Conversion 15 1

CONVERSIONS FOR ADDITION POLYMER

HCl
1. CaC2 
H2 O
 (P)  
(1eq.)
 (Q)
(128 gm) (50%)

H2 /Pd
2. (P)   (R)
BaSO4

Red hot CH3COCl NaBH4 H2SO4

3. (P)   (S) 
Fe tube

AlCl3
 (T) 
EtOH
 (U)  
 (V)
(40%) (75%) (80%) (x gm)

4. Mg
Q 
THF
  W     X  
(i) CO2
(ii)H
NH3

  Y  
P2O5
   Z

N 2H4
5. (i)CH3 MgBr
Z  
(ii)H2 O
  A  EtO,   B 
NBS
   C  
Alc.KOH

   D

Mg
6.  D  
HBr(1eq)
40 C
  E  Et O  F 
2
CH Cl
   G  
3 Cl
H
H 2

7.  H  
H O
  I  
2 Al O

 J 
2 3

 Z    K     L     M     N    O

(i)SnCl /HCl CH MgBr Cu PCl EtO
8.  2
(ii)H O
2

H O
3
300 C
 5


 2
Draw All polymers

Monomer Polymer Uses

R
(i)
(at high temp)

R
(ii)
(with AlCl3/TiCl4)

(iii) Q

Tetrafloro
(iv)
derivative of R

(v) V

(vi) Z

(vii) J

(viii) O

(xi) V&D

(x) Z&D
 3
CONDENSATION POLYMER

 excess    A     B    C     D
1. 
HBr/H2O2 Na
Et 2O
Cl2
H
aq.
NaOH

(41 gm)
(50%)

2.  D 
CrO
  E  
 3
H
  F 
NH OH H SO

  G  
2H O

H
 H 2 4 2
⊕

NH3, 
3.  C 
H O

2
  I  
KMnO
J 4
 K     L  (z gm)
LiAlH 4

 excess 
  Et O
H , 2
(x gm) (y mole)

4.  I  
Pd/C
  M  
C H Cl
AlCl
  N  
3

CH COCl
AlCl
7
  O  
3
  P 
KMnO

3 4

(40 %)

5.  N  
O
h
  Q  
2 dil.
H SO
  R    S
2 4

6. S 
I
NaOH
  T  BTHF
2
H
 U  H180C
SO
  V  Co
2

6

ld KMnO
(P gm)
  W  (QHIO
gm)  
 X
2 4 4 4

7.  T  
Red P
Cl
  Y  
2
NH

 excess   Z
3

8.  J  
AgOH,Br
 excess 
  a  
2  M
AlBr
  b  
FeBr
  c  
hot
KMnO
3
d  3
4

Cl

9.  d  
NH

  e  
3 KOH

EtOH
  f  (i) CH –CH-
(ii) H O
CH –CO Et 3

2 2
(g) 
NaNO2
HCl
 h 
3

Cl
10. (e) KOH
(i) Et–CH–CH2–CO2Et KOH NaNO2
()
EtOH (j) (k) HCl
H2O
 4

Monomer Polymer Uses

(i) H

(ii) J&L

(iii) P&W

(iv) h&

R&X
(v)
(linear)

(vi) d&W

(vii) H&Z

R&X
(viii)
(Branching)

(ix) Melamine & X

(x) Urea & X