490-PRO Micro GC User Manual
490-PRO Micro GC User Manual
Micro Gas
Chromatograph
User Manual
Agilent Technologies
Notices
© Agilent Technologies, Inc. 2016 Warranty (June 1987) or DFAR 252.227-7015 (b)(2)
(November 1995), as applicable in any
No part of this manual may be reproduced The material contained in this docu- technical data.
in any form or by any means (including
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agreement and written consent from in future editions. Further, to the max-
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United States and international copyright law, Agilent disclaims all warranties, CAUTION
laws. either express or implied, with regard
to this manual and any information A CAUTION notice denotes a
contained herein, including but not hazard. It calls attention to an oper-
Manual Part Number
limited to the implied warranties of ating procedure, practice, or the
G3581-90006 merchantability and fitness for a par- like that, if not correctly performed
ticular purpose. Agilent shall not be or adhered to, could result in
Edition liable for errors or for incidental or damage to the product or loss of
Fifth edition, June 2016 consequential damages in connection important data. Do not proceed
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If software is for use in the performance of
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Contents
1 Introduction
Safety Information 16
Important safety warnings 16
Hydrogen safety 16
Safety symbols 17
Safety and regulatory information 17
General safety precautions 18
Shipping Instructions 21
Cleaning 21
Instrument Disposal 21
2 Instrument Overview
Principle of Operation 24
Front View 26
Back View 27
Inside View 28
Carrier Gas Connection 29
Sample Gas 31
Handling a sample 31
Using the external filter unit 31
Heated sample lines 32
How to connect your sample to the 490-PRO Micro GC 33
Power 40
Power source 40
Power requirements 40
Disposal 40
Specifications 41
Ambient Pressure 41
Ambient Temperature 41
Maximum Operation Altitude 41
4 GC Channels
Carrier Gas 58
Micro Electronic Gas Control (EGC) 59
Inert Sample Path 59
Injector 59
Column 60
Molsieve 5Å columns 61
CP-Sil 5 CB columns 62
CP-Sil 13 and CP-Sil 19 CB columns 63
PoraPlot 10 m column 64
Hayesep A 40 cm heated column 65
COX and AL203/KCI columns 66
MES (NGA) and CP-WAX 52 CB columns 67
Column conditioning 68
Backflush Option 69
Tuning the backflush time (except on a HayeSep A channel) 71
Tuning the backflush time on a HayeSep A channel 72
To disable backflush 73
TCD Detector 74
5 Interfaces
Access the Connection Ports 84
Ethernet Connections 88
PROstation 88
Firewall configuration 88
FTP server 95
Modbus TCP/IP 95
Web server 102
Multiple 490-PRO analyzers 104
USB WIFI 105
Access the 490 Micro GC webserver via a wireless network 105
Access to the 490 Micro GC via PROstation 108
Change USB AP name (SSID) and passphrase (security key) 110
I/O Connections 112
External Digital I/O 112
External Analog I/O 113
Serial COM Connections 116
Connector layout 116
Stream selector valve 117
Modbus serial 118
LCD screen 118
USB Connection 119
Interface Examples 120
8 PROstation Installation
System Requirements 139
Hardware 139
Software 139
Install PROstation 140
10 Instrument Configuration
Main Menu 162
Login procedure 162
Main Menu Functions 166
Configured instrument menu 166
Control menu 167
Virtual instrument 168
Instrument Configuration 170
490-PRO Configuration 171
Communication Frame 173
Ethernet communication 173
Find instruments on the network 173
Assign new IP address 174
Configuration Frame 175
21 Errors
Error Handling 718
Error List 719
22 WinDCS
Setting up the WinDCS Communication 726
Serial communication settings 726
Ethernet communication settings 726
General Modbus communication settings 727
WinDCS Modbus Table 729
Register type 729
Data type 729
WinDCS Modbus table setup 729
23 History Log
Operation 734
Starting the application 734
Setup for data download 735
Data download 736
Setup for report 737
Report control 743
Chromatogram control 745
Exit history log 746
Report Data 747
Header 747
Calibration results 747
Analysis data 747
Avg/Min/Max 747
Power on 748
Alarm status change 748
Parameter change 748
1
Introduction
Safety Information 16
Shipping Instructions 21
Cleaning 21
Instrument Disposal 21
Agilent Technologies 15
1 Introduction
Safety Information
Hydrogen safety
Hydrogen is a commonly used GC carrier gas. When mixed with air,
hydrogen can form explosive mixtures and has other dangerous
characteristics.
When using hydrogen (H2) as the carrier gas, be aware that hydrogen gas
WA R N I N G
can create a fire or explosion hazard. Be sure that the supply is turned off
until all connections are made.
Hydrogen is flammable. Leaks, when confined in an enclosed space, may
create a fire or explosion hazard. In any application using hydrogen, leak
test all connections, lines, and valves before operating the instrument.
Always turn off the hydrogen supply at its source before working on the
instrument.
Safety symbols
Warnings in the manual or on the instrument must be observed during
all phases of operation, service, and repair of this instrument. Failure
to comply with these precautions violates safety standards of design
and the intended use of the instrument. Agilent Technologies assumes
no liability for the customer’s failure to comply with these
requirements.
See accompanying instructions for more
information.
Indicates a hot surface.
Indicates hazardous voltages.
Indicates earth (ground) terminal.
Indicates potential explosion hazard.
Indicates electrostatic discharge hazard.
Indicates a hazard. See the Agilent 490-PRO
Micro GC user documentation for the item
labeled.
Indicates that you must not discard this
electrical/electronic product in domestic
household waste
This device has been tested and found to comply with the limits
for a Class A digital device, pursuant to part 15 of the FCC
rules. These limits are designed to provide reasonable
protection against harmful interference when the equipment is
operated in a commercial environment.
This equipment generates, uses, and can radiate radio
frequency energy and, if not installed and used in accordance
with the instruction manual, may cause harmful interference to
radio communications.
Operation of this equipment in a residential area is likely to
cause harmful interference in which case the user will be
required to correct the interference at his own expense.
Shipping Instructions
If your Micro GC must be shipped for any reason, it is very
important to follow these additional shipping preparation
instructions:
• Place all the vent caps on the back of the Micro GC (see
Figure 4 on page 27).
• Always include the power supply.
• Include, if used, the inlet filter(s).
Cleaning
To clean the surface of the Micro GC:
1 Switch the Micro GC off.
2 Remove the power cable.
3 Put protection plugs on the sample and carrier gas inlets.
4 Put protection plugs on the column vents.
5 Use a soft brush (not hard or abrasive) to carefully brush
away all dust and dirt.
6 Use a soft, clean cloth dampened with mild detergent to
clean the outside of the instrument.
• Never clean the inside of the instrument.
• Never use alcohol or thinners to clean the instrument;
these chemicals can damage the case.
• Be careful not to get water on the electronic components.
• Do not use compressed air to clean the instrument.
Instrument Disposal
When the Micro GC or its parts have reached the end of their
useful life, dispose of them in accordance with the
environmental regulations that are applicable in your country.
2
Instrument Overview
Principle of Operation 24
Front View 26
Back View 27
Inside View 28
Carrier Gas Connection 29
Sample Gas 31
Power 40
Ambient Pressure 41
Ambient Temperature 41
Maximum Operation Altitude 41
Agilent Technologies 23
2 Instrument Overview
Principle of Operation
The 490-PRO Micro GC can be equipped with one to four
independent column channels. Each column channel is a
complete, miniaturized GC with electronic carrier gas control,
micro-machined injector, narrow-bore analytical column and
micro thermal conductivity detector (µ TCD), Figure 1.
The 490-PRO Micro GC analytical channels can optionally be
equipped with a back flush option. The advantages include the
protection of the stationary column phase against moisture and
carbon dioxide. Next to that, it results in shorter analysis times
as late elution compounds, which are not of interest, do not
enter the analytical column.
Front View
Ready LED
LED OFF: System not ready
LED ON (green): System is ready
Run LED
LED OFF: No run
LED blinking (orange): Run in progress
Error LED
LED OFF: No error
LED blinking (red): Error present
See “Error List” on page 719
Power LED
LED OFF: No power
LED ON (blue): Power OK
LED blinking (blue): Voltage < 10 Volt
Back View
Vents
It is possible to connect long vent lines to
these fittings in order to safely guide
hazardous fumes to a fume hood or other
appropriate vent.
Power connector
Power connector (male)
See “Power” on page 40
Figure 4 Back view of the 490-PRO Micro GC (shown with fitting caps in place)
Inside View
First shipments of the latest version of the mainboard
(p/n G3581-65000) starting middle of 2014.
Open the right side cover and the cable connectors will be
visible.
Assign IP address switch
See “Ethernet Connections” on
page 88. LAN indicators
Red LED: Transmit data
Green LED: Receive data
COM 1
COM 3 and COM 4 RS-232 communication
RS232, RS422, or RS485 interface
communication
interface.
See Table 15 on page 86.
Digital I/O
Analog I/O Digital input and output
External analog I/O signals, such as start_stop,
signals. ready_out, and start_in.
See “External Analog See “External Digital I/O” on
I/O” on page 113. page 112.
Do not use any kind of plastic tubing since air will diffuse through the
CAUTION
tubing, which may cause noisy baselines and decreased sensitivity. The
metal tubing must be clean for GC use. Buy either flamed or
chromatographically clean tubing.
Sample Gas
The Micro GC is built for the analysis of gases and vapors only.
You are advised to prepare a noncondensing gaseous standard
sample for routine checkup of the instrument. Sample pressure
should be between 0 and 100 kPa (0 to 15 psi). Sample
temperature should be between 0 and 110 °C. The sample must
be filtered, preferably through a 5-mm filter. Agilent always
recommends the use of the external filter kit (CP736729).
For more details, see “Using the external filter unit” on page 31.
Handling a sample
If possible, filter and dry the sample before introducing it to the
Micro GC. Agilent advises using an external sample filter unit
between the injector and the sampling device.
WA R N I N G The metal surfaces of the sample line heater can be very hot.
Before connecting a sample line, allow the sample line heater to
cool to ambient temperature.
Male 1/16-inch
Swagelok fitting
Internal inlet
For connecting the micro-gasifier, Enrichment and Desorption
Unit (EDU) and a heat-traced sample line, the system's internal
sample inlet should be used.
Figure 9 Open the side panel, remove the top insulation and loosen the internal sample inlet.
Figure 12 Install the back panel and micro-gasifier, and connect the
micro-gasifier sample line to the internal sample inlet using a
1/16-inch Swagelok fitting.
Genie filter
Bypass
Ensure separated liquids are properly drained via the bypass tubing out-
CAUTION
side of the Micro GC. To operate properly, the bypass must remain free of
blockage.
WA R N I N G The metal surfaces of the column, injector and sample inlet can be
very hot. Before connecting a sample line, allow the GC
components to cool to ambient temperature.
Lower mounting
bolts
3 Remove the lower mounting bolts from the rear panel of the
GC.
4 Mount the bracket to the GC using the two M4 x 12 mm
screws provided.
5 Mount the Genie Filter 170 to the bracket using two pan
head screws (1290116500).
6 Screw the bracket to the internal bracket using a M4 x 8 mm
screw (CP86757).
Power
Power source
• 90 to 264 Vac, frequency between 47 to 63 Hz.
• The room power outlet circuit must be exclusively reserved
for the instrument(s).
• The network should be properly grounded.
• Installation Category (overvoltage category): II
Power requirements
The Micro GC requires 12 Vdc, 150 W.
The Gasifier requires 12 Vdc, 150 W.
Only use the power supply provided with your Micro GC.
CAUTION
This Power Supply, see Figure 18, is tailored to meet the power
needs of your Micro GC.
Disposal
Disposal of the Power Supply must be carried out in accordance
with all environmental regulations applicable in your country.
Specifications
Table 2 Power supply specifications
Ambient Pressure
The Micro GC automatically shuts down if the ambient pressure
is greater than 120 kPa.
Ambient Temperature
The Micro GC automatically shuts down if the ambient
temperature exceeds 65 °C.
3
Installation and Use
Pre-Installation Requirements 44
Inspect the Shipping Packages 44
Unpack the Micro GC 45
Review the Packing List 46
490-PRO Micro GC Installation 47
Restore the Factory Default IP Address 52
Create the Test Method 54
Perform a Series of Runs 55
Shut Down Procedure 56
Long Storage Recovery Procedure 56
Agilent Technologies 43
3 Installation and Use
Pre-Installation Requirements
Prepare the installation site as described in the Site Preparation
Guide (G3581-90002), including the recommended Gas Clean
filters.
Protective shipping
caps
DHCP Switch
The reset button can be accessed behind the right panel on the
mainboard, see Figure 23. To restore the factory default IP
address, follow this procedure:
1 Power off the Micro GC.
2 Press and hold the reset button and power on the Micro GC.
3 Release the reset button shortly after powering on the GC
(approximately 3 seconds).
Note 1: When the reset button is released too quickly (less
than 1 second), it may result in the IP setting not reverting
to its factory defaults.
Use the data system to set up the checkout parameters for each
GC channel. Apply the checkout method settings to the Micro
GC and allow the instrument to stabilize at the initial operating
conditions. Monitor the instrument status using the data
system’s status display (refer to the data system help for
details).
Each test method has been designed to determine if the
instrument channel is functioning properly and includes an
example test chromatogram.
The detector can be damaged by improper shut down. If shutting down the
CAUTION
instrument for more than a few days, carry out the procedure below.
4
GC Channels
Carrier Gas 58
Micro Electronic Gas Control (EGC) 59
Inert Sample Path 59
Injector 59
Column 60
Backflush Option 69
TCD Detector 74
490-PRO Micro GC Optional Pressure Regulators 75
Agilent Technologies 57
4 GC Channels
Carrier Gas
The Micro GC is configured for use with either He and H2 or
N2 and Ar.
Your Micro GC is configured either for carrier gas He and H2 or N2 and Ar.
CAUTION
Use the carrier gas type for which your instrument is configured, otherwise
the detector filaments can be damaged.
Columns
(analytical and
Microelectronic
Gas clean unit reference)
gas control
(optional)
(EGC) Injector µTCD
Reference vent
Column vent
Carrier gas
Injector
The injector has a built-in 10-µl sample loop that is filled with
the gaseous sample. The pressure of the sample should be
between 0 and 100 kPa (0 to 15 psi) and the sample temperature
between 0 to 110 °C.
When the chromatographic data system sends a START
command, the vacuum pump aspirates the gas sample through
the loop. The gas samples is injected onto the analytical column
using the carrier gas flow. A typical injection time is 40 ms. This
equals an average injection volume of 2 µL. Injection time will
be rounded to a multiple of 5 ms. A practical minimum value is
40 ms. A value of 0 to 20 ms might result in no injection.
Column
A variety of column configurations are possible on the Micro
GC. The columns you require for your specific analyses have
been installed at the factory. Other configurations are, of
course, possible, but altering the GC channels is a delicate
matter that can only be handled by an Agilent service engineer.
Table 7 shows several standard columns as supplied in the
Micro GCs and selected applications. Other columns are
available by contacting Agilent Technologies.
All columns except the HayeSep A (160 °C) and MES (110 °C) columns can
CAUTION
be used up to 180 °C, the maximum temperature of the column oven.
Exceeding this temperature will cause the column to lose efficiency
instantly and the column module will need replacement. All channels have
a built-in protection that prevents a setpoint above the maximum
temperature.
Molsieve 5Å columns
The Molsieve 5Å column is designed to separate: hydrogen,
carbon monoxide, methane, nitrogen, oxygen, and some noble
gases. Higher molecular weight components have much higher
retention times on this column.
Table 8 Molsieve 5Å instrument parameters
CP-Sil 5 CB columns
The natural gas components, mostly hydrocarbons, separate in
the same order on the nonpolar and medium-polar CP-Sil CB
columns. Nitrogen, methane, carbon dioxide, and ethane are not
separated on these columns. They produce a composite peak.
For separation of these components, consider a HayeSep A
column.
Table 9 CP-Sil 5 CB instrument parameters
19
25
14
15
9 5
5 4
5
4
4
-5 -1
0 5 10 15 20 25 30 35 0 10 20 30 40 50 60 70
Seconds Seconds
0 -0.5 2
-0.2
-1
-0.4
-1.5
-0.6
-0.8 -2
0 10 20 30 40 50 60 70 80 90 0 10 20 30 40 50 60
Seconds Seconds
PoraPlot 10 m column
15
180
10 5 5
5 4 80 4
0
-20
2 6 10 14 18 22 26 30 34 38 42 46 50 0 10 20 30 40 50
Seconds
mV Hayesep A 40 cm heated
345
2
295
245
195
145
95
45
3
1
-5
0 10 20 30 40 50 60 70
Seconds
1.5 55
3
4
1
5 35
0.5
0
1 15 45
-0.5 -5
0 50 100 150 200 250 0 10 20 30 40 50 60 70
Seconds Seconds
-500 -2
0 20 40 60 80 100 120 140 1 6 11 16 21 26 31 36
Seconds Seconds
Column conditioning
Follow this procedure to ensure that any water that might be
present inside the analytical column is removed before the TCD
is switched on.
Also follow this procedure if the Micro GC module has been
stored for a long period.
Backflush Option
Backflush to vent is an advanced technique used to prevent
later-eluting compounds from reaching the analytical column
and detector. The main reason for applying this technique is to
keep the analytical column clean and reduce analysis time.
The Micro GC is optionally available with GC modules that
incorporate backflush capabilities.
1 2
1 2 3 4 5
1 = Methane
3 5
2 = Ethane
3 = Propane 4
4 = iso-Butane
5 = Butane
6 = iso-Pentane
6
7 = Pentane
7
8 50 s 8 50 s
Natural gas analysis, straight Natural gas analysis, with backflush at 8 seconds
Restriction
Injector Backflush
vent
Injector Backflush
vent
9 10 11 12 13
100
80
60 Peaks of Interest
mVolt
Methane
Unwanted Peak
Carbon Dioxide
Ethane
40
Nitrogen
Propane
i--Butane
Appropriate
20 Backflush Time
To disable backflush
To disable backflushing, set the Backflush Time to 0. This puts the
system in normal mode during the entire run.
TCD Detector
Each GC channel is equipped with a thermal conductivity
detector (TCD). This detector responds to the difference in
thermal conductivity between a reference cell (carrier gas only)
and a measurement cell (carrier gas containing sample
components). The construction of a TCD is such that the
changing thermal conductivity of the carrier gas stream, due to
components present, is compared to the thermal conductivity of
a constant reference gas stream.
G3581-S0003
The Agilent pressure regulator assembly (G3581-S0003)
provides a pressure regulator, Genie filter (for sample drying)
and needle valve, along with the required mounting bracket and
hardware required for installation.
Figure 30 shows the components and connection points for the
Agilent pressure regulator assembly (G3581-S0003).
Dried sample to
analytical channels -
rear sample inlet of GC
Out
Genie 170
In Vent
Pressure Needle
regulator valve
Sample
Sample
OUT
IN
(Drain)
The pressure regulator is factory set, and has been tested to the
following, fixed specifications:
Attribute Specification
Input 25 bar (2.5 Mpa)
Output 0.7 bar (10.1 psi or 70 Kpa)
Flow 20 mL/min
The sample flows through the pressure regulator and into the
Genie filter. Dried sample is then applied to the rear sample
inlet of the GC.
The minimum working pressure of the Genie filter is 0.5 bar. Sample will
NOTE
not flow through the filter if this working pressure is not maintained.
G3581-S0003 Installation
The G3581-S0003 pressure regulator assembly is supplied fully
assembled, and ready to install at the rear of the GC. To install
the assembly, do the following:
1 Shut down the GC, and allow the column and injector to
cool. See “Shut Down Procedure” on page 56.
WA R N I N G The metal surfaces of the column, injector and sample inlet can be
very hot. Before connecting a sample line, allow the GC
components to cool to ambient temperature.
Lower mounting
bolt
3 Remove the lower mounting bolt from the rear panel of the
GC.
4 Position the G3581-S0003 pressure regulator assembly at
the rear of the GC, and secure using the lower mounting
bolt.
Sample to rear
sample inlet
Sample IN
Needle valve
Sample OUT
(drain)
G3581-S0004
G3581-S0004 provides a pressure regulator and needle valve,
along with the required mounting bracket and hardware
required for installation.
The block diagram below shows the components and connection
points for the G3581-S0004 pressure regulator assembly.
Pressure Needle
regulator valve
Sample
Sample
OUT
IN
(Drain)
The pressure regulator is factory set and has been tested to the
following, fixed specifications:
Attribute Specification
Input 25 bar (2.5 Mpa)
Output 0.7 bar (10.1 psi or 70 Kpa)
Flow 20 mL/min
The sample flows through the pressure regulator and into the
rear sample inlet of the GC.
A needle valve provides for venting the sample for draining.
G3581-S0004 Installation
The G3581-S0004 sample inlet pressure regulator assembly is
supplied fully assembled and ready to install at the rear of the
GC. The install the assembly, do the following:
1 Shut down the GC and allow the column and injector to cool.
See “Shut Down Procedure” on page 56.
WA R N I N G The metal surfaces of the column, injector and sample inlet can be
very hot. Before connecting a sample line, allow the GC
components to cool to ambient temperature.
Lower mounting
bolt
3 Remove the lower mounting bolt from the rear panel of the
GC.
4 Position the G3581-S0004 assembly at the rear of the GC and
the secure using the lower mounting bolt.
Sample to rear
sample inlet
Sample IN
Needle valve
Sample OUT
(drain)
5
Interfaces
Access the Connection Ports 84
Ethernet Connections 88
USB WIFI 105
I/O Connections 112
Serial COM Connections 116
USB Connection 119
Interface Examples 120
Agilent Technologies 83
5 Interfaces
COM 1
RS-232 communication
interface
COM 3 and COM 4
RS232, RS422, or RS485
communication
interface.
See Table 15 on page 86.
Digital I/O
Analog I/O Digital input and output
External analog I/O signals, such as start_stop,
signals. ready_out, and start_in.
See “External Analog See “External Digital I/O” on
I/O” on page 113. page 112.
Ethernet Connections
PROstation
The Agilent data systems require an Ethernet network for data
communications with the Micro GC. This network can be a local
area network (LAN) or wide area network (WAN).
General requirements:
• Micro GC with mainboard G3581-65000 installed (100 Mbps
connection)
• Cat6, Cat5e, or Cat5 UTP/STP cabling.
• The network should comply with Standard Ethernet
(IEEE 802.3).
• The network must be100BASE-T, 10/100BASE-TX, or
10/100/100BASE compatible hubs or switches.
• TCP/IP should be used on the network.
Firewall configuration
The 490-PRO Micro GC (and PROstation) communicate over a
TCP/IP network. On the TCP/IP network 490-PRO Micro GC and
PROstation use some standardized protocols and some custom
protocols. All protocols used, make use of User Datagram
Protocol (UDP), Transmission Control Protocol (TCP) or
Internet Control Message Protocol (ICMP). Any of these
protocols can be blocked by a firewall, preventing the 490-PRO
Micro GC and PROstation from communicating with each other.
Therefore, the firewall should be configured as showed below.
Table 16 490-PRO custom data protocols using TCP protocol
IP Addresses
• An IP address uniquely identifies a computer or device on
the network or internet.
• IP addresses are made up of four 8-bit numbers, and each of
these numbers is separated by a decimal point.
• Each of the 8-bit numbers can represent a decimal value of
0-255.
• Each part of an IP address can only be in that range (for
example, 198.12.253.98).
A network can be public (addressable from the internet) or
private (not addressable from the internet). A private network
can also be isolated, that is, physically not connected to the
internet or other networks. In many cases, you can set up an
isolated LAN for instruments. For example, an isolated, private
LAN may consist of a workstation computer, four Micro GCs, a
printer, a LAN switch, and cabling. Isolated LANs must use IP
addresses in the “private” ranges shown in Table 20 on page 90.
Peer-to-peer
Crossover cable or
regular patch cable
Data system PC
Any IP address allowed
Micro GC with
mainboard G3581-65000
Single 490-PRO connected to a local
workstation. IP address in the same
subnet range as the computer subnet
range.
Switch
Patch cable
Data system PC
Any IP address allowed
Subnet 1
Switch
Patch cable
Data system PC
IP address in subnet range of Subnet 1
Can also control Micro GC in Subnet 2.
Subnet 2
Switch
FTP server
The FTP server provides external storage capacity for run data,
reports and diagnostics. The 490-PRO Micro GC has no
capabilities for storing data, except for the last run. By
obtaining a “35-day logging” license, the 490-PRO Micro GC
becomes capable of storing data.
Modbus TCP/IP
This is the main connection to the control computer (DCS,
Web server
The 490-PRO Micro GC built-in web server can be accessed
within your local network using an internet browser by entering
the instrument’s IP address (for example
http://192.168.100.100) in the address/search bar.
The web server provides instrument status information, sample
results, system control, network configuration, firmware update
and a reference to support documents. Some of these functions
are password protected with the following credentials:
• Login name: admin
• Password: agilent
Status
The Instrument Status section provides instrument status, see
Figure 50 on page 103 for an example. The Instrument Results
section reports the calculated application results, like ESTD and
calorific power results. These screens are refreshed every
Control
The 490-PRO can be identified by an acoustic (beep) or visual
(blinking LEDs) signal using Identify. With Reset, the
instrument’s operating system can be rebooted.
Configuration
The configuration section provides an overview of the
instrument’s network setting from Network. These setting can be
changed and downloaded to the instrument from this section.
Names gives an overview and the ability to change the system’s
network hostname.
Maintenance
Instrument firmware upgrade can be done from the Update
section using a file provided by Agilent.
Support
Micro GC support documentation, such as data sheets and
application notes can be accessed from Agilent. The 490-PRO
Micro GC Help file/User manual can be viewed from the User
Manual.
USB WIFI
Preparation: One USB Network Interface Card (NIC) with a
Realteck RTL8188 family chipset.
Table 21 USB WIFI Adapters
Figure 56 Open a GC
6 The new settings will take effect after you reboot your GC or
unplug and replug the USB NIC. Your PC will not
automatically connect to the new AP hotspot until after you
manually connect once.
I/O Connections
490-PRO Micro GC
Pin 1 Digital IN1
2 Digital IN2
3
4 Digital OUT1 (not defined)
5 Digital OUT2 (not defined)
6 2
Reserved (I C bus)
7
8 Reserved Micro-GC will only start in external ready mode when
9 Start-IN Start-IN detects a contact closure pulse
10 External Ready-IN
11 External system reset
12 Digital Input (galvanic separated)
* 13
OUT Relay 1
14
* 15
OUT Relay 2
16
* 17
OUT Start 500 ms contact closure when injection will take place
18
* 19
OUT Ready/not ready
20
21 Reserved
22 +5 VDC out (electronic fused max 500 mA)
23
24 +12 VDC out ( electronic fused max 500 mA)
25
Start In signal starts one single run when the contact is closed.
Ready Out will be ready when the system is not in a
chromatographic run phase and all temperatures, pressures
(selectable external Ready In) are ready.
Extension boards
Analog extension
8 x 4-20mA
Digital extension
8 relay,
Basic board
Extension bus 8 digital inputs
8 relays, 8 digital
inputs, 6 analog
inputs
Alarms
External (relay open/
Events, close)
External relay
Events, Alarms open/
relay (relay open/ close
open/ close)
close
Stream
selection
Stream
(solenoids)
selection
(solenoids)
Connector layout
The COM ports on instrument mainboard can be used for serial
connection to a computer or industrial devices. Table 15 on
page 86 gives an overview of the communication options.
The port layout details for the 490-PRO Micro GC (mainboard
part number G3581-65000) is given in Figure 67 and Table 22 on
page 117.
Part number for connector COM 3/4 on mainboard with part number
NOTE
G3581-65000 is p/n 0360-3106.
Function
Pin number RS232 RS422 RS485 2-wire RS484 4-wire Comport
1 CTS RX- not used RX- COM 3
2 RX RX+ not used RX+ COM 3
3 TX TX+ Data+ TX+ COM 3
4 RTS TX- Data- TX- COM 3
5 GND GND GND GND COM 3
6 CTS RX- not used RX- COM 4
7 RX RX+ not used RX+ COM 4
8 TX TX+ Data+ TX+ COM 4
9 RTS TX- Data- TX- COM 4
10 GND GND GND GND COM 4
Modbus serial
From Modbus, analysis results, GC-status, external device
status, etc. are provided to the DCS and certain operations can
be requested by the DCS.
A total of 2 Modbus Serial Masters Can connect to the same
490-PRO simultaneously.
LCD screen
The optional 4-line LCD screen can display instrument
information, such as:
• Actual operating conditions
• Instrument and run status
• Calculated values
• Instrument errors
• and more.
See also “Micro GC LCD Module Installation” on page 125 for
installation and “Application – Local User Interface (LCD)” on
page 360 for setting up the LCD screen.
USB Connection
The USB port can be used to connect external accessories
directly or with a USB hub.
Interface Examples
490-PRO Micro GC
DCS ModBus Autonome Controls
Stream Selector control, Stream Selector
(Distributed Control (TCP/IP and/or serial)
Analysis, Calibration, and
System) verification sample
ModBus
4-20 mA Analog
Extension
Board
4-20 mA Analog
Extension
Board
DCS
490-PRO Micro GC Stream 1
(Distributed Control
System) Stream Selector Stream 2
Autonome
Analog Stream 3
Calibration request
Status and Control External Devices Digital Inputs
Verification request
Select request
Execute single line request
Start/Stop automation request
(DCS, operator)
External device
Analog Inputs status
Flow / P
controllers
6
Local User Interface (LCD)
Installation Requirements 124
Micro GC LCD Module Installation 125
Mechanical Product Specifications 128
Connectors 129
Shipping Instructions 129
Cleaning Instructions 129
Disposal Instructions 129
Installation Requirements
Environmental requirements
• Intended for indoor use.
• Protect the Micro GC LCD Module from corrosive chemicals
or gases, dust/particulate accumulation, and direct venting
of air conditioners, heaters, furnaces, or fans.
• Build in an external housing before operating.
Micro GC
The Micro GC LCD Module need specific level of hardware and
software to function correctly.
For problems or questions about the Micro GC hardware or
software, please contact your nearest Agilent Technologies
representative.
Space requirements
Allow sufficient bench space to permit installation of
workstations, integrators and other Micro GC equipment.
Power source
The LCD Module is powered throughout the Micro GC.
Inspection
The Micro GC LCD Module will arrive packed in one small box.
Inspect the cartons carefully for damage or signs of rough
handling. Report damage to the carrier and to your local Agilent
office.
Unpacking
Before performing the unpacking procedure be sure to wear an ESD (Elec-
CAUTION
tronic Static Discharges) strap.
Packing list
LCD Module
Cable, 9 pins
The LCD Module is 100 % tested at the factory. The display has
sensitive electronic components, and must be handled with
care, especially concerning damage by ESD (electrostatic
discharge).
The LCD Module can be built in a housing using the “Mechanical
Product Specifications” on page 128.
Agilent is NOT responsible for any damage occurred during
mechanical handling.
To connect the LCD Module to the Micro GC use the included
cable and connect according to Figure 78.
490-PRO Micro GC
Female
Cable, 9-pin
Female LCD Module
Connect to COM2
Connect to J1
Figure 78 LCD Module connection to Micro GC mainboard (left mainboard with p/n G3581-65000, right
mainboard with p/n CP740010).
Connectors
J1 pin-out Definition
Pin Function Signal name from Micro GC serial port
1 NC NC
2 NC RxD
3 RS232 Data In TxD
4 PWRA Not used
5 GND GND
6 NC NC
7 PWRB RTS
8 NC CTS
9 LCD supply +5 Volt DC
Shipping Instructions
If the Micro GC LCD Module for any reason must be sent back to
the factory it is very important to follow the additional shipping
instructions.
Include all cables.
NOTE
Cleaning Instructions
To keep the Micro GC LCD module surface clean:
• Clean only when the Micro GC LCD Module is disconnected
from the Micro GC or other equipment.
• Use a soft (not hard or abrasive) brush to carefully brush
away all dust and dirt.
• If the outer case is dirty (never clean the inside), clean it
with a soft, clean cloth dampened with mild detergent.
• Do not get water on the electronics components.
• Do not use compressed air to clean.
Disposal Instructions
Disposal must be carried out in accordance with all
(environmental) regulations applicable in your country.
7
490-PRO Cycle Scheme
490-PRO Cycle and Stream Selector 132
490-PRO Chromatographic Run and Electronic Pressure 134
PROstation;
Start Automation,
Start single run, Chromatogram stored Update Modbus registers
External Start IN (Chrom.dat)
. Application results file stored (samprslt.txt)
Time
PROstation;
Start Automation,
Start Calibration Table,
Start Verification Table,
Start Execute Single sequence Line
External Start IN, Chromatogram stored Update Modbus registers
PROstation Start single run (Chrom.dat) Application results file stored (samprslt.txt)
Time
Integration,
Identification, FTP-Service
Stream selection
Calibration.
PROstation;
Start Automation,
Start Calibration Table,
Start Verification Table,
Start Execute Single sequence Line,
Start Single Run,
PROstation single run Chromatogram stored Update Modbus registers
External Start IN (Chrom.dat) Application results file stored (samprslt.txt)
Time
Integration,
Flush time
Identification, FTP-Service
Calibration.
Injection + 1 sec.
Flush time next stream
Pressure
1) After the start run 3) Pressurization delay 4) During injection time
sampling is begun. (240 ms), used to the sample is transported
This means that the pressurize the sample to the column by
sample is (mostly) to the same pressure the carrier gas.
sucked into the as the column head
sample-loop. pressure.
initial pressure
2) Fixed equilibration 5) The real analysis (run) 6) After the specified run-time
delay of 40 ms. This time and data-acquisition is started. has elapsed, the run is finished.
allows the sample to settle
in the sample-loop.
Pressure
Not ready
Final pressure
Time
Run time
The remaining final time depends on the total run time, the
duration of the initial time, and the pressure rise. This means
that it is possible that the final time is zero. Another situation is
that the final pressure is limited because of these settings. The
software will check all parameter -values and change them into
realistic values.
8
PROstation Installation
System Requirements 139
Install PROstation 140
System Requirements
Hardware
• Processor speed: Processor with 2 GHz CPU or higher
• Internal RAM: Recommended 4 GB RAM or more using
Windows 7
• Peripherals: CD-ROM player
• Free Ethernet port
• Free USB slot for the PROstation USB license key
Software
• Supported Microsoft Windows versions: Windows XP
professional edition (ServicePack 2 or higher), Windows 7
32 or 64 bit (ServicePack 1 or higher), or Windows 8.1.
• Other BootP services must be disabled.
Install PROstation
1 Insert the CD-ROM 490-PRO Software Tools; the CD will
autostart.
2 Select Install PROstation to start the installation.
Users must log in as a Windows administrator.
Ensure no other Windows applications are running during
the PROstation installation.
3 After choosing the PROstation item from the setup menu, a
welcome screen is visible. The welcome screen shows the
version of PROstation and points to some important notes.
Note that the version you will install from the CD-ROM
probably will be newer than the one displayed in this
picture. (Figure 85)
Figure 92 Crypto-Box
9
GC Emulator: A Simple User Guide
Installation 148
Create a new instrument by importing a configuration file 150
Open Emulation Mode 153
Offline Data Processing 156
Close an Emulated Instrument 159
The GC Emulator is a Microsoft Windows application and an
optional component of PROstation that mimics the behavior of a
490-PRO micro GC.
The GC emulator can be thought of as the Windows version of
the Micro GC firmware. In other words, the program acts like a
digital 490-PRO GC.
Installation
To install the GC Emulator:
1 Double click the PROstation setup file.
2 The PROstation setup wizard appears. Follow the onscreen
instructions.
The title bar and status bar indicate that the instrument is
emulated.
3 Apply the method you wish to use. You may create a new
method, or modify an existing method, by opening the
existing file and manually changing it or using the wizard
(File > Method > Wizard).
10
Instrument Configuration
Main Menu 162
Main Menu Functions 166
Instrument Configuration 170
490-PRO Configuration 171
Communication Frame 173
Configuration Frame 175
Services Frame 203
PROstation Operation 204
Main Menu
PROstation can be started from the Windows desktop or the
Windows menu. After a login procedure, you enter the main
menu manager where you can configure 490-PRO instruments.
Login procedure
After starting PROstation, a login screen is displayed. In this
screen, you can type the username and password. Depending on
the username and password you will log in as one of the three
default security levels. Table 23 displays the default usernames
and passwords.
Change password
The password can be changed to the user preference. Press the
Change button to change the password.
There are two options:
No Password option: enabling this option gives the user the
ability to log in to PROstation without password.
Edit a new password in the Password field (admin/new
password?)
• Click the OK button. PROstation will return to the main login
window.
• Password should be changed successfully.
Table 24 Privilege
Administrator
Privilege level Service level Read only level
Reading all available status X X X
parameters
Open, Edit and save X
Method-, application-,
sequence-, datafiles,
Modbus- and FTP settings,
Up-/download and Edit X X
calibration amounts
Up-/download Method X X
Up-/download Application X
Up-/download Sequence X X
(Automation)
Up-/download and Edit site X X
information
Up-/download Modbus X
settings
Up-/download FTP service X
Up-/download X
chromatogram data
Up-/download Real time X X
clock
Uploading sample results X X
Uploading diagnostics X X
Administrator
Privilege level Service level Read only level
Up-/download Usersettings X X* X*
from the Configuration
Starting and stopping the X
instrument
Full control over the X
instrument
* upload only
Demo
Normal No Agilent authorization key found,
Option Agilent authorization key found Offline instrument
Create a virtual instrument X X
Create online instrument X
Number of active instruments at the same 4 1
time
Number of instruments created 100 1
Open Method-, application-, sequence-, X* X
datafiles, Modbus- and FTP settings
Saving Method-, application-, sequence-, X* X
datafiles, Modbus- and FTP settings
Download Method-, application-, sequence-, X*
datafiles, Modbus- and FTP settings
Getting status information of an connected X
instrument
Start or stop an instrument X*
* logged in as administrator only
Control window
A maximum of four instruments can be
shown in the control window, only one
can be controlled at a time.
Configure Instrument X
Configures the selected instrument.
Delete Instrument X
Removes the selected instrument permanently from the list
with configured instruments and from PROstation.
Control menu
The Control window is the frame where all controllable
instruments are visible. The maximum number of controllable
instruments is four.
Virtual instrument
After creating a new instrument you can choose whether you
want the instrument to be a real instrument or a Virtual
instrument.
In PROstation Created, instruments can be either new,
configured or Virtual.
• New instrument is the instrument state directly after creation.
• Configured instrument is a new instrument, which had contact
with a 490-PRO instrument and uploaded its configuration. If
a configured instrument is used, the status will be either
Busy or Off.
• Virtual instrument is used for creating a method without the
need to be connected to an instrument. In the instrument
configuration menu, hardware tab you can set the Virtual
instrument mode.
Configured Configured
instrument opened instrument Opened
Option New instrument ** normally Offline Virtual instrument
Hardware Configuration X X
editable
Selecting to create an Virtual X***
instrument
Configure network-settings X X
Upload Configuration X X
Download Usersettings X*
Download PROstation X*
settings
Open/Edit Method-, X* X* X*
application-, sequence-,
datafiles, Modbus- and FTP
settings
Saving/Edit Method-, X* X* X*
application-, sequence-,
datafiles, Modbus- and FTP
settings
Upload a method X
Download Method-, X*
application-, sequence-,
datafiles, Modbus- and FTP
settings
Getting status information of X
a connected instrument
Start or stop an instrument X
* Logged in as administrator only
** After configuring network settings and uploading configuration, the new instrument becomes
configured.
*** When selecting this option an upload is not possible
Instrument Configuration
Configuration of instruments and detectors is done from the
Main Menu of PROstation. To access instrument configuration,
either create a new instrument or select an instrument by
highlighting it, then select the Control/Configure… command. Or,
click the instrument with the right-mouse button and select
Configure… from the popup menu.
You must have PROstation Administrator privileges to configure
instruments.
To configure a new instrument:
• Select File\New Instrument or Ctrl+N.
• A Configure Instrument window will appear, see Figure 115.
• Instrument Serial number is not identified yet.
• Click the Configure button. The 490-PRO configuration window
appears displaying the configuration settings of the
instrument.
At this point, the default settings of PROstation are displayed.
When you select the Configure command for a 490-PRO, a
configuration dialog box appears, see Figure 116 on page 171.
Instrument Type
Select 490-PRO Micro GC
Serial Number
Instrument serial number will
be displayed once
communication is established.
Title
Enter an identification name
for the instrument. The name
will appear in the icon and in
the application window, as
well as in other areas.
490-PRO Configuration
In this configuration screen, the 490-PRO Micro GC can be
configured. The screen is divided into three frames:
• Communication Frame
• Services Frame
• Configuration Frame
Communication Frame
Ethernet communication
Select the Setup IP address button to setup the IP address for the
instrument. If the IP address is already known (and in the
correct subnet range) only the IP address has to be typed in, see
Figure 117.
It is also possible to change the IP address and to view all the
490-PRO Micro GCs connected to the subnet.
Configuration Frame
In this frame, different tabs are available:
Hardware tab 175
User settings tab 177
PROstation tab 179
Automation tab 180
Info tab 199
Always click the Upload Config button before editing the various
tabs (except if you want to create a virtual instrument).
The instrument hardware settings, user settings, instrument
serial number, available licenses, and general information (such
as software version numbers, etc.) will be uploaded from the
490-PRO and displayed in the Configuration tabs.
Hardware tab
The Hardware Tab contains the hardware settings of the
490-PRO. These can be uploaded from the instrument by
pressing the Upload Config button.
Carrier gas
Select the carrier gas for the application. Changing carrier gas
requires a special procedure, which must be followed. The GC
driver will guide you through the special procedure.
Pop up window: Reboot your instrument. In this example,
system carrier gas type is changed from He to N2.
Channel disabled
Disable an installed channel. Once an installed channel is
disabled, the 490-PRO Micro GC will ignore this channel.
Continuous Flow
Select continuous flow if this is required.
Peak simulation
Peak simulation can be used for demonstration and
communication testing. If it is selected, all the GC channels will
generate a default chromatogram.
Flush cycles
The number of flush cycles is configurable. Select between None,
1, 2, and 3 flush cycles. The Flush cycle is invoked at startup of
the instrument or when pressure is restored after a
low-pressure error.
490-PRO activation
Activate 490-PRO behavior. The connected instrument must
have a 490-PRO License before activation is possible. See
“Available Licenses and Options” on page 176.
PROstation tab
• Channel description
The channel descriptions are uploaded from the Electronic
Data Sheets (EDS) of the GC channels each time the Upload
Config button is pressed. This will be the description of the
column installed. The descriptions will appear on top of
each chromatogram window in Instrument control. The
channel description can be replaced by any other text if this
is desired, for instance the application name (hydrocarbons,
permanent gases, etc)
• Pressure units
Select between kPa and PSI. The column and ambient
pressures status will be displayed in the selected pressure
units in the Method Setup on page 230 and Instrument
Control window of instrument control on page 649.
Automation tab
Settings for control over a number of external devices can be
configured through the contents of the Automation tab.
A C G
D E
A. IO settings
The I/O settings show the availability and usage of the different
types of I/O.
Timed relays Can be used for a timed program based upon the
states of the run. For example a relay can be switched
X seconds after injection. Enter the number of Timed relays to
use.
Column description
I/O type Gives the type and number of the specific I/O’s.
For more details about extension board functionality and setup see the
NOTE
separate extension board manual.
valve is a 16 port valve. If three valves are used, the first and
second valve must be equipped with 16 ports. Multiple valves
should be connected in cascade mode. The outlet of valve 2 (and
valve 3) should be connected to stream number 16 on the
previous valve. See Figure 129 for logical stream numbers as
used in the 490 PROstation.
For each valve a serial cable is required. Moreover, multiple
serial cables should be connected using a multi drop cable to
com port 2. For more details about stream connections and
cable part numbers, see Figure 129.
3 Open PROstation
4 Configure your 490 Micro GC. For one VICI Valve, the
number of streams is <= 16.
You can also click the Configure USB button to check whether the
attached USB-to-serial converter is recognized. The 490 Micro
GC will ignore any USB serial device with an invalid SN.
The Configure USB table is read only. Currently, a valid SN
will have the pattern 067b2303* for a FTDI FT232 series
chipset, or 04036001* for a Prolific PL2303 family chipset.
7 Input the stream number you want to switch, and click OK.
The VICI valve will switch to the target stream, and the
Sample stream # will change to match.
3 Open PROstation.
4 Configure your 490 Micro GC. For one VICI Valve, the
number of streams is <= 16.
You can also click the Configure USB button to check whether
the attached USB-to-serial converter is recognized. The 490
Micro GC will ignore any USB serial device with an invalid
SN.
G. Download
After changing the automation settings, it is mandatory to
download these settings to the 490-PRO. After a download, a
reboot of the instrument is required to enable all settings.
Info tab
The Info tab contains information about software versions,
MPU
Software version of the GC application in the MPU of the
490-PRO.
Part number#
Part number of each GC channel.
GC_DLL
Software version of the GC_DLL.dll library used by the
PROstation. This library contains the communication and
protocol layer.
InstDataExchange
Software version of the InsDataExchange.dll used by
PROStation. This library creates a connection between the
different parts of PROstation.
I/O Controller
Software version of the I/O Controller, a micro controller in the
490-PRO
Exit configuration
Exit configuration screen by clicking the OK button. The
instruments serial number is displayed in the Configure
Instrument screen.
Services Frame
End configuration
After all necessary information has been entered and
downloaded to the 490-PRO instrument, the configuration must
be exited and accepted by pressing the OK button on the
490-PRO configuration window and OK from the configuration
instrument window.
Now the instrument is completely configured and the
configuration information is stored.
From the PROstation main menu, one can select and open an
instrument by double-left clicking on the appropriate
instrument icon to continue method development.
PROstation Operation
Once programmed, the 490-PRO gas chromatograph is capable
of running samples and report results to external computers
without any workstation connected. Programming the 490-PRO
is done using the PROstation package.
PROstation is the communication interface between your PC
and the 490-PRO.
PROstation allows up- and downloading of various method
parts. Inside PROstation, the methods can be edited only.
PROstation is not a standard data handling system. It can not
do any integration or result calculation. That is handled inside
the 490-PRO.
PROstation is capable of collecting and showing results only.
After the instrument(s) have been configured, a method should
be developed.
Method development takes a number of separate steps: The first
part is the development of the chromatographic method:
1 Set Clock (it is advised to use the PC clock).
2 Run a (test or calibration) sample with correct analytical
instrument settings.
3 Develop and set integration parameters.
4 Run the method wizard.
5 Complete the identification table.
6 Set up calibration parameters.
7 Run the application wizard.
8 Complete all application features.
9 Run a sample and show integration and application results.
10 Setup automation (sequence, FTP service, etc).
11 Start full automation.
11
PROstation Instrument User Controls
Log in 208
Instrument Method Setup 209
User Log In 210
Toolbar Instrument Control 214
Log in
When PROstation is started, User Name and Password are
requested. Press the Change button to set up passwords for
different end users. The default password is demo for all users.
User Log In
There are three user levels for logging into the instrument. Each
level requires a unique login. Set up a unique password for each
user, see Figure 158.
Figure 160 Service menu for changing methods for service engineers
12
PROstation Instrument File Menu
Import/Export 216
Method Wizard 219
Application Wizard 220
Sequence Wizard 222
Modbus Wizard 223
Import/Export
PROstation stores chromatograms in a proprietary format with
a .pdat file extension. Using the import/export functionality of
PROstation it is possible to exchange chromatograms between
OpenLAB CDS EZChrom, Galaxie CDS, PROstation FTP service,
and PROstation.
The file menu gives access to this functionality, see Figure 165.
The exported ascii file contains two columns, the Time column
in minutes and the Value column.
selecting the SSI Ascii (*.asc) file type, see Figure 167. For more
details see the OpenLAB CDS EZChrom manual.
Method Wizard
The method wizard can be used to easily generate a Method
containing Peak identification/Calibration settings extracted
from an analysis run.
Application Wizard
From the Application menu Normalization, Calorific Power, Analog,
and Digital Control can be defined.
An Application or Verification check is only required when
Calorific values, IO’s or an LCD screen are defined.
• Activate Application Wizard. Select File\Application\Wizard.
• Select from the Application window, select option Generate
Normalization table from Method-Peak table, see Figure 169 on
page 221.
• Select the options required for later instrument operation
and click OK.
• Save Application (Save as... option). Edit a proper application
file name.
To access the sequence, select Automation\Sequence. Fine tune
the sequence after the sequence wizard has created most of the
parameters.
Find information about Sequence setup in the chapter
“PROstation Automation Menu” on page 387.
Save sequence and download sequence to the instrument, see
Figure 169 on page 221.
Sequence Wizard
Select the sequence wizard to quickly set up a sequence from
scratch.
To activate the sequence wizard, from the PROstation toolbar
select File\Sequence\Wizard.
Modbus Wizard
Select the Modbus Setup Wizard to generate a modbus table
from scratch containing a list of modbus registers holding the
sample results, instrument status, instrument control, etc. To
activate the Modbus wizard, from the PROstation toolbar select
file\Modbus\wizard. More information can be found in
“Automation – Modbus Setup” on page 402.
13
PROstation Instrument View Menu
View 226
View
From the PROstation toolbar, select View:
Application workspace
Detailed instrument status, application report and the actual
channel data. The chromatogram window has all kinds of
scaling functionality. This is identical to the scaling functions in
the Calibration chart, see “Calibration chart” on page 284.
Figure 172 on page 226 is an example of the Application
Workspace.
User workspace
The user workspace displays a fixed number of windows on the
screen which cannot be changed.
14
PROstation Instrument Method Menu
Instrument Setup 230
Integration Events 236
Peak Identification 254
Peak Calibration 266
Method Advanced 292
Method Properties 293
Instrument Setup
Before you can make a run with your 490-PRO, you must set up
the instrument and data acquisition parameters for one or both
channels of the instrument. To access the Instrument Setup
dialog, click the Instrument Setup icon on the toolbar, or select the
Method/Instrument Setup command from the menu.
Sample time
Sample time determines the amount of time the pump operates
to draw the sample into the sample loop. The sample time
entered here applies to all channels.
Stabilizing time
If a value larger than zero is entered for Stabilizing time, an
extra instrument state will be created, the Stabilizing state.
Continuous flow
This is the current continuous flow setting in the 490-PRO. At
startup of Instrument control, this setting is uploaded from the
490-PRO.
Flush cycles
This is the current number of flush cycles in the 490-PRO. At
startup of Instrument control this setting is uploaded from the
490-PRO.
Peak simulation
This is the current peak simulation setting in the 490-PRO. At
the startup of Instrument control, this setting is uploaded from
the 490-PRO.
Stabilization Time
The stabilization state becomes active as soon as all individual
temperature and pressure states of all channels are in the
Ready state. In the Stabilizing state, all individual temperature
and pressure states are checked.
If they all remain ready during the stabilizing period, the overall
instrument state will become Ready. If during the stabilizing
period one of the channel temperatures or pressures becomes
Not Ready, the overall instrument state will jump to Not Ready
and the whole process will start again. Enter zero for
Stabilizing time if the stabilizing period is not required.
Column temperature
Enter the desired column temperature, in °C. The GC driver
checks on the maximum allowed temperature, which can be
found in the Hardware tab of the instrument configuration.
Injector temperature
Enter the desired injector temperature, in °C. This is only
possible if the GC channel is equipped with heated injector
hardware.
Inject time
Enter the Inject Time. The Inject Time determines the amount
of time the injection valve will be open. A practical minimum
value is 20 ms.
Backflush time
Enter the backflush time in seconds. This is only possible if the
GC channel is equipped with backflush to vent hardware. A
backflush time of zero means no backflush.
Detector state
Select this box to turn the detector filaments on.
Invert signal
Select this box to invert (change polarity) of the acquired
detector data.
Sensitivity
Select the desired detector sensitivity – Auto (auto ranging),
Low, Medium, High or Extra high. Auto is highly advised as it
gives the widest linear dynamic range, with the lowest noise
level.
Pressure Mode
Select the pressure-programming mode to be used. Choose
Static for nonramped mode. Choose Programmed if you want to
enter a programming ramp rate. If you select Programmed, the
following parameters will become available.
Run Time
Run Time determines the length of time, data will be sampled.
Initial Pressure
Enter the initial pressure setting, in kPa or PSI (depending on
configuration).
Initial Time
Enter the time to hold the initial pressure, in seconds.
Pressure Rise
Enter the rate of pressure change for the ramp, in kPa/min or
PSI/min (depending on configuration). Positive rise only.
Final Pressure
Enter the final pressure setting, in kPa or PSI (depending on
configuration).
Final Time
The final time will be calculated and displayed, based on the Run
time you have set in the Acquisition Parameters.
If the final time displayed is 0, this means that your Run time is
equal to or less than the sum of your initial time and the time to
ramp the pressure to the final pressure setting. You should
change your run time accordingly.
If you have entered an incorrect parameter for any of the above
items, an error message will be displayed in this field to aid you
in correcting the setting.
Integration Events
To access integration events, click Method and select Integration
Events….
Chromatogram markers
PROstation presents the chromatograms collected from the
490-PRO Micro GC to the user. These chromatograms are
instrumented using several markers.
A. Component name
The component name is assigned to a peak using the criteria
of the Peak Identification, see “Peak Identification” on
page 254.
The component name is shown in blue in the chromatogram
above the identified peak, see Figure 180.
If the defined peak width value is too large, the peaks will not
be detected. A peak width must be defined before integrating
the chromatogram. The default peak width is 0.2 seconds.
Set threshold
This parameter is used to define the start and the end of peaks
and eliminates the lowest signal variations due to noise or to
detector signal drift.
The chromatogram is first normalized to 100,000 (Highest peak
of the chromatogram) to obtain a similar detection from one
analysis to another (for example, if the injected quantity varies).
Next, the points are grouped depending on the peak width
defined above. The mean height of a group of points is
compared to the mean height of the following group. If the
difference is higher than the threshold, the integrator marks the
beginning of a peak. The position of the marker is adjusted by
only considering the points. The peak will only be kept if its area
and height are larger than minimum values defined by user.
The peak ends are detected in the same way, using the
threshold.
The value of the threshold is important. If a too high threshold
value is defined, the peak starts will be detected too late and the
peak ends too early. Moreover, small peaks could not be
detected at all. If a too small threshold value is defined, the
peak starts will be detected too early, and the peak ends too
late, and signal noise can be detected as peaks.
The user can define the threshold value, or the 490-PRO can
estimate it using Estimate threshold according to the peaks that
should be detected. It is also possible to add a value to the
threshold using Add to threshold. For example, if the threshold is
estimated at the beginning of the analysis, and the signal noise
increases at the end of the analysis, the threshold should be
increased only at the end. Note that it is possible to add a
negative value in order to decrease the threshold value. The
default threshold value is 10.
Estimate threshold
If the event Estimate threshold is not defined, solvent peaks are
integrated. The user can define several Estimate threshold events.
Each time the event is defined, the 490-PRO calculates
threshold.
After:
Add peaks/grouping
This event enables addition of several peaks. All the peaks
defined between the activation and the deactivation of this
event are grouped into one peak. For example, isomers whose
names are not known peak by peak, but contain nearly the same
response factors can be considered as one group. The peak
grouping is considered as one peak. Note that the peak start or
stop position is automatically adjusted around the defined time
to avoid the baseline cut by the signal.
In the above example, the peaks between 10.5 and 12.5 seconds
are added.
Split peak
This event will split a peak into two parts, and can be used
either to separate peaks that are not base line resolved or to
obtain specific results on parts of some peaks in certain
applications.
This integration event is time. Variation in peak retention times vary from
NOTE
one analysis to another, may result in incorrect results.
Baseline processing
Each peak has its own baseline drawn from the peak start
marker to the peak end marker.
Horizontal baseline
This event enables the definition of a horizontal baseline. A
horizontal baseline is drawn from the activation of this event
until its deactivation. It is imperative to define the event couple
(ON and OFF) to apply this event.
The height of the baseline is the height of the signal when the
event is activated. It is better to use the Horizontal baseline by peak
event, because the height of the baseline will be related to the
start or the end of a peak, and not to the event activation time.
(between the top of the peak and the stop marker), it becomes
operative at the peak stop marker time.
Force baseline
This event forces all the peaks between the events Force baseline
On and Force baseline Off to have a common baseline. The peak
markers of the first and last peaks are, therefore, modified by
this event. To prevent modification of the first and last peak
markers, the recommended event to use is Force baseline by peak.
As a consequence, the two associated events Force baseline On
and Force baseline Off must be defined.
instead of
instead of
Baseline now
This event forces the baseline to pass through the signal at the
event time.
instead of
Shoulder peaks
To integrate a peak as the skimming of another, both peaks need
first to be integrated. Thus, it is important to define correct
detection parameters (Set peak width and Set threshold) before
defining the skimming parameters.
The tangent skim Next Peaks event does not work when the
mother peak is not fully resolved (has a valley with the previous
peak). The use of a Baseline Now event has the effect of removing
the valley, and thus allows the skimming event to work properly.
Figure 198 Without the baseline now event, there is a group of three
peaks sharing a common baseline
Figure 199 The baseline now event breaks the group of peaks
Peak Identification
The Peak Identification/Calibration contains settings to identify a
peak based on its retention time.
To access the Peak Identification/Calibration Table, click on Method,
then select Peak Identification. If no method is developed before,
it is easier to start with running the Method Wizard. Read the
information in “Method Wizard” on page 219.
Peak Name
The name of the compound corresponding to the peak. Two
different peaks cannot have the same name.
Retention Time
The theoretical retention time of the peak. Two different peaks
cannot have the same retention time.
Reference
To select reference peaks, check the Ref box in the appropriate
line(s) to indicate that the selected peak is now considered a
reference peak.
The theoretical retention times of the peaks will be corrected
according to the difference between theoretical and
experimental retention time of these peaks (see Nonreference
peaks expected retention time).
The reference peaks must be chosen carefully. Reference peaks
must be common constituents that will always appear in the
chromatogram.
If a reference peak is not present, another peak could be
incorrectly assigned as the reference peak, and thus, the
identification of the other peaks will be severely affected.
Reference peaks should be easily recognizable. It is better to
choose very high or large peaks, or the last peak of the run (with
the certainty that no other peak will occur afterward).
Selection Mode
This column defines which peak will be chosen if several peaks
are included in the identification window.
Nearest
The peak will be the one whose retention time is the closest
to the defined time.
Max height
The peak will be the highest one.
Max area
The peak will be the largest one.
First
The peak will be the first peak found in the reference
window.
Last
The peak will be the last peak found in the reference
window.
Peaks are always listed in the retention time order.
Identification process
Peaks are identified by their retention times, according to the
identification window defined by the user.
In simple cases, peak retention times are reproducible from one
analysis to the other. In the case of nonreproducible retention
times from one chromatogram to the other (due to analysis
conditions, samples etc.), identification is more complicated
and the definition of easily identifiable reference peaks is
advisable.
In the first step, the 490-PRO will identify the reference peaks
and will estimate the time offset (according to the retention
time) that will be applied during the identification of the other
peaks of the chromatogram (nonreference).
First, the 490-PRO checks that the identification windows of the
reference peaks do not overlap each other. If window overlap
occurs, the 490-PRO resolves the overlaps and the reference
peak identification is processed.
Using the experimental reference retention times, the 490-PRO
calculates the other expected retention times, resolves the
nonreference peak window overlaps, and the nonreference
peaks are identified with these retention times and windows.
Since the reference and nonreference peaks are processed
separately, it is possible to define larger reference windows
because it does not matter if they overlap with the nonreference
identification windows.
For example:
• Example 2
A peak window belongs entirely to another.
Peak 1: RT1= 1.7 ID window: 0.45: [1.25 -2.15]
Peak 2: RT2= 1.99 ID window: 0.04(W2) [1.95 -2.03]
Nearest
The peak will be the one whose retention time is the closest
to the defined time.
Max height
The peak will be the highest one.
Max area
The peak will be the largest one.
First
The peak will be the first peak found in the reference
window.
Last
The peak will be the last peak found in the reference
window.
Once the reference peaks are identified, the 490-PRO will
identify the other peaks.
Where
• RT is the expected retention time for a nonreference peak.
• RT1 is the real retention time of the reference peak preceding
the peak.
• RT2 is the real retention time of the reference peak following
the peak.
• RTID is the theoretical retention time of the peak defined in
the identification table.
• RTID1 is the theoretical retention time of the reference peak
preceding the peak, defined in the identification table.
• RTID2 is the theoretical retention time of the reference peak
following the peak, defined in the identification table.
Nearest
The peak will be the one whose retention time is the closest
to the defined time.
Max height
The peak will be the highest one.
Max area
The peak will be the largest one.
First
The peak will be the first peak found in the reference
window.
Last
The peak will be the last peak found in the reference
window.
If a reference peak is not found, its retention time is the
retention time set in the identification table, as if it had not
shifted at all. The identification of the peaks placed between the
previous and the next reference peak may be affected.
If no reference peak is defined or found, peaks are identified by
the retention times set in the identification table. Each peak
retention time is compared to the identification window defined
in the identification table.
Example
Assume that three peaks exist in a chromatogram with
theoretical retention times (saved in the identification table) of
5, 6, and 10 seconds.
When the sample is analyzed, the retention times have shifted to
6, 7.2, and 12 seconds. If the identification windows are
0.5 minute wide, and reference peaks are not used, the peaks
will not be identified.
However, if the last peak at 12 seconds is defined as the
reference peak, and it elutes 1.2 times later than the defined
theoretical retention time of 10 seconds, the expected retention
times for the two other peaks (nonreference peaks) can be
calculated.
First peak: 5 × 1.2 = 6 seconds.
Second peak: 6 × 1.2 = 7.2 seconds.
The first two peaks can now be identified correctly with these
new corrected retention times.
Retention Update%
With the Retention Update% parameter, one can set the
percentage of shifting the Retention Window as defined in the
Peak Identification/Calibration Table.
Peak Calibration
The aim of this step is to define the calibration parameters. To
define the calibration parameters select the Method/Peak
Calibration menu.
Response Mode
Define the Response Mode. Select Area or Height from the list.
This defines the processing of the peak concentration. For most
applications on a 490-PRO Micro GC, area must be selected.
Calibration Mode
External Standard mode is the fixed mode for the calibration
run.
R.F. type
Define how the Response factor should be determined.
RF Unknown peaks
It is possible to process the Response Factor of unknown
components in two different ways.
Calibration Check
A calibration check is used to check whether the response
factor (curve) drifts away in time after every new calibration.
Initial calibration
If it is required to check the Response factor of a new
calibration run against current Response factor (determined in
last calibration run) and initial Response factor (determined in
an Initial Calibration run), select this option.
• Intercept Coeff
The calculated intercept coefficient of the calibration curve.
Can also be set manually if the calibration is determined
off-line. Find more information in “Multi Level Calibration”
on page 677 and “Download Calibration Curve with
method” on page 276.
• Linear Coeff
The calculated linear coefficient of the calibration curve.
Can also be set manually if the calibration is determined
off-line. Find more information in “Multi Level Calibration”
on page 677 and “Download Calibration Curve with
method” on page 276.
• Quadratic Coeff
The calculated Quadratic coefficient of the calibration
curve. Only required if calibration curve is set to Quadratic
of Cubic. Can also be set manually if the calibration is
determined off-line. Find more information in “Multi Level
Calibration” on page 677 and “Download Calibration Curve
with method” on page 276.
• Cubic Coeff
The calculated Cubic coefficient of the calibration curve.
Only required if calibration curve is set to Cubic.Can also be
set manually if the calibration is determined off-line. Find
more information in “Multi Level Calibration” on page 677
and “Download Calibration Curve with method” on
page 276.
• Rw factor
The calculated Rw coefficient of the calibration curve. Only
required if a multilevel calibration is performed with a field
correction calibration. Find more information in “Rw
Calibration” on page 685.
• Manual RF selection
Select this option if the Response factor can/should not be
determined by the instrument and will be set manually by
the operator. This option can only be used in single level
calibration for a component. If selected enter a Response
Factor in the next column Manual RF. Find more information
in “R.F. type” on page 268.
• Manual RF value
Enter a manual Response factor if Manual RF was selected in
the previous column. Find more information in “R.F. type”
on page 268.
• Initial RF%
This is the percentage limit that the calculated Response
Factor from a new calibration run can differ from the Initial
Response Factor for that component. The entire calibration
for all components will be rejected if exceeding this limit.
Use this setting only for a single level calibration. Find more
information in “Calibration Check” on page 270 and
“Calibration Validation” on page 701.
• Current RF%
This is the percentage the limit that the calculated Response
Factor from a new calibration run can differ from the
Current Response Factor for that component. The entire
calibration for all components will be rejected if exceeding
this limit. Use this setting only for a single level calibration.
Find more information in “Calibration Check” on page 270
and “Calibration Validation” on page 701.
GOST R7 Coefficients
The four columns containing the GOST R7 coefficients will be
enabled when the GOST calibration is enabled. For further
explanation on GOST calibration method please refer to “Use
GOST calibration” on page 271.
Calibration chart
The Calibration graph has a certain functionality that makes it
easier to work with and inspect the Calibration curve.
Change list
Click the Changelist button to load the change list. The function
of the change list is explained in “Remove and revert calibration
outliers” on page 287.
Zoom functionality
By selecting a location (rectangle) in the calibration chart with
the left mouse button, and then dragging from the left upper
position to right bottom (keeping the left mouse button
pressed), will show a zoom rectangle. If the left mouse button is
released, the chart will zoom in on the rectangle shown.
Drag functionality
Select any location in the calibration chart with the right mouse
button and drag the mouse, keeping the button pressed. The
calibration lines and points are dragged along in the chart
window. When the button is released, the calibration chart
remains as shown at that moment.
Scale setting
The scale button can be used to quickly inspect what
shape/behavior the calibration curve has for higher
concentrations. Typically, this function can be useful for
nonlinear calibration curves.
The scale button switches between three steps. The default step
is the same as the fully zoomed out view. The two other scale
modes show the calibration curve for an amount respectively
4 times bigger and 20 times bigger than the biggest amount
currently in the calibration graph.
Full screen
Click Full screen to show the calibration chart maximized within
the Review Peak Calibration window. All calibration chart
functionality, such as drag and zoom functionality, are available
in this view.
Note that if calibration points are very close to each other, the
red colored calibration point might not be visible.
To view the calibration point change list, open the change list
viewer by clicking the Changelist button. The change list viewer
shows the GC channel, component, calibration level, Area and
Amount of the calibration points that are marked for deletion.
The change list can contain numerous points of different
channels, components, and levels.
6 To revert all points at once, click the Revert All Points button.
Method Advanced
In Method\Advanced, define the analysis parameters which
should be exported to a tab separated text file (export file), for
processing and diagnostics in MS Excel at a later stage.
• Select Method\Advanced.
• Select Export enabled option. Define which parameters to
export.
• Save the method. A method download is not required since
the export parameters exist only in PROstation.
Method Properties
The method properties define what the 490-PRO executes after
the chromatographic run has ended. If Peak integration,
Identification and Calibration calculations is disabled, all runs will
be performed without calculations.
If only the upper box is checked, the run data will be integrated;
peak identification and concentration calculations will be
performed and presented in the Integration Report. If the upper
box is unchecked, the underlying lines are not accessible.
If the middle box is checked, which is only possible in
combination with a checked upper box, application calculations
will be performed and Input output signals are controlled. The
sample results are presented in the Application Report.
If the bottom box is checked, which is only possible in
combination with a checked middle box, application
calculations will be performed using test amounts instead of
actual calculated amounts.
15
PROstation Instrument Application
Menu
Application – Normalize 296
Application – Calorific Power 300
Application – Verification Check 345
Application – Alarms 347
Application – Analog Outputs 349
Parameters 351
Application – Timed Relays 356
Application – Analog Inputs 358
Application – Digital Inputs 359
Application – Local User Interface (LCD) 360
Application – Normalize
Normalization is a standard calculation available in the
490-PROstation, in addition to calculated external standard
concentrations.
The Normalization table is activated under the Application menu.
If the Normalization table is empty, run the Application Wizard.
This automatically generates all peaknames in the
Normalization table for all configured peaknames in the Peak
Identification/Calibration Table.
• Peak Name
The name must be identical to the peakname in the Peak
Identification/Calibration Table. It can also be filled in
automatically using the Application Wizard.
• Channel
The GC channel on which the peak is detected.
• Ignore
If checked, the external standard concentration for this peak
is excluded from the normalization calculation.
• Bridge Component
A bridge component is used to bridge two GC channels and
compensate for an injection difference between the two
channels, a so-called bridge component. This requires a
component to be detected on two GC channels.
Select 0.none if not using a bridge component.
Select 1.comp.1 for a component which is detected on two GC
channels. Mark the same component on the other channel
also with 1.comp.1.
If the instrument is equipped with three or four channels,
two other channels can be bridged by marking the two
components 2.comp.2.
Once a bridge component is defined, the instrument
calculates a bridge factor of the component marked as
1.comp.1. This factor is the result of dividing the two external
standard concentrations. Note that this factor should be
close to value 1.0. All peak concentrations of one channel
will be multiplied with this bridge factor. Select Ignore for
only one appearance of the bridge component. This will
exclude one instance of the components concentration from
the normalization concentration.
• Estimate
Select to add a component that is not identified in the
chromatographic run to the Application Normalization. Give
a name in the name-field. The added component can either
have an absolute value to be provided in the Estmate Conc
field or the concentration can be set relative to an identified
peak (add indexnumber to RefConcPeak# field) and a fixed
percentage peak (add %number to RefPeakConc% field) of that
peak.
• Test Conc
Value to check the normalization calculation method. Any
value given here will overrule the actual calculated
normalized concentration. Note that you have to select the
appropriate box Application Use test Amount under
Method\properties.
• RefConcPeak#
Must be used in combination with Estimate. See parameter
Estimate.
• RefPeakConc%
Must be used in combination with Estimate. See parameter
Estimate.
• Group#
Multiple components can be grouped together. Groups will be
separately reported in the Application Report. Add a
component to a group by giving the group number, range: 1-9.
If, for instance, components Methane, Ethane, and Propane
are to be grouped, enter a 1 in the Group# column for all three
components.
Synchronize
Introduction
Natural Gas is an energy source used throughout the world. The
energy is generated by the reaction of the natural gas with
oxygen (also known as combustion). For example, when
propane is burned in air, the following reaction occurs.
C3H8 + 5O2 3CO2 + 4H2O + heat
where
HG = total heat value (Gross, Higher, Superior, Maximum)
This allows the calculation of the Gross Heat and Net Heat
values on per compound basis. When combined with the
identification of the compounds in the natural gas to estimate
the heat content.
The analysis of natural gas by gas chromatography is used to
estimate the energy content of the natural gas. This provides a
means to monitor custody transfer of the natural gas from the
P = pi
where
pi is the partial pressure on compound i.
where
xj = mole fraction of compound j
Once Open is selected, the user can choose from the following
preloaded .papp files or from applications they have already
saved. There are 11 application files initially available. In
addition to a default.papp file, files for ISO 6976, GPA 2172,
The Superior Heating Value (Hs) and Inferior Heating Value (Hi)
are defined by the choice of the metering temperature and the
combustion temperature, the Summation Factor (SF) is defined
by the metering temperature and MW is the molecular weight of
the component. The 490-PRO calculates physical properties of
the gas on volumetric base, therefor component specific values
for Hs and Hi from Table 5 in ISO 6976:1995 (with the
correction for Propane) should be used. The heating values are
given in MJ m-3.
In the Application Report, and on the instruments webpage, the
following results are presented for Energy:
Gas density ideal kg/m3 D1 = B1 air Z air t2.p2 D2 = B2 air Z air t2.p2
Gas density real kg/m3
D1 D2
E1 = ------- E2 = -------
F1 F2
2
Zmix (compressibility) - F1 = 1 – X j b j F2 = 1 – X j b j
2
1 – X water + X water b_water
Hs mass MJ/kg
K1 K2
M1 = ------- M2 = -------
A1 A2
Hi mass MJ/kg
L1 L2
N1 = ------- N2 = -------
A1 A2
In the table shown above, each parameter value has both dry
and saturated (sat) descriptions. Dry indicates that there is no
water in the natural gas. Saturated indicates that water has
been saturated in the natural gas. In ISO 6976, the reference
temperate is 0 C, 15 C, or 20 C. The saturated water mole
fraction is 0.6%, 1.68%, and 2.31%.
The 490-PRO has the ability to convert into other units as
explained below.
Conversion factor
selection Multiplier Units
No Conversion 1 MJ/m3
MJ/m3 -> KJ/m3 1,000 KJ/m3
MJ/m3 -> KWH/m3 (1/3.6) KWH/m3
MJ/m3 -> kcal/m3 239.00573613767 kcal/m3
MJ/m3 -> BTU/ft3 26.84875658 BTU/ft3
Calculations
Molar mass
The molar mass is molar weight.
The molar mas is calculated by:
where
xj = mole fraction of component j
where
Mair = 28.9626
airB1 Z t2.p2
Relative density real dry: C1 = ---------------------------------------
Z mix
B2 Z
air t2.p2
Relative density real sat: C2 = ---------------------------------------
Z mix_Saturated
where
Zair(t2, p2) is air compressibility; values are:
• 273.15 K (0.99941)
• 288.15 K (0.99958)
• 293.15 K (0.99963)
Where
air is real air density:
D1
Gas density real, dry: E1 = -------
F1
D2
Gas density real, sat: E2 = -------
F2
Zmix (Compressibility)
Compressibility is the departure from ideal gas behavior. For
each compound in the sample, the following is calculated:
2
Zmix dry: F1 = 1 – X j b j
2
Zmix sat: F2 = 1 – X j b j 1 – X water + X water b_water
where
Xj = Mole fraction of compound j
Hs volume ideal
Hs ideal volume is based upon ideal gas superior heating value:
where
Hs_j is the superior heating value of compound j
Hs volume real
Hs volume real is volume based on real gas superior heating
value:
G1
Hs volume real dry: H1 = -------
F1
G2
Hs volume real sat: H2 = -------
F2
Hi volume ideal
Hs ideal is the volume based idea gas inferior heating value:
where
Xj is the mole fraction of compound j
Hi volume real
Hi volume real is the volume based real gas inferior heating
value:
I1
Hi volume ideal dry: J1 = -------
F1
I2
Hi volume ideal sat: J2 = -------
F2
Hs molar
Hs molar is the molar gas superior heating value expressed as
KJ/mol:
Hs molar sat:
K2 = X j H sj.molar 1 – X water + X water H water.molar
where
Hi molar
Hi molar is the molar based gas inferior heating value expressed
as KJ/mol:
where
Xj is the mole fraction of compound j
Hs mass
Hs mass is the mass based gas superior heating value expressed
as MJ/kg:
K1
Hs mass dry: M1 = -------
A1
K2
Hs mass sat: M2 = -------
A2
Hi mass
Hi mass is the mass based gas inferior heating value expressed
as MJ/kg:
L1
Hi mass dry: N1 = -------
A1
L2
Hi mass sat: N2 = -------
A2
Wobbe superior
Wobbe index based on superior heating value:
H1
Wobbe superior dry: O1 = -----------
C1
H2
Wobbe superior sat: O2 = -----------
C2
Wobbe inferior
Wobbe index based on inferior heating value:
J1
Wobbe superior dry: Q1 = -----------
C1
J2
Wobbe superior sat: Q2 = -----------
C2
GPA2172 / ASTM-D3588
Relative -
A1 A2 A3
density ideal B1 = ----------- B2 = ----------- B3 = -----------
(Molar mass M air M air M air
ratio)
Relative -
B1 B2 B3
density real C1 = ------- Z air C2 = ------- Z air C3 = ------- Z air
(SG) F1 F2 F3
In the table shown above, each parameter value has Dry, Actual
(act), and Saturated (sat) values. Dry indicates natural gas
(containing no water). Actual indicates the known actual water
mole fraction in real measured natural gas. Saturated indicates
natural gas saturated with water. In GPA2172 and ASTM-D3588,
tested base pressure is 14.696 psi, base temperature is 60 F,
accorded saturated water mole fraction is 1.74 %, and actual
water mole fraction is 0 (Dry) and 1.74 % (sat).
Conversion factor
selection Multiplier Units
BTU/ft3 -> BTU/m3 (1/0.0283268466) BTU/m3
BTU/ft3 -> MMBTU/ft3 (1/1,000,000 MMBTU/ft3
BTU/ft3 -> MMBTU/m3 (1/1,000,000* MMBTU/m3
0.02831684666)
BTU/ft3 -> MJ/m3 (1/26.83914663) MJ/m3
BTU/lbm -> MJ/kg (2.326/1,000) MJ/kg
Calculations
Molar mass
The molar mass is molar weight.
The molar mass is calculated by:
A2 – w% M water
Molar mass dry: A1 = -------------------------------------------
-
1 – w%
where
Xj is mole fraction of component j, including actual water
mole fraction
Mj is molar mass of component j
A1
Relative density ideal dry: B1 = -----------
M air
A2
Relative density ideal act: B2 = -----------
M air
A3
Relative density ideal sat: B3 = -----------
M air
where
Mair = 28.9626
B1
Relative density real dry: C1 = ------- Z air
F1
B2
Relative density real act: C2 = ------- Z air
F2
B3
Relative density real sat: C3 = ------- Z air
F3
where
Zair is the compressibility of air = 0.9996
D1
Gas density real dry: E1 = -------
F1
D2
Gas density real act: E2 = -------
F2
D3
Gas density real sat: E3 = -------
F3
Zmix (Compressibility)
Compressibility is a departure from ideal gas behavior. For each
compound in the sample, the following is calculated:
i X b – w% b
i w
2
Zmix dry: F1 = 1 – P b -------------------------------------------
-
1 – w%
2
Zmix act: F2 = 1 – P b X i bi
Zmix sat:
X i b i – w% b w 2
F3 = 1 – 1 – 1.74% -------------------------------------------- + 1.74% b w P b
1 – w%
where
Pb is the base pressure =14.696 psi
G2 – w% H wv
H Gross volume ideal dry: G1 = -------------------------------------
1 – w%
where
Xj is the mole fraction of component j
G1
H Gross volume real dry: H1 = -------
F1
G2
H Gross volume real act: H2 = -------
F2
G3
H Gross volume real sat: H3 = -------
F3
I2 – w% H
H Net volume ideal dry: I1 = --------------------------------w-
1 – w%
where
Xj is the mole fraction of component j
I1
H Net volume real dry: J1 = -------
F1
I2
H Net volume real act: J2 = -------
F2
I3
H Net volume real sat: J3 = -------
F3
H Gross Mass
H Gross Mass is the real gas mass based, gross heating value,
and is calculated as follows:
Mw
K2 – w% H wm --------
M
H Gross Mass dry: K1 = ----------------------------------------------------
Mw
1 – w% --------
M
M
H Gross Mass act: K2 = X j ------j H s_j.mass
M
where
Xj is the mole fraction of component j
H Net Mass
H Net Mass is the real gas mass based, net heating value, and is
calculated as follows:
Mw
L2 – w% H wm --------
M
H Net Mass dry: L1 = ---------------------------------------------------
Mw
1 – w% --------
M
M
H Net Mass act: L2 = X j ------j H i_j.mass
M
M
H Net Mass sat: L3 = L1 1-1.74% -------w-
M
where
Xj is the mole fraction of component j
H Gross molar
H Gross molar is the molar based, gross heating value, and is
calculated as follows:
M2 – w% H
wm
H Gross molar dry: M1 = ---------------------------------------
1 – w%
where
Xj is the mole fraction of component j
H Net molar
H Net molar is the molar based, net heating value, and is
calculated as follows:
N2 – w% H
H Net molar dry: N1 = ----------------------------------w-
1 – w%
H1
Wobbe index, real dry: O1 = -----------
C1
H2
Wobbe index, real act: O2 = -----------
C2
H3
Wobbe index, real sat: O3 = -----------
C3
act Q – W% GPM w
GPM total, real dry: Q1 = ------------------------------------------------
-
1 – W% F1
where
Xi is the mole fraction of component i
Pb = base pressure
GPA 2172
For the calculations based on GPA 2172, selection of the
metering temperature and the combustion temperature are
defined at 60 °F. It is necessary to input the Base Pressure,
normally 14.696 psia (1atm) is used unless a different base
pressure is specified (GPA 2172 cites other common base
pressures as 14.65psia, 14.73psia, and 15.025psia).
Calculations
Compressibility
For each compound in the sample the following is calculated.
cfj= xj * SFj
where
xi= Mole fraction of compound j
CF = Σcfj
Compressibility = 1-CF2
Molar mass
Molar mass is calculated by:
Molar mass = Σ xj * Mj
where
xj = mole fraction of component j
where
xi = mole fraction of component i
Pb = Base pressure
The total heat value of the mixture is the sum of each mole
fraction multiplied by the calorific value of the compounds in
the mixture.
where
xi = mole fraction of component i
Pb = Base pressure
Hvid(wet) = (1-xw)*Hvid(dry)
xw = Pwsat/Pb
where
xi = mole fraction of component i
Pb = Base pressure
The total heat value of the mixture is the sum of each mole
fraction multiplied by the calorific value of the compounds in
the mixture.
where
xi = mole fraction of component i
Pb = Base pressure
Hvid(wet) = (1-xw)*Hvid(dry)
xw = Pwsat/Pb
Specific gravity
Specific gravity is also known as relative density and is
calculated from the molar mass.
d° = Σ xj * [Mj /Mair]
where
d° = relative density of the ideal gas
Mj = molar mass of component j
where
zair = compression factor for air at t1
Wobbe index
Wobbe = Hv act/√Rel. Density
Hv act MJ/M3
To convert from BTU/CF to MJ/M3
hv act MJ/M3
To convert from BTU/CF to MJ/M3
Density
The density of the ideal gas
P
t p = ---------------- x j M j
R T
where
Specific volume
Specific volume = 1/Density
GPM total
This is the liquid volume equivalent expressed as gallons per
1000 cubic feet of gas
N
GPM = Σ (xi *1000) * Pb) / (Vi *14.696)
I=1
xi = mole fraction of compound I
N = number of components
ASTM D3588
For the calculations based on ASTM D3588, selection of the
metering temperature and the combustion temperature are
necessary. The ASTM calculations are the same as the GPA
calculations. The Application Report provides the same
calculations as the GPA Application Report. The application
D3588.papp has the values from Figure 247 in the ASTM D3588
standard. These are based on the ASTM D3588-1989 version.
Footnote A of Table 1 shown in Figure 247 states: This table is
consistent with GPA 2145-89, but it is necessary to use the
values from the most recent edition of GPA 2145 for custody
transfer calculations.
Updating the application file with GPA 2145 updates for custody
transfer calculations
Comparing the Component Constants to GPA 2145-09 does
show some differences. Using n-pentane as an example, the
value of Hv (Gross Heating Value) has changed from 4008.9 to
4008.7, the value of hv (Net Heating Value) has changed from
3703.9 to 3707, the value of SF (Summation Factor) has changed
from 0.0631 to 0.0606, and MW (Molecular Weight) from 72.15 to
72.1488. The updated values can be entered by clicking on the
cell and entering the updated value.
The Summation Factor for Air have also been updated. See
Figure 248.
When using the Estimate feature, air is not required in the Peak
Identification Table, only the Normalization Table. See Figure 250.
GOST 22667
When GOST 22667 is selected, the Calculation Method tab shows
the following screen. GOST 22667 does not require the selection
of metering temperature and the combustion temperature. See
Figure 251.
Calculations
Relative Density
For each compound in the sample the following is calculated.
sgi= xi *(MWi/MWAir) where
Wobbe Index
The Wobbe Index is calculated for the gas sample:
Wobbe = Heat Value (Maximum or Minimum)/√(Relative
Density)
The GOST standard allows the Wobbe index to be reported as
the Maximum and Minimum values in either MJ/m3 or kcal/m3.
GOST 31369
The availability of this functionality depends on your license.
The Superior Heating Value (Hs) and Inferior Heating Value (Hi)
are defined by the choice of the metering temperature and the
combustion temperature, the Summation Factor (SF) is defined
by the metering temperature and MW is the molecular weight of
the component. The 490-PRO calculates physical properties of
the gas on volumetric base, therefor component specific values
for Hs and Hi from Table 29 in GOST 31369 should be used. The
heating values are given in MJ m-3.
In the Application Report and on the instrument’s webpage, the
following results are presented for Energy:
Use the Download Application from the Control menu to store the
Verification settings to the 490-PRO. Only the Activated lines in
the Verification Table will be downloaded to the 490-PRO.
Find more information in “Verification run” on page 701.
Application – Alarms
Alarm relays can be used to indicate whether parameters are
out of limits. Such as:
• External standard or normalized concentrations of
components listed in the Application Report.
• Sample results such as sum or group total and bridge
component as defined in the Normalization window
(Application menu).
• Analog Inputs using the (sampling) converted values as
defined in the Analog Input window.
• Calorific Power results as defined in the Energy Calculation
window (Application menu).
• GC Status such as ambient temperature and pressure.
• External Digital inputs from other devices such as flowmeter.
The analog outputs are set after processing a certain run type
(or when using Recalculate Current Run). The run type is defined
in the Update On column. Choices are:
• Analysis
• Blank
• Calibration and
• Verification
Enable the Analog Output Table in the Settings tab.
Parameters
The parameters for verifications, alarms, and analog output are
listed in Table 31.
Sample
Run cycle time
Injection
started
Inject
time
Run
time Stream selected
[new stream]
(stream ahead)
The timing of the events Stream Selected and New Stream depends
on the Stream Ahead Scheduling option (Sequence Properties tab of
Automation Sequence). Without Stream Ahead, the stream selector
position is updated at the end of the run followed by the Flush
Time. With Stream Ahead, the stream selector position is updated
just after the injection. Flushing is started and the remaining
Flush Time shorted.
To indicate that the chromatography system is in action, make
the following definition in the Timed Relays tables.
The first line defines the Energize event (Injection Started) for
the Timed Relay 1. The second line defines the De-energize event
(Sample Calculation).
To pulse a relay if a new stream is selected, make the following
definition.
0. None
Display line is not configured, will result in empty line in LCD.
Displays the molar mass of the actual sample from the last run
calculated according to selected standard.
Displays the real gas density of dry sample from the last run
calculated according to selected standard.
I/O parameters
This section gives an overview of the available I/O parameters
that can be displayed on the LCD. For each parameter, an I/O
channel number in the Channel# column should be set, see
Figure 289 for an example.
API21 Parameters
Statistical parameters
This section gives an overview of the available API21 average,
minimum and maximum parameters which can be used in the
LCD configuration. For each parameter the channel# and peak#
needs to be set. The channel# should be set to the stream
number. The stream number can be set from 1 till the maximum
number of available streams. The peak# should be set to one of
the API21-ParamID, see Table 34 on page 383.
The CHAN identifies from which stream the results are
requested. The API21-ParamID identifies which value is
requested, for instance PARAM_ID = 101 identifies the Heating
value superior.
Historical parameters
This section gives an overview of the available API21 Latest,
previous, 2nd previous and 3rd previous result parameter
which can be used in the LCD configuration. This parameter
provides access to the stored API21 values. For this parameter
the channel# and peak# should be set. The channel# should be
set to one of the following options:
• 0. Latest results
• 1. Previous results
• 2. 2nd Previous results
• 3. 3rd Previous results
The peak# should be set to one of the API21-ParamID, see
Table 35.
16
PROstation Automation Menu
Automation Sequence 388
Sequence Table 392
Verification Properties 394
Verification Table 396
Calibration Properties 397
Calibration Table 399
Automation – Site Information 401
Automation – Modbus Setup 402
Advanced Modbus Information 414
Modbus Parameter ID Reference 423
Automation – FTP Service 631
USB Storage 633
Automation – Real Time Clock 645
Automation – Reprocess List 647
Automation Sequence
If no Sequence is available, execute the Sequence Wizard. This
will generate a sequence upon the selections in the wizard, see
“Sequence Wizard” on page 222.
To access Sequence, click the Automation pull down menu from
the PROstation Toolbar and select Sequence.
The Sequence menu has two different layouts, depending on
stream selection hardware present. A hardware setup with no
stream selection device is unable to switch to different sample
streams, or select calibration- or verification gas streams while
being automated. A hardware setup with a VICI sample
selection device or a Relay type sample selector has the ability
to switch sample streams, run blank samples, run and perform
timed calibrations or verifications.
A hardware setup with no stream selection device is unable to
switch to different sample streams, or select calibration- or
verification gas streams while being automated.
The sequence Run Properties will look like Figure 291. As only
one single sample is connected, one run type can be performed.
In case of a necessary calibration or verification, the sequence
must be stopped, the appropriate sample connected and the
Run Properties must be changed or another sequence opened
and downloaded to the instrument. To resume normal operation
again, the Run type must be reset to Analysis.
Continuous analysis
The instrument will run continuously. An internal watchdog
will monitor the ongoing process. If for some reason the ongoing
process is disturbed, the instrument will be rebooted. Always
have the Restart on reboot option enabled in the Automation -
sequence page in order to let the instrument continue a
sequence which was interrupted by reboot.
Number of repeatings
The number of times a sequence should be repeated.
Home position
Determines the position of the stream selection device at power
startup and after completion of the sequence (including
aborting the automation) or when the system has encountered
an error. This option ensures that a known sample stream flows
through the sample lines in case there is no analysis being
performed by the system.
Sequence Table
If a sequence is required with automatic calibration by means of
a stream selector, it is recommended to put only analysis runs
(Sample Type = Analysis) in the Sequence Table. In addition, fill
the Calibration Table only with the required calibration runs and
finally set the triggering for a calibration in the Calibration
Properties.
Sample type
The sample type for this line (run). Can be set to None, Analysis,
Blank, Calibration, Verification. Sample type = None represents a
blank run without sample being injected (injectime = 0 msec).
Replicates
The number of runs for this line in the Sequence Table.
Calib. level
Sets the calibration level for the line. The number of Calibration
levels available is determined by the calibration method. This
field is only relevant when sample type is set to Calibration or
Verification. For an Analysis run type, just enter 0.
Stream #
The sample stream number for this line.
Flush time
Sets the time in seconds the sample selected in Stream# is
flushed through the tubing before the actual injection is made.
When Stream Ahead Scheduling is enabled, the flushing process of
the next sample stream will be invoked five seconds after
injection.
Solution slot #
A solution is a set of method and application settings.
PROstation allows you to create and store multiple solutions for
use by the GC. Each solution is stored in a solution slot.
Existing solutions can be downloaded to the GC on demand, as
well as be associated with one or more runs in a defined
sequence. See “Solutions” on page 657.
Verification Properties
On sequence start up
Checking On Sequence Startup forces the system to run the
Verification Table on starting automation. Once the Verification
Table is completed, the system will revert back to the Sequence
Table contents.
Verification Table
Replicates
Determines the number of cycles for this particular line in the
Verification Table.
Calib. level
Set the calibration level for the line. The number of Calibration
levels that are available is determined by the calibration
method. Verification calculation is done against the set level of
calibration
Stream #
Sets the sample stream for this particular Sequence Table line.
Flush time
Sets the time in seconds the sample selected in Stream# is
flushed through the lines before the actual injection is
performed. Note that when Stream Ahead Scheduling is enabled,
this flushing process may be started during the previous run.
Calibration Properties
On Sequence Start up
Checking On Sequence Startup forces the system to run the
Calibration Table on starting automation. Once the Calibration
Table is completed, the system will revert back to the Sequence
Table contents.
On Verification Failure
When this option is selected, the system will run the calibration
block after verification has failed to meet its criteria for that
particular calibration level. System will complete Calibration
Table and revert back to Verification Table, complete that and
revert back to Sequence Table.
Note that the system will always complete the run in progress
before switching to Calibration Table contents. In case a
Calibration Table is running it will be completed at all times,
before switching to verification block or reverting back to
Sequence Table.
Calibration Table
Replicates
Determines the amount of cycles for this particular line in the
Calibration Table.
Calib. Level
Set the calibration level for the line. The number of Calibration
levels is determined by the calibration method. Calibrating will
add data points to the calibration curve according to Calib level
set.
Calib. Type
This field sets the way the calibration result is handled.
Available options are Ignore, Replace, or Append. Selecting Ignore
causes the calibration to be rejected and they will not be added
to the calibration curve. This can be used for flushing runs. This
cleaning the system without performing an update of the
calibration curve. Selecting Replace will delete all available older
calibration points for the particular level in the calibration
curve and the new calibration result for the level is added
instead. Selecting Append simply adds the result to the existing
calibration curve.
Stream #
Sets the sample stream for this calibration line.
Flush time
Sets the time in seconds the sample selected in Stream# is
flushed through the tubes before the actual injection is
performed. When Stream Ahead Scheduling is enabled, this
flushing process may be started during the previous run.
Protocol
Change the Modbus protocol from standard MODICON to other
derived Modbus protocols. Modbus MODICON is a standard
protocol for SCADA systems. Differences between Modbus
MODICON and other Modbus protocols can mainly be found in
the holding and input registers above the address 4999 range
and above the 6999 range. Above address 4999, the
non-MODICON protocol will return 4 byte integers, above 6999
the protocol will give 4 byte floating point values.
Slave address
The Modbus serial slave address of the 490-PRO. Every serial
Modbus device must have a unique slave address. This way the
Modbus Master (DCS, flow computer) knows how to contact a
specific 490-PRO.
In a Modbus TCP/IP network, the slave address is ignored in the
490-PRO. If there is a conversion from Modbus TCP/IP to serial
Modbus by a Modbus bridge, although ignored by Modbus
TCP/IP devices, the slave address is vital when the Modbus
request is passed from Modbus TCP/IP to Modbus serial by a
Modbus bridge. For more information see “Modbus bridge” on
page 420.
Baud rate
Baud rate of the serial connection. The speed in characters per
second in which data is transmitted over the serial connection
between the 490-PRO (Modbus client) and the DCS or flow
computer (Modbus Master).
Port settings
The port settings on which the primary and secondary comport
are configured. This configuration is set in “D. Communication
port settings” on page 184.
Comport Primary
The Comport to which the first Modbus master is connected as
set in “D. Communication port settings” on page 184.
Comport Secondary
The Comport to which the second or redundant Modbus master
is connected as set in “D. Communication port settings” on
page 184.
• No: where for register 500 a request for register 500 is sent
out (as the 490-PRO has always done)
• 1 down: where for register 500 a request for register 499 is
sent out (which can mostly be found in the field)
• 1 up: Where for register 500 a request for register 501 is sent
out (rarely used)
For more information see “Modbus register address shift” on
page 416
Register Type
Data Type
In the Data Type column, you can choose the register output
data type.
Parameter ID
Channel
Peak#
Fixed values
By using parameter “9000. Fixed Value (Int16, MB, PEAK=fixed
value)” on page 630 “fixed values”, Modbus registers can be set
up to return a fixed definable value. Enter the required value
(INT16 value) in the “peak” column of the Modbus table. This
parameter can be used for additional identification.
Execute commands
The “Execute commands” on page 616 (0-36) can be used to
remotely perform an action. Although these parameters trigger
some action in the 490-PRO, they still require regular Modbus
parameters to be written to Modbus.
If, for example, the 490-PRO Micro GC must be rebooted on
request, create the following line in the Modbus table:
To prepare a new run, the Modbus master must set Run type,
Calibration level and stream position, parameter ID’s 60, 61,
and 62 (page 438), and then start a single run (parameter ID 0).
Predefined calibration and/or Verification Tables can simply be
started by sending out an execute command.
* These are priority runs. They will be executed after the
current run is completed. In instrument idle mode, priority
runs will be executed at once.
Modbus MODICON
Table 36 Modbus MODICON
Modbus bridge
Because of the variety of Modbus variants and connection
possibilities, one can come across a Modbus network
configuration that the 490-PRO does not or cannot support. The
same problem can occur when a Modbus serial network is
required and all 490-PRO serial ports are occupied for
additional equipment. In such cases, a Modbus bridge can be the
solution.
Two
Set Value The kind or allowed range of set value for a write
only parameter (Corresponds with return and set value field in
the Modbus Master). If successful, 0 will be returned, otherwise
a Modbus error is returned.
Modbus data type The advised data type that should be used to
work with a particular Modbus parameter.
Remarks
When recovering from a too low pressure error, a flush cycle is
always performed. A too low pressure error occurs when
changing a gas bottle or certain gas errors.
See also
Flush cycle setting. The chapter about the factory default
settings briefly mentions the flush cycle. For detailed
information about the flush cycle, refer to the 490 Micro GC
manual.
Remarks
0 = stabilizing time off
See also
Stabilizing Time
Stabilizing Time method setting
Explanation chromatographic run in 490-PRO Micro GC
cycle schema
Hardware
Accuracy
1 hour
Modbus Register Type
Holding Register
Modbus data type
Int16 (16 bit integer)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This option only applies to full automation calibration runs.
Accuracy
1 day
Modbus Register Type
Holding Register
Modbus data type
Int16 (16 bit integer)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This option only applies to full automation calibration runs.
Accuracy
1 minute
Modbus Register Type
Holding Register
Modbus data type
Int16 (16 bit integer)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This option only applies to full automation verification runs.
See also
Execute command “29. Stop Cleaning Cycle (Execute Cmd,
MB)” on page 625
Parameter “95. Set Channel to clean, 1=On (Bit, CHAN)” on
page 443
4 = Ready
5 = Critical or Fatal Error
6 = Advisory Fault
7 = Broken
8 = Not ready
9 = Waiting for external ready in
10 = Cleaning
Modbus Register Type
Holding Register/Input Register
Modbus data type
Int16 (16 bit integer)
Channel (PROstation)
Mainboard (value = 0)
Unit
Kilopascal (kPa)
Accuracy
Floating point single precision
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Channel (PROstation)
Mainboard (value = 0)
Remarks
After reading this parameter the value will be reset to 0.
Channel (PROstation)
Mainboard (value = 0)
See also
Application - Analog Inputs
Channel (PROstation)
Mainboard (value = 0)
See also
Application - Analog Inputs
Channel (PROstation)
Mainboard (value = 0) See also
Application - Analog Inputs
Remarks
To obtain the error number use parameter “132. Status:
Error Number (Int32, MB)” . This parameter only sets a
notification (return value = 1) when the 490-PRO has an
error in one of the severity classes Advisory Fault, Critical Error,
or Fatal Error. As soon as the 490-PRO is no longer in error,
this parameter is reset and will return value 0.
See also
Parameter “2212. Application: Alarm status On Index (Bit,
MB, PEAK=Index)”
Parameter “2211. Application: Overall Alarm status (Bit,
MB)”
Parameter “2402. Appl.: Stream Alarm on Index(Bit,
CHAN=stream, PEAK=index)”
Remarks
This value is set at the beginning of a run and will not be
reset until the next run is being analyzed from a different
stream. If there is no following run, the last returned value
will remain until the 490-PRO is switched off.
Accuracy
1 °C
Modbus Register Type
Holding Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Channel (value = 1 to 4)
Channel (PROstation)
Channel (value = 1 to 4)
Remarks
Note that the initial pressure anywhere in PROstation is
shown in kPa.
Channel (PROstation)
Channel (value = 1 to 4)
Channel (PROstation)
Channel (value = 1 to 4)
Remarks
The build number is only returned from firmware version
2.00 and up.
Return value
0 = Channel 2 is not installed
1 = Channel 2 is installed
Modbus Register Type
Coil status/Input Status
Modbus data type
Bit (1 bit)
Channel (PROstation)
none
Set Value
Integer value from 1 to 99
Unit
Years
Accuracy
1 year
Modbus Register Type
Holding Register/Input Register
Modbus data type
Int16 (16 bit integer)
Channel (PROstation)
Mainboard (value = 0)
Accuracy
1 min
Modbus Register Type
Holding Register/Input Register
Modbus data type
Int16 (16 bit integer)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter will only be set at the end of the calibration
run. If in the following run the error or alarm doesn’t occur
anymore, the return value is reset to 0. This parameter only
supplies valid data of the last run when a synchronization
parameter is set to 1.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Channel (PROstation)
Channel (value = 1 to 4)
Peak (PROstation)
Peak number index as used in integration result table or the
integration report. The integration peak numbers starts
with 1 for the first peak in the list, increasing with 1 for each
following peak in the integration result table.
Remarks
This parameter only supplies valid data of the last run when
a synchronization parameter is set to 1.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Peak (PROstation)
Peak number index as used in integration result table or the
integration report. The integration peak numbers starts
with 1 for the first peak in the list, increasing with 1 for each
following peak in the integration result table.
Remarks
This parameter only supplies valid data of the last run when
a synchronization parameter is set to 1.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
MetPeak (PROstation)
Peak number index as used in method peak table. The
method peak table index number starts with 1 for the first
peak in the list, increasing with 1 for each following peak in
the integration result table.
Remarks
This parameter only supplies valid data of the last run when
a synchronization parameter is set to 1.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Channel (PROstation)
Channel (value = 1 to 4)
MetPeak (PROstation)
Peak number index as used in method peak table. The
method peak table index number starts with 1 for the first
peak in the list, increasing with 1 for each up following peak
in the integration result table.
Remarks
This parameter only supplies valid data of the last run when
a synchronization parameter is set to 1.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
MetPeak (PROstation)
Peak number index as used in method peak table. The
method peak table index number starts with 1 for the first
peak in the list, increasing with 1 for each following peak in
the integration result table.
Remarks
This parameter only supplies valid data of the last run when
a synchronization parameter is set to 1.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Remarks
After a restart of the 490-PRO, this parameter is reset to 0.
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Description
Returns whether the last run is an ignored calibration. An
ignored calibration is a calibration run that will not be
accepted as such. In other words flush run with calibration
gas.
Return value
0 = A normal calibration run
1 = A calibration run that will be ignored
Modbus Register Type
Coil status/Input Status
Modbus data type
Bit (1 bit)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter returns 0 if the last run was an Analysis,
verification or blank run. Ensure the run type is known
before using this parameter This parameter only supplies
valid data of the last run, at the end of the run. Use one of
the synchronization parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Remarks
If the stream selector is controlled by the 490-PRO, the
maximum number of stream positions depends on the
number of streams selected in the configuration. This
parameter only supplies valid data of the last run, at the end
of the run. Use one of the synchronization parameters to
detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Return value
0 = Deactivated
1 = Activated
Modbus Register Type
Coil status/Input Status
Modbus data type
Bit (1 bit)
Channel (PROstation)
The CHAN argument selects the digital input.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Unit
The unit as calculated in the analog input table.
Accuracy
Floating point single precision
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
The CHAN argument selects the analog input.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Description
Returns the total number of peaks of the application report.
These are peaks that are defined in the normalization table
(maximum 100 peaks) and which are also detected in the
integration report.
Return value
0 to maximum number of peaks in the application report
(maximum 100 peaks)
Modbus Register Type
Holding Register/Input Register
Modbus data type
Int16 (16 bit integer)
Channel (PROstation)
Mainboard (Value = 0)
Remarks
The application report is a system wide report, so one
cannot select peaks per channel from the application report.
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
See also
Parameter “2229. Application: Total Unknown peaks. (Int16,
MB)” .
Parameter “1202. Int.Rep.: Number of Peaks, Named +
Unnamed(Int16, CHAN)” .
Parameter “1214. Int.Rep.: Number of Named Peaks(Int16,
CHAN)” .
Parameter “1215. Int.Rep.: Number of Unnamed
Peaks(Int16, CHAN)” .
Channel (PROstation)
Mainboard (Value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Unit
Months
Accuracy
1 month
Modbus Register Type
Holding Register/Input Register
Modbus data type
Int16 (16 bit integer)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Unit
Minutes
Accuracy
Floating point single precision
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Peak (PROstation)
Use the PEAK argument to select a Peak (component) in the
last application report. To do so, fill in the peak index of the
corresponding peak in the normalization table.
Remarks
The application report is a system wide report, so one
cannot select peaks per channel from the application report.
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Peak (PROstation)
Use the PEAK argument to select a Peak (component) in the
last application report. To do so, fill in the peak index of the
corresponding peak in the normalization table.
Remarks
The application report is a system wide report, so one
cannot select peaks per channel from the application report.
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Remarks
The application report is a system wide report, so one
cannot select peaks per channel from the application report.
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Remarks
The application report is a system wide report, so one
cannot select peaks per channel from the application report.
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters “2200. Sync: Data available
(Bit, MB)” , “2201. Sync: Data available with reset(Bit, MB)” ,
or “2238. Sync: Data available2 with reset(Bit, MB)” can be
used.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Description
Returns the volume based dry real Hs value of the sample
reported in the application report of the last run. This value
is only valid if ISO 6976, GOST 31369 or GOST 22667 energy
calculation method is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Description
Returns the saturated real Hv value of the sample reported
in the application report of the last run. This value is only
valid if GPA 2172 or ASTM 3588 energy calculation method
is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Description
Returns the Zair value of the sample reported in the
application report of the last run. This value is only valid if
GPA 2172 or ASTM 3588 energy calculamtion method is
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Return value
A positive floating point value
Unit
gal/1000ft3
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Description
Returns the dry ideal gas density value of the sample
reported in the application report of the last run. This value
is only valid if ISO 6976, GOST 31369 or GOST 22667 energy
calculation method is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Description
Returns the saturated ideal Hv value of the sample reported
in the application report of the last run. This value is only
valid if ISO 6976, GOST 31369 or GOST 22667 energy
calculation method is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Description
Returns the saturated ideal hv value of the sample reported
in the application report of the last run. This value is only
valid if GPA 2172 or ASTM 3588 energy calculation method
is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Description
Returns the actual hmass value of the sample reported in
the application report of the last run. This value is only valid
if GPA 2172 or ASTM 3588 energy calculation method is
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Description
Returns the saturated real relative density value of the
sample reported in the application report of the last run.
This value is only valid if GPA 2172 or ASTM 3588 energy
calculation method is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Return value
A positive floating point value
Unit
MJ/m3
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (value = 0)
Remarks
This parameter only supplies valid data of the last run, at
the end of the run. Use one of the synchronization
parameters to detect the end of the run.
For synchronization, parameters "2200. Sync: Data available
(Bit, MB)" , "2201. Sync: Data available with reset(Bit, MB)" ,
or "2238. Sync: Data available2 with reset(Bit, MB)" can be
used.
Peak (PROstation)
Use the PEAK argument to select an alarm (by line
number/index) from the alarm table.
See also
Parameter “2403. Appl.: Stream Overall Alarm Status (Bit,
CHAN=stream)” .
Parameter “2211. Application: Overall Alarm status (Bit,
MB)” .
Parameter “2212. Application: Alarm status On Index (Bit,
MB, PEAK=Index)” .
Parameter “152. Status: Instrument Error Status(Bit, MB)” .
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
actual Zmix.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
actual molar mass.
Description
Returns the volume based dry real Hs value of the sample
reported in the application report of the last run. This value
is only valid if ISO 6976, GOST 31369 or GOST 22667 energy
calculation method is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
volume based dry real Hs.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
dry Wobbe inferior.
Description
Returns the saturated real Hv value of the sample reported
in the application report of the last run. This value is only
valid if GPA 2172 or ASTM 3588 energy calculation method
is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
saturated real Hv.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
actual Hv.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
dry real hv.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
actual hv.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
saturated water mole.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
dry Wobbe index.
Description
Returns the saturated ideal relative density value of the
sample reported in the application report of the last run.
This value is only valid if ISO 6976, GOST 31369, GOST
22667, GPA 2172 or ASTM 3588 energy calculation method is
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
saturated ideal relative density.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
saturated real relative density.
Description
Returns the saturated ideal gas density value of the sample
reported in the application report of the last run. This value
is only valid if ISO 6976, GOST 31369 or GOST 22667 energy
calculation method is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
saturated ideal gas density.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
actual ideal hv.
Description
Returns the saturated Hmolar value of the sample reported
in the application report of the last run. This value is only
valid if GPA 2172 or ASTM 3588 energy calculation method
is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
saturated Hmolar.
Description
Returns the saturated hmass value of the sample reported in
the application report of the last run. This value is only valid
if GPA 2172 or ASTM 3588 energy calculation method is
used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
saturated hmass.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
dry ideal gas density.
Description
Returns the dry real gas density value of the sample
reported in the application report of the last run. This value
is only valid if GPA 2172 or ASTM 3588 or energy calculation
method is used.
Return value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
dry real gas density.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
dry total GPM.
Channel (PROstation)
Use the CHAN argument to select the stream to retrieve the
dry Hv.
Description
Returns/sets the Density value, which is inserted in the Site
Info area. The Density value is taken from the specification
on the Calibration gas bottle.
Set Value
A positive floating point value
Modbus Register Type
Holding Register/Input Register
Modbus data type
Float (32 bit floating point)
Channel (PROstation)
Mainboard (Value = 0)
Read chromatogram
With this set of parameters it is possible to read
chromatogram data through Modbus.
API21 parameters
Statistical parameters
This section gives an overview of the available API21
parameters which can be used in the Modbus configuration. For
each parameter, the channel# and peak# should be set. The
channel# should be set to the stream number. The stream
number can be set from 1 up to the maximum number of
available streams. The peak# should be set to one of the
API21-ParamID, see Table 40.
The CHAN identifies from which stream the results are
requested. The API21-ParamID identifies which value is
requested, for instance PARAM_ID = 101 identifies the Heating
value superior.
Return value
The value returned is the average over the current day
interval.
Modbus Register Type
Holding Register/Input Register
Modbus data type
Depending on the configured PARAM_ID
Historical parameters
This section gives an overview of the available API21 latest,
previous, 2nd previous and 3rd previous result parameter which
can be used in the Modbus configuration. This parameter
provides access to the stored API21 values. For this parameter
the channel# and peak# should be set. The channel# should be
set to one of the following options:
• 0. Latest results
• 1. Previous results
• 2. 2nd Previous results
• 3. 3rd Previous results
The peak# should be set to one of the API21-ParamID, see
Table 41.
Table 41 API21-ParamID
Execute commands
Unlike all other Modbus parameters, these Modbus parameters
perform an action rather than return or set a value. Most of
these execute commands can also be requested from
PROstation.
See also
Parameter “99. Set Extension Bus Relay (Int16, CHAN,
PEAK)” on page 445
Execute command “9. Energize Relay 1 (Execute Cmd, MB)”
on page 618
Execute command “10. De-energize Relay 1 (Execute Cmd,
MB)” on page 619
Execute Command “12. De-energize Relay 2 (Execute Cmd,
MB)” on page 620
Execute Command “31. Reset Timed Relays (Execute Cmd,
MB)” on page 626
Execute Command “32. Reset Alarm Relays (Execute Cmd,
MB)” on page 626
Execute Command “33. Reset Analog Outputs (Execute
Cmd, MB)” on page 627
Execute Command “35. Reset All Alarms (Execute Cmd,
MB)” on page 628
Channel (PROstation)
Mainboard (Value = 0)
Remarks
Start automation does not necessarily start the sequence. If
the sequence settings instruct to first start the verification
or Calibration Table, the 490-PRO will perform as
instructed.
See also
Parameter “16. Start Automation (Execute Cmd, MB)” on
page 622
Parameter “24. Start Calibration Table (Execute Cmd, MB)”
on page 624
Parameter “25. Start Verification Table (Execute Cmd, MB)”
on page 624
Parameter “17. Stop Automation (Execute Cmd, MB)” on
page 623
Set Value
0 = No effect
1 = Execute the command specified
Modbus Register Type
Coil
Modbus data type
Bit (1 bit)
Channel (PROstation)
Mainboard (Value = 0)
Remarks
Running the Verification Table will stop after 17. Stop
Automation is executed. If automation was running before
the Verification Table was started, then the automation will
be stopped as well.
See also
Parameter “16. Start Automation (Execute Cmd, MB)” on
page 622
Parameter “17. Stop Automation (Execute Cmd, MB)” on
page 623
Parameter “24. Start Calibration Table (Execute Cmd, MB)”
on page 624
Channel (PROstation)
Mainboard (Value = 1)
Remarks
The extra relays that become available when using one or
more optional extension board can be connected as
normally open or normally closed. Relays that are connected
as normally open will be reset to open and oncs that are
connected as normally closed will be reset to closed. The
standard onboard relays are normally open only.
See also
Parameter “99. Set Extension Bus Relay (Int16, CHAN,
PEAK)” .
Execute command “9. Energize Relay 1 (Execute Cmd, MB)”
on page 618
Execute command “10. De-energize Relay 1 (Execute Cmd,
MB)” on page 619
Execute command “11. Energize Relay 2 (Execute Cmd,
MB)” on page 619
Execute command “12. De-energize Relay 2 (Execute Cmd,
MB)” on page 620
Execute Command “31. Reset Timed Relays (Execute Cmd,
MB)” on page 626
Execute Command “33. Reset Analog Outputs (Execute
Cmd, MB)” on page 627
Execute Command “35. Reset All Alarms (Execute Cmd,
MB)” on page 628
Remarks
Analog outputs are only available when using an analog
extension board in combination with a basic extension
board.
See also
Parameter “99. Set Extension Bus Relay (Int16, CHAN,
PEAK)” .
Execute command “9. Energize Relay 1 (Execute Cmd, MB)”
.
Execute command “10. De-energize Relay 1 (Execute Cmd,
MB)” .
Execute command “11. Energize Relay 2 (Execute Cmd,
MB)” .
Execute command “12. De-energize Relay 2 (Execute Cmd,
MB)” .
Execute command “31. Reset Timed Relays (Execute Cmd,
MB)” .
Execute command “32. Reset Alarm Relays (Execute Cmd,
MB)” .
Execute command “35. Reset All Alarms (Execute Cmd,
MB)” .
MB)” .
Execute command “12. De-energize Relay 2 (Execute Cmd,
MB)” .
Execute command “31. Reset Timed Relays (Execute Cmd,
MB)” .
Execute command “32. Reset Alarm Relays (Execute Cmd,
MB)” .
Execute command “33. Reset Analog Outputs (Execute Cmd,
MB)” .
USB Storage
USB menus
You may access the USB from the file menu, toolbar icons, and
automation menus.
File menu
File > USB Storage > ...
Toolbar icons
Automation menu
You may either enter the time as is, or select Use PC Time. Leave
this window open and select Download from the Control menu,
check Real Time Clock and press OK to set the time in the
instrument.
Close this window and you will be asked to enter a name. The
list will be stored under this name. This list can always be
reopened using the menu File – Reprocess – Open.
From the Control menu, select Start, Recalculate Reprocess List.
PROstation will download the first chromatogram from the list
to the 490-PRO and request the instrument to process this
chromatogram. When the 490-PRO completes the calculations,
the result and chromatogram are shown in PROstation. Now the
second chromatogram will be downloaded to the instrument.
This will continue till the results of the last processed
chromatogram are uploaded to PROstation.
Note that you can only reprocess chromatograms on a
nonrunning instrument. PROstation itself has no process
capabilities.
17
PROstation Instrument Control Menu
Start the Analyzer 650
Stop Column Reconditioning 654
Stop 654
Upload 655
Download 656
Instrument Status 660
Stream Selector Test 662
Control – Reset I/O 663
Control – Test I/O 664
Reset Alarms 665
Reboot Instrument 665
Clear Error Log 666
Full Automation
This will start the execution of the Full Automation sequences as
developed under automation and downloaded to the
instrument. The automation consists of a main sequence and
Single Run
This will start a Single Run. This consists of sample injection,
chromatographic separation, integration, and calculation.
Depending on the availability of an application method, this will
be performed as well.
This option requires the parameters Stream Position and Sample
type.
If a run is a calibration run, Level and Type must be filled in.
Column Reconditioning
To bake out the column(s) on the maximum allowed
temperature for that column for a period of time, select the
Column Reconditioning option.
Stop
To stop 490-PRO Micro GC activity, select Control/Stop or click
directly on the Stop icon.
On a Stop Automation the current run will first be completed,
before Automation is stopped.
When an execute block is performed, the current run will be
aborted immediately and the Automation will be stopped.
When Automation is stopped, all Timed Relays will be reset to their
default state.
Upload
Uploading from the instrument to PROstation.
From the PROstation toolbar, select Control/Upload.
Download
Downloading from PROstation to the instrument.
From the PROstation toolbar, select Control/Download
Select the items to download:
Solutions
A solution is a set of method and application settings.
PROstation allows you to create and store multiple solutions for
use by the GC. This allows to use store multi method and
application setting in the instrument and use these different
settings in a sequence.
Existing solutions can be downloaded to the GC on demand, as
well as be associated with a defined sequence.
Creating a solution
Solutions can either be created within PROstation, or created by
uploading the current method and application being used on
the GC to a solution slot in PROstation.
Instrument Status
The Control/Instrument Status command is used to bring up a
real-time status screen for your 490-PRO. The instrument
method settings (Set column) will only appear if a method is up
or downloaded from/to the 490-PRO.
Automation
Current Automation State, Sample type, Sample stream, Flushing time,
Calib. Level and more are displayed.
GC
Instrument State, Sample line temperature and Error Status appear.
GC channel
The channel status contains settings and actuals. Status data is
colored blue if the actuals are within the settings window and
colored red if they are outside the settings windows.
Enhanced status
Reset Alarms
From the PROstation toolbar, select 'Control/Test I/O'.
Reboot Instrument
From the PROstation toolbar, select Control/Reboot.
If it is required to reboot the system, click OK.
18
PROstation Instrument Report Menu
Integration Report 668
Application Report 670
Stream Application Report 674
Diagnostics 674
Print Integration/Application Report 675
Auto Print Application Report After Calibration or Alarm 675
Integration Report
• Sep.Code
Peak separation code identifying the baseline relative to the
peak
This can be BB, BV, VB, VV in which B = baseline and V =
value
• Validation
Not used
• Pk Start [s]
Start time for the peak
• Pk End [s]
End time for the peak
• Asym 5%
Peak asymmetry factor at a height of 5 %
• Used RF
Response factor used to calculate the external standard
concentration
This parameter is only reported in a single level calibration.
• Rw
Factor calculated from measured concentration of
calibration sample divided by given calibration of level 8
value from the Peak Identification/Calibration Table.
Response factor used to calculate the external standard
concentration.
This parameter is only reported in a multilevel calibration
performing a calibration of level 8.
• Init RF Alarm
A calibration failure based on a too large difference of the
new response factor compared to the initial response factor.
This parameter is only reported for a calibration run in a
single level calibration.
• Current RF Alarm
A calibration failure based on a too large difference of the
new response factor compared to the current response
factor. This parameter is only reported for a calibration run
in a single level calibration.
• Rw Alarm
Response factor used to calculate the external standard
concentration.
This parameter is only reported in a multilevel calibration
performing a level 8 calibration.
Application Report
SAMPLE
• Sampling time
The time the sample was injected according the 490-PRO
internal clock.
• Analysis #
Run ID number, increases with every analysis by 1. This
number resets at reboot of the instrument.
• Run type
Indication of the run type: analysis, calibration, verification
or blank run
• Calibration level
Identifies the calibration level (range 1 to 8) of a calibration
run. For a non calibration 0 is reported
• Sum ESTD
Sum of external standard concentrations for all components
listed in the normalization table excluding components
marked as Estimate
• Sum Estimates
Sum of all component concentrations defined in the
normalization table as Estimate
• Sum Area
Sum of area of all peaks in all channels detected
• Total Peaks
Total identified peaks in all GC channels
• Is Startup Run
Identifies if the current run is the first run after an
instrument reboot (power up)
• Unknown peaks
Number of unidentified peaks in all GC channels
• Current stream #
The current stream number at the moment the report is
generated in the 490-PRO.
• Alarms
All alarms, as defined in the Alarming window under the
Application menu, are reported here on Alarm Index, if an
alarm occurs.
ENERGY
All parameters related to calculating calorific value of a gas
mixture are reported in this section. The report will be slightly
different depending on the energy method selection (ISO, GPA,
ASTM, GOST).
ENVIRONMENT
• Sampling Analog #
These are the converted analog input values as defined in the
Analog Input window under the Application menu. During the
sampling state part of a chromatographic run, analog input
signals are measured, converted to real units and stored in
the 490-PRO.
• Cabinet Temperature
Internal analyzer temperature, measured by a temperature
sensor on the mainboard
• Ambient Pressure
Internal analyzer ambient pressure, measured by a pressure
sensor on the mainboard
SITE INFO
This data was defined in the Site Info window found under the
Automation menu.
COMPONENTS LIST
The component list contains the peaks as defined in the
Normalization window found under the Application menu. It
contains the following parameters:
• #
Index number
• Channel
The GC channel peak was identified.
• Peak name
The name of the peak as defined in the Normalization table
found under the Application menu.
• ESTD Conc
The external standard concentration of the peak found in the
integration report.
• Norm Conc
Calculated concentration after normalization following
the normalization table. For ignored bridge components no
Norm Conc is calculated, these compounds are presented as
bridged cmp.
• Retention[s]
The retention of the peak found in the integration report
• Area
The area of the peak found in the integration report
• Height
The height of the peak found in the integration report
• Meth-Index
Peak index number as the peak is defined in the
Normalization table
• Group #
This peak is part of a group as defined in the Normalization
table.
• RF
Response factor used to calculate external standard
concentration. This parameter is only reported in a single
level calibration.
• Rw
The Rw factor used to calculate external standard
concentration from the corrected curve.
This parameter is only reported for a multilevel calibration
with field calibration correction.
• Weight %
Mass per component relative total mass
• GPM
Theoretical hydrocarbon liquid content per component. This
results is shown when GPA 2172 or ASTM D3588 energy
calculation are chosen.
Depending on the extent of the application as well as the
configured stream selection, specific information becomes
available.
The application report is updated after every run.
Diagnostics
The diagnostic report becomes available after uploading using
Control\Upload Diagnostics. The information is brought on screen
after Report\Diagnostics is selected from the PROstation toolbar:
• Workstation errors
(errorlist.txt on PROstation computer)
Information about uploads from the instrument and
downloads to the instrument; any communication that has
taken place. The file is cleared after a start (run, sequence,
recalculation) has been sent to the 490-PRO.
• Internal instrument errors
(errorlog.txt on instrument flash memory)
This file contains all class 1 and higher errors that have
occurred. Also the firmware updates are recorded.
More extended error information is provided in “Errors” on
page 717.
The file can be cleared after a remote request: from the
PROstation toolbar select Control/Clear Error Log File.
• Current application report
(samprslt.txt on instrument flash)
The bottom field shows the last report as stored on flash.
This is made available for diagnostics after a system crash.
19
Multi Level Calibration
Chromatogram 678
Calibration Options 679
Rw Calibration 685
Relative RF 688
Setting Up a Typical Single Level Calibration 689
Setting Up a Typical Multilevel Calibration 692
Single Point Calibration with Multiple Calibration Mixtures 698
Multiple Point Calibration with Multiple Calibration Mixtures 700
Calibration Validation 701
Chromatogram
The primary data from a GC is a chromatogram, as seen here.
Calibration Options
The relation between the area and the concentration of a
component can be determined using a calibration mixture
containing known concentrations for all components. A unique
calibration mixture with known concentrations is called a level.
Calibrating with only one level is called a single level calibration
and is described in “Single level calibration” below. Calibrating
with more than one level is called a multilevel calibration and is
described in “Multilevel calibration” .
a = 3.5/2850 = 0.0012
Multilevel calibration
By using multiple calibration mixtures, a multilevel calibration
can be performed.
Each calibration level results in a point on the calibration curve.
The calibration curve gets more accurate by calibrating with
more than one calibration level.
The relation between the area and concentration is described
using a polynomial curve, up to cubic is supported. Linear and
quadratic curves can be achieved by setting the coefficients a
and b to zero.
Y = a * x3 + b * x 2 + c * x + d
x represents the Area
y represents the Concentration
Example:
Data set:
Offline calibration
The coefficients of the polynomial equation can be determined
in third party mathematical tools. This is called Offline
Calibration.
The coefficients for the polynomial equation can only be set if
the option Allow overriding Curve Coefficients is enabled in the
Peak Calibration screen, see screen dumps below.
The Peak Calibration screen can be opened using the menu option
shown below.
Online calibration
The 490-PRO is capable of performing the calibration by itself.
The sequence containing the Calibration Table can be
downloaded to the 490-PRO.
A typical calibration sequence for seven calibration levels is
shown in the following figure:
Figure 362 Peak Identification Table, Curve Type, and Thru origin
Rw Calibration
After determining the relation between the area and
concentration through the fit, the validity of the curve should be
checked periodically. Typically, a daily interval is chosen.
The ambient pressure and detector aging are factors for which a
correction should be made.
Figure 365 on page 685 shows the fitted curve in the middle and
two possible field calibrations: one above the fitted curve and
one below the fitted curve.
The concentration of the Rw calibration gas must be filled in,
this is called Level 8 Rw. During the calibration, the 490-PRO
calculates the factor between the concentration found using the
fitted curve and the concentration entered (see Figure 365).
This factor is called the Rw factor.
5 Fitted Curve
Corrected curve (Rw 0.9)
Amount
4 Field Calibration Point
Corrected curve (Rw 1.1)
3 Field Calibration Point
0
0 5000 10000 15000 20000 25000
Area
y = Rw * (a * x3 + b * x2 + c* x + d)
“x” represents the Area
“y” represents the Concentration
Relative RF
When it is not possible to determine a calibration curve for a
component, it is possible to refer to a component that does have
a curve.
During an analysis, the 490-PRO will use the curve of the
referred component in combination with the Relative RF factor.
Typical use: C6+ components refer to the C3 curve with a
Relative RF factor.
The Relative RF factor can be determined using a Lab GC.
Environment
The description of this section is based on the environment
described in this paragraph.
• Three streams to analyze continuously
• One calibration stream
Sequence
The sequence is setup using the Sequence Table and the Sequence
Properties. The Sequence Properties determine how the Sequence
Table will be used.
Sequence Table
The Sequence Table defines which analyses should be run, and
in what order. Figure 370 shows that three streams are to be
analyzed, starting with stream 1, followed by stream 2 and then
stream 3. Each stream starts with flushing for 60 seconds to
prevent mixing of the different streams.
Sequence Properties
The sequence properties define how the Sequence Table is being used.
Figure 371 on page 690 defines that the sequence should start at
startup of the 490-PRO and that it should run continuously. The
option Home Position (on error and when sequence stops) defines the
position of the stream when the sequence has been interrupted. This
option can be used to prevent waste of (expensive) calibration
mixture in case of an error.
Calibration Table
The Calibration Table defines how a calibration should be
performed. In this example, the calibration mixture is
connected to stream 4.
The concentration of the calibration level and curve type must
be entered in the Peak Identification table.
The calibration consists of two steps: the Ignore step and the
Append step. The Ignore step is responsible for flushing the
490-PRO to ensure a reliable calibration. The Append step, with
the number of replicates set to two, forces the 490-PRO to clear
the previous calibration points and add two new calibration
points. Based on these points, the coefficient of the linear curve
is determined.
Calibration properties
The calibration properties define how the Calibration Table will be
used. The figure below defines that the calibration should start
at 07:00 o’clock every day.
Environment
The description of this section is based on the environment
described in this paragraph.
The 490-PRO will be used in two different contexts, the
Calibration of the multilevel curve and the daily usage.
Calibration of the multilevel curve:
• Seven calibration streams
• One Rw calibration stream
Daily usage:
• Three streams to analyze continuously
• The Rw calibration stream
Sequence
The sequence is setup using the Sequence Table and the Sequence
Properties. The Sequence Properties determine how the Sequence
Table will be used.
Sequence Table
The Sequence Table defines which analyses should be run and
in what order. The figure below shows that two streams are to
be analyzed.
Sequence properties
The sequence properties define how the Sequence Table is being
used. Figure 381 on page 696 defines that the sequence should
start at startup of the 490-PRO and it should run continuously.
The option Home Position (on error and when sequence stops)
defines the position of the stream when the sequence has been
interrupted. This option can be used to prevent waste of
(expensive) calibration mixture in case of an error.
Calibration Table
The Calibration Table defines how a calibration should be
performed. In this example, the Rw calibration mixture is
connected to stream 4.
The calibration is set up with two steps: the Ignore step and the
Replace step. The Ignore step is responsible for flushing the
490-PRO to ensure a reliable calibration. The Replace step forces
the 490-PRO to clear the previous calibration points and add
one new calibration point. Based on this point, the Rw factor is
determined.
Calibration properties
The calibration properties define how the Calibration Table is
being used. Figure 383 on page 697 defines that the calibration
should start at 0700 every day.
Calibration Validation
There are two distinct methods available for validating the
calibration in the 490-PRO: the verification run and response
factor (R.F.) limit checking during a new calibration run.
Verification run
The Verification run can be used to verify whether the
calibration curve for every component is still valid. Typically
the calibration gas mixture is used for this verification,
although it might be another gas sample.
The validation criteria (defined lower and upper limits) for the
Verification run are configured in the 'Verification Check'
window found in the 'Application' menu.
The window below contains two criteria: the Normalized
Amount of Methane must be within 82.0 and 82.5, the
Normalized Amount of Ethane must be within 5.1 and 5.3.
The components used in this table must be defined in the
'Normalize' window part of the Application. Also ESTD
concentrations refer to the Normalize window. Also calorific
values can be checked in energy meter configurations.
Calibration limits
The 490-PRO has multiple options for checking the calibration
values, before accepting them.
Checking the Response Factor (RF) against the initial RF and
current RF is called RF checking see “RF checking” . This is used
in single level calibration.
Multilevel calibration is used in combination with the so called
Rw factor. The Rw factor is determined using an Rw calibration
(Level 8) and tested against the Rw limit, see “Rw Limit” .
RF checking
RF checking against the initial RF requires the determination of
the initial RF. The initial RF can be determined like a normal
calibration, only with the option Calibration Check and Initial
Calibration enabled followed by a download of the Application.
After running an Initial Calibration, the 490-PRO will store the
value of the Initial RF for every component. In the Peak
Identification table, limits can be entered for a calibration.
The settings from the screen below allow 5 % deviation from the
Initial RF and 5 % deviation from the Current RF. These limits
are only active when the option Calibration Check is enabled.
Each component can have its own InitialRF% and CurrentRF%.
If any peak fails for Initial-- or Current R.F. validation, the
entire calibration will be rejected for all peaks and the 490-PRO
Rw Limit
An Rw calibration can be performed when a multilevel
calibration curve has been determined. Typically this is used in
non linear calibration curves. When the multilevel calibration
curve is accurate, the value of the Rw factor should be
approximately 1.0. The 490-PRO can be configured to test the
Rw factor before accepting it. The settings of the screens below
enable the testing of the Rw Limit (Calibration Check) and allow
a value of 1.0 ± 10 % (0.9 to 1.1).
If any peak Rw exceeds its limit, the entire calibration for all
peaks will be rejected and the 490-PRO will continue using the
current Response Factors as determined in the last successful
calibration run.
20
I/O Cases
General Setup 706
Case 1: Analog Output 709
Case 2: Alarms 713
Case 3: Timed Relays 714
Case 4: Digital Inputs 715
The cases below describe how all I/O's can be configured and
used in a 490-PRO Micro GC. The following hardware has been
used for these cases:
• Extension boards: basic extension board (CP741116), analog
output board (CP741117), digital extension board
(CP741118)
• 25-pin digital I/O interface cable and 15-pin analog I/O
interface cable (CP741120)
General Setup
The following licenses have been activated:
Cases preparation
1 Perform an analysis of gas sample and ensure peak
integration and calculation is enabled.
Integration report
After analysis or recalculation, the integration report is
generated.
You can now scale lower and upper input values (X1, X2) to
lower and upper output values (Y1, Y2) and select an occasion
on which the outputs are updated.
The link between the method peak tables and the Application
Report is defined by the normalization table. This table holds all
system-wide parameters and defines which parameters are
shown in the Application Report. On its turn, the normalization
table serves as an input to all I/O tables, including peak naming.
See the schematic overview of and interaction between various
tables/processes:
Ethane Nitrogen
Methane Butane
Ethane – chan 1
Methane – chan 1
Nitrogen – chan 2
n-butane – chan 2
Ethane – chan 1
Ethane – chan 1 Methane – chan 1
Methane – chan 1 Nitrogen – chan 2
Nitrogen – chan 2 unidentified – chan 2
n-butane – chan 2
Case 2: Alarms
Alarming can be used to inform the user (or a subsystem) that
certain parameters are in or out of range. See table below as an
example:
Explanation:
1 20 seconds after injection started, Timed Relay 1 will be
energized.
2 25 seconds after injection started, Timed Relay 1 will be
de-energized.
This shows that:
Relay 1 is energized for a period of 5 seconds from 20 to
25 seconds after start of injection.
3 30 seconds after sampling started, Timed Relay 2 will be
energized.
4 35 seconds after sampling started, Timed Relay 2 will be
de-energized.
This shows that:
Relay 2 is energized for a period of 5 seconds from 30 to
35 seconds after start of sampling.
This table does NOT force the relays to an initial state before
they are energized, so it could well be the case that both timed
relays are already energized before they are energized after
expiration of the delay timer.
21
Errors
Error Handling 718
Error List 719
Error Handling
During operation, a series of events and error messages are
generated indicating the start or finishing of certain actions and
procedures as well as smaller and fatal errors somewhere in the
instrument. This section describes how the Micro GC reacts to
these events or messages.
The following error classes as well as the subsequent actions are
available:
Class 2 Critical errors for logging; error LED ON: These are
critical errors for which the user needs immediate warning (a
popup or warning may appear in the data system and the Error
LED lights). The run in progress is stopped since its results will
definitely be wrong. Corrective action by the user or instrument
service may be required.
Class 3 Fatal errors for logging; instrument shutdown, error LED and
buzzer ON: These are fatal errors for which the user needs
immediate warning. The Error LED lights. An instrument
shutdown occurs. Corrective action by the user or service is
required.
All errors, regardless of class, are available to the data system
under instrument status (for troubleshooting). All Class 1 and
higher errors are also logged in the instrument’s flash memory.
Individual numbers identify all errors; these numbers are built
using the error class and a number. Events are not numbered.
Error List
The GC error code is reported as CLNNN in which:
C = error class (severity)
L = location
NNN = error number or event number.
The Error class can be one of the following values:
• 0=diagnostic error.
• 1=advisory error.
• 2=critical error.
• 3=fatal error.
There are five locations:
• 0=mainboard.
• 1=channel 1.
• 2=channel 2.
• 3=channel 3.
• 4=channel 4.
22
WinDCS
Setting up the WinDCS Communication 726
WinDCS Modbus Table 729
IPAddress
Fill in the IP address of the 490-PRO you want to connect to.
Slave Address
The Slave address in Modbus TCP/IP is only used if a modbus
ModbusType
MODICON/Daniel and others
Change the protocol from standard MODICON to other derived
protocols.
Difference will only be found in the holding and input registers
above the address 5000 range and above the 7000 range. Above
address 4999 the non-MODICON protocol will return 4 byte
integers, above 6999 the protocol will provide 4 bytes floating
point values.
Options
• Swap Floating-Point bytes
A floating point consists of four bytes. Swapping floating
points means that the first two bytes are swapped with the
last two bytes. This option will not be needed for connecting
to the 490-PRO.
• Swap 32 bit integer bytes
A 32-bit integer consists of 4 bytes. Swapping 32 bit integers
means that the first 2 bytes are swapped with the last
2 bytes. This option will not be needed for connecting to the
490-PRO.
• Shift Modbus register one up
Some Modbus applications or Modbus devices count Modbus
registers starting with 0 instead of 1, while the register count
shown to the user starts at 1. When the Modbus table in such
an application or device shows Register 7001, it will send a
request for register 7000. This option will not be needed for
connecting to the 490-PRO.
Export Data
• Export Sample Results
With selecting this option, Sample results recorded from the
490-PRO are stored on disk in the file WinDCS_Analysis.txt,
located in the directory where WinDCS is installed.
• Export Instrument Status
With selecting this option, Instrument Status recorded from
the 490-PRO is stored on disk in the file WinDCS_Status.txt,
located in the directory where WinDCS is installed.
Register type
In the WinDCS Modbus Table, four types of Modbus registers
can be used in the Register type column:
Input status(R): This is a single bit. Can only be read from the
490-PRO.
Coil status (RW): This is a single bit. Can be read from and written to
the 490-PRO.
Input register (R): This is an integer register; Can only be read from
the 490-PRO.
Holding register (RW): This is an integer register; Can be read from and
written to the 490-PRO.
Data type
In the WinDCS Modbus Table, four Datatypes can be used in the
Date Type column:
Bit: a single 0 or 1 value
Int16: 16-bit integer value.
Int32: 32-bit integer value.
Float: 4-byte floating-point value.
Ensure the data type used is identical to the data type used in
the PROstation table.
23
History Log
Operation 734
Report Data 747
Operation
To use the History Log, see:
“Starting the application” on page 734
“Setup for data download” on page 735
“Data download” on page 736
“Setup for report” on page 737
“Report control” on page 743
“Chromatogram control” on page 745
“Exit history log” on page 746
In the XML files box, the file for data storage is selected. When a
non existing *.xml file is typed, History Log will generate this file.
The XSML Style Sheet file is selected. This file is responsible for
the layout of the output document. The XSML file is supplied
with the installation.
When a report is generated, it is stored in the XHTML output
file. This file has an *.html extension. This file will also be
generated by History Log if it does not exist.
Data download
When everything is properly configured, a download can be
performed. Press Start Download from GC. When Yes is selected, a
Processing bar will appear and the data is stored in the selected
XML file under Settings/Application.
With each new download, the XML file with data from the last
download is cleared and new data is stored in this file. When
the last download has important data, it is possible to save this
data first with the XML/Save As option.
After downloading the 490-PRO data, the screen will show that
data is available and how old the data is. If the last data
download exceeds the time selected in Settings/Application a
warning will appear. The text will become red and a warning
icon is blinking.
Report interval
The data which is selected as a standard of the History Log is
between the date and time of download (start) and 35 days
before (end)
Use the arrows next to the time box to change the time, or click
time and enter a new time with the keyboard. To change the date,
click the arrow and a calendar is shown, It is also possible to
change the date by clicking in the box and change the date by
entering a number with the keyboard.
When the selected time exceeds the end date of the download, a
warning appears, because no data is available after your last
download. If you want this data, a new download is necessary.
When the selected time in the start box lies before 35 days, a
warning will appear. However, it is still possible that this data is
available. The 490-PRO buffers all its data and when the
490-PRO was shutdown for a few days, it is possible that data
from 36 days ago is still available, because its buffer was not full
yet.
Another option is to select all data available. With this option all
the data stored until the last download is used for the report. It
is possible that data older than 35 days is displayed, because the
buffer of the 490-PRO was not full yet.
The reset button restores the original start and end dates.
Report selection
Two types of report selection are possible: a standard report
selection or a report selection for one time purpose.
When the standard selection is not used, the user can rapidly
select the options he/she wants. For example, if for some reason
the 490-PRO stops working now and then, it is possible to only
select power on events to see when and in what condition the
490-PRO stopped. But also other analysis options can be
selected see Figure 424 on page 740.
With the standard selection checkbox enabled, the options
selected in Settings/Report are used. See Figure 425 on
page 740.
The Standard Report Settings resembles the settings for the one
time report configuration.
In the Header Data, Calibration Data, Power On, Alarm Status Change
and Analysis Data all options desired can be selected. These
options are used in both the one time report as in the standard
report.
For Analysis Data you can select the number of decimal places
used.
With the free parameter, all decimals available in the data from
When all selections for the reports are made and confirmed
with OK, save the configuration. Go to File/Save As.
Report control
In the Report Control box three options are available; display, print
and store report. When the user wants to display the report, a
pop-up box appears:
The file is stored in *.html format and gets a date and time
stamp automatically. The name can be changed to a more
intuitive name, like power on events 20040519 1259.html.
Chromatogram control
Chromatogram Control can show the analysis chromatogram for:
• The last five alarms;
• The last calibration for all two calibration streams;
• The last sample stream for all four sample streams.
After the selection shown and the Display button is pressed, the
Processing bar will appear and the chromatogram for the
selected option is shown.
To save the settings, click Yes, to ignore the changes, click No, to
stop exiting, click Cancel.
Report Data
HistoryLog can generate several types of reports.
Header
Every report has a header. It contains information about the
company selected in report settings. For example, when the
checkboxes Site Name, Company ID and Software Version are
selected, these items are shown in the header.
Calibration results
If the checkbox Calibration Results is selected, calibration data is
shown. Use the report settings to select the options to appear in
the report, for example Area, Retention Time and Initial Response
factor.
Analysis data
When Analysis Data is selected, the data can be displayed in
either concentrated or extended form. In the concentrated
version, all data is placed on one line after each other. In the
extended version, all data is stretched out in separate headers.
This makes it easier to read one analysis. However for a lot of
analyses the concentrated report is preferred.
In the Report Settings, all options for general and component
data for the analysis can be selected, including the number of
digitals. When free is selected, all digitals available are shown in
the analysis data.
Avg/Min/Max
The Avg/Min/Max shows the average, minimum and maximum
values of all selected general and component analysis for every
stream.
There are three types of Avg/Min/Max:
• Hourly
• Daily
• Monthly
When an Hourly Avg/Min/Max is selected and two days are
filtered, then 48 separate data of Average, Minimum and Maximum
are shown. For each stream there is also an Average, Minimum
Power on
With the Power On option it is possible to see when the 490-PRO
was started. Only the last 10 Power On events are stored. In the
report settings it is possible to enable the Last Analysis at the
power on events. With this option selected the power on event
and its last known analysis is shown. The user might find a
reason why the Micro GC shut itself down, in case of
malfunctioning.
Parameter change
With Parameter Change selected all parameters changed in the
490-PRO are shown with their old and new value. Parameters
are some of the header values like contract hour, Date/Time of
GC, Calculation Method, Tag No. and so forth. But also Pressure and
Temperature settings, which are changed with the PROStation
tool are displayed.
*G3581-90006*
G3581-90006