APPROVED COPY Rev0 Ballast Water Management Plan D 1 and D 2 Hull No.1586 - 119007218
APPROVED COPY Rev0 Ballast Water Management Plan D 1 and D 2 Hull No.1586 - 119007218
SDC3095-9150-Rev 0
Ballast Water Management Plan
REVISION HISTORY
The vessel was equipped with a Ballast water treatment system in 2020.
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Page ii
CONTENTS
BALLAST WATER MANAGEMENT PLAN ...................................................................... I
PURPOSE............................................................................................................ IV
This BWM Plan has been written by use of a DNV template (BWM-rev. 11, 06-2017)
Electronically published by ABS Yokohama.
Reference T2015139, dated 28-JUL-2020.
Page iii
6.1 Action to be taken by the vessel where coastal state has specific procedures for
discharge of ballast water 20
6.2 Action to be taken by the vessel where coastal state has no specific procedures
for discharge of ballast water 21
APPENDICES ....................................................................................................... 24
INTRODUCTION
Ballast water is essential to control trim, list, draught, stability, or stresses of the vessel.
However, ballast water may contain aquatic organisms or pathogens which, if introduced into the
sea including estuaries, or into fresh water courses, may create hazards to the environment,
human health, property or resources, impair biological diversity or interfere with other legitimate
uses of such areas.
This plan is written in accordance with the requirements of Regulation B-1 of the International
Convention for the Control and Management of Vessels' Ballast Water and Sediments, 2004 (the
Convention) and the associated Guidelines.
The purpose of the plan is to meet the requirements for the control and management of vessel’s
ballast water and sediments in accordance with the Guidelines for Ballast Water Management
and the Development of Ballast Water Management Plans (G4) resolution MEPC.127(53). It
provides standard operational guidance for the planning and management of vessels' ballast
water and sediments and describes safe procedures to be followed.
The selection of appropriate methods of Ballast Water Management should take into account the
need to ensure that Ballast Water Management practices used to comply with the Convention do
not cause greater harm to the environment, human health, property or resources of any States
and the safety of vessels, than they prevent.
This plan has been approved by the authority and no alteration or revision shall be made to any
part of it without the prior approval of administration or classification society.
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Page iv
VESSEL PARTICULARS
Vessel name Ridgebury Pallas
IMO number 9293143
Flag Republic of Marshall Islands
Port of registry Majuro
Call Sign V7IV5
Vessel type Oil Carrier
ABSClass Notation ✠ A1, Oil Carrier, ESP, Ⓔ, ✠ AMS, ✠ ACCU, FL 25,
SH, SHCM
RW, CPP, VEC, PMP
Designated officer (rank of officer) Chief Officer
Dimensions
Gross Tonnage 81072
Length b.p [m] 264.00 m
Beam [m] 48.00 m
Summer load line draught [m] mld 17.05 m
Minimum draught forward (bottom 5.80 m
slamming):
Minimum draught aft mark (propeller 8.50 m
immersion):
Total ballast water capacity [m3] 54676 (14 segregated BW tanks)
Main ballast water management method(s):
Ref to APPENDIX 6
Ballast Water Management Plan (Approved by Gemanischer Lloyd Ref. No 06-062419, dated 2006-
05-26)
PURPOSE
The ballast water management plan aims to assist governments, appropriate authorities, vessels'
Masters, operators, owners, port authorities as well as other interested parties, in preventing,
minimising and ultimately eliminating the risk of introducing harmful aquatic organisms and
pathogens from vessels' ballast water and associated sediments while protecting vessels' safety.
Good record keeping is critical to the success of a sound ballast water management program. The
appointed ballast water management officer is responsible for ensuring the maintenance of
appropriate records and that the ballast water management and treatment procedures are
followed and recorded. Please use example forms in APPENDIX 1.
It is the owners/managers or Master's responsibility to regularly review the plan and ensure that
the information contained therein is accurate and updated.
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Reference T2015139, dated 28-JUL-2020.
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This BWM Plan has been written by use of a DNV template (BWM-11)
Electronically published by ABS Yokohama.
Reference T2015139, dated 28-JUL-2020.
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This BWM Plan has been written by use of a DNV template (BWM-11)
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1.4 General
1.4.1 Main Ballast Water Management Method (Treatment)
Ballast Water Management System (BWMS) means any system which processes ballast water such that
it meets or exceeds the ballast water performance standard in regulation D-2. The BWMS includes ballast
water treatment equipment, all associated control equipment, monitoring equipment and sampling
facilities.
BWMS means equipment which mechanically, physically, chemically, or biologically processes, either
singularly or in combination, to remove, render harmless, or avoid the uptake or discharge of harmful
aquatic organisms and pathogens within ballast water and sediments. Ballast water treatment equipment
may operate at the uptake or discharge of ballast water, during the voyage, or at a combination of these
events.
It must be ensured that the ballast water treatment system installed is approved in accordance with
Regulation D-3 of the Convention. All systems (type) approved by any IACS Class society and physically
inspected by Class’ surveyor after installation should fulfil this requirement.
The system should only be operated in accordance with the system design criteria and manufacturer's
operational and maintenance instructions. When the system encounters malfunctions or failure, these
are to be recorded in the ballast water record book.
Ballast water exchange will be phased out as an acceptable method for complying with the Convention,
depending on ballast water capacity and date for renewal survey of the vessel. Therefore ballast water
treatment will be the only remaining option for complying with the Convention.
During normal conditions the treatment system is to be used for ballast water operations, however it is
possible to bypass this and then ballast exchange can be conducted.
It is the responsibility of the ballast water management officer to decide which method is to be used
(e.g. in port states where discharge of treated ballast water is not a requirement.)
It is the Master’s responsibility to control the safety of the vessel at all times. This includes evaluation of
stability, visibility and longitudinal strength throughout the sequential exchange sequence.
The sequence included in this document (APPENDIX 6) is only one example of an acceptable sequence
for one specific loading condition.
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Using the flow through method, it’s recommended that at least 3 times of the tank volume
should be pumped through the tank to achieve at least 95% volumetric exchange of BW.
Instructions are provided in the plan to record in the Ballast Water Record Book any reasons for not
complying with the regulation.
All local and/or national regulations should be taken into consideration as they may specify other depths
and distances from land.
A vessel shall not be required to deviate from its intended voyage or delay the voyage in order to comply
with any particular requirement as stated above.
The voyage should be planned taking into account when ballast water exchange in accordance with the
above criteria can be carried out.
Because of the possibility that partially exchange may encourage re-growth of organisms, ballast water
exchange should only be commenced in any tank if there is sufficient time to complete the exchange to
comply with the standard in Regulation D-1 and the vessel can comply with the distance from land and
minimum water depth criteria in Regulation B-4. As many complete tanks should be exchanged to the
standard in Regulation D-1 as the time allows, if for any tank the standard in Regulation D-1 cannot be
fully met the exchange should not be commenced for that tank.
In addition, if the master reasonably decides that an exchange would threaten the safety or stability of
the vessel, its crew or passengers because of adverse weather, vessel design or stress, equipment
failure, or any other extraordinary condition he is not required to comply with above requirements.
For a suitable pre-planning not only safety requirements have to be considered and observed but it is
also essential to know which ballast water will be discharged in the port of arrival depending on the
scheduled next loading condition. Ballast water which remains on board during the voyage need not be
exchanged. This will not only reduce time and cost but will also minimise risk.
When a vessel is required to conduct ballast water exchange and does not do so in accordance with
these requirements, the reasons shall be entered in the ballast water record book.
The applied ballast water exchange methods for this vessel are the following:
- sequential method
Please refer to APPENIDIX 6, for full information and special safety considerations for Ballast Water
Exchange.
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1) Range of flow rate from a minimum acceptable capacity up to the Treatment Rated Capacity acc.
to TAC. Refer to limits by Pump capacity in Chapter 1.3
Only qualified personnel should operate and maintain the treatment system after becoming thoroughly
familiar with proper operation, all warnings, safety notices, maintenance requirements and
troubleshooting.
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ECS disinfects invasive marine organisms in the ballast water with a one-time treatment by employing
full flow direct electrolysis during ballasting operation while the ballast water is passing through ECU
(Electro Chamber Unit). TRO (Total Residual Oxidant) which degrades over time remains active in the
ballast tanks even after treatment, resulting in preventing any organisms from reviving during the
voyage.
There are four disinfection mechanisms in the electrolysis process of ECS: Hypochlorous acid, Radicals,
ORP (oxidation reduction potential), and Residual chlorine. Hypochlorous acid, Radicals, and ORP
(oxidation reduction potential) sterilize harmful organisms contained in the ballast water and Residual
chlorine prevents harmful organisms from regenerating in the ballast tanks.
ECS does not treat the ballast water during de-ballasting operation. The only required process is to
neutralize the treated water before discharge to minimize the discharge of the residuals into waters.
ECS employs electrolysis method for active substance to disinfect micro-organisms in the ballast water.
The levels of active substances produced during the electrolysis of seawater are below the standards for
dangerous substances (United States standards). ECS adopts automatic neutralization system which is
ANU to neutralize the treated water in the ballast tanks, resulting in lowering the TRO value below
0.1mg/L before discharging in order not to interrupt marine environment.
Please refer to Treatment Systems OMS-Manual acc. Chapter 3.
The control equipment should be able to store data for at least 24 months and should be able to display
or print a record for official inspections as required. In the event the control equipment is replaced,
means should be provided to ensure the data recorded prior to replacement remains available on board
for 24 months.
This BWM Plan has been written by use of a DNV template (BWM-11)
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Reference T2015139, dated 28-JUL-2020.
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This BWM Plan has been written by use of a DNV template (BWM-11)
Electronically published by ABS Yokohama.
Reference T2015139, dated 28-JUL-2020.
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ECS (Electro-Cleen-System) disinfects invasive marine organisms in the ballast water with a one-time
treatment by employing full flow direct electrolysis during ballasting operation while the ballast water is
passing through ECU. TRO (Total Residual Oxidant) which degrades over time remains active in the
ballast tanks even after treatment, resulting in preventing any organisms from reviving during the
voyage.
The ballast water flows into the ship’s ballast pipelines through ballast pumps or other pumps via sea
chests and/or ballast tanks including aft peak tank and fore peak tank. The intake or internal circulating
seawater is disinfected by ECS, and the disinfected water remains in the ballast tanks until it is
discharged. The ECS system, controlled by CPC, carries out the disinfection procedure.
3.2.3.2 De-Ballasting
The neutralizer shall be injected with maximum rate at the initial stage of deballasting. And then the
amount of neutralizer shall be controlled in order that the TRO concentration may be less than 0.1mg/L. .
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3.2.5 By-pass
The Convention requires the control system of the BWMS to trig an alarm and log any by-pass of the
BWMS. This include bypass due to gravity filling or discharge of tanks.
Treatment is not required for internal transfer, but such operations will be recorded. The system will
always trig the alarm in case of by-pass.
For detailed instructions please refer to Treatment Systems OMS-Manual acc. Chpt 5.4.
Extract only:
Such by-pass valve is required by the International Convention for the Control and Management of
Ship’s BallastWater and Sediments 2004.
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To reduce the risk of contamination, the remaining water in the pipes should be recirculated through the
treatment system according operational manual (OMS-Manual acc. Chpt 5.6.1.)l and => Chapter 3.5
Ballast Water Handling in the event of mal function.
For this equipment, refer to OMS and Health, environment and safety (Appendix 7)
In the case of spillage or leakage of chemicals or gases, in General Material Safety Data Sheet for
Mercury Substance. Health, environment and safety (APPENDIX 7)
The safety instructions as stated in the manufacturer’s Operation and safety Manual (OMS-Manual acc.
Chpt 3.6.) are to be observed at all times.
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Bypass valve:
Untreated water:
If untreated water is pumped to a ballast tank, this water shall primarily be discharged to a reception
facility. When this is not possible, other discharge possibilities must be agreed with the port state
responsible for the waters where the ship is sailing and most importantly be agreed with the flag state
administration of the ship. Special measures may be requested for un-neutralized water.
Ref to APPENDIX 6:
Before maintenance, read the Preparations of maintenance section for applicable instructions in
The OMS Service manual (OMS-Manual acc. Chpt 6.2).
Essential safety information is stated before instruction to routines that might involve any danger.
Follow routine maintenance of equipment according (OMS Operation Manual Chapter 6.3)
Follow regular maintenance procedure according (OMS Operation Manual Chapter 6.4)
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Wherever possible, ballast water should be taken outside of port waters and as far from the coast as
practicable. Consideration should also be given to the use of dockside water supplies (water not taken
directly from the harbour, such as fresh water, potable water etc.) as source for ballast water.
When loading ballast water, every effort should be made to avoid the uptake of potentially harmful
aquatic organisms, pathogens and sediments that may contain such organisms. The uptake of ballast
water should be minimized or, where practicable, avoided in areas and situations such as:
1. areas identified by the port state in connection with warnings provided by ports concerning ballast
uptake and any other port contingency arrangements in the event of emergency situations
2. in darkness when organisms may rise up in the water column
3. in very shallow water
4. where propellers may stir up sediment
5. areas with current large phytoplankton blooms (algal blooms such as red tides)
6. nearby sewage outfalls
7. where a tidal stream is known to be more turbid
8. where tidal flushing is known to be poor
9. in areas close to aquaculture
10. where dredging is or recently has been carried out.
If it is necessary to take on and discharge ballast water in the same location, care should be taken to
avoid unnecessary discharge of ballast water that has been taken up in another location.
4 SEDIMENT MANAGEMENT
Water taken up as vessels' ballast can contain solid alluvial matter that, once the water is becalmed in a
vessel’s ballast tank, will settle out onto the bottom of the tank and other internal structures.
Aquatic organisms can also settle out of the ballast water and can continue to exist within the sediment.
These organisms can survive for long periods after the water they were originally in has been
discharged. They may thereby be transported from their natural habitat and discharged in another port
or area where they may cause injury or damage to the environment, human health, property and
resources.
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Due to the possibility that an enclosed space may have an oxygen deficient, flammable
or toxic atmosphere, which will not support life, or involves risk of explosion, it is
important establish that the risk and hazards have been eliminated and that the
enclosed space is safe for entry.
The procedures for Safe Tank Entry should be contained in the companies controlled
Safety Management System (SMS) Manuals.
IACS recommendation No. 72 regarding confined space safe practice should be observed:
Only enter a confined space when a permit to enter has been issued and if you consider
it is safe to do so, and then only remain in the inside for as long as it is necessary to
carry out the work. It is the full responsibility of the owner of the confined space (i.e.
ship, shipyard) to make and ensure that the confined space is safe to enter.
Ballast water management systems which uses or produces potential hazardous chemicals during
treatment of ballast water may introduce a hazardous atmosphere in the ballast water tanks. The BWTS
installed may introduce the following hazards in the ballast tanks:
Ships Ballast Water treatment system will not cause special contamination with chemicals during the
treatment process to the ballast tanks.
Before entering ballast water tanks the general precautionary procedures shall be followed.
One should be aware that sediments lying undisturbed for some time may give off toxic gases and
appropriate measures must be taken to protect the crew carrying out the job.
Part of the mud may be removed by water movement within a tank to bring sediments to suspension. In
double bottom tanks this is achieved by filling clean water 0.5-1 meter sounding in mild weather
conditions and keeping it for about 6 hours before pumping it out.
In addition the Master may decide to store the sediments onboard the vessel when this will not hamper
the security and operational maintenance of the vessel, her cargo and the crew. The sediments must
then be disposed of as described in 4.3 and above in this paragraph.
Special care is to be taken if ballast water has been carried in spaces designated for other purposes,
such as fuel, oil, fresh water tanks etc. More stringent requirements for disposal of the sediments are to
be considered depending upon the final mixture, e.g. if ballast water is carried in the fuel tanks.
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5.1 General
The table below indicates sampling and access points in pipelines and tanks, to enable crew members to
quickly assist the authorised officers of a party that have reasons to obtain samples.
For practical recommendations regarding sampling techniques and procedures, refer to Annex to
MEPC.173(58) – G2 Guidelines, addressing the following:
- Sampling from the ballast water discharge line
- Sampling and analysis protocols
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6 METHODS OF COMMUNICATION
This section contains procedures to assist the Master in coordinating the discharge of ballast in waters of
a coastal state, local government or other involved parties.
The quick and effective communication between the vessel and coastal state or other involved party
becomes vital in mitigating the effects of an unnecessary delay.
The requirements and roles of the various national and local authorities involved vary widely between
states and even from port to port. Approaches to the responsibility for ballast water exchange also vary.
In the majority of coastal states, responsibility for compliance with port state requirements is placed on
the vessel owner and the vessel.
The port state authorities should be contacted for specific ballast water discharge requirements and
reporting, prior to the vessel's arrival in port state's territorial waters.
Therefore, the Master with the responsible officer should timely obtain all necessary information and
prepare the vessel accordingly, taking into consideration the safety and operational restrictions as
described in this plan and relevant sections. Information on specific port state procedures can be
obtained by consulting the company and local agent for latest information and requirements.
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The Master must ensure that the ballast water management plan is clearly understood by the appointed
officer and by any other vessel staff that may need to be involved.
The ballast water management officer must keep the Master advised on the progress of the ballast water
management operations and any envisaged deviations from the agreed plan.
Should there be any doubt or if the management plan is not in line with the schedule, the Master shall be
advised accordingly.
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Owners, managers, operators and others involved in officer and crew training for ballast water
management should consider the following:
training for vessels' Masters and crews as appropriate should include instructions on the
requirements of the Convention, the ballast water and sediment management procedures
and the ballast water record book, drawing particular attention to matters of vessel safety,
maintenance of records and reporting requirements in accordance with the Convention.
Vessels' officers and ratings engaged in ballast water exchange at sea must be aware of what is
expected of them and should be familiarised and trained in the following:
vessel’s pumping arrangements including ballast arrangements;
location of air and sounding pipes of all ballast tanks;
positions of all ballast tank suctions and pipelines;
overboard discharge arrangements and openings for release of water on deck;
inspection and maintenance for ensuring that sounding pipes are clear and that air pipes and
non-return devices are in good order;
times and circumstances required to undertake the various ballast water exchange
operations;
methods used for ballast water exchange at sea, the related safety precautions and
associated hazards; and
location and suitable access points for sampling purposes.
The Master and ballast water management officer should ensure that the personnel assigned key
responsibilities in any ballast exchange procedures are suitable and well trained according to the above.
Special attention should be given to the safety aspects related with the subject procedures.
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9 RECORDING REQUIREMENTS
The ballast water management officer is to ensure that the Ballast Water Record Book and any other
necessary documentation and forms are kept up-to-date.
For example Record Book and detailed information please refer to APPENDIX I.
Instructions of the maintenance of the Ballast Water Record Book shall be in accordance with
Regulation B-2 and Appendix II of the International BWM Convention 2004.
Ballast Water record book entries shall be maintained on board the ship for a minimum period of two
years after the last entry has been made and thereafter in the Company's control for a minimum period
of three years.
The control equipment of the ballast water treatment system is able to store data for at least 24 months.
The requirements for type approval are that the control equipment should be able to display or print a
record for official inspections as required.
In the event the control equipment is replaced, means should be provided to ensure the data recorded
prior to replacement remains available on board for 24 months.
In the event of the discharge of Ballast Water pursuant to regulations A-3, A-4 or B-3.6 of the BWM
Convention or in the event of other accidental or exceptional discharge of Ballast Water not otherwise
exempted by this Convention, an entry shall be made in the Ballast Water record book describing the
circumstances of, and the reason for, the discharge.
The Ballast Water record book shall be kept readily available for inspection at all reasonable times and,
in the case of an unmanned ship under tow, may be kept on the towing ship.
Each operation concerning Ballast Water shall be fully recorded without delay in the Ballast Water record
book.
Each entry shall be signed by the officer in charge of the operation concerned and each completed page
shall be signed by the master.
The entries in the Ballast Water record book shall be in a working language of the ship. If that language
is not English, French or Spanish the entries shall contain a translation into one of those languages.
When entries in an official national language of the State whose flag the ship is entitled to fly are also
used, these shall prevail in case of a dispute or discrepancy.
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APPENDICES
Plans, drawings and information
Appendix 7: OMS Ballast System and Procedure Health, environment and safety.
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APPENDIX 1
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1 Introduction
In accordance with regulation B-2 of the Annex to the International Convention for the Control
and Management of Ships. Ballast Water and Sediments, a record is to be kept of each Ballast
Water operation. This includes discharges at sea and to reception facilities.
3.2 Whenever Ballast Water is circulated or treated for Ballast Water Management purposes:
.1 Date and time of operation
.2 Estimated volume circulated or treated (in cubic metres)
.3 Whether conducted in accordance with the Ballast Water Management plan
.4 Signature of the officer in charge of the operation
TANK DATE INITIAL FINAL GEOGRAPHIC PUMPS USED, DURATION OF SALINITY SIGNATURE OF RANK
LOCATION CONTENT CONTENT LOCATION OF or GRAVITATE OPERATION OFFICER IN
(tonnes) (tonnes) SHIP CHARGE
(Port or
Lat. & Long.)
Signature of Master ..
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Record here events which are relevant to ballast management, and which will be of interest to quarantine officers, such as sediment removal during drydock, or tank flushing
at sea. Each entry should be completed with the signature and rank of the officer making the entry.
Signature of Master ..
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APPENDIX 2
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MEPC 71/WP.9
Annex 8, page 8
ANNEX
Date of Submission (DD/MM/YYYY):____________________ Time of Submission (24:00 GST): ____________________ AMENDED FORM: Yes No
5. BALLAST WATER HISTORY: RECORD ALL TANKS/ HOLDS containing water taken on board to control trim, list, draught, stability or stresses of the ship,
regardless of ballast water discharge intentions, on page 2. Note: BW Sources are the last BW uptakes prior to any Ballast Water Management practices.
6. RESPONSIBLE OFFICER’S NAME AND TITLE: ____________________________________________________________________________________
MEPC 71/WP.9
Annex 8, page 9
Ballast Water Tank Codes: Forepeak = FP, Aftpeak = AP, Double Bottom = DB, Wing = WT, Topside = TS, Cargo Hold = CH, Other = O.
Methods: DM= Dilution, SM=Sequential, FM= Flow Through , T=Treatment.
Complete columns with (*) only if exchange was conducted.
***
APPENDIX 3
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APPENDIX 4
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DN500
DN500
DN500
DN500
DN125
DN125
DN500
DN500
DN500
DN125
DN500
DN125
Main BWTS 00
19-672-1_101
AUFTRAG NR. COM. NO. PROJEKT PROJECT Maßstab Format Blatt
Scale Size Side
19-672.1 BWTS Design Bari/Bastia/Brindisi A2 1 /1
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DN200
DN32
DN200
DN200
DN200
DN200
DN200
DN32
DN32
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APPENDIX 5
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APPENDIX 6
Important Note:
APPENDIX 7
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Pre-test documentation / General SHE impact assessment Potential hazards for the environment,
The electrolyzed ballast water includes chemical ingredients which have dynamic equilibrium with gas
on the surface of the water or which are completely dissolved. There is no chlorine gas generation since
the chlorine gas, generated in pH range of Electro-Cleen™ System operation, is hydrolyzed into
hypochlorous acid or hypochlorous acid ion after completely dissolved in ballast water. The electrolyzed
ballast water could generate peroxides and the concentrations of hydrogen peroxide and ozone are
very low compared to free chlorine. According to treated seawater test using ECS, the maximum
concentrations of hydrogen peroxide and ozone are less than 0.1mg/L. Having considered that the
hydrogen peroxide concentration of oxyfuel used as a disinfectant is around 40,000mg/L, this substance
For the ballast water management system using electrolysis, the additional filtration system is not
necessary because ballast water treatment is conducted after large sediments in inflowing water are
removed with a strainer. This electrolysis system disinfects with potential difference, radicals, and
electrode oxidization which are generated instantaneously and disappeared in several seconds. The
maintaining disinfectant is TRO. TRO concentration generated during ballast water treatment in this
system is around 10mg/L even though the generated concentration is different by characteristics such
as ballast water temperature, conductivity, types and concentration of materials dissolved in water. As
reviewed in the next paragraph, this range of concentration does not require particular cautions when
the crew or operators handle ballast water. Since the active substance in ballast water, hypochlorous
acid, is affected by voltage and current, TRO generation is being managed by controlling voltage and
current automatically so that the maximum concentration does not exceed 10mg/L.
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Electronically published by ABS Yokohama.
Reference T2015139, dated 28-JUL-2020.
TRO, generated as active substance during ballast water treatment with Electro-Cleen™ System, is
dissolved in water when its concentration is low, and then most of it turns to hypochlorous acid in pH
range of seawater. The maximum concentration generated from ECS operation is less than 10mg/L,
that is, less than 0.001%. Acute and chronic toxicity test result of hypochlorous acid is as follows and it
1) Inhalation Hypochlorite does not easily form into vapour. The amount of chlorine released from dilute
solution of hypochlorite solutions (less than 5.25%) under normal condition therefore is not significant.
However, with more concentrated solutions and if the pH is powered, or if the solution is heated or if
mixed with acids, higher amount of chlorine may be released. Mists formed from solutions can cause
mild to severe irritation of the nose and throat, depending mainly upon the airborne concentration and
the strength of the solution. There is no information about the short-term inhalation exposure to mists
2) Skin contact
Hypochlorite solutions can cause mild irritation to corrosive injury depending on the duration of contact,
the concentration and pH of the solution, based on human and animal information. No irritation was
experienced by 20 volunteers following the application of 1% hypochlorite solution (pH unspecified) for
48 hours in the form of a covered patch. When 2% solution (pH unspecified) was used, weak or
moderate irritation was experienced by 15 out of 69 volunteers. No skin reaction was observed in 3
volunteers following a 48-hour application of 0.252% solutions in the form of a covered patch. Severe
irritation was experienced by volunteers after 4-hour application of 5.25% hypochlorite solution (pH 10.7)
3) Eye contact
Hypochlorite solutions can cause mild irritation to corrosive injury, depending on the concentration and
pH of the solution, and the duration of the contact, based on human and animal information. There are
several reports of pain, and in some cases, slight damage to the surface of the eye and/or cornea, being
experienced after direct contact with commercial products containing sodium hypochlorite
(approximately 5%). The eyes were washed with water or a salt solution (saline) and the injury cleared
within 1-2 days. There are 3 reports of burning to the eyes with slow recovery following exposure to
4) Ingestion
Swallowing hypochlorite solutions can cause irritation, pain and inflammation of the mouth, throat and
stomach, as well as vomiting. In severe cases, serious effects including ulceration and perforation of
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ECS OMSM
Electronically published by ABS Yokohama.
Reference T2015139, dated 28-JUL-2020.
the gastrointestinal tract and death can result. The effects depend on several factors, e.g., the amount
ingested, the concentration and pH of the solution. About 29.5ml of a solution with 15% available
chlorine may be lethal. For sodium hypochlorite solution with 3-6% of available chlorine, a lethal dose
for humans of 200 ml has been reported. Severe injury has been observed in a person who ingested
approximately 1 liter of 5.25% sodium hypochlorite having pH of 10.8. A woman who intentionally
swallowed approximately 700ml of 5.25% sodium hypochlorite having pH of 11.5, showed falling mental
status, perforation of the stomach, and died of cardiac arrest 4.5 hours after ingestion. Deaths have
also resulted from aspiration of sodium hypochlorite solution into the lungs.
1) Skin Prolonged or repeated contact with hypochlorite may cause dry, red, cracked skin (dermatitis).In
a 5-year survey, 17/130 (13.1%) of first-time attacks of dermatitis reported among chemical factory
workers were attributed to the misuse of hypochlorite to the clear skin (frequency of use and
2) Skin sensitization
It is not possible to conclude hypochlorite as an occupational skin sensitizer. A few cases of skin
sensitization have been reported, in all but one case, the individuals were predisposed to this type of
reaction (reacting to other common allergens as well). Two non-occupational cases of sensitization to
sodium hypochlorite have been confirmed by patch tests. Both individuals reported a history of skin
reactions following exposures to products containing sodium hypochlorite or chlorine. Other family or
personal history of allergies has not been reported. Negative results (0/86 and 0/90 individuals
sensitized) have been obtained in two unpublished sensitization tests on human volunteers (human
3) Carcinogenicity
The International Agency for Research on Cancer (IARC) has concluded that hypochlorite is not
4) Teratogenicity and embryo toxicity No specific conclusions can be drawn about the potential
developmental toxicity of sodium hypochlorite from a human population study that examined the
potential effects of chlorinating drinking water with sodium hypochlorite. Exposure in this study was
based on the chlorination method, and not the measured amount of sodium hypochlorite or its
5) Reproductive toxicity
There is no human information available for reproductive toxicity. No firm conclusion can be drawn
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ECS OMSM
Electronically published by ABS Yokohama.
Reference T2015139, dated 28-JUL-2020.
6) Mutagenicity There is no information available for human. The available information for animal
suggests that sodium hypochlorite is not mutagenic. A positive result (sperm-head abnormalities) was
obtained in one test using live mice. This test did not directly measure genetic damage. Negative results
7) Potential for accumulation Hypochlorite does not accumulate in the body. It reacts with tissues (21).
A rat study using radio labelled hypochlorous acid has shown that it is absorbed fairly rapidly in serum
Total residual chlorine produced typically ranges from 6 to 10mg/L in the Electro-Clean system operating
with an applied voltage lower than 13 volts. No skin irritation was experienced by 20 volunteers after
application of a 1% hypochlorite solution (pH unspecified) for 48 hours under a patch. The possibility of
risk from the electrochemically treated water to personnel does not exist. The system is also sealed
tightly. This makes human exposure to treated water impossible under normal operational conditions.
Since the Electro-Clean system is fully automated, cutting-off electricity to the system alone can ensure
The concentration levels of total residual chlorine in treated water discharged from the Electro- Clean
system is extremely low. TRC is easily decomposed by sunlight, micro-organisms and other reductants.
Thus, residual chlorine will not be accumulated in harbors or ports. Octanol/ water partition coefficient
of TRC is calculated to be log P(oct) = -3.42. TRC is not persistent and bio-accumulative. In reality,
chlorine is used for the disinfection of drinking water not only in the United Kingdom and the United
The reactivity of the total residual chlorine in electrolytically disinfected ballast water is extremely high
so that it is rapidly decomposed in seawater. The concentration level of total residual chloride in the
ballast water is below 10mg/L. There is no possibility of explosion. Although there are only few
precautions to be taken for management, there may be need to ventilate hydrogen generated during
the electrolytic disinfection in order to prevent accumulation. A document that deals with the harmful
substances produced during electrolysis including the MSDS (IMDG code entry) data has been
1) MSDS The Material Safety Data of 2~3% w/w sodium hypochlorite solution have been reported to
be hazardous in case of eye and skin contact. For the carcinogenic effects, this material is not known
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Electronically published by ABS Yokohama.
Reference T2015139, dated 28-JUL-2020.
to cause cancer in animals or humans. There is no available Material Safety Data sheet for the 0.001%
2) IMDG IMDG Code 8186, UN No.1791, Class 8, Packaging Group II/III, EmS No.8-08, MFAG table
No.741 covers the hypochlorite solutions with more than 5% available chlorine. However, it does not
cover the 0.001% sodium hypochlorite solution which is generated in the Electro-Clean system.
10mg/L of TRO(Total Residual Oxidant) with less than 10mg/L of TRO in the worst cases to satisfy IMO
D‐2 standard. ECS has been tested and proven to have not made a significant effect on corrosion of
ballast tank. The corrosive effect of ECS was evaluated with the ‘International Paint Ltd’ in June 2010.
2) H2 gas There are no potential effect by low concentration of hydrogen gas on a Vessel’s
infrastructure so far.
When the H2 gas is leaked, an alarm shall be activated in case the concentration of H 2 gas is over 25%
of LEL and the system shall be shut down in case the concentration of H 2 gas is over 50% of LEL. In
such cases the ship’s crew must ensure that enough ventilation (at least 6 air changes per hour) has
been carried out by mechanical ventilation fan or natural ventilation by air vent heads prior to entering
1) It was found that total residual chlorine at the concentration of 10mg/L recommended for ballast water
treatment is completely degraded already after 1.1 days under light condition.
2) The hydrogen peroxide and ozone concentration of the electrolytic solution is very low in comparison
with the free chlorine. The maximum concentration produced during electrolysis of seawater is below
3) From the acute toxicity test, no skin irritation was experienced by 20 volunteers after application of a
1% hypochlorite solution (pH unspecified) for 48 hours under a patch. The possibility of danger to
4) Since chlorine is being used to disinfect drinking water not only in the United Kingdom and the United
States, but also in most other countries, there is almost no concern over PBT levels.
The half-life of total residual chlorine was 0.58 day under light condition and 2.0 days under dark
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