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What Is The Difference Between Iodometry and Iodimetry

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480 views2 pages

What Is The Difference Between Iodometry and Iodimetry

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admiraldamian67
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© © All Rights Reserved
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What is the difference between iodometry

and iodimetry?
CHARACTERISTICS IODIMETRY IODOMETRY
DEFINITION IN IODIMETRIC TITRATIONS, IN IODOMETRIC TITRATIONS, THE
AN IODINE SOLUTION IS IODINE THAT HAS BEEN
DIRECTLY TITRATED WITH A PRODUCED AS A RESULT OF THE
REDUCING SOLUTION PREVIOUS REDOX REACTION HAS
BEEN TITRATED WITH A REDUCING
WHEN AN ANALYTE THAT IS A AGENT
REDUCING
AGENT(OXIDATION) IS WHEN AN ANALYTE THAT IS
TITRATED DIRECTLY WITH A OXIDISING AGENT (REDUCTION) IS
STANDARD IODINE SOLUTION ADDED TO EXCESS IODIDE TO
IS CALLED IODIMETRY. PRODUCE IODINE AND THE IODINE
PRODUCED IS DETERMINED BY
TITRATION WITH SODIUM
THIOSULFATE, IS CALLED
IODOMETRY.

NATURE OF THE DIRECT TITRATION INDIRECT TITRATION


METHODE
NUMBER OF REDOX 1 REDOX REACTION 2 REDOX REACTION
REACTION OCCUR
REACTION ANALYTE+TITRANT, 1. ANALYTE(UNKNOWN)+ I- =I2
I2(KNOWN)=PRODUCT (IODIDE, I-)
2. I2+TITRANT, STANDARD
THISULFATE (KNOWN)=PRODUCT
"Iodimetry is a direct titration iodometry is an indirect titration
method used to quantify the method used to measure the
amount of reducing agents in amount of oxidizing agents in a
a sample by titrating with a sample by adding excess iodide
standard iodine solution. For to produce iodine, followed by
example, sulfur dioxide (SO2) titrating the iodine with a
or sulfite ion (SO32-) can be standard sodium thiosulfate
analyzed using iodimetry. (Na2S2O3) solution. An example
of an oxidizing agent that can be
analyzed using iodometry is
hydrogen peroxide (H2O2)."
Application To quantify reducing agent To quantify the oxiding agent
INDICATORS
1. What are 2 types of indicators?
Visual indicators
o Non-specific redox indicators- respond to the potential of the system
o Change the color indicator
o Use in acid-base
o Exp: phenolphthalein
Specific indicators

2. What is the indication used for the detection of the endpoint?


Self-indicator
Starch indicator
Redox indicator

3. What is self-indicator?
Generally a strong colour a result in charge transfer transitions
Used if the titrant is highly colored to detect the endpoint.
Example: KMnO4(potassium permanganate)
Purple to pink

4. What is the starch indicator?


Titration involving iodine
Starch form with dark blue colored with iodine
After the iodine was titrated and consumed,
The disappearance of the dark blue color indicates the endpoint
Example: iodine solution

5. What is redox indicator


Highly colored dyes: weak reducing or oxidizing agents
A redox indicator will change color if it changes the redox state ( oxidized to reduces or
reduced to oxidizes)
Example: phenolphthalein used in acid-base
Pink to colourless.

Indicator Reduced form Oxidized form solution E node (V)

NEITROFERROIN RED PALE BLUE 1.OMH2SO4 1.25


FERROIN RED PALE BLUE 1.OMH2SO4 1.06
DIPHENYAMINE COLOURLESS VIOLET 1.0 MH2SO4 0.76

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