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Tests for anions
anion test test result
carbonate, add dilute acid then test for effervescence, carbon dioxide CO32− carbon dioxide gas produced chloride, Cl − [in acidify with dilute nitric acid, white ppt. then add aqueous silver nitrate solution] bromide, Br − [in acidify with dilute nitric acid, cream ppt. then add aqueous silver nitrate solution] iodide, I− acidify with dilute nitric acid, yellow ppt. [in solution] then add aqueous silver nitrate add aqueous sodium hydroxide, nitrate, NO3– then aluminium foil; warm ammonia produced [in solution] carefully acidify with dilute nitric acid, sulfate, SO42− then add aqueous barium white ppt. [in solution] nitrate the acidified aqueous add a small volume of acidified potassium manganate(VII) sulfite, SO32− aqueous potassium changes colour from purple to manganate(VII) colourless Tests for aqueous cations effect of aqueous sodium cation effect of aqueous ammonia hydroxide 3+ white ppt., soluble in excess, aluminium, Al white ppt., insoluble in excess giving a colourless solution ammonium, NH4+ ammonia produced on warming — calcium, Ca2+ white ppt., insoluble in excess no ppt. or very slight white ppt. chromium(III), green ppt., soluble in excess green ppt., insoluble in excess Cr3+ light blue ppt., soluble in excess, copper(II), Cu2+ light blue ppt., insoluble in excess giving a dark blue solution green ppt., insoluble in excess, green ppt., insoluble in excess, iron(II), Fe2+ ppt. turns brown near surface on ppt. turns brown near surface on standing standing red-brown ppt., insoluble in iron(III), Fe3+ red-brown ppt., insoluble in excess excess white ppt., soluble in excess, white ppt., soluble in excess, zinc, Zn2+ giving a colourless solution giving a colourless solution Tests for gases gas test and test result ammonia, NH3 turns damp red litmus paper blue carbon dioxide, turns limewater milky CO2 chlorine, Cl 2 bleaches damp litmus paper hydrogen, H2 ‘pops’ with a lighted splint oxygen, O2 relights a glowing splint sulfur dioxide, turns acidified aqueous potassium manganate(VII) from purple to SO2 colourless Flame tests for metal ions flame metal ion colour lithium, Li+ red sodium, Na+ yellow potassium, K+ lilac calcium, Ca2+ orange-red barium, Ba2+ light green copper(II), blue-green Cu2+