rtlF l~})l \ l\ ~'--'ll0 <H,1 l\.L\<.;t)~)M 0l l>,\ H.

lt\ L\
.FJRST l ' t~JlM,KM.ML,\.\llON1 JlN •l(U-4
STD: XII «-lWMtsnn 'M '~"~ -..(\
\'l\,n' .\ h 1,

1
Gcncntl lnstrnccions:
Read th,, fnlhmln1t h,stnh' llons ,·ord'ul~, ,
1 (a) Then• 1u-c 33 questions In chis 1.tucslh\11 llill'k'I· "iCh hlt<'l"llill ,,h,\t,~'.
(h) SF,( 'TION A consists of H, 11111ltit)k •d11,kc quc'~litrn :,i ,'ill'l, h\~ I nun-\.. '°"'''h.
(c) SECTION n consists of~ shlH't MIS" '' '' qt1'\'ltlims ,' 1\1'1·~ In~ l 1m"''--s C'f\d1,
( d) SECTION C consists of 7 shcu·t ,rns" ,,,. q1wst11m~ ,' :ffl':\ ht~ ,\ m,u·\..-s ,'M,' h,
(c) SECTION l) conslst1- of 2 CI\S,' . bns"'' q1h\0iillims ''"'''~ h112 4 m,o'ks '""''h,
(f) SECTION E consists llf J l,m~ 1111s" ,.,. qth.' )l(hlll)I ,•:11·1~ 11111. ~ mi11•ks ""'' " ·
(~) All questions nrc compuls,u~ .
(h)Log pupcrs will b,• prm 1«1,•,I.
1 (i) There nn~(} prlnkd p1112e.'I in this q11"~tic111 P"llt't\

SECTION A
The followinR questions 11r,• multipk~• hc,i,·,• ,11u•stlons " Ith 1Uh' ,'t)t' t'l'l' t .,ms""''- l;'_al,, h
11ucstion c:lt'rics I nrnrk. Tlwre is 1111 lnh'l'1111I d101,,,, In chi~ Sl¼'tl.111.

Which ~11no11g the f11llnwi11!). is :111 <'~:1111plc ,1f :1 s,1l id s,1h11i,11r.1

a) copper di:--solvcd in ~11ld ,1) S1.':l \\Mc't
"c)sugar solutio11 \ d) s11h)l-<'

2 Which of the followi11 g aquc1ms s,1l11t i1111s sh,mld h:,w the hi)lhcst h1,ilin~ p,,i11r,1
a) 1.0 M NoOI I h) 1.0 M N:1>S04 () t ,() M ~111,·Mc .t) 1.1) i\1 1-.N( ),

3 Which one of the foll0wi11g will 1111t f1w111 :111 idc:11 s11l11ti1,11·.1
a) lk111cnc and 'l'l)luc11e h) Nitric :h' \\I :ind \\;ltc'f,
c) I fcxunc a11d I kpta11e d) Hro11111cth:11w :rnd t ' hl,11,wt hi111l'

4 When a non-volatile so lid is added 111 pure water it" ill:

H) hoi I above I()()" (' tllld frcc:,.c oh1r11.' ()·\'
"-h) boi I below I 00°C and frcc:r.c nbovc l)•l ('
c) boil ahove I00°C ttnd frcc:1.c hchn:v O·'C
.,.d) boil below I 00"C 1111d frcczo below O''l '

5 Kohlrausch given the followin~ relation fr,r str@!l, clc•,·11,1lytcs: /\ A''

Which of t11c followin g equality h11lds?
a) II - 11rl ai. C - • ✓I\ h)A - 11'1 as<'
C) /I /IOns ( . · • I) d) /\ /\'1 ;1s ( • I
 ,, I
~ h •l.11 II 11•, \ .\ ' 1111) 111 in 111111c d i1111 in11 ,,f Nn~'l, I IL'I and (. ' 11 ,( 't )( )('lo nrl' I ."!().-I.
1·,'thhh ' I h
,L> ~ :1th! I.) l.ll S ,' 111~ 111111 1 1\·~pt•,·1i, cly . .\'1m ll'I' C' I I,COOi i " i11 b1:.

11) I Sll.5 S ~m ) 111c1I 1

1: ) '2 90.8 s cm~ nwl 1 d) 390.5 S crn- mo
. ,.,
\'lw ~1m1d:11\l c't111'.,f ll w ,·di in" l1kh tht· t'\:'Hl'li,111
-' \ ).: • \ :hl) 1 11; l~) 4 2 A~ (s)-1 .: I l 1 l lhJ ) oc,:111-:- is ().80\/. Thi.: swndnrd reduction P0 tent i ol
I''' ' $' \ ~ ,~ :1)\UHl \ ' h) - !UWV 1·) 0.-rnv d) -0.40\ '.

-\ 11 dt'\'1t\1dwmk:1I cdl hdrnws likt' nn i..:kl.."trolvtic Ct' II when.

:I ) h,•ll h) F,~·11 '"") 1::--<'\trm.~I
• -... cCc-r ll
F <'wm~I ()
, d) Ei~,rrmnl < Ecrll

n 1k' ,,r 1\':\1' t h,n is 1lw snnw ns that of tht' rate nmstant for a
1
> l'lw 1111i1 ,, f tlw
:1) Fi1~1 ,,l\kr t'\:':h'ti,,n h) St'cond t,rder reaction.
, ) t t'l\) 111\kr •~ncti,m J) half order renction.

W In th,· ~r:1ph pll,tl l. " d b,·t\\t't'n Jr, IRl nnd r for a fi rst order renction. the intercept on y-axis is
.1) - I- h)[ R]l, c) /n[R]o d)- k/2.303

II F,,r :1 t\':Ktinn ~ + \' -.. l tlw rat,' (,f reaction hecomes twentv-seve n times when the concentratio n
,,t' :\ is im·~as,~d thn:-1.." times. What is t11e order oft11e reactio;1?
:112 h) l c)'., d)O

12 \'he l'kl.'tn1!~tl' is ust'<i in Lt·ad stomge buttery.

:1) Pa:-tl' of KOH and ZnO b) 38% solution ofH~S04
~-) ~ \oist pn:-tt' nf N 11£ 1 :md ZnCL: d) Moist NaOH

l\ 1r quest iL'flS 13 to 16. two statements are given-one labelled as Assertion (A) and the other
labc•lkd as Renson tR)
~c·k·rt the most :lppropriate answer from t11e options given below:
:1) Bnth .·\ imd Rare true. and R is the correct explanation of A
1') Both ..\ and R are true. but R is not the correct explanation for A.
d .-\ is true but R is false .
d) .-\ is false hut R is true.

L~ As:-erti0n: Cryoscopic constant depends on the nature of the solvent.

Reas0n: Cryoscopic constant is a universal constant.

J-t Assert.ion: Aquatic species are more comfortable in cold water rather than in warm water. "(
Reason: Difle rent gases have different KH values at the same temperature.

15 Assertion: Am for weak electrolytes shows a sharp increase when the electrolyte solution
is diluted.
Reason: For weak electrol~1es. degree of dissociation decre.ases with dilution in solution .
 s.:1mc un it.
16 Asserti on : /\ vernge rule nnd instunlnneous rate or u reaction have the
interval is too <imall.
Reason : Avi.:rag c rnti.: becomes an instantaneous rate when the time

I
t
J)"
2
Z n(s) + 2 Ag\aq ) ➔ Zn + (aq) + 2Ag(s)
SECTI ON B
In a galvani c cell , the fo llowing reaction occurs:
E0cell = 1.56 v
2

a) ls the directio n of flow of e lectrons from zinc to silver or silver to zinc.?

b) How w ill the concen tration of Zn + ions and At ions be affected when
2 the cell function s?

g of thi s reactant take to

A first o rder reactio n has a rate constan t I. 15 x 10- s- • How long will 5
3 1 2
.)8
reduce to 3 g?
OR
...---Uerive integra ted rate equatio n for a zero-or der reaction .

e of 1.002 bar at 2
~ An aqueou s so~~tio n c?ntain ing 4% nonvol atile solute exerts a pressur
c;_;; the normal bo1l111g pomt of the solvent ·. What is the molar mass of the solute?
(Vapor pressur e of pure water= 1.013 bar).

n from Raoult' s law? 2

Define azeotro pes. What type of azeotro pe is formed by negativ e deviatio
Give an exampl e.
2
Define fuel cell ? Write its two advanta ges.
- --- -
SECTION C
3 is 1500 n. What 3
The resistan ce of a conduc tivity cell contain ing 10- M KCI solution at 25°C
3
solution at 25°C
is the cell constan t and molar conduc tivity if conduc tivity of 10- M KC]
is ] .5 X ] 0-4 S Cm-I?
the overall reaction s 3
What type of battery is lead storage battery? Write the anode, cathode , and
in a lead storage battery when current is drawn from it.?

freezing point of 1.62 K. 3

d.. 3.9 g of benzoic acid dissolv ed in 49 g of benzen e shows a depress ion in
~ Calcula te the Van't Hoff factor and predict the nature of solute (associa ted or dissociated).
1)
(Molar mass of benzoic acid= 122 g mol- , Kr for benzen e= 4.9 K kg moJ-
1

~ State Henry's law and write its two applications. 3

3
~ Write three differen ces betwee n order and molecularity.
3
/ _,,. @ A first-ord er reaction takes 69.3 min for 50% comple tion. What is the time
needed

for 80% of the reaction to get comple ted?

t' /

OR

3
I

i
 A first order reaction is 50% complete in 30 minutes at 300 K and the same
reaction is again 50 % complete in IO minutes at 320 K. Calculate activation
energy (Ea) for the reaction. [R =8.3 14 JK: 1mol-1 J

3
28 Consider the decomposition of hydrogen peroxide in alkaline medium which is catalysed by
iodide ions.

Alkaline medium
This reaction takes place in two steps as given below:
(1) Hp2 + r ➔ H20 + 10- (slow)

(2) HP2 + 10- ➔ Hp + 1- + O, (fast)

a) Write the rate law expression. b)Write the order of the reaction with respect to H2O2
~ hat is the molecularity of each individual step.

SECTION D
The following questions are case-based questions. Read the passage carefully and
answer the questions that follow.

29 The osmotic pressure of a solution is the excess pressure that must be applied to a solution to
prevent osmosis, The direction of osmosis can be reversed if a pressure larger than the osmotic
pressure is applied to the solution side. That is, now the pure solvent flows out of the solution
through the semi permeable membrane.

Two solutions having same osmotic pressure at a given temperature are called isotonic solutions.
When such solutions are separated by semipermeable membrane no osmosis occurs between them.
For example, the osmotic pressure associated with the fluid inside the blood cell is equivalent to
that of 0.9% (mass/ volume) sodium chloride solution, called normal saline solution and it is safe
to inject intravenously.

a) Which process I method is used for desalination of sea water?

b) In which of the following cases blood cells will shrink:
i)when placed in water containing more than 0.9% (mass/ volume) NaCl solution.
ii)when placed in water containing less than 0.9% (mass /volume) NaCl solution.
iii)when placed in water containing 0.9% (mass/volume) NaCl solution.
iv)when placed in distilled water.

~ etermine the osmotic pressure of a solution prepared by dissolving 2.5 x 10-2 g ofK2so4 in
2L of water at 25°C, assuming that it is completely dissociated.
(R = 0.0821 L atm K- 1 mo1- 1, Molar mass ofK2SO4 = 174 g mol- 1) 2
OR .
c)A 4 % solution of urea (Molar mass =60 g/mol) is isotonic with 5.2 % solution of an unknown
organic substance. Calculate the molar mass of the unknown organic substance.

4
,_A6 In an clc4-1r<,l yt,'- cell external <1ourcc o f vo ltage is inusedthetolaboratory
bring about a chemical reaction. The
and the chemical industry.
cl(;(..1r<K.-hemical prncc<.se<, are of great importance

Pmdu4-1..<-i o f clcctro ly<.is dc,,1)e11d on the nature of material being electrolysed and the type of
clcctrO<Jc<j being used. ·1he products of electrolysis depend on the different oxidising and reducing
<,pccicc.: prc¼-nt in the electrolytic cell and their standard ele<-"trode potentials. Some of the
clcctro<:ht.-mical proce<1<;ec.i although feasible, are so slow kinetically that at lower voltages these
d,~n' t ~cm to take place and extra potential must be applied , which makes such process more
difficult to occur.

aJ ~talc f-araday'~ First Law of Electro lysis.

b) During d ectrolysis o f aqueo us solution of NaCl :
i) f-h(g) i<. liberated at cathode ii) Na is formed at cathode
iii) (~ (g) i~ liberated at anode iv) Ch(g) is liberated at cathode.

CJ What m ass (in grams) o f nickel could be electroplated from a solution of Ni (N03)2
by a current of 0.25 amperes flowing fo r IO hours?
[Atomic mass ofNi=58.7lu, I F=96500 Coulomb]
OR 2
c). i) Following re-.:tC1ions occur at cathode during the electrolysis of aqueous copper(ll) chloride
solution :

l
H + (aq ) + e- - - - -:;- Hi g) E
0
= 0.00 V

On the basis of their standard reduction electrode potential (E ) values, which reaction is feasible
0

at the cathode and why?

2
ii)How much charge is required for the reduction of 1 mol of MnO4- to Mn +?

SECTION E

31 a) Define ebullioscopic constant. 5

b) What is an ideal solution? Write its two c haracteristics.
c)A glucose solutio n which boils at 101.04°C at I atm. What will be relative lowering of vapour
pressure of an aqueous sol ution of urea which is equimolal to given g lucose solution.?
1
[Kb for water is 0.52 K kg mol- ]

r ~

OR . ,., '
I
I I

i) State Raoult' s law for a nonvolatile solute in a volatile liquid. •

ii) \\'hat type of deviation from Raoult' s law is shown by chloroform and acetone. Why?

iii) Ca lculate the boiling point of a solution containing 0.61 g of benzoic acid [MM = 122 g/mo l]

5
 \

" " 111 l

in 5g 11f ( ·s:. Ass11111 ing 8-1° o dimerisot ion of ncid. the boiling point ond
", : .trt'

46.2°c and 2JKkg '11101 rcspl'ctivcly.

32 a) Write 1he name ufthc cdl \\hid1 is gi.:ncrally used in heuring aids.
Wrill· the reaction s taking placc at thl' anodl· and the cntll(ldc of this cd l.
2AgCI (s) + 11: tg) t I 01111) _. ::!Ag (s) 1 211 tO. I M) 2CI (0.1 M ).
1 1
b) For the reaction
1\G1' - - 43600 .I nt 25°r. Cnkulntt· the e.m.f. ()f thc ci.:11.
OR

i)State Kohlrausch ·s law <if indepen dent 111igrnt ion of ions.

ii) Why does the conductivity or a solution decrease with diluti\ln '.1
@ What is the qu~ntit
1 y of d cctr:icity_in Cnulombs r~~uired to produce -l.~ g of ~1~ fro_m_
How much Cu will be producl·d the snmc amount drctnc 1ty
molten MgCb? 11 11 1 \Hl!.--

!Atomic mass nf Mg 2-l 11. utomic mass ll l'Cn 40 11I

pussed through molten CnC'I/!
5
33 Answer any five of the fo llowing:

\,.a) Predict the order or the reaction in the given plots:

i) ii)

ii '/
•
tL1c=
i~ ... _
L
IR lo
[R lo
Where IRj o is the initial concentration of the reoctnnt.

\fifWhat is the effect of temperature on the rale constunt 111' a rcuct inn?
c) Define Pseudo first order reaction.
JI) Mention the factors that. affect the rule of u chemical reucti1m
J) A reaction is of first order in A mid of second order .in U.
Write the differential rate equatio n for this reaction
'1 mol 1 1 s '·
f) In the given reaction A + 3B ➔ 2C. the rute of f'nrmntion of' C is 2.5 x Io
Calculate the rate of disnppeurance of B.
.
g~ What is the effect or ndding a catalyst on i) Gibbs energy of the reaction
ii) Activation energy

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ii