FST - 05

PAPER 1 COURSE : JEE XII-XIII

240

GENERAL % Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. Use the Optical Response Sheet (ORS) provided separately for answering the question.
3. Submit the ORS after each exam. Tear the OMR along the marking.
4. Use extra sheets for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.

QUESTION PAPER FORMAT AND MARKING SCHEME :

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

6. Each section as detailed in the following table :

Category-wise Marks for Each Question Maximum

Number of
Section Question Type Marks of the
Questions Negative
Full Marks Partial Marks Zero Marks Section
Marks
+4 +1
0
If only the bubble(s) For darkening a bubble –2
One or More Correct If none of
1 16 corresponding to all corresponding to each correct In all other 64
Option(s) the bubbles
the correct option(s) option, provided NO incorrect cases
is darkened
is(are) darkened option is darkened
+4 +1
0
Comprehension If only the bubble(s) For darkening a bubble –2
If none of
2 (One or More Correct 4 corresponding to all corresponding to each correct In all other 16
the bubbles
Option(s)) the correct option(s) option, provided NO incorrect cases
is darkened
is(are) darkened option is darkened

OPTICAL RESPONSE SHEET :

9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of each examination.
11. Don not tamper with or mutilate the ORS.
12. Write your name, roll number and sign with pen in the space provided for this purpose on the original. Do not write any of these
details anywhere else.

DARKENING THE BUBBLES ON THE ORS :

13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are evaluated.

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 PART : I MATHEMATICS
SECTION – 1 : (Maximum Marks : 64)

 This section contains SIXTEEN questions

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

 x(t  1), when x  t

1. Let G(x, t) = 
 t(x  1), when t  x and t is continuous function of x in [0, 1]
1
If g(x) =  f(t)G(x,t)dt, then which is/are correct
0

(A) g(0) + g(1) = 0 (B) g(0) = 0

(C) g(1) = 1 (D) g”(x) = f(x)

2 2
2. Consider line L1 : x – 3 = 0 and circle S : x + y – 4x + 3 = 0. The area enclosed by S = 0, L1 = 0
and the lines which touches the circle and passing through origin, is less than or equal to

3 3  
(A)  (B) 3 3 
2 2 2

(C) 3 3   (D) 3 2  

1
3. The function f is continuous and has the property f  f(x)  = 1 – x for all x  [0, 1] and J =  f(x)dx
0

then

 1 3 1
(A) f   + f   = 1 (B) the value of J equal to
4 4 2

2
 1  2 sin x dx
(C) f   · f   = 1 (D)  (sin x  cos x) 3
has the same value as J
3 3 0

4. Let z1, z2 be two complex numbers represented by points on the circle |z| = 1 and |z| = 2
respectively, then
(A) max |2z1 + z2| = 4 (B) min |z1 – z2| = 1

1
(C) z 2  3 (D) min |z1 – z2| = 3
z1

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 1
5. Let f(x) be a 4 degree polynomial satisfying f(r) = for r = 1, 2, 3, 4, 5 then which of the following
r

is /are CORRECT ?

1
(A) f(6)  (B) f(x) = 0 has no negative root
6

(C) f(0) = 0 (D) f'(x) = 0 for atleast one x  (3, 6).

2 2 2
6. The equations of the common tangents to the ellipse, x + 4y = 8 and the parabola y = 4x are

(A) 2y – x = 4 (B) 2y + x = 4

(C) 2y + x + 4 = 0 (D) 2y + x = 0

7. If y is a function of x given by 2log(y–1) – log x – log (y–2) = 0 then

(A) domain is [4,  ) (B) domain is (0,  )

(C) range is (2,  ) (D) range is (0,  )

8. Which of the following is/are correct.

2
(A) f(x) = min(|x| – 5|x|, 1) then f(x) is non differentiable at 3 points

tan x sin x
(B) lim  exists
x0 x x

tan1 x sin1 x
(C) lim  does not exist
x0 x x

e x 
(D) Number of integers in range of f(x) = log  x  3  are 4
e –1/ 9
 4e 

9. Number of all 6-Digit natural numbers such that the sum of their digits is 10 and each of the digits

0, 1, 2, 3 occurs at least once in them is . Then  is divisible by

(A) 3 (B) 4

(C) 5 (D) 7

2
10. Lines y = 3x + 4 and y = mx + 1 intersect the parabola x + x – y + 1 = 0 at four distinct concyclic

points, if

(A) m = 3 (B) m = 0

(C) m = –3 (D) m = 1

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 3 2
11. If the equation whose roots are the squares of the roots of the cubic x – ax + bx – 1 = 0 is

identical with the given cubic equation, then which of the following may be true ?

(A) a = 0, b = 3 (B) a = b = 0

(C) a = b = 3 (D) a,b are roots of x² + x + 2 = 0

2 2 2
12. If distinct numbers a, b, c are in A.P. and a , b , c are in H.P., then which of the following may be

true ?

2
(A) ac < 0 (B) b = ac

2 ac 2
(C) b = (D) 2b + ac = 0
8

2 2
13. If x + ay + 4xy + (2b + 1)x + 30y + 50 = 0 represent pair of straight line of parallel lines then

(A) a = 4 (B) b = 7

(C) distance between parallel lines = 5 (D) distance between parallel lines = 3

14.
A C
45º

B
1
As shown in the diagram, the volume of tetrahedron D-ABC is . Also ACB = 45º and
6
AC
AD + BC + = 3, then CD is less than
2
(A) 2 (B) 3 (C) 1 (D) 4
         
15.  
Let a  î  2 ĵ  2k̂ , b  2î  3 ĵ  k̂ and c is a vector such that a  b  c  a  b  c , c  6 , then  
     
(A) a b c   244 (B) a b c   0
       
(C) a b b  c   244 (D) a b b  c   244

cos ec 2 x – 7 –m –n
16. If  dx = – (sin x) (cos x) + c then
cos 7 x
(n– 2m)

(A) m, n are coprime numbers (B)  sin x dx = 0

0
m
{ x}
(C) e dx = e – 1 (D) m + n is composite number
0

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 SECTION – 2 : (Maximum Marks : 16)
 This section contains TWO paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct 
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.
Paragraph for Question Nos. 17 to 18
        
If a  ˆi  2ˆj  2kˆ , b  ˆi  ˆj , a  c  2iˆ  6ˆj  5kˆ , a . c  4 , d is a vector coplanar with vectors a , c
  
and perpendicular to c , also b . d = 3
17. Which of the following is/are CORRECT ?
  
–1 4
(A) c = 2iˆ  3ˆj (B) angle between a and c is – cos
9
  
–1 4
(C) angle between a and c is cos (D) c = 2iˆ  ˆj  2kˆ
9
18. Which of the following is/are CORRECT ?
   
(A) [ b c d] = 72 (B) [ b c d] = 54 (C) d = 17iˆ  14 ˆj  10kˆ (D) d = 12iˆ  9ˆj  5kˆ

Paragraph for Question Nos. 19 to 20

Two circles C1 and C2 both passes through the points A(1, 2) and E(2, 1) and touch the line

4x – 2y = 9 at B and D respectively. The possible co-ordinate of point C such that the quadrilateral

ABCD is a parallelogram is (p, –q)

19. Which of the following is/are correct ?

2 2
(A) p – q = 3 (B) p + q = 17
3 3
(C) p + q = 65 (D) p + q = 3

20. Let p prizes are distributed among p + q students then which of the following is/are correct ?
5
(A) If no student gets more than one prize, then the number of ways is P4
3
(B) If no student gets more than one prize, then the number of ways is P3

(C) If each student is eligible for all the prizes, then the number of ways is 625

(D) No student get all the prizes, then the number of ways is 620

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 PART - II : PHYSICS

SECTION – 1 : (Maximum Marks : 64)

 This section contains SIXTEEN questions

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is(are) correct

 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

 For each question, marks will be awarded in one of the following categories :

Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)

darkened.

Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided

NO incorrect option is darkened.

Zero Marks : 0 If none of the bubbles is darkened.

Negative Marks : –2 In all other cases.

 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three

will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and

(B) will result in –2 marks, as a wrong option is also darkened.

21. A weight W is used to hoist two unequal slender uniform iron bars of same cross-section. One bar
2
is of length 2 m, while the other is of length m. The weight moves down at speed 4 m/s as
3
shown. For the instant shown, the speed of

2
B m
2m 3
30º
A C
4
(A) Point A is m/s
3
2
(B) Point C is m/s
3
4
(C) Center of mass of bar AB is m/s
3
(D) Center of mass of two bars is 4 3 m/s
cx
22. A particle of mass 'm' moves under a conservative force with potential energy U(x) 
x 2  a2
where c and a are positive constants.
(A) Position of unstable equilibrium is x = +a
(B) The particle can oscillate about x = –a
c
(C) If particle's speed is more than at origin, then it will reach x = + 
ma

(D) If particle's speed in more than c at x = -a, then it will reach x = – 

ma
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23. A circular platform rotates around a vertical axis with angular velocity  = 10 rad/sec. On the
platform, there is a ball of mass 1 kg, attached to the long axis of the platform by a thin rod of
length  = 10 cm ( = 30º). Select correct alternative(s).




(A) Tension is rod is 10N

(B) Normal force on ball is 5N
(C) Net force on ball is zero
(D) Net electromagnetic force on ball is zero
24. Ideal gas at pressure ‘p0’ and volume ‘V0’ is enclosed by a piston in a cylinder. We start to move
the piston outwards at a constant velocity ‘u’. The cross-sectional area of the piston is A. While the
piston is moving, we can deliver heat to the gas through a heating filament so that temperature of
gas remains constant. Suppose the power of heating filament is P. Select correct statements.

p0 V0
(A) Pressure of the gas at any instant t is =
V0  Aut
(B) Power should be p0Au at beginning.
(C) Power of filament should remain constant.
(D) Power of filament will decrease with time.

25. Figure shows analog voltmeter and ammeter. These meters are used to measure the potential
difference across a resistor and the current through it. Assume that meters are ideal. Select correct
alternative(s)
2 4 20 40

0 8 0 60

V mA
(A) The percentage uncertainty in voltmeter reading is 2.5%
(B) The percentage uncertainty in ammeter reading is 4 %
(C) The percentage uncertainty in calculation of resistance is 9 %
(D) The percentage uncertainty in calculation of power across resistance is 9%

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26. A uniform rod of mass m and length L is sliding along it’s length on a horizontal table whose top is
partly rough and rest rough with friction coefficient . The rod after moving through smooth part,
enter the rough with velocity v0. Take this moment as t = 0. Suppose v0 is taken minimum so that
the rod just stops when it is completely on rough part.
L

V0

Smooth Rough

Select correct statements

(A) v0 = gL
v0
(B) Velocity of the rod when it’s half part is on rough table is
2
 L
(C) The rod will slide for time Space for Rough Work
2 g
2v 0
(D) The rod will slide for time .
g

27. A piece of copper foil is bent into the shape as illustrated in figure. The gap between two parallel
planes ‘d’ is very small in comparison to rest dimensions. Current I which is uniformly distributed
over width  enters in from edge AB and leaves at edge CD.
A B
d

C D


Select correct alternatives
0I
(A) The magnetic field at centre of cylinder is

(B) The ratio of energy stored in cylindrical volume and energy stored in space between planes
R2
is =
ad
0 2
(C) The self inductance of the arrangement is (R + ad)

20 ( R2  ad)2 I2
(D) Total energy stored in arrangement is
2

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28. Suppose a photon of initial frequency is emitted by a star of mass M and radius R. As the photon
moves away from the star –
(A) The frequency of the photon decreases
(B) The wave length of the photon decreases
GM
(C) The relative change in frequency when photon is beyond the gravitation field is
C2R
GM
(D) The relative charge in frequency beyond the gravitation field is
2C2R

29. A Short electric dipole of dipole moment p is placed at centre of a cylindrical gaussian surface of
length  = 2R and radius R. Electric flux linked with
(A) The curved surface will be zero if the dipole is placed along axis of the cylinder
(B) The curved surface will be zero if the dipole is placed perpendicular to the axis
p
(C) One of the plane surface is if the dipole is placed along the axis
4 20R
p
(D) One of the plane surface is if the dipole is placed perpendicular to the axis
20R

30. The temperature of equal masses of three different liquids A, B and C is 12, 18 and 28ºC,
respectively. When A and B are mixed the temperature is 16ºC. When B and C are mixed, it is
23ºC. Select correct statements
(A) The ratio of specific heats of liquid A and B is 1 : 2
(B) The ratio of specific heats of liquid B and C is 1 : 3
(C) The ratio of specific heats of liquid A and C is 1 : 2
(D) When A and C are mixed, the equilibrium temperature will be 20ºC

31. Two heater coils of power P1 and P2 take individually time t1 and t2 to boil a fixed quantity of water.
The time they will take to boil the same quantity of water.
(A) t1 + t2 if they are connected to the mains in series
(B) t1 + t2 if they are connected to the mains in parallel
t1t 2
(C) if they are connected to the mains in series
t1  t 2

(D) t 1t 2 if they are connected to the mains in series

32. A combination of two thin convex lenses are placed as shown in the figure. An object is placed
5 cm in front of the first lens which has a length of 10 cm. The second lens is 10 cm behind the first
lens and has a focal length of 12 cm.
L1 L2

5 cm 10 cm
(A) Image by first lens is real and erect.
(B) Final image is real and inverted.
(C) Final image is 30 cm away from L2.
(D) Image by first leans is 10 cm away from L1.

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 th
33. Ideal liquid of density  is filled in a cylindrical container upto (3/4) height. Now the liquid is being
rotated about vertical axis passing through its axis of symmetry with constant angular velocity ,
such that liquid is on the verge of falling out of the container and free surface of liquid forms a
paraboloid. Whole situation is shown in the figure. Choose the correct options.

 h0
h x

h gh dp dp
(A) h0 = (B)  = (C)  2 x (D)  g
4 R2 dx dy

34. Three blocks of masses m1, m2 and M are arranged as shown in figure. All the surfaces are
frictionless and string is inextensible. Pulleys are light. A constant force F is applied on block of
mass m1. Pulleys and string are light. Part of the string connecting both pulleys is vertical and part
of the strings connecting pulleys with masses m1 and m2 are horizontal.

F F
(A) Acceleration of mass m1 is (B) Acceleration of mass m2 is
m1  m2 m1  m2
Space for Rough Work m2F
(C) Acceleration of mass M is zero (D) Tension in the string is
m1  m2
35. A thin uniform rod of mass m and length L is hinged at one end and is free to rotate in the vertical
plane. A small ball of mass m is fixed to the other end of the rod. A constant horizontal force
F = mg is also acting as shown in figure.
m, L m
F

(A) Acceleration of the ball at the instant of releasing the rod is 9g/8.
5mg
(B) Hinge force of acts in vertical direction just after releasing rod.
16
3g
(C) Speed of the ball when the rod becomes vertical is .
2
3g
(D) Speed of the ball when the rod becomes vertical is .
4

36. A rod of mass m and length  is acted upon by two forces each of magnitude F as shown in the
figure. The length of the rod is , area of cross section is A, the young’s modulus of the material is
Y. Select correct alternative
F F

Smooth
F
(A) The stress in rod at mid point of the rod is .
A
 F
(B) The stress in rod at a distance from one end is .
4 2A
F
(C) Net change in length of the rod is .
AY
(D) Total elastic potential energy stored in the rod is zero.
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 SECTION – 2 : (Maximum Marks : 16)

 This section contains TWO paragraphs

 Based on each paragraph, there will be TWO questions.

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is(are) correct 

 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

 For each question, marks will be awarded in one of the following categories :

Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)

darkened.

Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided

NO incorrect option is darkened.

Zero Marks : 0 If none of the bubbles is darkened.

Negative Marks : –2 In all other cases.

 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three

will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and

(B) will result in –2 marks, as a wrong option is also darkened.

Paragraph for Questions 37 and 38

Consider a loop of freely deformable conducting wire with insulation of length 2, the two ends of
which are fixed (permanently) to the ceiling. A load of mass m is fixed to the middle of the wire
(the mass of the wire is negligible). There is also a horizontal magnetic field of induction B; free fall
acceleration is g. A current I is passed through the wire. Neglect the field induced by the wires.

I 
B

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37. If the block is in equilibrium then select correct alternatives
(A) The left and right part of wire will take shape of circular arc.
(B) The left and right part of wire will take shape of parabolic arc.
(C) Tension is constant along the wire.
(D) Total magnetic force on the wire must be equal to weight of the load.

38. Select correct alternative(s) for equilibrium condition

 2
(A) The maximum height by which the load can be lifted is   1– 
 
 3
(B) The maximum height by which the load can be lifted is   1– 
 
 3 mg
(C) To lift the load by   1–  the current in wire should be
   3 2 B
 3 mg
(D) To lift the load by   1–  the current in wire should be
   3 B

Paragraph for Questions 39 and 40

For the circuit shown in figure, R1 = 3R, R2 = R, C1 = C2 = C, and L1 = L2 = L. The electromotive
force of the battery is E. Initially the switch is closed and the system is operating in steady state.
The voltmeter is ideal and it measures VA – VB. The switch is opened at t = 0
A B
V
R1 R2

c1
L2
L1 C2

39. The reading of voltmeter -

(A) Just before the opening switch is E
(B) Just after the opening of switch is –2 E
(C) Long time after opening the switch is E
(D) Is zero at any moment

40. The total amount of heat that will be dissipated after opening the switch, and until a new
steady state is achieved
LE2 CE2
(A) in resistance R1 (B) in resistance R1
2R2 2
CE2 LE2 LE2
(C)  in resistance R2 (D) in resistance R2
2 2R2 2R2

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 PART - III : CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Maximum Marks : 64)

 This section contains SIXTEEN questions

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

41. Which of the following compound(s) have two  bond in it’s structure ?

X + Y + Z

H2O
P W

Space for Rough Work

(A) X (B) Y (C) W (D) P

50C60C 200C230C
42. M  4CO    
 ' X'     
 Metal   CO
(Impure) Metal (pure)
carbonyl
complex

Which of the following statement(s) is/are correct about given reaction process?
(A) Metal M is Ni
(B) Process is known as Mond’s process in which pure metal is obtained
3
(C) Hybridisation of metal in ‘X’ is sp
(D) Maximum five atoms are present in one plane in ‘X’

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43. Through a number of isobaric cooling and adiabatic compression steps 1 mol helium (consider as
an ideal gas) is compressed from 1 bar, 300K to 32768 bar, 300K. Let the process be
accomplished in three steps [Step AB, BC & CD]. At each step helium is firstly cooled and then
compressed. At the end of each step the pressure increases 32 times and temperature returns to
original value 300K as shown in diagram [R = 2 cal/K/mol]. Select correct option(s) :

T7 D
P
T5 C
T6
T3 B
T4 A
T1
T2

(A) T1 = T3 = T5 = T7 (B) T2 = T4 = T6
(C) Qtotal = –3375 cal (D) Ssys = 15 R ln2

44. When N2 gas is adsorbed on the surface of metallic iron, electron transfer occurs from the metal to

N2. The true statement(s) regarding this adsorbtion is/are :

(A) N2 is chemisorbed.

(B) N–N bond length is increased.

(C) Occupancy of antibonding molecular orbitals in N2 is increased.

(D) Entropy is decreased.

r
+ – A 2 2
45. A hypothetical solid A B has  then correct statement(s) is/are :
R 2
B

–
(A) B touches total 18 ions
+
(B) A touches total 6 ions

(C) Each body diagonal passes through the centre of 2 cations and 1 anion of a unit cell.

(D) Each body diagonal passes through the centre of 2 anions and 1 cation of a unit cell.

46. Which is/are correct about SO2Cl2 ?

O > OSCl
(A) OS  > ClS
Cl bond angle

(B) Number of p– p bonds < Number of p–d bonds

(C) 1 mol of this reacts with 0.1 mol P4

(D) It's aqueous solution does not give pink colour with phenolphthalein.

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 K
47. 3A  Products. Rate law is, rate = K [A]°, then (Here Ct = Concentration of reactant at time t,
C0 = concentration of reactant at time t = 0)
(A) Slope of graph of Ct v/s t is – K
(B) Slope of graph of Ct v/s t is – 3K
(C) Slope of graph of (C0–Ct) v/s t is 3K
(D) Slope of graph of (C0 – Ct) v/s t is –K

–1
48.  of 0.01 M MgCl2 is 220 S.cm2.mol .
–1
  of MgCl2 is 240 S.cm2.mol .
–1
  of Mg2+ is 100 S.cm2.mol .
All above measurements are done in an electrolytic cell.
Assuming MgCl2 to be a strong electrolyte which of the following is/are incorrect?
2 –1
(A) Limiting equivalent conductivity of MgCl2 is 60 S.cm .eq
(B)  of MgCl2 varies linearly with its concentration
2 –1
(C)  of 0.04 M MgCl2 will be 160 S.cm .mol
2 –1
(D)  of 0.04 M MgCl2 will be 200 S.cm .mol

49. Balance the following chemical reaction with simplest integer coefficients: a, b, c, d and e and then
choose the correct option(s);
2– +
a Cr2O7 + b H2O2 + c H  d CrO(O2)2 + e H2O
(A) a is 1 (B) b is 6 (C) d is 2 (D) e is 5

50. Along with each complex two state of hybridisation concerned with two different elements of the
corresponding complex are mentioned. Correct match is/are :

(A) [Cu(NH3 ) 4 ]2 ,d x2 y2 sp 2 ,sp3

(B) [Ni(CO) 4 ], sp 3 , sp
(C) [Re(CN )6 ]4 , d x2  y 2 d z 2 sp 3 , sp

(D) [Co( NO2 ) 6 ]3 , d xy d yz d xz sp 2 , sp 2

51. Which of the following reaction/s is/are give aromatic compound.

H 2N CHO
(A) + H+/ (B)
CHCl3
  
KOH / 
H 2N CHO

Re d hot A l2O 3
(C) CH3–CCH   (D) n-Hexane  

iron tube Cr2O3 / 

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52. In which of the following reaction (s), reactant and products are correctly matched ?

(A)

(B)

(C) Space for Rough Work

(D)

53. Three isomeric compound M, N and P (C5H10O) give the following tests:
(i) M and P react with sodium bisulfite to form an adduct.
(ii) N comsumes 1 mole of bromine and also gives trubidity with conc. HCl / anhydrous ZnCl2 after
prolong heating.
(iii) M reacts with excess of iodine in alkaline solution to give yellow crystalline compound with a
characteristic smell.
(iv) p-Rosaniline treated with sulphur dioxide developes pink colour on shaking with P.
The structures of M, N and P, respectively can be:

M N P

O |
OH H
(A) || | ||
| O

O O
(B) || ||
| OH
H

O H
|| | |
(C) ||
OH
O

O H
|| || | |
(D)
| OH
O

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 H2/Pt
Compound (Q) C8H18
(Optically inactive)
Compound (P)
54.
C8H12 H2 + Pd + BaSO4
(Optically active Compound (R) C8H14
enyne) Lindlar's catalyst
(Optically active)

Na / liq. NH3
Compound (S) C8H14
(Optically inactive)
Which amongs the following is/are correct for above sequence of reactions ?
(A) Oxidative ozonolysis product of P, R & S will be achiral
(B) R & S are diastereomers
(C) Product Q & R are formed by syn addition & S is formed by anti addition
(D) P must have cis configuration
55. Which statements are correct in the following ?
(A) Cyclopentadiene reacts with NaNH2 and releases NH3 gas however cyclopropene does not.
(B) Cyclopropenone has a greater dipole moment than acetone
(C) Cyclobutadiene does not exist at room temperature but cyclobutene exists at room
temperature
(D) 7-Bromocyclohepta-1,3,5-triene ionizes faster however 5-bromocyclopenta-1,3-diene does not

56. Glucose

The correct statements about above structure of glucose are :

(A) It is a Pyranose form (B) It is a furanose form
(C) It is a -anomer (D) It is a D -sugar

SECTION – 2 : (Maximum Marks : 16)

 This section contains TWO paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct 
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

Paragraph for Question Nos. 57 to 58

A solid (A) is water insoluble, while a red solid (B) is water soluble. Heating (A) and (B) produces a
colorless gas (C) and a reddish brown gas (D) respectively, leaving residues (E, yellow) and
(F, black). (A) and (B) when heated together produce a green colored solid (G). (G) is also
obtained on heating (E) and (F) together. (E) becomes white on adding water, but it fails to
dissolve in water. Then

57. (A) and (B) are respectively :

(A) ZnCO3 and Pb3O4 (B) CrO3 and ZnSO4
(C) CoCO3 and ZnSO4 (D) ZnCO3 and Co(NO3)2

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58. When (E) and (F) react to give (G) then select incorrect option(s) :
(A) (E) functions as an acid (B) (E) functions as an base
(C) (E) functions as an oxidant (D) (E) functions as a reductant

Paragraph for Question Nos. 59 to 60

On the bases of following information answer the given two questions.

dil.H2SO4
C5H10O Q + R R reduces Tollens reagent
(P) (1) I2+NaOH (1) I2+NaOH
(2) H3O (2) H3O

CHI3 + S CHI3 + T

59. P will be –
(A) CH2=C–O–CH2–CH3 (B) CH2=CH–O–CH2–CH2–CH3
CH3
(C) CH2=CH–O–CH–CH3 (D) CH2=CH–CH2–O–CH2–CH3
CH3

60. Which amongs the following is/are correct statement/s –

(A) [Q] is also formed when propene is reacted with dil.H2SO4.
(B) [Q] will also give coloured complex with neutral FeCl3.
(C) The product formed by dry distillation of calcium salt of [S] is acetone.
(D) [T] will also give positive test with ammonical solution of AgNO3.

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