TEST SERIES : TEST-12

(JEE MAINS PATTERN)

Time : 3 hrs. M.M. : 360

TOPIC COVERED :
PHYSICS: Complete XI and XII Syllabus.
CHEMISTRY: Complete XI and XII Syllabus.
MATHEMATICS: Complete XI and XII Syllabus.

GENERAL INSTRUCTIONS :

1. The Test Booklet consists of 90 questions. The maximum marks are 360.

2. There are three subjects in the question paper Mathematics, Physics and Chemistry having
30 questions in each subject of equal weightage. Each question allotted 4 (four) marks for
each correct response.

3. Candidates will be awarded marks as in Instruction No. 2 for correct response of each question.
1 marks will be deducted for indicated incorrect response of each question.

4. There is only one correct response for each question. Filling up more than one response in
each question will be treated as wrong response and marks for wrong response will be
deducted accordingly as per instruction 3 above.

5. Four alternatives are given for each question out of which one is correct. Darken the correct
alternative on the given answer-sheet, with a pencil or pen.

6. Use of calculator is not permitted.

7. Use of unfair means shall invite cancellation of the test.

Name of the Student : ____________________________________________________________________

Section : __________________________ Centre : ______________________________

Invigilator’s Signature: ____________________________________________________________________

[1]
 MATHEMATICS
Choose the correct answer : (a) –2 < k < 2 (b) k > 2

1. If , ,  are the roots of the equation x3 + (c) 0 < k < 2 (d) none of these
mx2 + 3x + m = 0, then the general value of 6. Let p, q, r be three mutually perpendicular
tan–1 + tan–1 + tan–1 is vectors of the same magnitude. If a vector
( 2n  1) 
(a) (b) n x satisfies the equation p × {(x – q) × p} + q
2
n × {(x – r) × q} + r × {(x – p) × r} = 0, then x is
(c) (d) none of these given by
2
1 1
2.  n
Ci is equal to (a) (p + q – 2r) (b) (p + q + r)
2 2
0i  j  n
(a) n · 2n–1 (b) (n + 1) · 2n–1 1 1
(c) (p + q + r) (d) (2p + q + r)
(c) (n + 1) · 2n (d) none of these 3 3

3. Let f (x) = a0 + a1 | x | + a2 | x |2 + a3 | x |3 7. If px2 + qx + r = 0 has no real roots and p, q,

r are real such that p + r > 0 then
where a0, a1, a2, a3 are constants. Then only
(a) p + r < q (b) p + r > q
one of the following statements is correct.
Which one is it? (c) q > 0 (d) none of these

(a) f (x) is differentiable whatever be a0, 8. If a, b, c are unit vectors, then the
a1, a2, a3 maximum value of | a + b – c | 2 +
| b + c – a |2 + | c + a – b |2 must be
(b) f (x) is not differentiable whatever be
(a) 12 (b) 9
a0, a1, a2, a3
(c) 15 (d) none of these
(c) f (x) is not differentiable, then a1  0
9. Let f (x) be a differentiable function such
(d) f (x) is not differentiable, then a1 = 0, a3
that f (x) f (x) > 0  x  R and f (0) = 1,
0
then
4. Two of the straight lines given by 3x3 + n
f ( xi )  n xi 
3x2y – 3xy2 + dy3 = 0 are at right angles if (a) 
i 1
n 
 f
 n
 i 1 
  xi  R

(a) d = –1/3 (b) d = 1/3 (b) f (x) does not have a local minima
(c) d = –3 (d) d = 3 (c) f (x) has one minima
5. The equation | z + i | – | z – i | = k n
f ( xi )  n xi 
represents a hyperbola if (d) 
i 1
n 
 f

  xi  R

 i 1 n 

[2]
10. The total number of functions ‘f’ from the 2n
Cn  2 2n
2n
(a) Cn (b)
set {1, 2, 3, ..., m} into the set {1, 2, 3, ..., n} 2 2 n 1
such that f (i)  f (j),  i < j, is equal to 2n
Cn 2 2 n  2 n 1  2n
Cn
(c) (d)
(a) n
Cm (b) m
Cn 2 2n
2 n 1
m+n–1 m–1
(c) Cn–1 (d) Cn–1 15. In ABC, cos A + 2 cos B + cos C = 2, then
which one of the following is wrong
11. ‘G’ is the centroid of triangle ABC and A1
and B1 is the mid point of sides BC and  A C 
(a) tan   tan    3
AC respectively. If  1 be the area of 2 2
quadrilateral GA1CB1 and  be the area of  A C 
(b) cot   cot    3
 2 2
triangle ABC, then  is equal to
1   A   C   B
(c) cot  2   cot  2   2 cot  2 
3      
(a) (b) 3
2 (d) a, b, c are in AP
1
(c) (d) none of these sin 4 x cos 4 x 1
3 16. If   , then
a b ab
12. In a ABC, the line segments AD, BE and b
CF are three altitudes. Then a side of the (a) tan2x =
a
DEF will be a
(b) cos2x =
(a) a sin B (b) c cos B ab
sin 6 x cos 6 x 1
(c) a sin A (d) b cos B (c)  
a2 b2 (a  b) 2
13. The equation x – loge (1 + ex) = c has a (d) none of these
solution
17. If | z | < 4, then
(a) for every c  1 (b) for every c < 1
(c) for every c < 0 (d) for every c > –1 (a) 2 < | iz + 3 – 4i | < 8
(b) 3 < | iz + 3 – 4i | < 7
2
n 1 n1  1  (c) 1 < | iz + 3 – 4i | < 9
14. The sum of the series: C 1  C2  
2 2 (d) none of these
3 n
 1 1 ae x  b cos x  ce  x
 n  2C 3    ....  2 n  1C n   must be
2 2 18. If xlim  2 , then
0 x sin x
(a) a = c (b) c = 2
(c) a =2 (d) b = 1

[3]
19. If 1 < x < 2 , the number of solutions of sin B · sin C sin C · sin A sin A · sin B
the equation tan–1(x – 1) + tan–1x + tan–1(x (b)   <
sin A sin B sin C
+ 1) = tan–13x is sin A + sin B + sin C
(a) 0 (b) 1
sin B · sin C sin A · sin C sin A · sin B
(c) 2 (d) 3 (c)   >
sin A sin B sin C
20. The number of points of intersection of y sin A + sin B + sin C
= x and y = log(log(log x)) is sin B · sin C sin C · sin A sin A · sin B
(d)   
(a) 0 (b) 1 sin A sin B sin C
sin A + sin B + sin C
(c) 2 (d) 3
n
21. A triangle is Inscribed in a circle of radius 25. If a1, a2, ...., an are in HP and f () = a r  a
1, the maximum value of sum of the r 1

squares of the sides is a1 a2 a a

then , , 3 , ...., n are in
(a) 3 (b) 6 f (1) f ( 2) f (3) f ( n)
(c) 9 (d) 12 (a) A.P. (b) G.P.
22. If all the roots of z3 + az2 + bz + c = 0 are of (c) H.P. (d) none of these
unit modulus, then
26. A tangent to the ellipse is cut by the
(a) | a |  3 (b) | b |  3
tangents at the ends of major axis in P and
(c) | c |  1 (d) all of these
Q. A circle whose diameter is PQ, will
 
23. Non-zero vectors a and b are equally (a) pass through the foci of ellipse
 
inclined to vector c , if c is equal to
 (b) pass through the centre of ellipse

|b |  |a| 
(a)   a    b (c) pass through one end of minor axis
|a ||b | |a ||b |
  (d) none of these
|a|  |b | 
(b)   a   b
|a ||b | |a ||b | 27. If A is a skew symmetric matrix, then B =
 
|a|  |b |  (I – A)(I + A)–1 is (where I is an identity
(c)   a   b
|a |2|b | |a| 2|b | matrix of same order as of A)
(d) none of these (a) unitary matrix
24. In triangle ABC, (b) symmetric matrix
sin B · sin C sin C · sin A sin A · sin B (c) orthogonal matrix
(a)   
sin A sin B sin C
(d) none of these
sin A + sin B + sin C

[4]
28. If equation x2 + y2 + 2hxy + 2gx + 2fy + c equal to
= 0 represents a circle, then the condition (a) (k – 1)n (b) kn
for the circle to pass through three (c) (k + 1)n (d) kn+1
quadrants only is
(a) f 2 > c, g2 > c, c = 0, h = 0 30. If P 1 = 100 101 , P 2 = 101 100 , P 3 = 99 100 ,
(b) g2 > c, f 2 < c, c > 0, h = 0 P4 = 10099, then which of the following is
true
(c) f 2 > c, g2 < c, h = 0, c  0
(a) P1 > P2 > P3 > P4 (b) P1 > P3 > P2 > P4
(d) f 2 > c, g2 > c, c  0, h = 0
(c) P1 > P4 > P3 > P2 (d) none of these
n n1 nk 3 nk 2 nk1

29.   ....    n Cn k
n  nk
Cnk1 nk
n1  0 n2  0 nk 2  0 nk1  0 nk  0

n  nk1 n  nk2
Cnk 2  nk1 Cnk3 nk 2 ..... n n2 Cn1  n2 is

PHYSICS
31. In the arrangement shown, mass of the will blow when the current through it
block B and A is 2m and m respectively. reaches 5A. The switch is closed at t = 0.
Surface between B and floor is smooth. The fuse will blow :
The block B is connected to the block C by (a) just after t = 0
means of a string pulley system. If the (b) after 2s
whole system is released from rest, then (c) after 5s
find the minimum value of mass of block (d) after 10s
C so that block A remains stationary w.r.t.
33. A ball is thrown from a point on ground
B. Coefficient of friction between A and B
at some angle of projection. At the same
is  :
time a bird starts from a point directly
m 2m  1
(a) (b) above this point of projection at a height h
  1
horizontally with speed u. Given that in
3m its flight ball just touches the bird at one
(c)
 1 point. Find the distance on ground where
6m ball strikes
(d)
 1
h 2h
(a) 2u (b) u
32. In the circuit shown, the cell is ideal. The g g
coil has an inductance of 4H and zero 2h h
resistance. F is a fuse of zero resistance and (c) 2u (d) u
g g

[5]
34. Two massless string of length 5 m hang  second & B needs 4 second to
from the ceiling very near to each other as complete half revolution then; angular
shown in the figure. Two balls A and B of velocity A : B at t = 5 s are in the ratio
masses 0.25 kg and 0.5 kg are attached to (a) 4 : 1 (b) 20 : 1
the string. The ball A is released from rest (c) 80 : 1 (d) 20 : 4
at a height 0.45 m as shown in the figure. 37. The figure shows a nonconducting ring
The collision between two balls is which has positive and negative charge
completely elastic. Immediately after the non uniformly distributed on it such that
collision, the kinetic energy of ball B is 1 J. the total charge is zero. Which of the
The velocity of ball A just after the following statements is true?
collision is
(a) 5 ms–1 to the right
(b) 5 ms–1 to the left
(c) 1 ms–1 to the right
(d) 1 ms–1 to the left
(a) The potential at all the points on the
35. Cut off potentials for a metal in
axis will be zero.
photoelectric effect for light of wavelength (b) The electric field at all the points on
1, 2 and 3 is found to be V1, V2 and V3 the axis will be zero.
volts if V1, V2 and V3 are in Arithmetic (c) The direction of electric field at all
Progression then 1, 2 and 3 will be in points on the axis will be along the
(a) Arithmetic Progression axis.
(b) Geometric Progression (d) If the ring is placed inside a uniform
external electric field then net torque
(c) Harmonic Progression
and force acting on the ring would be
(d) None of these
zero.
36. Two bodies A & B rotate about an axis, 38. F = 2x2 – 3x – 2. Choose correct option
such that angle A (in radians) covered by (a) x = – 1/2 is position of stable
first body is proportional to square of time, equilibrium
& B (in radians) covered by second body (b) x = 2 is position of stable equilibrium
varies linearly with time. At t = 0, A = B (c) x = – 1/2 is position of unstable
= 0. If A completes its first revolution in equilibrium
(d) x = 2 is position of neutral equilibrium

[6]
39. In the YDSE shown the two slits are 42. Monochromatic radiation of wavelength 
covered with thin sheets having thickness is incident on a hydrogen sample in
t & 2t and refractive index 2 and . Find ground state. Hydrogen atoms absorb the
the position (y) of central maxima light and subsequently emit radiations of
(a) zero ten different wavelengths. The value of 
tD is
(b)
d (a) 95 nm (b) 103 nm
tD (c) 73 nm (d) 88 nm
(c) 
d
(d) None of these 43. A light semi cylindrical gate of radius R is
pivoted at its mid point O, of the diameter
40. An observer starts moving with uniform as shown in the figure holding liquid of
acceleration 'a' towards a stationary sound density . The force F required to prevent
source of frequency f. As the observer the rotation of the gate is equal to
approaches the source, the apparent (a) 2R 3 g
frequency f' heard by the observer varies (b) 2gR3 l
with time t as:
2 R 2 l g
(c)
3
(d) none of these
(a) (b)
44. At time t = 0, N1 nuclei of decay constant
1 & N2 nuclei of decay constant 2 are
mixed . The decay rate of the mixture at
(c) (d)
any time t is:
    t
(a) N1 N 2 e 1 2
41. The ratio of period of oscillation of the
conical pendulum to that of the simple  N     t
(b)   1 e 1 2
pendulum is : (Assume the strings are of  N2 
the same length in the two cases and  is
the angle made by the string with the

(c)  N11e  1 t  N 2  2 e   2 t 
1  2  t
vertical in case of conical pendulum) (d)  N11 N22 e
(a) cos  (b) cos 
(c) 1 (d) none of these

[7]
45. A body is projected horizontally from the (a) when the extension of the spring is
surface of the Earth (radius = R) with a maximum the velocities of A and B
velocity equal to ‘n’ times the escape are zero.
velocity. Neglect rotational effects of the (b) the maximum extension of the spring
earth. The maximum height attained by is 25 cm.
the body from the Earth’s surface is R/2. (c) maximum extension and maximum
Then, ‘n’ must be compression occur alternately.
(a) 0. 6 (b)  3 2 (d) the maximum compression occur for

(c) 0. 4 (d) None of these the first time after second
56
46. A capacitor C = 100 F is connected to three
48. A ray of light is incident at an angle of 75°
resistor each of resistance 1 k and a
into a medium having refractive index .
battery of emf 9 V. The switch S has been
The reflected and the refracted rays are
closed for long time so as to charge the
found to suffer equal deviations in oppo-
capacitor. When switch S is opened, the
site direction then  equals
capacitor discharges with time constant
3 1 3 1
(a) 33 ms (a) (b)
3 1 2
(b) 5 ms
2 2
(c) 3.3 ms (c) (d) None of these
3 1
(d) 50 ms
49. The equation of a wave disturbance is
47. Two blocks A (5 kg) and B(2 kg) attached
 
to the ends of a spring of force constant given as : y = 0.02 cos   50t  cos (10x),
2 
1120 N/m are placed on a smooth
where x and y are in meter and t in second.
horizontal plane with the spring
Choose the INCORRECT statement.
undeformed. Simultaneously velocities of
(a) Antinode occurs at x = 0.3 m
3 m/s and 10 m/s along the line of the
(b) The wavelength is 0.2 m
spring in the same direction are imparted
(c) The speed of the constituent waves is
to A and B as shown then
4 m/s
(d) Node occurs at x = 0.15 m

[8]
50. A resistance coil connected to an external (a) from P to Q
battery is placed inside an adiabatic (b) from Q to P
cylinder fitted with a frictionless piston
(c) heat does not flow
and containing an ideal gas. A current i
flows through the coil which has a in PQ
resistance R. At what speed must the (d) data not sufficient
piston move upward in order that the
53. A metal ball of radius R is placed
temperature of the gas remains
concentrically inside a hollow metal
unchanged? Neglect atmospheric
sphere of inner radius 2R and outer radius
pressure.
3R. The ball is given a charge +2Q and the
i 2m hollow sphere a total charge – Q. The
(a)
Rg electrostatic potential energy of this system
is :
Rmg 3R
(b) 7Q 2 2R
i2 (a) R
24 R 0
mg i 2R 5Q 2
(c) (d) (b)
i2 mg 160 R
51. Power factor of an L-R series circuit is 0.6 5Q 2
(c) (d) none of these
and that of a C–R series circuit is 0.5. If the 80 R
element (L, C, and R) of the two circuits 54. A charged particle of specific charge  is
are joined in series the power factor of this released from origin at time t = 0 with

circuit is found to be 1. The ratio of the velocity V  Vo î  Vo ĵ in magnetic field
resistance in the L-R circuit to the 
B  Bo î . The coordinates of the particle at
resistance in the C–R circuit is 
time t  are (specific charge = q/m)
(a) 6/5 (b) 5/6 Bo 
4 3 3  Vo 2Vo  Vo 
(c)
3 3
(d)
4 (a)  2B  , B , B  
 o o o 
52. Three identical rods AB, CD and PQ are   Vo 
(b)  2B  , 0, 0 
joined as shown. P and Q are mid points  o 
of AB and CD respectively. Ends A, B, C  2Vo Vo  
and D are maintained at 0°C, 100°C, 30°C (c)  0, B  , 2B  
 o o 

and 60°C respectively. The direction of  Vo  2Vo 

heat flow in PQ is (d)  B  , 0,  B  , 
 o o 

[9]
55. The dimensional formula for the physical rate of water from the tap must be about
E 2 0  0 (a) 2.2 litre/min (b) 4.9 litre/min
quantity is (E = electric field and
B2 (c) 0.5 litre/min (d) 7.6 litre/min
B = magnetic field)
59. OABC is a current carrying square loop,
(a) L0 M0 T0 (b) L1 M0T–1
an electron is projected from the centre of
(c) L–1 M0 T1 (d) L 1/2 M0T–1/2
loop along its diagonal AC as shown. Unit
56. In the circuit shown, what is the potential vector in the direction of initial accelera-
difference VPQ?
(a) + 3V tion will be
(b) + 2V (a) k̂
(c) –2V
 î  ĵ 
(d) none of these   
(b)  2
 
57. Two masses m and M are attached to the
(c) – k̂
strings as shown in the figure. If the system
is in equilibrium, then î  ĵ
(d)
2
2M
(a) tan = 1 +
m 60. Two billiard balls undergo a head-on
2m collision. Ball 1 is twice as heavy as ball 2.
(b) tan = 1 +
M Initially, ball 1 moves with a speed v
2M towards ball 2 which is at rest.
(c) cot = 1 +
m Immediately after the collision, ball 1
2m travels at a speed of v/3 in the same
(d) cot = 1 +
M direction. What type of collision has
occured?
58. A laminar stream is flowing vertically
(a) inelastic
down from a tap of cross-section area
(b) elastic
1 cm2. At a distance 10 cm below the tap,
(c) completely inelastic
the cross-section area of the stream has (d) Cannot be determined from the
reduced to 1/2 cm2. The volumetric flow information given

[10]
 CHEMISTRY

61. By how much would the oxidising power (b) A and B are identical mixtures of
of the MnO4–Mn2+ couple change if the H+ CH3OH and (CH3)3C—I
ions concentration is decreased 100 times? (c) A is mixture of CH3I and (CH3)3C—
(a) Increases by 189 mV OH; B is a mixture of CH 3OH and
(b) Decreases by 189 mV (CH3)3C—I
(c) Increases by 19 mV (d) None of these
(d) Decreases by 19 mV 65. Which of the following will react with
62. In an fcc arrangement of A and B atoms, acetone to give a product containing
where A atoms are at the corners of the C = N–?
unit cell, B atoms at the face centers, two (a) C6H5NH2 (b) (CH3)3N
atoms are missing from two corners in (c) C6H5·NHC6H5 (d) C6H5NHNH2
each unit cell, then the simplest formula
66. What volume at NTP of ammonia gas will
of the compound is
be required to be passed into 30 mL of N
(a) A7B6 (b) A6B7
H2SO4 to bring down the acid normality
(c) A7B24 (d) AB4 to 0.2N?
63. The enthalpy of combustion of H2(g) at 298 (a) 556.5 mL (b) 480.5 mL
K to give H2O is –298 kJ mol–1 and bond (c) 537.6 mL (d) 438.4 mL
enthalpies of H–H and O = O are 433 kJ
67. What is A in the following reaction?
mol–1 and 492 kJ mol–1, respectively. The
bond enthalpies of O–H is Et2CO + NaCN +NH4Cl 
NH OH
A 4

(a) 464 kJ mol–1 (b) 488.5 kJ mol–1

(a)
(c) 232 kJ mol–1 (d) –232 kJ mol–1
conc.HI
64. B(mix) 2
 (CH 3 ) 2 C—O—CH 3
(b)
anhydrous.HI
 I
  A (mix)
(a) A and B are identical mixtures of CH3I (c)
and (CH3)3C—OH
(d) No reaction takes place

[11]
68. Among the following species identify the (d) Product I is the isomer of dimethyl
isostructural pairs: ether, while Product II is the
NF3, NO3–, BF3 H3O+, HN3 dehydrated compound of Product I.
(a) [NF3, NO3– and [BF3H3O+] 72. How many chlorine atoms can you ionize
–
(b) [NF3, HN3] and [NO3 , BF3] in the process Cl  Cl + + e–, by the
(c) [NF3, H3O+] and [NO3–, BF3] energy liberated from the following
(d) [NF3, H3O+] and [HN3, BF3] process?
Cl + e–  Cl– for 6 × 1023 atoms
69. Lanthanoid ion which is most likely to be
reduced by Cr(+II) is Given electron affinity of Cl = 3.61 eV, and
(a) Sm (b) Yu IP of Cl = 17.422 eV.

(c) Yb (d) All of these (a) 1.24 × 1023 atoms

(b) 9.82 × 1020 atoms
70. The reaction; 2O3  3O2, is assigned the
following mechanism. (c) 2.02 × 1015 atoms
(d) None of these
(I) O3 O2 + O
73. 0.5 g of fuming H2SO4 (oleum) is diluted
(II) O3 + O Slow
 2O2
with water. This solution is completely
The rate law of the reaction will therefore
neutralised by 26.7 ml of 0.4 N NaOH. The
be
(a) r  [O3]2[O2] (b) r  [O3]2 [O2]–1 percentage of free SO3 in the sample is
(c) r  [O3] (d) r  [O3] [O2]–2 (a) 30.6% (b) 40.6%

71. Product I  (c) 20.6% (d) 50%

 C 2 H 5 Br 
aq KOH alc KOH

Product II 74. The half-life of a first order reaction is 24
(a) Product I is obtained by the hours. If we start with 10 M initial
elimination reaction. concentration of the reactant, then the
(b) Product II is obtained by the concentration after 96 hours will be
substitution reaction.
(a) 6.25 M (b) 1.25 M
(c) The molecular formula of Product I is
(c) 0.125 M (d) 0.625 M
C2H4, while the molecular formula of
Product II is C2H6O.

[12]
75. The principal organic compound formed O
in the following reaction is ||
79. HO  CH 2 CH2 CH 2  C  OH on reaction
CH2 = CH(CH2)COOH + HBr  Peroxide
with H+ forms
(a) CH 3  CH (CH3 )8 COOH
|
Br (a) (b)
(b) CH2 = CH(CH2)8COBr

(c) CH 2  CH 2 (CH2 )8 COOH

| (c) (d)
Br

(d) CH 2  CH(CH 3 )7  CH COOH 80. Consider the following acids:

| (1) o-CH3OC6H4COOH;
Br
(2) o-HO C6H4COOH;
76. Sec. butyl chloride will undergo alkaline
(3) C6H5COOH
hydrolysis in the polar solvent by
hydrolysis Arrange the acids in the decreasing order
of their acidity.
(a) SN2 (b) SN1
(a) 2 > 1 > 3 (b) 2 > 3 > 1
(c) SN1 and SN2 (d) None of these
(c) 1 > 2 > 3 (d) 3 > 1 > 2
77. A solution of sodium sulphate in water is
electrolysed using inert electrodes. The 81. How many enantiomers pairs are
products at cathode and anode are, produced by the monochlorination of
respectively, 2-methyl-2-butane?

(a) H2, O2 (b) O2, H2 (a) 1 (b) 2

(c) O2, Na (d) O2, SO2 (c) 4 (d) 6

78. Which of the following compounds yields 82. 20 mL of a weak acid HX is titrated against
only one product on monobromination? 0.1 M NaOH. At the point of half
equivalence the pH of solution is 5.7.
(a) Neopentane (b) Toluene
Hence, Ka of acid is
(c) Phenol (d) Aniline
(a) 7.0 × 10–5 (b) 2.0 × 10–5
(c) 7.0 × 10–4 (d) 2.0 × 10–6

[13]
83. The number of isomers possible for C4H8 87. The conjugate acid of HPO42– is
are (a) PO 4 3– (b) H2 PO4 –
(a) 4 (b) 3 (c) H3 PO4 (d) HPO3 –
(c) 2 (d) 5
88. Blister copper is obtained by
84. The oxide which cannot act as a reducing (a) bessemerisation (b) roasting
agent is (c) poling (d) refining
(a) NO2 (b) SO2
89. The ion that connot be precipitate by both
(c) CO2 (d) ClO2 HCl & H2S is
(a) Pb+2 (b) Cu+
85. For reaction A(g) + B(g) AB(g), we
(c) Ag+ (d) Sn+2
start with 2 moles of A and B each. At
equilibrium, 0.8 moles of AB is formed. AgOH
 CH 3  I P Q
Then how much of A changes to AB? excess
90. N
(a) 20% (b) 40% H

(c) 60% (d) 4% 

R . R is
86. The pH of a buffer solution changes from
6.20 to 6.17 when 0.003 mole of acid is
added to 500 mL of the buffer. The buffer (a) N (b) N
capacity of the system is, therefore, CH3 CH3 CH3 CH3
(a) 0.1 (b) 0.3
(c) 0.2 (d) 0.4

(c) N (d) N
Me Me Me Me

[14]
 TEST SERIES : TEST-12
(JEE MAINS PATTERN)

Time : 3 hrs. M.M. : 360

ANSWERS
Mathematics
1. (b) 2. (a) 3. (c) 4. (c) 5. (a)
6. (b) 7. (b) 8. (a) 9. (a) 10. (c)
11. (b) 12. (d) 13. (c) 14. (d) 15. (d)
16. (c) 17. (c) 18. (a) 19. (a) 20. (a)
21. (c) 22. (d) 23. (a) 24. (d) 25. (c)
26. (a) 27. (c) 28. (a) 29. (c) 30. (a)

Physics
31. (c) 32. (d) 33. (c) 34. (d) 35. (c)
36. (c) 37. (a) 38. (a) 39. (b) 40. (a)
41. (b) 42. (a) 43. (d) 44. (c) 45. (a)
46. (d) 47. (c) 48. (b) 49. (c) 50. (d)
51. (d) 52. (a) 53. (a) 54. (d) 55. (a)
56. (b) 57. (a) 58. (b) 59. (b) 60. (b)

Chemistry
61. (b) 62. (d) 63. (b) 64. (c) 65. (d)
66. (c) 67. (a) 68. (c) 69. (d) 70. (b)
71. (d) 72. (a) 73. (c) 74. (d) 75. (c)
76. (b) 77. (a) 78. (a) 79. (a) 80. (a)
81. (b) 82. (d) 83. (d) 84. (c) 85. (b)
86. (c) 87. (b) 88. (a) 89. (d) 90. (a)

[15]
 TEST SERIES : TEST-12
(JEE MAINS PATTERN)
HINTS/SOLUTIONS
Time : 3 hrs. M.M. : 360

Mathematics
A C
cos
 s 1  s3  2 2
1  m  M 
1. (b): tan–1  1  s   tan   1  3   0 cos
A C
 2    2
2. (a): Conceptual.
A C 1
 tan tan 
3. (c): Conceptual. 2 2 3
4. (c): dm3 – 3m2 + 3m + 3 = 0 sb 1
  2x = 3b a + c = 2b
3 s 3
given m1m2m3 = 
d 16. (c): b2sin4x + a2cos4x – 2ab sin2x cos2x = 0
3  (b sin2x – a cos2x)2 = 0
 m3 =
d
sin 2 x cos 2 x sin 2 x  cos 2 x
then d = –3   
a b ab
5. (a): |k| < 2
sin 6 x a cos6 x b
  , 
6. (b): Conceptual. a 2
( a  b)3
b 2
( a  b )3
7. (b): q2 – 4pr < 0 and p + r > 0
17. (c): 5 – 4 < |iz + 3 – 4i| < 5 + 4
 p, r > 0
18. (a): a – b + c = 0 ...(i)
f (–1) > 0  p – q + r > 0
ae x  b sin x  ce  x
lim 2
8. (a): 9 –2 ( a .b  b .c  c .a )  9  3 x0 2x
9. (a): Conceptual. a–c=0 ...(ii)
10. (c): x1 + x2 + .... + xn = m 1 2x 1 2x
19. (a): tan 1  ( x 2  1)  tan 1  3x 2
11. (b): Conceptual.
12. (d): Conceptual.  2x = 0 or 1 – x2 = 2 – x2

13. (c): 1 + ex = ex – c for sol. – c> 0  c < 0  2x2 = –1

14. (d): Put n = 2 20. (a): x = log log log (x)

21. (c): Considering a = b = c.
AC A C B
15. (d): 2cos cos = 4 sin2
2 2 2 22. (d): |a|  |z1|+|z2|+|z3 |
 |a|  3

[16]
23. (a): If c is angle bisector 2h
R = uT = 2u g
24. (d): Put A = 30°, B = 60°, C = 90°

n 34. (d): mA = 0.25 kg, mB = 0.5 kg

a
 ar
 r 1
1 uA = 2gh = 3 m/s; uB = 0
25. (c): n n
 ar  a  ar  a  mA  mB  0.25
r 1 r 1
vA =  m  m  uA   0.75  3
 A B 
26. (a): x2 + (y – b)2 = a2
27. (c): BT = (I –A)–1 (I + A) = –1 m/s

then BBT = I hc
35. (c): eV0 = 

28. (a): f2 > c, g2 > c
hc
29. (c): Conceptual.  = eV  
0
30. (a): Let f (x) = x1/x.
V1, V2, V3 in A.P.
 eV1, eV2, eV3 also in A.P.
Physics  eV1 + , eV2+ , eV3+  in A.P.
31. (c): mg = µma eV1   eV2   eV3  
 , , in A.P.
hc hc hc
g
a=
 hc hc hc
 eV   , eV   , eV   , in H.P.
Let mass of C is M, 1 2 3

g Mg 1, 2, 3 in H.P.

a= 
 3m  M 36. (c): Let A = at2 and B = bt
3m For A, A = 2, t =  s
 M
1
a=2
di For B, B =, t = 4 s
32. (d): L 2
dt
 b = 1/4
5 t
d A d
 4 di   2 dt A   2 at ; B  B  b
0 0 dt dt
20 = 2t  t = 10 s A 225

33. (c): The horizontal component of velocity of  
B t 5 s
1 / 4 = 80
projectile is also u. And it touches the
37. (a): Potential due to positive and negative
bird at its highest point.
charge will have same magnitude and
2 2 2
u sin  T g opposite sign.
h= 
2g 8
38. (a): F = 2x2 – 3x –2
8h F = (2x + 1) (x –2)
 T g
du
F=  = (2x + 1) (x –2)
dx

[17]
 du 1 43. (d): The net force due to liquid will pass
= 0  x =  and 2
dx 2 through centre O at the gate, therefore
no rotation of gate due to hydrostatic
d2 u
 (4 x  3) force.
dx 2
44. (c): After time t,
1
= + 5 at x = 
2 N1 = N 1 e 1t
= – 5 at x = 2
N'2  N 2 e 2 t
1
 u is minimum at x =  and dN
2  = 1N1 + 2N2
dt
maximum at x = 2.
45. (a): u = n 2 gR
{t1 (1  1)  t2 ( 2  1)}D
39. (b): = shift By conservation of angular momentum
d
{t1 (2  1)  2t(  1)} D  R
shift = muR = mv  R  
d  2

tD 2u 2n
= v  2 gR
d 3 3
40. (a): v0 = at By conservation of energy

 v  at  R
f ' mg
f 1
m( u2  v 2 )  2
 v  R
2 1
41. (b): For conical pendulum, 2R

v= rg tan  solving we get,

n  0.6
2 r r
T1 =  2 46. (d): = Req C
v g tan 
= 0.5 × 103 × 100 × 10–6
l
T1 = 2  = 0.05 s = 50 ms
g cos 
47. (c): Conceptual.
l 48. (b): Deviation in reflection
T2 = 2 
g
= 180 – 2 × 75 = 30°
 T1 : T2 = cos  : 1 Deviation in refraction = 30°
n( n  1)  i – r = 30°
42. (a):  10
2 75° – r = 30°
n=5
r = 45°
 1 1  12400
13.6  2  2   µ sin 45° = 1 sin 75°
1 5  
3 1
13.6  24 12400 solving we get, µ =
 2
25 
49. (c): A = 0.02 cos (10 x)
 = 949.75 Å  95 nm

[18]
 at x = 0.3 
 = t = B0 × B 
A = 0.02 cos (3)= –0.02 0

 it is antinode. =

2 Charged particle rotate in Y – Z plane,

k = 10  =  = 0.2 m
 mV V0
 r  qB  B
 50 0 0
v= = = 5 m/s
k 10 
V0 
50. (d): Q = W x = V0t = B 
0
i2Rdt = mgvdt
 E 2  0 0   2 1 
2
i R 55. (a):  2   c  2 
v=  B   c 
mg
= [L°M°T°]
51. (d): XL = XC = X (say)
6
R1 56. (b): Current through 2 V battery (i1) = =2A
3 3
0.6  R1  X
R12 X 2
4
5
Current through 1 V battery (i2) = = 1A
R2 5
X
0.5 =  R2 
R22  X2 3 VPQ = VP – VQ = –2 + 4 = 2V.
57. (a): 2T1 sin45° = mg
R1 3 3
 
R2 4 mg
T1 =
2
52. (a): P will be at higher temperatures than Q
T2 cos  = T1 sin 45°
when PQ rod will not there.
mg
53. (a): Charge on outer surface of ball = 2 Q. T2 cos  =
2
Charge on inner surface of thick shell
mg
= – 2Q. T2 =
2 cos 
 charge on outer surface of thick shell T1 cos 45° + Mg = T2 sin 
=Q mg mg tan 
 Mg 
4Q 2 4Q 2 Q2 2 2
U  
80 R 8 0 (2 R ) 8 0 (3 R ) 2M
 tan  = 1 
m
4Q 2 2Q 2 2Q 2
   58. (b): A1v1 = A2v2
8 0 (2 R ) 4 0 (3 R ) 4 0 (3 R)
1
7Q 2 1 × v1 = v2
U 2
24 0 R
v2 = 2v1
54. (d):  = B0 1
gh = ( v22  v12 )
in time t, 2
2gh = 3v12

[19]
 2 is its oxidising power. Hence, the
v1 = gh
3 oxidising power decreases by 0.189 V.
volumetric rate of flow 62. (d): Since there are six atoms (a) in the corner
of the unit cell, the contribution of atoms
2 4
= A1v1 = 1  10   10  0.1 in 1 unit cell is 6/8.
3
= 0.816 × 10–4 m3/s Since 3 face-centered atoms (b)
= 4.9 lit/min contribute to one unit cell, the formula

59. (b): Force will be along centre to O. is A6/8B3 or A6B24 or AB4.

60. (b): 2m  v m 63. (b): H2 + 1/2O2  H2O + H

= –298 kJ mol–1
v
2m  m  v
3  1 
 H  HH H   HO=O   [2  HO  H ]
 2 
 m1  em2 
v1 =  m  m v
 1 2   1 
298   433   492   [2  HO H ]
 2 
v  2m  em 
 v 433  246  298
3  2m  m 
HO – H =
2
e=1
= 488.5 kJ mol–1
Anhy.HI
64. (c): (CH 3 ) 2 C – PCH 3   CH 3 I +
Chemistry
(CH3)3C – OH
61. (b): MnO4– + 5e– + 8H+  Mn2+ + 4H2O
Conc.HI
(CH) 2 C – OCH 3   CH 3 OH +
According to nernst equation.
(CH3)3C – I
0.059  [Mn 2+ ] 
Ered = E°red – log   + 8
5  [MnO 4 ][H ]  65. (d): 

Let [H+]initial = X
Ered(initial) =

0.0591  [Mn 2+ ] 
66. (c): Meq. of H2SO4 (original) = 30 ×1 = 30
Eored log   + 8
5  [MnO 4 ][H ] 
Meq. of H2SO4 after passing
X X NH3 = 30 × 0.2 = 6
[H+]final = = 2
100 10
Meq. of H2SO4 reacted = Meq. of NH3
Ered(final = Ered° =
= 30 – 6 = 24
0.0591 [Mn 2+ ]× 1016
Eored log WNH 3
5 [MnO 4 ]  [X]8  × 1000 = 24,  WNH 3 =0.408 gm
17
0.0591 0.408
Ered(final) – Ered(initial) = log 1016  VNH3 at STP =  22.4
5 17
= –0.1891 V = 0.5376 liters = 537.6 mL
This E red decreases by 0.189 V. The
tendency of the half cell to get reduced

[20]
67. (a): (0.5  x ) x
  1000   1000
98 / 2 80 / 2
= 26.7 × 0.4
 x = 0.103

0.103
% of SO3 =  100 = 20.6%
0.5
74. (d): Number of half-lives = 96/24 = 4
68. (c): NF3 and H3 O+ have sp 3 hybridisation;
Concentration remaining after 96 hrs
NO3– and BF3 have sp2 hybridisation.
= 10/(2)4 = 0.625 M
69. (d): All of them on being reduced will get
either stable half filled orbitals or stable 75. (c): This follows the peroxide effect.
completely filled orbitals. HBr
 CH2 = CH(CH2)8COOH  
Peroxide
70. (b): Step II, being r.d.s.
CH 2  CH 2 (CH2 )8 COOH
Rate of overall reaction = Rate of Step II |
Br
= KII [O3][O]
Putting the value of [O] from the 76. (b): Polar medium sec. alkyl halide
equilibrium of undergoes SN1 mechanism.

Step I, we get 77. (a): Na+ ions are not reduced at cathode and
SO42– ions are not oxidized at anode.
2
K II K C [O 3 ]
Rate = Cathode: 2H2(l)  O2(g) + 4H+(aq) + 4e–
[O 2 ]
aq KOH
Anode: 2H2O(l) + 2e– H2(g)+2OH– (aq)
71. (d): C2H5Br   C2H5OH (Product I)
(Nucleophilic substitution reaction) CH3
|
aq KOH
C2H5Br   C2H4 (Product II) 78. (a): CH 3  C  CH3 has twelve equivalent
|
(elimination reaction) CH3

C 2 H 5 OH (Product I) is isomer of 1°H. Hence, H forms only one product

CH3OCH3 . on monobromination.
dehydration
C2H5OH   C 2H 4
72. (a): Energy released in conversion of 6 × 1023 H 

79. (a): 

H O

atoms of Cl– ions = 6 × 1023 × electron 2

affinity
80. (a): Both ortho-substituted acids are stronger
= 6 × 1023 × 3.61 = 2.166 × 1024 eV
than benzoic acid due to ortho effect.
Let x Cl atoms be converted to Cl+ ion.
Salicylic acid is strongest because of
Energy absorbed = x × ionization energy intermolecular H-bonding.
24
 x × 17.422 = 2.166 × 10
CH3
 x = 1.243 × 1023 atoms |
81. (b): CH 3  CH  CH 2  CH 3 ; it has four sets of
73. (c): Meq. of H2SO4 + Meq. of SO3 = Meq. of
equivalent hydrogens which result in the
NaOH

[21]
 formation of four different oxidation number of C is +4, which
monochlorination product. When cannot be further increased. Hence, CO2
chlorination takes place at first and cannot act as reducing agent.
second carbon, this results in the
85. (b): A(g) + B(g) AB(g)
formation of a racemic mixture.
Initial moles: 2 2 0
82. (d): At the point of half neutralization the
mixture will be an acid buffer with at equilibrium: 2–x 2–x x = 0.8

[salt] 0.8
 % of A Changed to AB =  100
[acid] = 1 2

pH = pKa + log1 = 40%

 pKa = 5.7 86. (c): Buffer capacity

No.of molesof acid added perliere of buffer
Ka = 2.0 × 10–6 = Changein pH

83. (d): 0.006

=  0.2
0.03
87. (b): Conjugate acid and base differ by one
proton. Hence, the conjugate acid of
HPO42– is H2PO4–.
88. (a):
84. (c): Reduction is accompanied by an
89. (d):
increase in oxidation number of the
reducing agent. C belong to IVA group, 90. (a): Hofmann elimination reaction.

so the maximum O.N. is +4. In CO2, the

[22]