MATERIAL SAFETY DATA SHEET SCOTCHKOTE Brand 226P Hot Melt Patch Compound 07/10/12

Material Safety Data Sheet

Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: SCOTCHKOTE Brand 226P Hot Melt Patch Compound
MANUFACTURER: 3M
DIVISION: Infrastructure Protection Division

ADDRESS: 3M Center, St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 07/10/12

Supercedes Date: 02/16/12

Document Group: 05-8659-4

Product Use:
Intended Use: Coating
Specific Use: Patch Stick color matched to Scotchkote 226N Pipe Coating

SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
POLYAMIDE RESIN 68139-70-8 70 - 80
WOLLASTONITE 13983-17-0 20 - 30
TITANIUM DIOXIDE 13463-67-7 <1
QUARTZ SILICA 14808-60-7 < 0.5

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW
Specific Physical Form: Solid Material in Stick Form
Odor, Color, Grade: Solid Material in Stick Form, Green
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause thermal burns. Contains a chemical or chemicals
which can cause cancer.

3.2 POTENTIAL HEALTH EFFECTS

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Eye Contact:
Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.

Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain,
tearing, and blurred or hazy vision.

Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or
hazy vision.

During heating:
Thermal Burns: Signs/symptoms may include severe pain, redness and swelling, and tissue destruction.

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

During heating:
Thermal Burns: Signs/symptoms may include intense pain, redness and swelling, and tissue destruction.

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.

Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal
discharge, headache, hoarseness, and nose and throat pain.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

Ingredient C.A.S. No. Class Description Regulation

QUARTZ SILICA 14808-60-7 Grp. 1: Carcinogenic to International Agency for Research on Cancer
humans
TITANIUM DIOXIDE 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE
MOLTEN MATERIAL. Get immediate medical attention.
Skin Contact: Immediately flush skin with large amounts of cold water for at least 15 minutes. DO NOT ATTEMPT TO
REMOVE MOLTEN MATERIAL. Cover affected area with a clean dressing. Get immediate medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.

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SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature No Data Available
Flash Point No flash point
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable

5.2 EXTINGUISHING MEDIA

Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Use fire extinguishers
with class B extinguishing agents (e.g., dry chemical, carbon dioxide).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).

Unusual Fire and Explosion Hazards: Not applicable.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Not applicable.

6.2. Environmental precautions

Not applicable.

Clean-up methods
Not applicable.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid skin contact with hot
material. Avoid eye contact with vapors, mists, or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining.
For industrial or professional use only. Avoid breathing of airborne material. Keep out of the reach of children.

7.2 STORAGE
Store away from heat. Store away from areas where product may come into contact with food or pharmaceuticals. Store in a cool, dry
place. Store away from flammable and combustible materials.

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS

Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If
ventilation is not adequate, use respiratory protection equipment.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face Protection
During heating:
Avoid eye contact with vapors, mists, or spray.

The following eye protection(s) are recommended: Safety Glasses with side shields
.

8.2.2 Skin Protection

Avoid skin contact. Avoid skin contact with hot material. Wear heat insulating gloves when handling this material to prevent thermal
burns.

8.2.3 Respiratory Protection

Avoid breathing of dust created by cutting, sanding, grinding or machining.
During heating:
Avoid breathing of vapors.

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full
respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce
inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
Half facepiece or full facepiece air-purifying respirator suitable for particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

8.2.4 Prevention of Swallowing

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

Ingredient Authority Type Limit Additional Information
QUARTZ SILICA ACGIH TWA, respirable 0.025 mg/m3
fraction
QUARTZ SILICA OSHA TWA concentration, 0.1 mg/m3
respirable
QUARTZ SILICA OSHA TWA concentration, 0.3 mg/m3
as total dust
TITANIUM DIOXIDE ACGIH TWA 10 mg/m3
TITANIUM DIOXIDE CMRG TWA, as respirable 5 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, as total dust 15 mg/m3

SOURCE OF EXPOSURE LIMIT DATA:

ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration

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AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Specific Physical Form: Solid Material in Stick Form
Odor, Color, Grade: Solid Material in Stick Form, Green
General Physical Form: Solid
Autoignition temperature No Data Available
Flash Point No flash point
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Boiling Point Not Applicable
Density 1.15 g/cm3
Vapor Density Not Applicable

Vapor Pressure Not Applicable

Specific Gravity 1.15 [Ref Std: WATER=1]

pH Not Applicable
Melting point No Data Available
Solubility In Water Not Applicable

Evaporation rate Not Applicable

Volatile Organic Compounds 0%
Kow - Oct/Water partition coef No Data Available
Viscosity Not Applicable
Flash Point as text No flash point

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid:

10.1 Conditions to avoid
None known

10.2 Materials to avoid

None known

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

Substance Condition
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Oxides of Nitrogen Not Specified

SECTION 11: TOXICOLOGICAL INFORMATION

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Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION
Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Dispose of waste product in a sanitary landfill. As a disposal alternative, incinerate in an industrial or
commercial facility in the presence of a combustible material.

EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number(s):
80-6107-4959-2

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS
Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

STATE REGULATIONS
Contact 3M for more information.

CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.

All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information.

INTERNATIONAL REGULATIONS
Contact 3M for more information.

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

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SECTION 16: OTHER INFORMATION

NFPA Hazard Classification
Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.

Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of
the product have not changed. We encourage you to reread the MSDS and review the information.

Revision Changes:
Section 7: Handling information was modified.
Section 7: Storage information was modified.
Section 8: Engineering controls information was modified.
Section 8: Eye/face protection phrase was modified.
Section 8: Skin protection phrase was modified.
Section 8: Respiratory protection information was modified.
Section 8: Respiratory protection - recommended respirators information was modified.
Section 8: Respiratory protection - recommended respirators was modified.
Section 8: Respiratory protection - recommended respirators guide was modified.
Section 8: Respiratory protection - recommended respirators punctuation was deleted.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M

3M USA MSDSs are available at www.3M.com

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