetamiprid 135410-20-7 -
log Pow 0.79
Source Manufacturer 0.79

12.4 Mobility in soil

No data available.

12.5 Results of PBT and vPvB assessment

Results of PBT and vPvB assessment
PBT assessment The components of this product are not considered to be a PBT.
Lk.2045
vPvB assessment
Lk.2046
The components of this product are not considered to be a vPvB.

12.6 Other adverse effects

No data available.

12.7 Other information

Other information
Lk.34056
This product is not bioaccumulable.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement
with the regional waste disposal company.
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the
regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified
by the regional disposer.

SECTION 14: Transport information

14.1 Transport ADR/RID/ADN

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Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

Class 9
Classification code M7
Packing group III
Hazard identification no. 90
UN number UN3077
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Technical name acetamiprid
Tunnel restriction code -
Label 9
Environmentally hazardous Symbol "fish and tree"
substance mark

14.2 Transport IMDG

Class 9
Packing group III
UN number UN3077
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Technical name acetamiprid
EmS F-A, S-F
Label 9
Marine pollutant mark Symbol "fish and tree"

14.3 Transport ICAO-TI / IATA

Class 9
Packing group III
UN number UN3077
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Technical name acetamiprid
Label 9
Environmentally hazardous Symbol "fish and tree"
substance mark

14.4 Other information

No data available.

14.5 Environmental hazards

Information on environmental hazards, if relevant, please see 14.1 - 14.3.

14.6 Special precautions for user

No data available.

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not relevant

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations

Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any
substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC)
1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain
substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject
to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON
THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any
substances requiring authorisation as listed on Annex XVII of the REACH regulation (EC) 1907/2006.
Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances

Page 9 of 10
Safety data sheet in accordance with 1907/2006/EC

Trade name: GAZELLE SG

Product no.: NI 021 C0052/UK
Current version : 1.0.3, issued: 09.07.2019 Replaced version: 1.0.2, issued: 05.07.2019 Region: GB

This product is subject to Part I of Annex I, risk category: E1

15.2 Chemical safety assessment

A chemical safety assessment has not been carried out for this mixture.

SECTION 16: Other information

Sources of key data used to compile the data sheet:
Regulation (EC) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case.
EC Directives 2000/39/EC, 2006/15/EC, 2009/161/EU
National Threshold Limit Values of the corresponding countries as amended in each case.
Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.
The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the corresponding
chapter.
Full text of the H- and EUH- phrases drawn up in sections 2 and 3 (provided not already drawn up in these
sections)
H315 Causes skin irritation.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Department issuing safety data sheet
UMCO GmbH
Georg-Wilhelm-Str. 187, D-21107 Hamburg
Tel.: +49 40 / 555 546 300 Fax: +49 40 / 555 546 357 e-mail: [email protected]
This information is based on our present knowledge and experience.
The safety data sheet describes products with a view to safety requirements.
It does not however, constitute a guarantee for any specific product properties and shall not establish a legally valid
contractual relationship.

Alterations/supplements:
Alterations to the previous edition are marked in the left-hand margin.
Document protected by copyright. Alterations or reproductions require the express written permission of UMCO GmbH.
.
Prod-ID 755710

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