Class 12th JEE

MRJM/12 Milestone Test-0 Phase-2

DURATION: 180 Minutes DATE: 09/06/2024 M.MARKS: 300

Topic Covered

Physics : Electric Charges and Fields

Chemistry : Solutions, Electrochemistry
Mathematics : Determinants, Matrices

GENERAL INSTRUCTION
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 3 hours duration.
3. The test booklet consists of 90 questions. The maximum marks are 300.
4. There are three sections in this question paper. Sections I, II and III, are of Physics, Chemistry and
Mathematics, respectively. Each section consists of 30 questions, of which the first 20 are mandatory and
are of Multiple Option type and the last 10 are of integer answer type. You need to attempt any 5 integer
type questions (out of 10) in each of the three sections.
5. There is only one correct response for each question.
6. Each correct answer will give 4 marks while 1 Mark will be deducted for a wrong response.
7. No student is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone,
any electronic device, etc. inside the examination room/hall.
8. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
 SECTION-I (PHYSICS)
Single Correct Type Questions (1-20) 5. A comb run through one’s dry hair attracts small
1. A thin conducting ring of radius R is given a bits of paper. This is due to
charge +Q. The electric field at the centre O of the (1) Comb is good conductor
ring due to the charge on the part AKB of the ring (2) Paper is good conductor
is E. The electric field at the centre due to the (3) The atoms in the paper get polarized by the
charge on the part ACDB of the ring is charged comb
(4) The comb possesses magnetic properties

6. The electric field due to an electric dipole at a

distance r from its centre in axial position is E . If
the dipole is rotated through an angle of 90° about
its perpendicular axis, the electric field at the same
point will be
(Note: r is very larger than dipole length)
(1) E along KO (2) 3  along
E OK E
(3) 3  along
E KO (4) E along OK (1) E (2)
4
E
2. Two charges of equal magnitudes and at a distance (3) (4) 2E
2
r exert a force F on each other. If the charges are
halved and distance between them is doubled, then 7. Three infinitely large non conducting charged
the new force acting on each charge is sheets are placed as shown in figure. The electric
(1) F /8 (2) F /4 field at point P is
(3) 4 F (4) F /16 z

3. A pendulum bob of mass 30.7 × 10−6 kg and

carrying a charge 2 × 10−8 C is at rest in a
N
horizontal uniform electric field of 20000 . The
C
tension in the thread of the pendulum will be
(
approximately g = 9.8 m/s 2 ) 2σ 2σ ˆ
(1) k̂ (2) − k
ε0 ε0
4σ 4σ ˆ
(3) k̂ (4) − k
ε0 ε0

(1) 3 × 10−4 N (2) 4 × 10−4 N 8. An electron is moving around the nucleus of a

(3) 5 × 10−4 N (4) 6 × 10−4 N hydrogen atom lying at rest at origin in a circular

orbit of radius r. The coulomb force F

4. One of the following is not a property of field lines experienced by electron ( r is position vector of
(1) Field line between a positive and a negative 1
electron and K = ).
charge is a continuous curve without any 4πε0
break.
e2 e2 
(2) Two field lines cannot cross each other (1) − K 3
rˆ (2) K r
(3) Field lines start at positive charge and end at r r3
negative charge e2  e2
(3) − K r (4) K rˆ
(4) They form closed loop r3 r3
 
9. The torque acting on a dipole of dipole moment P ρr ρR
 (3) (4)
in an electric field E is ε0 ε0
   
(1) P.E (2) P × E
  14. A spherical portion is removed from a solid non
(3) Zero (4) E × P
conducting uniformly charged solid sphere as
10. Let there be a spherically symmetric charge shown in the figure. The electric field inside the
distribution with charge density varying as empty space is

5 r 
ρ(r ) = ρ0  −  upto r = R, and ρ ( r ) = 0
4 R
for r > R, where r is the distance from the origin.
The electric field at a distance r (r < R ) from the
origin is given by (1) Zero everywhere
4πρ0 r  5 r  ρ0 r  5 r  (2) Non-zero and uniform
(1)  −  (2)  −  (3) Non-uniform
3ε0  3 R  4ε0  3 R 
(4) Zero only at its centre
4ρ0 r  5 r  ρ0 r  5 r 
(3)  −  (4)  −  Electric point charges 𝐴𝐴 and 𝐵𝐵 repel each other.
3ε0  4 R  3ε0  4 R  15.
Electric point charges 𝐵𝐵 and 𝐶𝐶 also repel each

11. The direction of electric field intensity E at a ( ) other. If 𝐴𝐴 and 𝐶𝐶 are held close together, they will
(1) Attract
point on the equatorial line of an electric dipole of
 (2) Repel
dipole moment ( p ) is (3) Not affect each other
(1) Along the equatorial line towards the dipole (4) None of these
(2) Along equatorial line away from the dipole
(3) Perpendicular to the equatorial line and 16. A thin glass rod is bent into a semicircle of radius

opposite to ( p ) 𝑟𝑟. A charge +Q is uniformly distributed along the
upper half and a charge –Q is uniformly distributed
(4) Perpendicular to the equatorial line and
 along the lower half, as shown in Fig. The electric
parallel to ( p )
field 𝐸𝐸 at 𝑃𝑃, the centre of the semicircle, is

12. Three charges q1 = 1×10–6C, q2 = 2×10–6C and

q3 = –3×10–6 have been placed as shown. Then, the
net electric flux will be maximum for which of the
shown gaussian surface.
S2

S1 Q 2Q
S3 (1) (2)
q1 π ε0 r
2 2
π ε0 r 2
2
q2
q3
4Q Q
(3) (4)
π ε0 r
2 2
4π ε 0 r 2
2

(1) S1 (2) S2
17. Two point charges q1 (10µC ) and q2 ( −25µC ) are
(3) S3 (4) Same for all three
placed on the x-axis at x = 1 m and x = 5 m ,
13. An insulated solid sphere of radius R has uniform respectively. The electric field vector (in N/C) at
charge density ρ. The electric field at a distance r  1 
origin.  Take, = 9 × 109 N − m 2 C−2 
from the centre of the sphere (r < R)  4πε0 
ρr ρR
(1) (2) (1) −81 × 103 iˆ (2) 81 × 103 iˆ
3ε 0 3ε 0
(3) 27 × 103 iˆ (4) −27 × 103 iˆ

[3]
18. Two charges, each equal to q, are kept fixed at between q1 and q3 is F13, the ratio of magnitudes of
x = –a and x = a on the x-axis. A particle of mass F12
q forces is x. Find x.
𝑚𝑚 and charge q0 = − is placed at the origin. If F13
2
charge q0 is given a small displacement y(y << a)
23. If the linear charge density of a cylinder is 4µCm–1
along the y-axis, the net force acting on the particle of radius 2 cm then electric field intensity at point
is proportional to 3.6 cm from axis is n×106 NC–1. Find n.
(1) y2 (2) –y
1 1 24. A point charge +q is placed at the centre of a cube
(3) 2
(4) –
y y of side a. The electric flux emerging from the cube
x q
is . Find x.
19. Statement 1: If a proton and an electron are 5 ε0
placed in the same uniform electric field. They
experience different acceleration 25. Four charges +Q, −Q, +Q, −Q are placed at the
Statement 2: Electric force on a test charge is
corners of a square taken in order. At the centre of
independent of its mass
N
(1) Statement 1 is True, Statement 2 is True; the square electric field is k . Find k.
Statement 2 is correct explanation for C
Statement 1
(2) Statement 1 is True, Statement 2 is True; 26. When the distance between two charged particles
Statement 2 is not correct explanation for is halved, the force between them becomes x times
Statement 1 the initial force. Find x.
(3) Statement 1 is True, Statement 2 is False
(4) Statement 1 is False, Statement 2 is True 27. A sample of HCl gas is placed in a uniform electric
field of 3 × 104 NC−1 . The dipole moment of each
20. Determine the electric dipole moment of the HCl molecule is 6 × 10−30 Cm. The maximum
system of three charges, placed on the vertices of torque that can act on a molecule is x × 10–26 Nm.
an equilateral triangle of length  , as shown in the Find x.
figure :
28. A square surface of side L is in the plane of the

paper. A uniform electric field E , also in the plane
of the paper, is limited only to the lower half of the
square surface, (see figure). The electric flux
associated with the square surface is xEL2 . Find x.

(1) 2q ˆj (2) −2q ˆj

E
(3) 2 q ˆj (4) − 3 q ˆj

Integer Type Questions (21-30) 29. A point charge q produces an electric field of
magnitude 2NC–1 at a point 0.25 m from it. The
21. Three charges 1µC, 1µC and 2µC are kept at
x
vertices A, B and C of an equilateral triangle ABC value of charge is × 10−11 C. Find x.
of side 10 cm respectively. The resultant force on 18
the charge at C is x 3 N. Find 10 x. 30. A cylinder of length L and radius b has its axis
coincident with the x-axis (positive towards right).
22. Three equal charges q1, q2, q3 are placed on the 
The electric field in this region is E = 200iˆ . The
three adjacent corners of a square taken in that
flux through the left end of cylinder is yπb2. Find
order. If the force between q1 and q2 is F12 and that
(y + 200). (Assume SI units)
[4]
 SECTION-II (CHEMISTRY)
Single Correct Type Questions (31-50) 37. The standard electrode potential for the reaction
31. If Raoult’s law is obeyed, the vapour pressure of Ag+ (aq) + e– → Ag(s)
the solvent in a solution is directly proportional to Sn2+(aq) + 2e– → Sn(s)
(1) Mole fraction of the solvent at 25°C are 0.80 volt and – 0.14 volt, respectively.
(2) Mole fraction of the solute The emf of the cell.
(3) Mole fraction of the solvent and solute Sn | Sn2+(1M) | | Ag+(1M) | Ag is:
(4) The volume of the solution (1) 0.66 volt (2) 0.80 volt
(3) 1.08 volt (4) 0.94 volt
32. What is the mole ratio of benzene (PB0 = 150 torr)
and toluene (PT0 = 50 torr) in vapour phase if the 38. The reduction electrode potential E(in V), of 0.1
given solution has a vapour pressure of 120 torr? M solution of M+ ions (E°RP = – 2.36 V) is:
(1) 7 : 1 (2) 7 : 3
(1) –2.41 (2) +2.41
(3) 8 : 1 (4) 7 : 8
(3) –4.82 (4) +4.82

33. At 323 K, the vapour pressure in millimeters of

39. When two half-cells of electrode potential of E1
mercury of a methanol-ethanol solution is
represented by the equation p = 120 XA + 140, and E2 are combined to form a half cell of
where XA is the mole fraction of methanol. Then electrode potential E3, then (when n1, n2 and n3 are
p no. of electrons exchanged in first, second and
the value of lim A is (where PA is vapour combined half-cells) (Consider E1, E2 and E3 are
x A →1 X A
reduction potentials and third half cell reaction is
pressure of A)
attained by adding 1st and 2nd half cell reaction
(1) 250 mm (2) 140 mm
directly).
(3) 260 mm (4) 20 mm
(1) E3 = E2 – E1
34. An aqueous solution containing 28% by mass of a E1n1 + E2 n2
(2) E3 =
liquid A (mol. mass = 140) has a vapour pressure n3
of 160 mm at 37°C. Find the vapour pressure of E1n1 − E2 n2
the pure liquid A. (3) E3 =
n32
(The vapour pressure of water at 37°C is 150 mm).
(1) 360 mm (2) 150 mm (4) E3 = E1 + E2
(3) 160 mm (4) 520 mm
40. Which graph correctly correlates Ecell as a function
35. Azeotropic mixture are: of concentration for the cell
(1) Mixture of two solids Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s), Eºcell = 1.56V
(2) Those which boil at different temperature [ Zn 2+ ]
(3) Those which can be fractionally distilled Y-axis: Ecell, X-axis: log10
[ Ag + ]2
(4) Constant boiling mixtures

36. The oxidation potential of Zn, Cu, Ag, H2 and Ni (1) (2)
are 0.76, –0.34, –0.80, 0, 0.55 volt respectively.
Which of the following reaction will provide
maximum voltage?
(1) Zn + Cu2+ → Cu + Zn2+
(2) Zn + 2Ag+ → 2Ag + Zn2+ (3) (4)
(3) H2 + Cu2+ → 2H+ + Cu
(4) H2 + Ni2+ → 2H+ + Ni

[5]
41. Among the following, that does not form an ideal (1) –1.02 Volt (2) +0.52 Volt
solution is- (3) + 1.02 Volt (4) –0.52 Volt
(1) C6H6 and C6H5CH3
(2) C2H5Cl and C6H5OH 47. W g of copper deposited in a copper voltameter
(3) C6H5Cl and C6H5Br when an electric current of 2 ampere is passed for
(4) C2H5Br and C2H5I 2 hours. If one ampere of electric current is passed
for 4 hours in the same voltameter, copper
42. List-I and List-II contains four entries each. deposited will be (in grams):
Entries of List-I are to be matched with entries of (1) W (2) W/2
List-II. (3) W/4 (4) 2W
List- I List- II
48. The ratio of weights of hydrogen and magnesium
I AlCl3, if α = 0.8 P i = 3.4 deposited by the same amount of electricity from
aqueous H2SO4 and fused MgSO4 are:
II BaCl2, if α = 0.9 Q i = 2.8 (1) 1 : 2 (2) 1 : 12
Na3PO4, if α = 0.9 R i = 3.8 (3) 1 : 16 (4) None of these
III

K4[Fe(CN)6], if α = 0.7 S i = 3.7 49. An electrolysis of a oxytungsten complex ion

IV
using 1.10 A for 40 min produces 0.838 g of
(1) I-P ; II-Q ; III-S ; IV-R tungsten. What is the charge of tungsten in the
(2) I-Q ; II-P ; III-S ; IV-R material? (Atomic weight: W = 184)
(3) I-Q ; II-R ; III-P ; IV-S (1) 6 (2) 2
(4) I-R ; II-S ; III-Q ; IV-P (3) 4 (4) 1

50. How many coulombs of electricity are consumed

43. The substance A when dissolved in solvent B
when 100 mA current is passed through a solution
shows the molecular mass corresponding to A3.
of AgNO3 for 30 minutes during an electrolysis
The vant Hoff’s factor will be-
experiment:
(1) 1 (2) 2
(1) 108 (2) 18000
(3) 3 (4) 1/3
(3) 180 (4) 3000
44. If P0 and P are the vapour pressures of a solvent Integer Type Question (51-60)
and its solution with non-volatile solute 51. The ionization constant of a weak electrolyte is
respectively and N1 and N2 are the mole fractions 25×10–6 while the equivalent conductance of its
of the solvent and solute respectively, then correct 0.01M solution is 19.6 S cm2 eq–1. The equivalent
relation is: conductance of the electrolyte at infinite dilution
(1) P = P0N2 (2) P = P0N1 (in S cm2 eq–1) will be
(3) P0 = PN1 (4) P = P0(N1/N2)
52. Benzene and toluene form nearly ideal solutions.
45. If relative decrease in vapour pressure is 0.4 for a At 20ºC, the vapour pressure of benzene is 75 torr
solution containing 1 mol NaCl in 3 mol H2O, and that of toluene is 22 torr. The partial vapour
NaCl is .... % ionized. pressure of benzene at 20ºC for a solution
(1) 60% (2) 50% containing 78 g of benzene and 46 g of toluene in
(3) 100% (4) 40% torr is:

53. Density of a 2.05 M solution of acetic acid in

46. The standard electrode potentials of the two-half
water is 1.02 g/mL. The molality of the solution is
cell are given below:
‘x’, then 10 x in nearest integer is:
Ni2+ + 2e– → Ni ; E° = – 0.25 V
Zn2+ + 2e– → Zn ; E° = – 0.77 V 54. Resistance of 0.1 M KCl solution in a
The emf of cell formed by combining the two half conductance cell is 300 ohm and conductivity is
cells would be: (consider cell reaction to be 0.013 Scm–1. The value of cell constant is: (in cm–1)
spontaneous) (nearest integer)
[ 6]
55. At infinite dilution, the eq. conductances of 58. The % of phenol dimerized in benzene if 20 g of
CH3COONa, HCl and CH3COOH are 91, 426 and phenol in 1 kg benzene exhibits a freezing point
391 mho cm2 eq–1 respectively at 25°C, The eq. depression of 0.69 K.
conductance of NaCl at infinite dilution will be: K – kg
(Kf benzene = 5.12 ), (MW phenol = 94)
mol
56. The weight of silver (in grams) (eq. wt = 108) (nearest integer)
displaced by that quantity of current which 59. A solution of x moles of sucrose in 100 grams of
displaced 5600 ml. of hydrogen at STP is: water freezes at −0.2ºC. As ice separates the
freezing point goes down to –0.25ºC. How many
57. Electro chemical equivalent of a substance is grams of ice would have separated?
0.0006735; its eq. wt. is: (in grams/eq) (nearest
integer) (1 F = 96500C) 60. A solution of glucose (C6H12O6) is isotonic with
4g of urea (NH2–CO–NH2) per liter of solution.
The mass of glucose in 1 litre of solution is (in grams)

SECTION-III (MATHEMATICS)
Single Correct Type Questions (61-80) 64. If A is a square matrix of order 3, then the true
statement is (where I is unit matrix).
61. A 3 × 2 matrix whose elements are given by
(1) det (–A) = –det (A)
aij = 2i – j is (2) det A = 0
1 2 1 2 (3) det (A + I) = 1 + det A
(1) 3 2 (2)  1 1  (4) det (2A) = 2 det A
 
 5 4   0 3 
65. Let A and B be two symmetric matrices of order 3.
1 0  1 0  Statement-1 : A(BA) and (AB)A are symmetric
(3)  3 −2  (4) 3 2 
 
matrices.
 5 4  5 4  Statement-2 : AB is symmetric matrix if matrix
multiplication of A with B is commutative.
(1) Only statement-1 is true
 x2 + x x   0 −1 0 −2  (2) Both statements are true
62.   +   =   then x
 3 2  − x + 1 x  5 1  (3) Only statement-2 is true
(4) Both statements are false
is equal to -
(1) – 1 (2) 0 1 0   0 1
66. If I =   ,J=   and
(3) 1 (4) No value of x 0 1   −1 0 
 cos θ sin θ 
63. Which one of the following is WRONG? B=   , then B =
 − sin θ cos θ 
(1) The elements on the main diagonal of a
(1) I cos θ + J sin θ
symmetric matrix are all zero (2) I cos θ − J sin θ
(2) The elements on the main diagonal of a (3) I sin θ + J cos θ
skew - symmetric matrix are all zero (4) − I cos θ + J sin θ
1
(3) For any square matrix A, (A + AT) is 67. If A and B are square matrices of order 2, then
2 (A + B)2 =
symmetric matrix (1) A2 + 2 AB + B2
1 (2) A2 + AB + BA + B2
(4) For any square matrix A, (A–AT) is skew
2 (3) A2 + 2 BA + B2
-symmetric matrix (4) A2 + B2

[ 7]
  λ 1  8 5  −4 −1
68. If A =   and A2 =   then λ is 75. If A =   , then the determinant of the
 −1 2   −5 3 3 1
equal to matrix (A2016 – 2A2015 – A2014) is
(1) ±3 (2) 2 (1) 2014 (2) 2016
(3) 3 (4) –3 (3) –175 (4) –25

69. Let A = [aij]n × n where aij = i2 – j2 . Then A is :

(1) skew-symmetric matrix. 1 + a2 + a4 1 + ab + a 2b 2 1 + ac + a 2 c 2
(2) symmetric matrix 76. 1 + ab + a 2b 2 1 + b2 + b4 1 + bc + b 2 c 2 =
(3) null matrix 1 + ac + a 2 c 2 1 + bc + b 2 c 2 1 + c2 + c4
(4) unit matrix
(1) (a – b)2 (b – c)2 (c – a)2
70. Let A be a 2 × 2 matrix. (2) 2(a – b) (b – c) (c – a)
Statement-1 : adj(adj (A)) = A. (3) 4(a – b) (b – c) (c – a)
Statement-2 : |adj A| = |A|
(4) (a + b + c)3
(1) Statement-1 is true, Statement-2 is true.
(2) Statement-1 is true, Statement-2 is false.
(3) Statement-1 is false, Statement-2 is true. 2cot x −1 0
(4) Statement-1 is false, Statement-2 is false. 77. Let f(x) = 1 cotx −1 then match
0 1 2cot x
−x a b
column-I with column-II
71. Let a, b > 0 and ∆ = b − x a , then
Column-I Column-II
a b −x
(1) a + b – x is a factor of ∆ π
A f'   P – 32
(2) x2 + (a + b)x + a2 + b2 – ab is a factor of ∆ 2
(3) ∆ = 0 has three real roots if a = b
(4) all of these π
B f  Q –4
4
72. If A is a 3 × 3 matrix such that |5.adjA| = 5, then
|A| is equal to : π
C f'   R 8
(1) ±
1
(2) ±
1 4
5 25
(3) ± 1 (4) ± 5 π
D f  S 0
2
73. If A, B are two n × n non-singular matrices, then
(1) AB is non-singular matrix
A B C D
(2) AB is singular matrix
(1) Q R P S
(3) (AB)–1 = A–1 B–1
(4) (AB)–1 does not exist (2) Q P R S
(3) P S Q R
 1 −1 0  (4) S R Q P
74. IfA–1=  0 −2 1  , then
 0 0 −1   2 −1  1 4
78. For matrices A =   and B =  
(1) | A | = 2  −1 2   −1 1 
(2) A is singular matrix which relation is true
 1 / 2 −1 / 2 0  (1) (A + B)2 = A2 + 2AB + B2
 −1 
(3) Adj. A =  0 1/ 2  (2) (A–B)2 = A2 – 2AB + B2
 0 0 −1 / 2  (3) AB = BA
(4) A is skew symmetric matrix (4) AB ≠ BA

[ 8]
  1 0 85. If for a matrix A, |A| = 6 and
79. If P =  1  , then P50 is:  1 −2 4 
 1
2  adj A =  4 1 1  , then k is equal to :
 1 0 1 25  −1 k 0 
(1)   (2)  
 25 1  0 1 
 1 0 1 50  5 0 0 
(3)   (4)   86. If B is a non-singular matrix and A = 0 2 0 
50 1  0 1 
0 0 3
80. Let I be an identity matrix of order 2 × 2 and then det (B–1 AB) is equal to
 2 −1
P=  . Then the value of n ∈ N for which
 5 −3 1 0 0 1 0 0
P n = 5I – 8P is equal to 87. If A =  0 1 1  , I = 0 1 0
  and
(1) 8 (2) 12  0 −2 4   0 0 1 
(3) 4 (4) 6 1 2
A–1 = (A + cA + dI ) then the value of (d – c)
6
Integer Type Question (81-90)
is
81. The number of different possible orders of
matrices having 18 identical elements is 1 1 b b 
88. Let A =   and B =  1 2  . If
0 1 b3 b4 
82. The sum of the minors of all elements in the 10A10 + adj(A10) =B, then b1+ b2 + b3 + b4 is equal to
1 −3 2
second row of determinant 4 −1 2 is –k
89. If α, β ≠ 0 and f (n) = α n + βn and
3 5 2
3 1 + f (1) 1 + f (2)
then k is
1 + f (1) 1 + f (2) 1 + f (3)
1 + f (2) 1 + f (3) 1 + f (4)
x2 + x x +1 x−2
83. If 2 x + 3x − 1
2
3x 3 x − 3 = ax – 12, then = K (1 − α) 2 (1 − β) 2 (α − β) 2 , then K is equal to

x2 + 2 x + 3 2x −1 2x −1
90. Let P = [aij] be a 3 × 3 matrix and let Q = [bij],
‘a’ is equal to : where bij = 2i+jaij for 1 ≤ i, j ≤ 3. If the
determinant of P is 2, then the determinant of the
84. If A and B are square matrices of order 3 such
matrix Q is 2λ then λ is
that |A| = – 1, |B| = 3, then |3A2B| is equal to

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