Class 12th JEE

MRJM/12 Milestone Test-02 Phase-1

DURATION: 180 Minutes DATE: 16/06/2024 M.MARKS: 300

Topic Covered

Physics : Electrostatic Potential and Capacitance

Chemistry : Chemical Kinetics
Mathematics : Relations and Functions

GENERAL INSTRUCTION
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 3 hours duration.
3. The test booklet consists of 90 questions. The maximum marks are 300.
4. There are three sections in this question paper. Sections I, II and III, are of Physics, Chemistry and
Mathematics, respectively. Each section consists of 30 questions, of which the first 20 are mandatory and
are of Multiple Option type and the last 10 are of integer answer type. You need to attempt any 5 integer
type questions (out of 10) in each of the three sections. Answer to integer type questions shall be rounded
off to nearest integer if needed.
5. There is only one correct response for each question.
6. Each correct answer will give 4 marks while 1 mark will be deducted for a wrong response.
7. No student is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone,
any electronic device, etc. inside the examination room/hall.
8. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
 SECTION-I (PHYSICS)
Single Correct Type Questions (1-20)
1. A ball of mass 1 gm carrying a charge 10−8 C
moves only under the influence of an electrostatic
field from a point A at potential 600 V to a point B
at zero potential. The change in its kinetic energy
is
q
(1) −6 × 10−6 erg (2) −6 × 10−6 J (1) –q (2)
2
(3) 6 × 10−6 J (4) 6 × 10−6 erg
−q
(3) –2q (4)
2. A parallel plate capacitor with oil (dielectric 2
constant 2) between the plates has capacitance C.
7. In the case of a charged metallic solid isolated
If oil is removed, the capacitance of capacitor
sphere, potential (V) changes with respect to
becomes
distance (s) from the centre as
(1) 2C (2) 2C
C C
(3) (4)
2 2

3. Charges 2q, −q and –q lie at the vertices of an

(1)
equilateral triangle. The value of E and V at the
centroid of the triangle will be
(1) E ≠ 0 and V ≠ 0 (2) E = 0 and V = 0
(3) E ≠ 0 and V = 0 (4) E = 0 and V ≠ 0

4. A uniform electric field having a magnitude E0 and

direction along the positive x–axis, exists. If the (2)
potential V is zero at x = 0, then its value at x = + x will
be
(1) V(x) = +x E0 (2) V(x) = −x E0
(3) V(x) = +x E0 2
(4) V(x) = −x2 E0

5. Two thin wire rings each having a radius R are (3)

placed at a distance d apart with their axes
coinciding. The charges on the two rings are +q
and –q. The potential difference between the
centres of two rings is
qR
(1) (4)
4πε0 d 2
q 1 1 
(2)
2πε0 R − 
 R2 + d 2  8. Two spheres of radii R1 and R2 joined by a fine
(3) Zero long wire are raised to a potential V. Let the
surface charge densities at these two spheres be σ1
q 1 1 
(4)
4πε0 R −  σ
and σ2 respectively. Then the ratio 2 has a value
 R2 + d 2  σ1
R1 R2
6. Three charges are placed at the vertex of an (1) (2)
equilateral triangle as shown in figure. For what R2 R1
2
value of Q, the electrostatic potential energy of the  R2 
system is zero? (3) 1 (4)  
 R1 
9. Potential energy of two equal negative point 14. Two identical capacitors, have the same
charges 2μC each held 1 m apart in air is capacitance C. One of them is charged to potential
(1) 2 J (2) 2 eV V1 and the other to V2. Likely charged plates are
(3) 4 J (4) 0.036 J then connected. Then, the decrease in energy of the
combined system is
10. Two parallel plates each of area A are separated by 1
two different dielectric as shown in figure. The net (1) C (V12 − V22 )
4
capacitance is
1
(2) C (V12 + V22 )
4
1
(3) C (V1 − V2 ) 2
4
1
(4) C (V1 + V2 ) 2
4
ε0 A ε A
(1) (2) 0
2d d
15. Two capacitors of capacitance C are connected in
3ε0 A 4ε0 A
(3) (4) series. If one of them is filled with dielectric of
d 3d
dielectric constant K, what is the effective
11. In a charged capacitor the energy is stored in
capacitance?
(1) The positive plate only
(1) KC (2) C (K + 1)
(2) The negative plate only
(1 + K )
(3) The field between the plates
(4) None of the above (3) 2 KC (4) None of these
(1 + K )
12. Statement I: A dielectric is inserted between the
plates of a capacitor connected with the battery. 16. Taking infinite as reference an isolated hollow
The energy of the capacitor increases metallic sphere of radius R is given a charge Q.
1 Then, the potential at the centre is
Statement II: U = CV 2 .
2 Q
(1) Zero (2)
(1) Both the statements are true and the 4πε0 R
statement-II is the correct explanation of 2Q Q
(3) (4)
statement-I. 4πε0 R 4πε0 (2 R )
(2) Both the statements are true and the
statement-II is not the correct explanation of
17. In the given figure, a hollow spherical capacitor is
statement-I.
shown. The electric field will not be zero
(3) Statement-I is true and statement-II is false
(4) Statement-I is false and statement-II is true

13. Four capacitors are connected as shown in figure.

The equivalent capacitance between A and B is
1µF
D C

1µF 1µF

A (1) r < r1
B
1µF (2) r 1 < r < r2
(1) 4 µF (2) 0.25 µF (3) r < r2
(3) 0.75 µF (4) 1.33 µF (4) None of these

[3]
18. In the below shown region with electric field lines 23. A hollow metal sphere of radius 10 cm is charged
(arrows), the points having equal potentials are such that the potential on its surface becomes 80V.
The potential at the centre of the sphere is xV.
Find x.

24. The effective capacitance between points A and B

is x µF. Find x.

3µF 3µF
(1) P and Q (2) S and Q A B
(3) S and R (4) P and R 3µF

19. The energy required to be delivered by a battery to

25. Capacitance of a parallel plate capacitor becomes
charge a parallel plate capacitor of plate separation
4
d and plate area of cross-section A such that times its original value, if a dielectric slab of
3
uniform electric field between the plates is E, is
d
1 ε0 E 2 ε0 E 2 thickness t = is inserted between the plates [d
(1) (2) 2
2 Ad Ad
is the separation between the plates]. The dielectric
1
(3) ε0 E Ad
2
(4) ε0 E 2 Ad constant of the slab is
2
26. The equivalent capacitance between the points A
20. A battery is used to charge a parallel plate
and B in the following circuit is x µF. Find x.
capacitor till the potential difference between the
plates becomes equal to the electromotive force of
the battery. The ratio of the energy stored in the
capacitor and the work done by the battery will be
(1) 1 (2) 2
1 1
(3) (4)
4 2
27. A parallel plate capacitor having plates of area S
Integer Type Questions (21-30)
and plate separation d, has capacitance C1 in air.
21. The potential difference between points A and B in When two dielectrics of different relative
the circuit shown is nV. Find n. permittivities (ε1 = 2 and ε2 = 4) are introduced
between the two plates as shown in the figure, the
7
capacitance becomes C2. The ratio C2 is .
C1 x
Find x.

22. The plates of a parallel plate capacitor with air as

medium are separated by a distance of 8 mm. A
medium of dielectric constant 2 and thickness 4
mm having the same area is introduced between
the plates. For the capacitance to remain the same,
the distance between the plates will be P mm. Find
P.

[4]
28. Two parallel plate capacitors of capacitances C
and 2C are connected in parallel and charged to a
potential difference V. The battery is then
disconnected and the region between the plates of
capacitor with capacitance C is completely filled
with a material of dielectric constant K. The
potential difference across the capacitors now
becomes  x 
V . Find x.
 K +2

30. Three capacitors of capacitance 1 µF, 2 µF and

29. In the given network, the value of C, so that an
3 µF are connected in series and a potential
equivalent capacitance between A and B is 3μF, is
difference of 11V is applied across the
x µF. Find x.
combination. Then, the potential difference across
the plate of 1 µF capacitor is xV. Find x.

SECTION-II (CHEMISTRY)
Single Correct Type Questions (31-50) (1) I-R ; II-S ; III-Q ; IV-P
31. In the formation of sulphur trioxide by the contact (2) I-S ; II-P ; III-Q ; IV-R
process 2SO2(g) + O2(g) → 2SO3(g) The rate of (3) I-Q ; II-S ; III-P ; IV-R
d(O 2 ) (4) I-R ; II-Q ; III-P ; IV-S
reaction is expressed as – = 2.5 × 10–4 mol L–1
dt
34. The rate constant of a first order reaction (A → B)
sec–1. The rate of disappearance of (SO2) will be–
is 4 × 10–3 sec–1. At a reactant concentration [A] of
(1) 5 × 10–4 mol L–1 S–1 0.02 M, the rate of reaction would be:
(2) – 2.25 × 10–4 mol L–1 S–1 (1) 8 × 10–5 M sec–1
(3) 3.75 × 10–4 mol L–1 S–1 (2) 4 × 10–3 M sec–1
(4) 50.0 × 10–4 mol L–1 S–1 (3) 2 × 10–1 M sec–1
(4) 4 × 10–1 M sec–1
32. The specific rate constant of a first order reaction
depends on the: 35. Select the rate law that corresponding to the data
(1) Conc. of the reactant shown for the following reaction A + B → C
(2) Conc. of the product
Exp. [A] [B] Initial rate
(3) Time
(4) Temperature 1. 0.012 0.035 0.10
2. 0.024 0.070 1.6
33. Match List I with List II and select the correct 3. 0.024 0.035 0.20
answer using the code given below the lists: 4. 0.012 0.070 0.80
List- I (Graph) List- II (Slope)
(1) Rate = K [B]3
(2) Rate = K[B]4
C Vs t (abscissa) for zero
I
order
P Unity (3) Rate = K[A][B]3
log C Vs t (abscissa) for
(4) Rate = K[A]2[B]2
II Q Zero
first order
36. The energy of activation of a forward reaction is
 −dC 
  Vs C for zero 50 Kcal. The energy of activation of its backward
III  dt  R –k
reaction is (If reaction is exothermic)
order
(1) Equal to 50 Kcal.
 −dC 
ln   Vs nC for −
k (2) Greater than 50 Kcal.
IV  dt  S
(3) Less than 50 Kcal.
2.303
first order (4) Either greater or less than 50 Kcal.
[5]
37. An exothermic reaction X → Y has an activation 42. For the reaction 2A + 3B  → products, when A
energy 30 KJ mol–1. If energy change (∆E) during is in excess and on changing the concentration of
the reaction is –20 KJ, then the activation energy B from 0.1 M to 0.4 M, rate becomes doubled,
for the reverse reaction is: Thus, order with respect to B would be:
(1) 1 (2) 2
(1) 10 KJ (2) 20 KJ
(3) –1 (4) 0.5
(3) 50 KJ (4) –30 KJ
43. From different sets of data of t1/2 at different initial
38. The reaction, X + 2Y + Z → N occurs by the concentration of reactant say 'a' for a given
following mechanism reaction, the product [t1/2 × a] is found to be
(i) X + Y M (very rapid equilibrium) constant. The order of reaction is:
(ii) M + Z → O (slow) (1) 2 (2) 1
(iii) O + Y → 1 N (very fast) (3) Zero (4) 3
What is the rate law for this reaction k
(1) Rate = k[Z] 44. A reaction 2A + B  → C + D is first order with

(2) Rate = k[X] [Y]2 [Z] respect to A and 2nd order with respect to B.
Initial conc. (t = 0) of A is C0 while B is 2C0. If at
(3) Rate = [N]
t = 30 minutes, the conc. of C is C0 /4 then rate
(4) Rate = k[X] [Y] [Z] expression at t = 30 minutes is:
(1) R = 7 C03 k/16
39. For a reaction of the type A + B → products, it is (2) R = 27 C03 k / 32
observed that doubling the concentration of A (3) R = 247 C03 k / 64
causes the reaction rate to be four times increased, (4) R = 49 k C03 / 32
but doubling the amount of B does not effect the 45. In a certain gaseous reaction between X and Y,
rate. The equation is X + 3Y → XY3, the initial rates are reported as
(1) Rate = K [A] [B] follows-
(2) Rate = K [A]2 [X] [Y] Rate
(3) Rate = K [A]2[B] 0.1 M 0.1 M 0.002 Ms–1
(4) Rate = K [A]2[B]2 0.2 M 0.1 M 0.002 Ms–1
0.3 M 0.2 M 0.008 Ms–1
40. The rate for the reaction 0.4 M 0.3 M 0.018 Ms–1
RCl + NaOH (aq) → ROH + NaCl is given by
The rate law is:
(1) r = K [X] [Y]3 (2) r = K[X]0[Y]2
rate = K1[RCl] The rate of the reaction is – (3) r = K [X] [Y] (4) r = [X]0[Y]3
(1) Doubled on doubling the concentration of
NaOH 46. If for a reaction in which A(g) converts to B(g)
(2) Halved on reducing the concentration of RCl the reaction is carried out at const. V & T. It
to half results into the following graph.
(3) Decreased on increasing the temperature of pB
reaction Partial
Pressure
(4) Unaffected by increasing the temperature of
pA
the reaction
Time
41. For the reaction 4A + B → 2C + 2D Then which of the following option is correct
(1) The reaction must be A(g) → 3B(g) and is a
The incorrect statement is:
first order reaction.
(1) The rate of disappearance of B is one fourth
(2) The reaction must be A(g) → 3B(g) and is a
the rate of disappearance of A second order reaction.
(2) The rate of appearance of C is half the rate of (3) The reaction must be A(g) → 3B(g) and is a
disappearance of B zero order reaction.
(3) The rate of formation of D is half the rate of (4) The reaction must be A(g) → 3B(g) and is a
consumption of A third order reaction.
(4) The rates of formation of C and D are equal
[ 6]
47. The decomposition of N2O into N2 & O2 in 53. The conversion of vinyl allyl ether to pent-4-enol
presence of gaseous argon follows second order follows a certain kinetics. The following plot is
kinetics with k = (5.0 × 1011 L mol−1 s−1) obtained for such a reaction.
–1

log (a–x)
41570 K
−
e (K stands for Kelvin units). The energy
T –2
–3
of activation of the reaction is
–4
(1) 5.0 × 1011 J (2) 41570 J –5
(3) 5000 J (4) 345612.98 J –6
0 2 4 6 8 10
48. For the reaction, N2(g) + 3H2(g) → 2NH3(g) time (min.)
under certain conditions of temperature and partial The order for the reaction is
pressure of the reactants, the rate of formation of
54. Consider the reaction 2A(g)  → 3B(g) + C(g).
NH3 is 0.001 mole h–1. What will be the rate of
Starting with pure A initially, the total pressure
consumption of H2 ?
doubled in 3 hrs. The order of the reaction might
(1) 0.001 mole h–1 (2) 0.0015 mole h–1
possibly be

(3) 0.0066 mole h–1 (4) 0.002 mole h–1

55. The decomposition of NH3 gas on a heated
tungsten surface gave the following results:
3
49. If half life (t1/2) = ; then what will be order? Initial pressure (mm) 65 105 y 185
2ka 2 Half-life (sec) 290 x 670 820
(1) 2 (2) 3 The value of (x/y) is: (Nearest integer)
(3) 0 (4) –2
56. The rate constant, the activation energy and the
50. The forward rate constant for the elementary frequency factor of a chemical reaction at 25°C
reversible gaseous reaction are 3.0 × 10–4 s–1, 104.4 KJ mol–1 and 6.0 × 1014 s–1
C2H6 2CH3 is 1.57 × 10–3 s–1 at 100 K respectively. The value of the rate constant as
What is the rate constant for the backward T → ∞ is ‘x’ × 1013 s–1. x is:
reaction at this temperature if 10–4 mole of CH3
and 10 moles of C2H6 are present in a 10 litre 57. The reaction A(g) + 2B(g) → C(g) + D(g) is an
vessel at equilibrium. elementary process. In an experiment, the initial
(1) 1.57 × 109 L mol—1 s–1 partial pressure of A and B are PA = 0.60 and
(2) 1.57 × 1010 L mol—1 s–1 PB = 0.80 atm. When PC = 0.2 atm, the rate of
(3) 1.57 × 1011 L mol—1 s–1 reaction relative to the initial rate is 1/x. Then x is:
(4) 1.57 × 107 L mol—1 s–1
58. For a given reaction, energy of activation for
forward reaction (Eaf) is 80kJ.mol−1.
Integer Type Questions (51-60)
∆H = −40kJ.mol−1 for the reaction. A catalyst
51. If a first order reaction is completed to the extent lowers Eaf to 20 kJ.mol−1. The ratio of energy of
of 75% and 50% in time intervals, t1 and t2, what activation for reverse reaction before and after
is the ratio, t1 : t2 ? addition of catalyst is:

d[A] 59. For an elementary process 2X + Y → Z + W, the

52. For the reaction A 
→ Products, – = k
dt molecularity is:
and at different time interval, [A] values are:
Time 0 5 min 10 min 15 min 60. A certain zero order reaction (A → B) has
[A] 20 mol 18 mol 16 mol 14 mol k = 0.025 M s–1 for the disappearance of A. The
concentration of A after 15 seconds if the initial
At 20 minutes, rate will be ‘x’ mol/min. The value
concentration is 0.50 M is ‘x’ M. Then 1000 x is:
of 10x is:

[ 7]
 SECTION-III (MATHEMATICS)
Single Correct Type Questions (61-80) 66. The domain of the function

The equivalent definition of f ( x=

) x − 1 is  5x − x2 
61.
f ( x ) = log10 
 4  is
− x − 1, x ≤ −1  
 x + 1, −1 < x ≤ 0
 (1) [1, 4] (2) [1, 0]
(1) f ( x) = 
 1 − x, 0 ≤ x ≤1 (3) [0, 5] (4) [5, 0]
 x − 1, x ≥1
 x − 1, x ≤ −1 67. Let A = {1, 2, 3} and B = {2, 3, 4} , then which of
 x + 1, −1 < x ≤ 0
 the following relations is a function from A to B?
(2) f ( x) = 
 x − 1, 0 ≤ x ≤ 1 (1) {(1, 2), (2, 3), (3, 4), (2, 2)}
 x + 1, x ≥1 (2) {(1, 2), (2, 3), (1, 3)}
(3) {(1, 3), (2, 3), (3, 3)}
 x + 1, x ≥ 0
(3) f ( x) =  (4) {(1, 1), (2, 3), (3, 4)}
 x + 1, x ≤ 0
 x − 1, x ≥ 0 68. Let f : R → R, g : R → R be two functions given
(4) f ( x) = 
 x + 1, x < 0 by f ( x ) =
2 x − 3, g ( x ) =
x3 + 5. Then, ( fog ) x
−1

is equal to
62. The domain of the function
1/3
 2 log10 x + 1  is  x−7
f ( x ) = log100 x   (1)  
 −x   2 
(1) ( 0,10−2 ) ∪ (10−2 ,10−1/2 )  x+7
(2) 
1/3

(2) ( 0,10−1/2 )  2 
1/3
 7
(3) ( 0,10−1 ) (3)  x − 
 2
(4) ( 0,10−2 )  x−2
1/3
(4)  
 7 
63. If R denotes the set of all real numbers, then the
function f : R → R defined by f ( x ) = x is
69. Let f : [ π, 3π / 2] → R be a function given by
(1) One-one
(2) Onto
f (=
x) [sin x ] + [1 + sin x ] + [ 2 + sin x ] , where [x]
(3) Both one-one and onto denotes greatest integer ≤ x.
(4) Neither one-one nor onto Then, the range of f ( x ) is

1
(1) {0, 3} (2) {1}
64. If f ( x ) = , then domain of fof(x) is (3) {0, 2} (4) {3}
−x
(1) ( 0, ∞ ) (2) ( −∞, 0 )
70. If the functions f ( x=
) log ( x − 2 ) − log ( x − 3)
(3) {0} (4) No value of x
and g ( x ) = log  x − 2  are identical, then
 x−3
65. If R is an equivalence relation on a set A, then R–1 is
(1) x ∈ ( 2, 3)
(1) Reflexive only
(2) Symmetric but not transitive (2) x ∈ ( 2, ∞ )
(3) Equivalence
(3) x ∈ ( 3, ∞ )
(4) Only transitive
(4) x∈R
[ 8]
71. Statement I: The relation R in the set of real 76. If R be a relation on natural numbers defined as
=
numbers, defined as R {(a, b) : a ≤ b 2 } is neither aRb ⇒ a – b > 0, then the relation is
reflexive nor symmetric nor transitive. (1) Reflexive only
Statement II: The relation R in the set of real (2) Symmetric only
(3) Transitive only
=
numbers, defined as R {(a, b) : a ≤ b3} is neither
(4) Symmetric and transitive only
reflexive nor symmetric nor transitive.

{ ( )}
(1) Statement I is correct, statement II is
incorrect 77. f ( x ) cos log10 x + x 2 + 1 , is
The function =
(2) Statement I is incorrect, statement II is
(1) Even (2) Odd
correct
(3) Constant (4) Neither even nor odd
(3) Both statements are incorrect
(4) Both statements are correct
78. The fundamental period of the function
f (θ ) =
4 + 4sin 3 θ − 3sin θ is
αx 2
72. f ( x)
Let = , x ≠ −1 . The value of α for
x +1 2π π
(1) (2)
( a ) a, ( a ≠ 0 ) is
which f = 3 3
π
(1) 1 −
1
(2)
1 (3) (4) π
a a 2
1 1
(3) 1 + (4) −1
If f ( 2 x + 3)= sin x + 2 , then f ( 4m − 2n + 3) is
x
a a 79.
equal to
73. If f : R → R and g : R → R are defined by
(1) sin ( m − 2m ) + 22 m− n
f ( x )= x − 3 and g ( x=
) x 2 + 1 , then the values
(2) sin ( 2m − n ) + 2(
m − n )2

of x for which g { f ( x )} = 10 are

(3) sin ( m − 2n ) + 2(
m + n )2
(1) 0, –6 (2) 2, –2
(4) sin ( 2m − n ) + 2
(3) 1, –1 (4) 0, 6 2m−n

1
74. The domain of the real function f ( x ) = 80. The range of the function f ( x ) =
x+2
is
4 − x2 x − 8x − 4
2

(1)  −∞, −1  ∪  −1 , ∞ 
is
(1) The set of all real numbers  4  20 
(2) The set of all positive real numbers
(2)  −∞, − 1  ∪  − 1 , ∞ 
(3) (–2, 2)  4   20 
(4) [–2, 2]
(3)  −∞, − 1  ∪  − 1 , ∞ 
 4   20 
75. f ( 0 ) 1,=
If = f (1) 5,=
f ( 2 ) 11 , then the equation (4) (–∞, ∞)
of polynomial f(x) of degree two is
(1) 4 x 2 + 1 =0 Integer Type Questions (81-90)
(2) x + 3 x + 1 =
2
0 81. If f is a real valued function such that
(3) 6 x − 2 x + 1 = ) f ( x ) + f ( y ) and f (1) = 5 , then the
f ( x + y=
2
0
(4) 5x – x + 1 = 0
2
value of f (100 ) is

[ 9]
 The period of the function sin  πx  + cos  πx  sin 4 x + cos 2 x
If f ( x ) =
82.
 2   2  87. for x ∈ R, then the
sin 2 x + cos 4 x
is
value of f ( 2010 ) is

83. If A = {1, 2} and the number of relations on the 88. []

If x denotes the greatest integer ≤ x , then
power set of A is 2k then value of k is
2 2 1  2 2   2 98  is
 3  +  3 + 99  +  3 + 99  + ... +  3 + 99 
       
84. =
Let A {2, 3, 4, 5,…,16,17,18} . Let R be a relation equal to
on A × A , defined by ( a, b ) R ( c, d ) , if ad = bc ,
then the number of ordered pairs (a, b) 89. Let f be a real – valued invertible function
corresponding to (c, d) = (3, 2) is  2x − 3 
such that f  =5 x − 2, x ≠ 2. Then the
 x−2 

value of f (13) is
−1
85. If f ( x ) . f (1=
/ x ) f ( x ) + f (1 / x ) and
f ( 4 ) = 65 , then f ( 6 ) is
90. A real valued function f ( x ) on R → R satisfies
the relation f (x) + f (2x + y) + 5xy = f (3x – y)
86. If A = {a, b, c} and relation on it, R = {(a, b), (a, c)},
then the minimum number of elements required y ∈ R , Then the value of f ( 4 )
+ 2x2 + 1 for ∀x,   
to make R transitive is is

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[10]
 Class 12th JEE

MRJM/12 Milestone Test-02 Phase-1

DATE: 16/06/2024

ANSWER KEY

PHYSICS CHEMISTRY MATHEMATICS

1. (3) 31. (1) 61. (1)
2. (4) 32. (4) 62. (1)
3. (3) 33. (1) 63. (4)
4. (2) 34. (1) 64. (4)
5. (2) 35. (3) 65. (3)
6. (4) 36. (2) 66. (1)
7. (2) 37. (3) 67. (3)
8. (1) 38. (4) 68. (1)
9. (4) 39. (2) 69. (1)
10. (4) 40. (2) 70. (3)
11. (3) 41. (2) 71. (4)
12. (1) 42. (4) 72. (3)
13. (4) 43. (1) 73. (4)
14. (3) 44. (4) 74. (3)
15. (1) 45. (2) 75. (2)
16. (2) 46. (3) 76. (3)
17. (2) 47. (4) 77. (1)
18. (3) 48. (2) 78. (1)
19. (3) 49. (2) 79. (4)
20. (4) 50. (4) 80. (1)
21. (2) 51. (2) 81. (500)
22. (10) 52. (4) 82. (4)
23. (80) 53. (1) 83. (16)
24. (9) 54. (0) 84. (6)
25. (2) 55. (3) 85. (217)
26. (1) 56. (60) 86. (0)
27. (3) 57. (6) 87. (1)
28. (3) 58. (2) 88. (66)
29. (48) 59. (3) 89. (3)
30. (6) 60. (125) 90. (7)
 SECTION-I (PHYSICS)
1. (3) 5. (2)
As work is done by the field, KE of the body 1 1 
=
∆V 2kq  −  (k = 1 / 4πε0)
increase by R
 R2 + d 2 
∆KE = q(VA − VB)
= 10−8(600 − 0) = 6 × 10−6 J
6. (4)
2. (4) Electrostatic potential energy of the system of
The capacitance of a parallel plate capacitor with charges is
dielectric (oil) between its plates is 1  Qq Qq q 2 
=
U  + + 
K ε0 A 4πε0  a a a
C= …(i)
d 1
where symbols have their usual meanings. When = U  2Qq + q 2 
4πε0 a  
dielectric (oil) is removed, so capacitance
ε A Given, U = 0
C0 = 0 …(ii) ⇒       2Qq + q 2 = 0
d
Comparing Eqs. (i) and (ii), we get q
⇒    Q = −
C = KC0 2
C C
⇒ C0 = = ( K = 2)
K 2

3. (3)
In an equilateral triangle distance of centroid from
all the vertices is same (say r). 7. (2)
1  2q q q  There exists no electric field inside the conductor,
∴  V = V1 + V2 + V3 = − − =0
4πε 0  r r r  hence potential remains constant and equal to
A q
2q potential on surface =
4πε0 R
r
+
+
+

r O r
+
+

+ + +

B –qC
+ +

–q
O R
But

+

1 2q
EA =
+

. along AO,
+

4πε 0 r 2
+
+

+
+
+

 1 q
EB = along OB q
4πε 0 r 2 1 .
R
 1 q  
and EC EB + EC
. 2 along OC . obviously   V
1
4πε 0 r r
Will also be in the direction of AO extended
  
and hence    ( )
E A and EB + EC being in same direction O
R
r

will not give zero resultant. 1 q

V=
4πε0 R
4. (2)
Also, outside the metallic sphere
dV
As     E = − 1 q
dr V= .
4πε0 r
V ( x ) − 0 
∴  + E0 = −  or Vx = − E0 x 1
x V∝
r
8. (1) = Ui − U f
Since the two spheres are joined by a wire, their 2
1 1 V +V 
potential are equal ie, = C (V12 + V22 ) − (2C )  1 2 
q1 q2 q1 R1
2 2  2 
= ⇒=
4πε 0 R1 4πε 0 R2 q2 R2 =
1
C (V1 − V2 ) 2
4
q q
Now, σ1 = 1 2 and σ 2 = 2 2 , NOTE: We can also apply the formula of loss of
4πε 0 R1 4πε 0 R2
energy under such situations.
2
σ 2 q2 R12  R 2  R1  C1C2
Hence = × =   Loss = (V1 − V2 ) 2
σ1 q1 R 22  R1  R 2  2(C1 + C2 )
σ R Here, C₁ = C2 = C
⇒     2 = 1
σ1 R 2
15. (1)
9. (4)
When plates of capacitor are separated by a
( )
2
q1q2 9 × 109 −2 × 10−6 dielectric medium of dielectric constant 𝐾𝐾 , its
=
PE = = 0.036 J
4πε 0 r 1 capacity
K ε0 A
=
Cm = KC0
10. (4) d
ε0 A ε0 A 4ε 0 A ie,        Cm = KC0
C= = =
d1 d 2 d 1 1  3d
+  +  Here,     C0 = C
K1 K 2 2 1 2 
∴         Cm =
KC
11. (3) Now, two capacitors of capacities KC and C are in
When a capacitor is charged, work is done by the series, their effective capacitance
charging battery. As the capacitor charges, the 1 1 1 1 1+ K
= + or       =
potential difference across its plates rises. The total C ′ KC C C ′ KC
amount of work in charging the capacitor is stored KC
up in the capacitor, in the form of electric potential ∴C ′ =
K +1
energy between the plates.
16. (2)
12. (1)
Potential at the centre of hollow metallic sphere
When we inserted dielectric the capacitance will
Q
1 V=
increase. Hence, energy = CV 2 increases. 4πε0 R
2

13. (4) 17. (2)

1 1 1 1 The electric field of a hollow spherical capacitor is
= + + =3
Cs 1 1 1 localised in between inner and outer surface of the
1 spherical conductor.
Cs = Therefore, at point r1 < r < r2 , the electric field will
3
Capacitance between A and B not be zero.
1 4
C p = + 1 = μF = 1.33μF
3 3 18. (3)
The points S and R are on the same line
14. (3) perpendicular to the uniform electric field, so these
ΔU = decrease in potential energy will be at equal potential.
19. (3) From Eqs. (iii) and (iv)
Energy given by the cell VB 1
=
E = CV 2
6 − VB 2
Aε0
=
Here, C   capacitance of capacitor   ∴ VB =
2 volt
d
V = potential difference across the plates = Ed ∴ VA − VB = 4 − 2 = 2 volt
 Aε 
Therefore, Energy =  0  ( Ed ) = Aε0 E 2 d
2

 d  22. (10)
Original capacity, with air
20. (4) ε0 A
C=
Ratio of energy stored in the capacitor and the work d
done by the battery When dielectric plate (medium) of thickness t is
1 introduced between the plates, then capacity
qV
2 1
= becomes
qV 2
ε0 A
C′ =
 1
21. (2) d ′ − t 1 − 
Consider the charge distribution as shown.  K
Considering the branch on upper side, we have But as given, C ′ = C
ε0 A ε A
∴ = 0
d  1
d ′ − t 1 − 
 K
t
Or d = d ′ − t +
K
4
Or d = d ′ − 4 +
2
Or 8= d ′ − 2
q Or d ′ = 10 mm
= 4 × 10−6
Vx − VA
q 23. (80)
= 2 × 10−6
VA − V y The potential at the centre of the sphere is 80 V
Here, Vx = 6 volt, Vy = 0 because it remains same at each point under the
q metallic hollow sphere.
∴ = 4 × 10−6 …(i)
6 − VA
q 24. (9)
= 2 × 10−6 …(ii)
VA − 0
1 2

3µF
From Eqs. (i) and (ii), we get
1 2 B 3 4 5 6 B 3 4
VA A
=2 A 3µF 3µF A 3µF 3µF
B
6 − VA
∴ VA =4 volt 5 6

Similarly for the lower side branch 3µF

q′ Here, all the three capacitors are connected in
= 2 × 10−6 …(iii)
6 − VB parallel. Therefore, equivalent capacitance between
q′ points A and B is
= 4 × 10−6 …(iv)
VB − 0 Ceq = 3 + 3 + 3 = 9μF.
25. (2)
The capacitance of air capacitor
ε A
C= 0
d
d
When a dielectric slab of thickness t = is
2
s
ε0 s 2ε0
2 2ε0 s
inserted between plates, the capacity becomes
Aε0 =
C1 = , C3 =
C′ = d d d
d 1 2
d − 1 − 
2 K  s
4ε 0 4ε s
4 Aε0 ε0 A ⇒ C4 = 2 = 0
= d
3 d d 1 d
d − 1 −  2
2 K 
s
 1 1  2ε0
3=
d 4d  1 − +  = C5 = 2 ε0 s
 2 2K  and
d d
1 1 
=3 4 +  C3C4
 2 2K  =C2 + C5
C3 + C4
4
Or = 3 − 2 or K = 2 4 ε0 s ε0 s
2K = +
3 d d
7 ε0 s 7
26. (1) = = C1
The two capacitors each of value 1.5μF are in 3 d 3
parallel. So, their equivalent capacitance C2 7
⇒ =
3µF 3µF 3µF C1 3
A B
= 1.5 + 1.5 = 3 μF
28. (3)
Now, three capacitors each of value 3μF are in
Total charge will remain unchanged. Hence,
series. Hence, their equivalent capacitance is given
by Q = Q' or 3CV = (KC + 2C)V'
1 1 1 1
= + +
C 3 3 3
1 3
Or =
C 3
Or C = 1 µF

 3 
27. (3) ∴ V '=
 V
 K +2

29. (48)
16
C
3= 5
16
+C
5
or       C = 48μF
16
C 5
30. (6) The total potential difference V = 11 volt
Let potential difference between the plates of the ∴   V =V1 + V2 + V3
capacitors C1 , C2 and  be
C3 V1 ,  and
V2 V3and q be q q q
⇒V = + + = 11
the charge. C1 C2 C3
=
Given, =
C1 1μF, C2 2μF,
= C3 3μF
1 1 1 
∴ 11= q  + + 
1 2 3 
11q
⇒ 11 =
6
⇒q= 6μC
q q q
=
Then, V1 = , V2 = , V3 q 6
C1 C2 C3 ∴   
V1 = = = 6 V
C1 1

SECTION-II (CHEMISTRY)
31. (1) 35. (3)
−d[O 2 ] 1 d[SO 2 ] 1 d[SO3 ] A+B→C
=– =
dt 2 dt 2 dt R = K [A]m [B]n
–4
= 2.5 × 10 Ms –1 compere exp. (1) (3)
0.2
d[SO 2 ] 2.5 × 10−4 = [2]m m = 1
= 5 ×10–4 MSe–1, so R = 0.1
dt 2
–4 –1
compere exp. (2) & (3)
= 1.25 × 10 MSe n
1.6  0.07 
=  n=3
32. (4) 0.2  0.035 
Based on theory (k ∝ temperature). R = k A] [B]3

33. (1) 36. (2)

∆H = Eaf – Eab < 0 (for exothermic)
(I) For zero order reaction C = Co–kt
50 – Eab < 0 So Eab > 50
(II) For first order reaction
k 37. (3)
log C = log Co – ×t
2.303 – 20 = 30 – Eab
−dC Eab = 50.
(III) For zero order reaction vs C equal to
dt
zero 38. (4)
Rate = k1 [M] [Z] .....(1)
−dC
(IV) For first order reaction = k[C], log [M]
dt from equation (1) Keq = .
[x][y]
 dC 
  = log k + log C M = keq [x] [y] .....(2)
 dt 
 −dC 
put the value of M from (2) to (1)
Hence plot of log   against log C Rate = k1 keq [x] [y] [z]
 dt 
(abscissa) will have slope equal to unity Rate = k [x] [y] [z]

39. (2)
34. (1)
Rate wrt A is 2 and wrt B is zero.
R = K [A]
R = 4 × 10–3 × 0.02 = 8 × 10–5 MS–1 40. (2)
Rate wrt RCI is 1.
41. (2) 47. (4)
4A + B → 2C + 2D Ea = 41570 × R = 41570 × 8.314 = 345612.98 J
1 d[A] d[B] 1 d[C] 1 d[D]
– =– =+ = 48. (2)
4 dt dt 2 dt 2 dt
N2(g) + 3H2 (g) → 2NH3(g)
42. (4) −d[N 2 ] 1 d[H 2 ] 1 d[NH3 ]
=
− =+
A is in excess, so Rate will be independent of dt 3 dt 2 dt
change in concentration. −d[H 2 ] 3 d[NH3 ] 3
= = × 0.001 = 0.0015 mole h–1
R = k [B]n dt 2 dt 2
1
R = R 4n [B]n n= .
2 49. (2)
t1/2 ∝ a1–n
43. (1) here t1/2 ∝ a–2
a0 a2 –2 = 1–n ⇒ n = 3
For zero order t1/2 = , so t1/2 × a 0 = is
2k 2k
not a constant. 50. (4)
For 1st order t1/2 is constant so t1/2 × a 0 is not k f [CH3 ]2
K=
eq =
constant. k b [C2 H 6 ]
1 10−4
For 2nd order t1/2 = so t1/2 × c0 =
k is ∴ =
[CH 3] = 10−5 M
a0k 10
constant. 1.57 × 10−3 (10−5 ) 2
=
kb 1
44. (4)
⇒ kb = 1.57 × 107 L mol–1s–1

51. (2)
t1 = 2 × t1/2 ; t2 = t1/2

52. (4)
A  → Product
a a–x
Since equal interval of time equal conc. decreased
then reaction zero order
∆A 20 − 12 8
Rate == = = 0.4
∆t 20 20

53. (1)
As – log (a – x) ∝ t, we have order = 1

54. (0)
45. (2)
2 A (g)  → 3 B (g) + C (g)
Rate is independent of conc. of x & increased 4
t=0 P0 0 0
times on doubling y.
3x x
t = 3 hour (P0 – x)  
46. (3) 2 2
0 0
From the given graph it is clear that the (P + x) = 2 P
concentration decrease linearly with time then x = P0
zero order Reaction and A → 3B type. Reaction is completed in limited time so reaction
is zero order reaction.
55. (3) 58. (2)
Initial pressure 65 105 y 185 ∆H = Ef – Eb – 40 = 80 – Eb
Half life 290 x 670 820
Eb = 120 kJ/mole,
Initial pressure of gas a Initial moles of gas in
above question. catalyst lower the Ef To 20 kJ/ mole for forward
Half life a Initial pressure Rxn then Ef' = 20 kJ/mol
So, it must be zero order reaction we know catalyst decreases the Activation energy
C P 65 equal amount in both direction
t1/2 = O = O 290 =
2k 2k 2k Eb' = (120 – 60) = 60 kj/mol
65
⇒ k = = 0.112 mm of Hg/sec Eb 120
2 × 290 = = 2.0
E 'b 60
105 × 2 × 290 y × 2 × 290
x= = 468 sec 670 =
2 × 65 2 × 64
⇒ y = 150 mm of Hg 59. (3)
For elementary process,
56. (60) Molecularity = Sum of stoichiometric
K = A × e– Ea/RT = A × e– Ea/R ×= A = 6.0 × 1014 s–1. coefficients.

57. (6) 60. (125)

Suppose At
We know (A0 – At) = kt for zeroth order
(0.50 – At) = 0.025 × t
0.50 – At = 0.025 × 15
At = 0.125 M

SECTION-III (MATHEMATICS)
61. (1) f ( x ) is defined if
We have,
2log10 x + 1
x > 0,100 x ≠ 1 and >0
f ( x=
) x −1 −x

1 − x , if x <1 ⇒ x > 0, x ≠ 10−2 and 2log10 x + 1 < 0

⇒ f ( x) = 
 x − 1, if x ≥1
⇒ x < 0, x ≠ 10−2 and log10 x < −
1
2
1 − x , if −1 < x < 1
⇒ f ( x) = 
⇒ x > 0, x ≠ 10−2 and x < 10−1/2
 x − 1, if x ≤ −1 or x ≥ 1

 1 + x,
 1 − x,
if −1 < x < 0 ( )
⇒ x ∈ 0,10−2 ∪ (10−2 ,10−1/2 )
 if 0 ≤ x ≤1
⇒ f ( x) = 
 − x − 1, if x ≤ −1
63. (4)
 x − 1, if x ≥1
The given function is
 x, x ≥ 0
62. (1) f ( x=
) x= 
We have,  x, x < 0
And f : R → R , then it is clear that function is
 2log10 x + 1 
f ( x ) = log100 x  
 −x  neither one-one nor onto.
64. (4) h ( x ) = fog ( x ) Then, h (=
Let  . x ) 2 x3 + 7
1
Given, f ( x) = Now,
−x
hoh −1 ( x ) = x
 1 
∴   fof ( x ) = f ( f ( x ) ) = f  
 −x  ( )
⇒ h h −1 ( x ) =
x
1
⇒     fof ( x ) =
{ }
3
1 ⇒ 2 h −1 ( x ) +7=x
−
−x 1/3
 x−7
⇒ h −1 ( x ) =
 
1  2 
Since, − is an imaginary.
−x
Hence, no domain of fof ( x ) exist. 69. (1)
Thus, the domain of fof ( x ) is an empty set. For x ∈ ( π,3 π / 2 ) , we have
−1 < sin x < 0
65. (3) ⇒ 0 < 1 + sin x < 1 and 1 < ( 2 + sin x ) < 2

∴[sin x ] =
−1, [1 + sin x ] =
0 and [ 2 + sin x ] =
Since, inverse of an equivalent relation is also an
1
equivalent relation.
∴ R–1 is an equivalent relation.
⇒ f (=
x) [sin x ] + [1 + sin x ] + [ 2 + sin x ]
=−1 + 0 + 1 =0
66. (1) For x = π, we have
For f ( x ) to be defined [sin x ] =0, [1 + sin x ] =1 and [ 2 + sin x ] =
2

5x − x2 ∴ f ( x) = 0 +1 + 2 = 3
≥ 1 ⇒ x2 − 5x + 4 ≤ 0
4 3π
For x = , we have
⇒ ( x − 4 )( x − 1) ≤ 0∴ x ∈ [1, 4] 2
[sin x ] = 0 and [ 2 + sin x ] =
−1,[1 + sin x ] = 1
67. (3) ∴ f ( x ) =−1 + 0 + 1 =0
In the given options only option (3) satisfies the
Hence, range of f ( x ) = {0, 3}
condition of a function.
Hence, option (3) is a function.
70. (3)
68. (1) We know that two functions f ( x ) and g ( x ) are
We have, identical, if their domains are same and
) 2 x − 3 and g ( x=) x3 + 5
f ( x= f ( x) = g ( x)

Clearly, f : R → R and g : R → R are bijections. Clearly, f ( x ) = g ( x )

Therefore, fog : R → R is also a bijection and Now, D1 = Domain ( f =
) ( 3, ∞ )
hence invertible And, D2 = Domain ( g ) = ( −∞, 2 ) ∪ ( 3, ∞ )
Now,
∴ D1 ∩ D2 = ( 3, ∞ )
( x ) f ( g=
fog= ( x ) ) f x3 + 5 ( ) Hence, f ( x ) = g ( x ) for all x ∈ ( 3, ∞ )
( )
= 2 x + 5 − 3= 2 x + 7
3 3
71. (4) Let the second degree equation be
1 1 1 1
I: (i)  ,  ∉ R as > ∴ R is not reflexive f ( x ) = ax 2 + bx + c
2 2 2 4
∴   f ( 0 ) = 0 + 0 + c   
⇒ c = 1                   …( i )
(ii) (1, 2) ∈ R as 1 ≤ 4
       f (1) = a + b    
+ c ⇒ 5 = a + b +1
but (2, 1)∉ R as 2 > 1 ∴ R is not symmetric
=⇒     a + b 4                                                 …( ii )
(iii) (5, 3)∈ R as 5 ≤ 9
(3, 2)∈ R as 3 ≤ 4       f ( 2 ) = 4a + 2b + c
But (5, 2)∉ R as 5 > 4 ∴ R is not transitive ⇒ 4a + 2b + 1 = 11
=⇒   2a + b 5                                             …( iii )
1 1 1 1
II: (i)  ,  ∉ R as > ∴ R is not reflexive On solving Eqs. (ii) and (iii), we get
 2 2  2 8
= =
   a 1,      
b 3
(ii) (1, 2) ∈ R as 1 ≤ 8
∴ The required equation is
but (2, 1)∉ R as 2 > 1 ∴ R is not symmetric
f ( x ) = x 2 + 3x + 1
(iii) (10, 3)∈ R as 10 ≤ 27
(3, 2)∈ R as 3 ≤ 8
76. (3)
But (10, 2)∉ R as 10 > 8 ∴ R is not transitive Since, R is defined as aRb iff a − b > 0 .
Reflexive : aRb iff a − a > 0
72. (3) Which is not true. So, R is not reflexive.
           f ( a ) = a Symmetric : aRb iff a − b > 0
Now, bRa iff b − a > 0
αa 2
⇒      =
a Thus, R is not symmetric.
α +1
Transitive : a > b and b > c ⇒ a > c
⇒     αa 2 = a 2 + a Thus, R is transitive only.
1
⇒       α = 1 +                     ( a ≠ 0 ) 77. (1)
a
73. (4) Since the function g ( x ) = cos x is an even function
Given, f ( x) =
x − 3,  g ( x ) =
x2 + 1
( )
and h ( x ) = log x + x 2 + 1 is an odd function
∴       g { f ( x )} =
g ( x − 3) Therefore, the function
10 =( x − 3) + 1
⇒                
2
goh=
 (  )
( x ) cos  log x + x 2 + 1  is an even
⇒                10 = x + 10 − 6 x
2
function
⇒            x ( x − 6 ) = 0 ⇒ x = 0, 6
78. (1)
Given
74. (3)
f (θ ) =
4 + 4sin 3 θ − 3sin θ
1
Given, f ( x ) =
4 − x2           = ( )
4 − 3sin θ − 4sin 3 θ =
4 − sin 3θ
For domain of f ( x ) , 2π
∴ Period of f ( θ ) =
3
⇒                  4 − x2 > 0
⇒                  x 2 < 4 79. (4)
⇒                  −2 < x < 2 Given, f ( 2 x + 3)= sin x + 2 x
∴ Domain = ( −2, 2 ) Put =
x 2m − n
∴ f  2 ( 2m − n ) +=
3 sin ( 2m − n ) + 22 m− n
75. (2)
f ( 0 ) 1,    
Given, = = f (1) 5,     
= f ( 2 ) 11 ⇒        f ( 4m − 2n +=
3) sin ( 2m − n ) + 22m−n
80. (1)  πx  2π πx
Period of sin   is = 4, Period of cos
x+2  2  π/2
We have, f ( x ) = 2
x2 − 8x − 4 2π
is = 4,
For f ( x ) to be defined, we must have π/2
x 2 − 8 x − 4 ≠ 0, i.e., x ≠ 4 ± 2 5 πx πx
So, period of sin + cos is LCM of ( 4, 4 ) = 4
{ }
2 2
∴ Domain ( f ) = R − 4 − 2 5, 4 + 2 5

Let y = f ( x ) . Then, 83. (16)

n(P(A)) = 4
x+2
y= number of relations = 24×4
x − 8x − 4
2

⇒ x 2 y − ( 8 y + 1) x − ( 4 y + 2 ) =
0 84. (6)
=
Given, A {2, 3, 4, 5,….,16,17,18}
(8 y + 1) ± (8 y + 1)2 + 4 y ( 4 y + 2 )
⇒x= And ( a , b ) R ( c, d )
2y
∴ Ordered pair corresponding to ( 3, 2 ) is
⇒x=
(8 y + 1) ± 80 y 2 + 24 y + 1
2y     {( a, b ) ∈ A × A : ( a,  
b ) R ( 3, 2 )}
For x to be real, we must have =
      {( a, b ) ∈ A × A :=
2a 3b}
80 y 2 + 24 y + 1 ≥ 0 and y ≠ 0
 2 
⇒ ( 20 y + 1)( 4 y + 1) ≥ 0 and y ≠ 0      ( a, b ) ∈ A × A=
= :b a
 3 
1 1  2  
⇒ y ≤ − or, y ≥ − , y ≠ 0       a, a  : a ∈ A × A
4 20
 3  
⇒ y ∈ ( −∞, −1 / 4] ∪ [ −1 / 20, ∞ ) and y ≠ 0
   = {( 3, 2 ) , ( 6, 4 ) , ( 9, 6 ) , (12, 8 ) , (15,10 ) , (18,12 )}
For x = −2, we have y = 0 and −2 ∈ Domain
∴ Number of ordered pairs = 6.
(f)
Hence, range ( f ) = ( −∞, −1 / 4] ∪ [ −1 / 20, ∞ ) 85. (217)
1 1
81. (500) Given, f ( x ). f =
  f ( x) + f 
 x  x
Given,
f ( x + y=
) f ( x) + f ( y) Let f ( x ) = 1 ± x n , where n ∈ I .

For= = y 1 we get
x 1,    Now, f ( 4 ) = 65
( 2 ) f (1) + f (1)
f= Case I
f (1) 10
= 2.= Let f ( x=
) xn + 1
Also ⇒         f ( 4) =
4n + 1
f ( 3) = f ( 2 ) + f (1) = 15
⇒    65 =4n + 1
⇒ f ( n ) = 5n
⇒       n =
3
∴ f (100 ) = 500 Case II
f(x) ≠ 1 – xn
82. (4) Therefore, f ( x=
) x3 + 1
We observe that
Now, f ( 6 ) = 63 + 1 = 216 + 1 = 217
86. (0) 89. (3)
R is already transitive  2x − 3 
We have f  = 5x − 2
 x−2 
87. (1) 2x − 3
⇒ f −1 ( 5 x − 2 ) ⇒
We have, x−2
sin 4 x + cos 2 x Let 5 x − 2 = 13, then x = 3
f ( x) =
sin 2 x + cos 4 x 2 ( 3) − 3
−1
Hence, f= (13) = 3
3− 2
(1 − cos2 x )
2
+ cos 2 x
( x)
⇒ f= = 1      for all x ∈ R
1 − cos 2 x + cos 4 x 90. (7)
∴ f ( 2010 ) =
1 Let 2 x + y = 3 x − y ⇒ 2 y = x ⇒ y =
x
2
x
∴ Put y =
88. (66) 2
 2 r  0,        r < 33  5x  5x
2
 5x 
 3 + 99  =
 ⇒ f ( x ) + f   + = f   + 2 x2 + 1
   1,  r ≥ 33  2  2  2 
98 32 98
2 r  2 r  2 r  x2
∴    ∑  + = ∑  +  + ∑  +  ⇒ f ( x) =
1−
=r 0 =  3 99  r 0= 3 99  r 33  3 99  2
=0 + 66 =66 ⇒ f ( 4) =
−7

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