2c?

3-L2 TSjE-{llCET Solvd Pape

I (t, ) t7 (a) 33 (d) 49 (b) 65 (a) 81 (c) 97 (b) I13 (a) 129 (b) i45 (c)
a (b) r8 (b) 34 (b) 50 (a) 66 (c) 82 (c) 98 1 d) rl4 (b) l3(} (c) r4s (d)

3 (a) t9 (b) 35 (c) 5l (a) 67 (.^) 83 (d) 99 (d 1t5 (c) 13I (b) l4? ( )

4 (d) 20 (a) 36 rd) 52 (c) 68 (b) 84 (b) rG0 (d) ll6 t rl) 132 (b) 148 (c)

5 (b) 2t (d) 31 (b) 53 (c) 69 (b) 85 (b) 101 (a) lr7 (d) 133 (c) 149 (c)

6 ( Brrnus ) 22 (c) 38 (c) 54 (b) 7t (c) 86 (b) tg2 (b) rI8 (d) 134 (c) 150 (c

7 (a) 23 (c) 39 (a) 55 (d) 7t ( Bonus) 87 (d) 103 (d) 119 (a) 135 (b) r51 (b)

I (b) 24 (b) 40 (c) 56 (c) ,t (a) 88 (a) lM (b) 120 (c) 136 (c) 152 (a)

I ( Bonus) ,< (a) 4l (l]trnus ) 5/ (c) 73 (a) 89 (d) 105 (b) t2t (c) 137 (b) 153 {h)

r0 (b) 26 (a) 42 (d) 58 (b) 74 (d) 90 (c) 106 1 (b) L22 (b) r3E ,., ,lS.t (b)
I

1l (e) 27 (d) 43 (b) 59 (c) 75 (b) 9l (None) 107 (b) t23 (c) 139 (a) 155 (d)

t2 (c) 28 (b) 44 (c) 60 (a) 76 (c) o, (a) 1(}8 (c) 124 (b) t,lO (a) r55 (b)

t4l
I

t3 (a) 29 (c) 45 (d) 6l (b) 71 (d) 93 (b) 109 (c) r25 (c) (d) 157 (a)
i
t4 (d) 30 (a) 46 (d) 62 (c) 78 (b) 94 (d) ll0 (c ) t26 (b 142 (b) 158 (b)

I5 (h) 3r ( C 47 (t) 63 (b) 79 (d) 95 (a) 111 (c) 121 (a) 143 (a) ls9 (b)

16 (c) 32 (a) 48 (c) 64 (d) 80 (c; 96 (b) tl2 '(a ) 128 (d) 144 (a) r60 (b)
 MATHEMATICS a A2 - PA = 21
I
(b) /{x)=8 ...(i) ⇒ =
I.
For x < 2
a[: !][� !]-P[� !] 2[� �]
f(x)=x2 - 4x + 3=8 7
x2-4x- 5 = 0
(x- 5)(x+ 1) =0
⇒ a
��]-P[� !]
[ 18
=2
[� �]
7 a - p 12 a -2P 2 o
X=-1, 5 ⇒ [18 a - 3P 3 1 a -5p ] = [ 2]
o
:. x=5 not possible .-. 7 a- P 2 ... (i)
·: x<2

and for x 2:: 2 12a -2P = 0 ⇒ or 6a- P=0 ...(ii)

=

f(x)= X- 3 = 8 ⇒ X= 11 Eqn. (i) - Eqn. (ii) a = 2

:. Number of solutions = 2 :. p=6a = 12
2. :. a2 + p = 4+ 12= 16
g(x) =x2 + 2 6.
(b) f{x)=3x-2

g of(x)=g[f{x)] =f{x)2+ 2
(Bonus)
(1+ a) 2 (1+ 2a) 2 (1+3a) 2 •
&fog (x)= ./[g(x)] =3[g(x)] - 2
(gof+ fog)(x) =f{x)2+ 2+ 3(g(x)] - 2 (2+a) 2 (2+2a) 2 (2+3a) 2 =K
= (3x - 2) 2 +3(x2 + 2) (3+a) 2 (3+2a) 2 (3+3a) 2
=9x2 + 4 - 12x +3x2 + 6
= 12x2 - l2x+ 10 ·: a =-2, putting in determinant
= 12 (x2 + 2) - 4 (3x- 2) - 22 1 9 25 0 8 16
= 12 g(x)- 4/{x) - 22 0 4 16 =K ⇒
0 4 16 = K
= axIO + bx 8 + ex 6 + dx4 +ex 2 + 12 x + 15 9 1 9
3. (a) f(x)
R 1 ➔ R 1 -R3
andf(4)=- 4 :. K= 16 x 8- 16 x 4 =64
X

15 7. (a) X+ y +Z=5
·: f(x)=ax9 + bx7 +cx 5 + dx3 +ex+ 12 + -
X+ 2y + 2z = 6

15 x+ 3y+'Az = µ
X

:. f(-x)=-ax9-bx 7 -cx 5 -dx3 - ex+ 12- - is solvable ⇒ IAI 0 *

1 1 1
:. f(x) �f(-x)= 24
X

1 2 2 0
j(4) +j(--4)=24
*
f(-4) = 24 - f(4) 1 3 ).
=24-(-4)=28 clearly).* 3
and at µ e R, solution exist
:. xT will be oforder 3 x 4
4. (d) P2,3, X4,3, Y4 ,3
.-. ). * 3, µ e R
and pT will be of order 3 x 2
.-. Order ofxTy =3 x 3 y =aa + bp, z =ap+ ba
8. (b) x =a+ b

:. Order of(XTY)-1 = 3 x 3 a =(J) and P=(J) 2

Now, order of P (XTY)-1 =2 x 3 ·: x + y + z=(a + aa+a�)+ (b + bp + ba)
.-. Order of P (XTYt 1 pT=2 x 2 = a (I +a+ P) + b ( 1 + P + a)
.-. Order of[P (XTYt 1 pT] 1 = 2 x 2 = a (1+ (J) + (J)2) + b(l + (J) + (J)2)=0
:. x 3+y3 + z3 = 3xyz
5. (b) A=[: !] =3 (a+ b)(a(J) + b(J)2) (a(J)2 + bro)
 =3( a3ro3+a21xo2+a 2bw4+ab2ro 3+ba 2 ro3+b2aro2+ Sit • • Sit
ab2 ro2+b3 ro3
l+cos-+ism-
[ 18 18 l =1
=3( a +b +a bro +a bw+ab +a 2b+ab2 w2+ab2 w 2) 51t .. 51t
l+cos--1 sm-
⇒
=3[a 3+b3+ ab2 (1 + w+w2)+a2b( w2+w+ l)]
3 3 2 2 2 2

18 18
=3( a 3+b3)
S1t "
(Bonus) z =
3+2i cos0 . . •
.. is purely 1magmary
2 cos2 S1t+i 2 sin Sit cos

1•
36 36 36 l =I
1- 21 sm0 [
Sit . Sit Sit
9.
2 cos2 --i 2 sm-cos-
⇒
3+2i cos 0 1+2i sin 0 36 36 36
=
z 1-2i sin 0 x 1+2i sin0
Sit • • 51t
cos +zsm
(3- 4 sin0 cos0)+i( 6sin0+2 cos0) 36 36
[ =1 ⇒ ( e-;snn6 = 1
)"

51t .. 51t
36

1+4 sin2 0
/5•/

cos--zsm-
⇒
36 36
for purely imaginary Re( Z) =0
3- 4 sin0 cos0 Snit 36K
----- =0 ⇒ ei5nnll8 =1 ⇒ 18 = 2 K1t, K E I ⇒ n = - 5-
1+4 sin2 0
:. 3-4 sin0 cos0 =0 :. n is multiple of36 ⇒ n =36
3 3 (a) x 2+ ax+2 =0
. .
sm0 cos0 = - ⇒ sm20 = - > 1 a+13 = - a , al3 = 2
13.

which is not possible

4
x2 -bx+c = 0
2
1 1 1 1
10. (b) zz + 3 =350 U. a 13 a. p 2
3 -+- = b, -=c=-

Z·Z(Z2 +Z 2 ) =350
(a+½) (13+�) (a-�) ( 13-½)
1z1 ((x-iy) +(x+iy)2 ) =350
2

1 a
2

/ Z 1 (x 2 y1 - 2:xyi+x2 - y 1+2:xyi) =350 = (a.13 +I+I+_!__·) (a.13+- - _f)

al3 al3 13 a
-
2

2·1 Z /2 (x2 - y 2) =350 I ( I a 2+p 2 1

= ( 4+ ) 2+ -
1z1 (X 2 - y 2 ) =17 5 = 25 X7
2
2 2 �J
l
9(5 (a+13) 2 - 2a.l3l
- I1 z - = 2s ⇒ IZI = s
.. =
a.13 J
I' 2 l2-
( c) Since, roots of equation x 2+x+1 =0 are complex
11.
cube roots of unity
=
�(%- a2
;
4J

a = OJ, 13 = m2
:. (a+ 13)2+(a.2 + 13 2)2+........+(a l2+131 2)2
9 a2 J=
= (ro+ro2)2+( ro2+m4)2+........+(m l2+w24)2 = �( � ¾(9- a2 )
·: 1 + ro + m2 =0 and m3 = 1
⇒ w11 + (co2t = 2, n is multiple c•3 (d) j(x),ef-x) = I
ro11+ (w2)'7 == -1, n is not multiple of3 is possible when
14.

:. [(-1) +(-1 )2+ ( 2)2 ]+............ 4 times Case 1:flx) = 1

= 6x 4 = 24 x 2 -7x+11 = I
2

• 2it •
I +sm-+icos- 2it " x 2 -7x+10=0
9 9] =l x = 2, 5
12. (c) [
. it
I+sm--,cos- . 2it Case 2: g(x) =0
9 9 x 2 - 6x -7=0
2
X = -�,7

Case 3:.f{x) = -1 and g(x) = even

x 2 -?x +11 = -1
x 2 -?x+1 2=0
x = 3, 4
n
⇒
 g(3)= 32 -6 (3)- 7 =-16 (even) = -1 [(-1)2 - 3(1)] + 3(-1)= 2 -3 =-1
g(4)= 42 - 6 (4)-7 =-15 (odd) (ii)➔ A
:. possible values of x =-1, 2, 3, 5, 7 only possible option is
sum = 16 (i)➔ A, (ii)➔ A, (iii)➔ D, (iv)➔ B
15. (b) P(x)=2x4 + ax3 + bx2 +ex+ d 18. (b) 6,00,000
P(I)=4 = 12 + 3 odd integers using 3, 6, 7, 8, 9, 0
P(2)= 7 = 22 + 3 First place can be filled by 6, 7, 8, 9
P(3)= 12 =32 + 3 and last place by 7, 3, 9
P(4)= 19=42 +3 Case 1: First place 6 or 8
:. P(x) = x2 + 3 2x4x3x2xlx3
But to make it degree 4 polynomial with leading
144 ways
coefficient = 2
Case 2: First place 7 or 9
=

P(x)= 2 (x- l )(x -2)(x- 3)(x- 4)+ x2 + 3

P(5)= 2 (5- 1)(5- 2)(5- 3)(5 - 4)+ (52 + 3) 2x4x3x2xlx2
= 2·4·3·2· l + 28 = 76 =96 ways
16. (c) Kx3- l 8x2 - 36x + 8=0 Total = 144 + 96 =240 ways
roots a, 13, y are in HP 19. (b) 6 men and 4 women
Considering equation where roots Excluding 1 particular man & 1 women
l 1 l Place rest 8 people in around table by 7! ways
-,-,- are in AP
a l3 y. •· Now 8 gaps are created
Select 2 gaps by 8C2 ways
8x3 - 36x2 - 18x + K =0
& arrange them in 2! ways
If roots are in AP
Total ways = 7! x 8C2 • 2!
let a - d, a, a + dare roots
8! 7 X 6!
36 9 3 = 7!x-- x2! = --x8! =7 x 81
a-d+a+a+d= -=- ⇒a = - ... (i) 2! 6! 6!
8 2 2
(a) AB C
-18
(a - d)a + a(a + d) + (a - d) (a+d) = -
20.
4 4 4 Total
8
Attempted
2a2 + a2 - d2 = -
-9
4
3!
⇒ 3.2.-d 2 = -� ⇒d2 =9 ⇒d=3 ...(ii) l 2 2 : 4c1 x 4c 2 x 4c2 x -
4 • 4 2!
-K
Total: C1 • C1 • C3 x ; + C1 • C2 • Cz ;
"'
:. (a - d) a (a+ d) =
8 (4 4 4 2
3') (4 4 4 3'2 j
- = 192 + 432=624
-3 +3 =
(% )%(% ) ; 3x 2 - _!_
(d) (1- 3x+ 2x3) (
9

-3 3 9 -K 2 3x)
21.
-x-x- = - ⇒ K = 81
2 2 2 8
3x 2 I
17. (a) x +x +x+ 1 = 0 for (- --)
9

2 3x
a, 13, y are roots
3 2

a + 13 + y =-1; al} + l3y +ya = l; al3y = -1

l l l
(i) -+-+- = -
a 13 y
al}+l3y + ra
al3y
. T,+ 1- •ct�T' (;�)'
l 9cr -r x 18 - 3 r
= ="i' =-1 ⇒(1)➔A (¾ r ( �J
l
=

(ii) a3 + 133 +y3 for coeff. of x0 : 18- 3r =0 ⇒r = 6

=(a+ 13 +y)(a2 + 132 +y2- al}- l3y-ya)+ 3al3y
=(a+ 13 +y) [(a+ 13+y)2 - 3(al3 + l3y +ya)]+ 3al3y
 7
:. Constant term = 9c6 (-3 ) (-1 )
3 {i

2 3 18
Coeff. orx- 1 = ii:1- 3r =-l
3r = 19
--- - =x(x - l)-2(x- 2t 1
(x -1)2 (x - 2)
X
24. (b)

r = .!..2_ (not possible) 1

3 Coefficient ofx4 = Coefficient ofx3 in
(x - l)2 (x _ 2)
Coeff.ofx- 3 : 18-3r = -3

:. Coeff. of:c3 = 9c 7 (
% r ( r ;�
⇒ 3r =2l ⇒ r = 7

:. Term independent ofx =l x constant term+2 x Coeff.

l
�

of x-3
7 -l 21- 4 17
=lx-+2 x- = - -=-
18 27 . 54 54
20

!
q
(c)
"""' 20+r c, -- 40c
22. .t... - 20
r=O

m = -49,n = 16
✓ Im+ ✓
nl = - 49 +161 = ✓33
I
25. (a) sm x cos 4 x = 1_
+ 5
• 4

3
39C19 +39C20 = 4oc20
2

3 sin 4 x + 2cos 4 x
4oc20 +4oc2, = 41c21
6 = 5
_ 41 4 o
- 21 c 2 0 ⇒ 15 sin x+.10cos 4x = 6
4

⇒ 5 sin4x +10(sin4x+cos 4x) = 6

:. P = 4l andq =2 1
P2 -q2 = 412 - 212 = 1 240
⇒ 5 sin4x+10 [(sin 2x +cos 2x)2 - 2 sin 2x cos 2x] = 6
3
⇒ 5 sin 4x+10(1 - 2 sin2x ( 1-sin 2x)) = 6
23. (c) ·: (l- x)-3/2 =1+ x ⇒ 5 sin4x+10- 20 sin2x+20 sin4x = 6
⇒ 25 sin 4x - 20 sin 2x +4 = 0
2
�-(l +1jx2 l(l +1 (l +2)
2 / +2 2 ) 2 x3
⇒ (5. sin2 x - 2)2 = 0 ⇒ sin 2x = 3.
+
2! 3!
2
5
5 5
:. sec 2x = -, cosec 2x = -
+2
+1 +3 3 2
%(% )(% )(½ )x4+...
+ 27 sec a+8 cosec a
4!
6 6

.,
putting x =� , we get = 2 1(�·) +8(�) = 21-� + 8-� 250
3 3

3 3 2 27 8
=

3
n sin acos a n tan a n tan a
2 5 5.7 5 7.9 (a) tan I-'ri. =----
l--)· -2· = 2 +-+--+--+ . 1- n cos 2 a sec 2 a -n (1-n)+tan 2 a
3
26•
( 2!3 3 !3 2 4!3 2 •••

l -2 -_ I
- 2.5 2.5.7 2 .5.7.9 tan-a+tan 13
3

l 3) -l4+-+--+-- +] tan ( a+f3) = -----

3 !3 2
f

2 2!3 4!3 2 ••• 1 - tan a tanl3

 ntana • 3C 3C C
tana+----- ⇒ sm- (2 cos- -cos-)
(1-n) + tan 2a 2 . 2 2
( ntana \ 3C
1-(tana)
l 1- n + tan 2a) ⇒ If sin 3C = 0 ⇒ = 0 or 1t ⇒ C = 0 or 21t
2 2 3
1-n+tan 2 a+n 41t .
tan a[------ ⇒ A= 0 or - (not possible)
(1-n) + tan 2 a ] 3
1- n + tan 2 a- ntan 2 a 3C C
= - =-------=

2 cos--cos--= O
-

1-n + tan 2 a 2 2
sec2 a C
tana-----­ 2 4cos3 - 3 cos�)-cos� =O
(1- n) (1 + tan 2 a) ( 2 2 2
=

tan a C e )
:.tan{a+�)=--
1-n
cos
2 (8cos 2- 7 = O
2

1 -I C C
tan (a+�)·cot a= ---= -- cos-= 0 ⇒ - =90° ⇒ C= 180°
1-n n-1 2 2
not possible
(d) cosA +cosB + cosC = 0 ...(i)
sinA +sinB +sine = 0 .. (ii) :. 8cos2 � =7 or cos2 �=7._
27.
. 2 2 8
Squaring (i) and (ii) and add,
(sin2A + cos2A) + (sin2B + cos2B) + (sin2C + cos2C) + 1=
2(cosA cosB +sinA sinB) +2(cosB cose +sinB sinC) + :. cose = 2( i)- ¾
2(cose cosA + sine sinA) = 0
= 3 +2[cos(A-B) +cos(B-C) +cos(e -A)]= 0 sinC= =
✓l -( ¾ J �
-3
:. cos(A-B) +cos(B-C) + cos(C-A) = - B= 1t- 3C
2
28. (b) sinx • coshy cos e ...(i) sinB = sin 3C = 3 sinC - 4 sin3C
cosx • sinhy= sin e .. .(ii) ✓ 4 X 7✓7
= 3( )
=
7

Squaring & adding (i) & (ii) 4 64

sin2x cos2hy +cos2.x • sin2hy = 1
12✓ - 7✓ 5✓7
sin2x (I +sin2hy) +cos2x (sin2hy) = 1
7 7

sin2x +sin2x sin2 hy +cos2x sin2 hy = I 16 16

=----

sin2x +sin2 hy tsin 2x +cos2x) = I :. b: c =sin B : sin e

:. sin2x +sin2hy = 1 5 ✓7 ✓ 5
= 16:4 = 4: 1=5: 4
sin2x +cos2hy - 1 = 1
7

sin2x +cos2 hy = 2 (a) (R) Given that r: R: r2= 1 : 2.5: 6 = 2 :5 : 12

29. (c) a, b, care in AP
⇒ r=2k,R =5kandr2= 12k
30.

⇒ sinA, sinB, sine are in AP B

⇒ 2sinB = sinA + sine we have r2-r =4R sin 2
2
⇒ 2sinB= sin2C +sine [·: A = 2C]
3C ⇒ 12k-2k=4 x5ksin2 B
⇒ 2.smB = 2.sm -cos- e 2
2 2
B . B 1
also A +B + e =1t ⇒ 3e +B= 1t ⇒ B = 1t - 3e ⇒ 1Ok= 2 0k sm . 2 - ⇒ sm - = r;: ⇒ 90°
2 2 v2
3e C
⇒ 2.sm(7t - 3e·)= 2 sm • - cos- Reason is true
2 2 Hence assertion is also true .
3C C 31. (c) al.b,al.c
⇒ 2.sm 3C = 2 .sm-cos-
2 2
- 21t
. 3e 3C . 3e e Angle b/w b & c =
⇒ 2sm-cos- = sm- cos-
2 2 2 2
3
 b +c
J;+3b-4;1 = (a+3b-4c) · (a+3b-4c) P = a+ (½) =
2 ➔ ➔

⇒ a+b+c
➔ •➔

2
➔ ➔ ➔

= 1 ;1 +3a·b - 4a·c+ b·a +9Jhl

2 2

� :. SA+SB+SC= SO
(i)➔ (D)
-12b·c -4c·a-12b·c+16 c also we know that centroid divides orthocentre &
➔➔ ➔➔ -➔➔ ➔2

circumcentre in 2 : 1
, 1

21t 2
= 1 +9+ 16-24 (1) (1) cos - =38 •G •s
3 0
- 2-
(a) Equation of vector passing through a and parallel OG = -OS
3
32.

to bis r=a +Ab (iv)➔ (B)

➔ ➔ ➔ ➔

only such option is

; = (2 i - j+ k)+A (i _+2J-- k) (1)➔ D, (;i) ➔ C, (iii)➔ A, (iv)➔ B
/1. I\ /1. I\

= (2 + A)t +(2A-l)] + (1-A)k 34. (b) ; - ; = b · b=; · ;= 5

r•c 9
Pro_iection of r on c = = ✓6
I
c I

(2 +A)+(2A -1)-2(1-A) 9 also I ; 12 = ; • ;

✓6 - ✓6
_
5'),,,- 1=9 ⇒ A=2 1 ;+ b - ; 1 = <;+b-;> · c;+ b-;>
2
⇒
:. ;: = 4i+ 3i - f
= a·a +a·b-a·c +b·a +b·b
➔➔ ➔➔ ➔➔ ➔➔ ➔➔

lrl = 4 2 +3 2 +(-1)2 = Ju,

✓ -b·c-c·a-b·c +c·c
➔➔ ➔➔ ➔➔ ➔➔

(d) SA= ;,SB= b,SC=c

= 15+2a·b-2b·c-2c·a ...(i)
33. ➔➔ ➔➔ ➔➔

and SO= P b +c-a = (b+c-a)· (b +c-a)

A ➔ ➔ ➔ ➔ ➔ ➔ ➔ ➔ ➔

·: SPIIAO
2
I 1

b·b +b·c-b·a +c·b +c·c

- b+c
➔➔ ➔➔ ➔➔ ➔➔ ➔➔

SP=- -
2 -c·a-a·b-a·c+a·a
➔➔ ➔➔ ➔➔ ➔➔

= KAO= K(p-a) ...(i) 8�'.:.:__JJ.__..J.L_____;=c = 15-2a·b +2b·c -2c·a

➔➔ ➔➔ -►➔
...(ii)
-- a+c _ _ -
Similarly, SQ= - - = KBO = K(p-b) ...(ii) c +a - b 1 = (c +a-b)· (c +a-b)
_, ➔

2
➔ ➔ ➔ ➔ ➔ ➔ ➔ ➔ ➔
2
I

from (i) and (ii) = 15-2a·b-2b·c +2c·a ...(iii)

➔➔ ➔➔ ➔➔

b+c a
p = --+a =-+c -- + b (i)+(ii)+(iii)
➔

2k 2k
➔ ➔

I ; + b-; 12 +I b +; - ; 12 + I ;+; - b 1 2
1
= ;+ ( k) b + ( ;
2 2 �) =45-2(a·b +b·c +c·a)=50
➔➔ ➔➔ ➔➔

1 1
= ;+( )b ..• a·b +b·c +c·a =-
-5
( 2k ) 2k 2
➔➔ ➔➔ ➔➔

Comparing· coefficients
(c) a, b,-c, d are coplaner
➔ ➔➔ ➔

k = _!._
35.
2 d J. a, d J. b, d J. c
➔ ➔➔ --➔ ➔
 ➔➔➔ ➔ ➔➔➔ ➔
Ways to get 7 : Probability
[abd]c-[abc]d

= (axb)x(cxd)
➔ ➔ ➔ ➔
[1, 6 ]:¼·¼=(¼f

1 1 1 1
3
:. [a b c] =0 (as vectors are coplaner)
➔➔➔

[11 5):-·-·-= ( -)
" 6 6 6 6
also [abd] = a·(bxd) = (axb)·d
➔➔➔ ➔ ➔ ➔ ➔ ➔ ➔

= I a x b I · I d I · cos 0° (": a x b .la, b ⇒ axb II d)

➔ ➔ ➔ ➔ -► ➔ ➔ ➔ ➔ ➔

l
I a I I b I sin 30° • I d I = -2
➔ ➔ ➔

1
i+2j+2k ⇒ c = 2i+4j+4k
' ' ' ,. ' '
➔ ➔

:. -c =
2

:. I ;I = 6
36. (d) x = 40
cr= 5.1
n= 100

:. �>; =4000
cr = 5.l 39. (a) P (both side head)= �
,,
Var(x) = (5.1)2 = 26.01 1

__ ; - (40)2= 26 .01 P (Fair coin) = �

�> 2
100 IO
·. rx/ = 162601 He d = _!_
6
p( � ) ( )
Incorrect Lx/ =162601 Fair 2
Head
Correct Lx/ = 162601- 502 +402=161701 p( )=l
Unfair
37. (b) Total numbers ofnon-zero matrices = 39 - 1
Now to make skew symmetric, diagonal elements must 2
-xl
16
=-
be 0 Probability= lO
6 17
2_xl + (_!_)
10 2 10
X�

40. (c) X P(x) x

i
x2 ·P(x) x·P(x)
also if we take a from -1, 0 or 1 then -a is also fixed, -2 0.1 4 0.4 -0.2
similarly for b -1 K l K -K
Hence, total number ofskew symmetric matrices=3 3 0 0.2 0 0 0
Out ofwhich ifwe select a = b = c = 0 then it will be zero l 2K l 2K 2K
matrix 2 3K 4 12K 6K
:. Non zero skew symmetric matrices = 3 3 - 1
3 K 9 9K 3K
33 -1 26 I
Probability = 9 - = Var(x)= L[x • P( x )]-(µj
3 1 196 82 = 757
2

38. (c) P (any number)=

1
6
J
Now ( µx)2 = [�)x· P( x ) = (IOK - 0.2)2
 also LP = I ⇒7K+ 0.3 = I ⇒K = 0. l ⇒12=(a - b)(a+b - 2) ... (i)
(µy =0. 64 P utting the value of b = - 1 and b =3 in equation(i) we
Var(x) =(24K+ 0.4) - 0. 64=2.16 get coordinate ofC are(5,3),(-3,3)(5, - 1) and(-3,- 1)
Now sum of the absolutes values of the distinct
coordinates ofC is 5+ 1-3 I+ 1 -1 I=9.
41. (Bonus)

B (": (5,3) and(-3, 3) are same withA).

C(h, k)
1 1 -1
P(-3,4)
44. (c) k 2 =0
4 2k 7
⇒ (14- 2k)-(7k - 4)-(2k 2 - 8)=0
0
⇒ 2k 2 +9k - 26 =0
⇒ 2k 2 +13k-4k-26=0
Equation of AB
y-4 = m(x+3) ⇒ k(2k+l3)-2(2k+13)=0
3 -4 ⇒ (2k+13)(k- 2)=0
A =(- : , 0 )and B=(0, 3 m +4)
-I3
⇒ k=2
-3m 4
. ..(i) ' 2
B ut at k =2,lines will be coincident
⇒ h= +
k -4
m
and k = 3m +4 ⇒ =m - 13
k= _
3
k -4 (d) m 1 x m2 =-I
-3(-- - ) -4
45.
3 2 . k
h= [from(i)J ⇒ - X-=-1 -
⇒ 2k=-(2k-3)(1 - k)
k-4 2k- 3 l-k
3
h (k - 4) =-k+4 - 4 ⇒ 2k =(2k-3)(k- l) = 2k 2 -5k+3
⇒
3 ⇒ 2k2 - 7k+3 = 0
⇒ xy - 4x + 3y = 0 ⇒ 2k2 - 6k - k+3= 0
42. (d) Let origin is shifted to the point P(h, k) ⇒ (2k-l)(k-3)= 0
then put X = x + h and Y = y +k, we get
2(x + h)2 + (y + k)2 -4 (x + h) +4 (y+ k) = O
' 2
k= 3 _!.
⇒ 2x2+y2 +(4h-4)x
+ (2k+4)y+ 2h 2 +k2 - 4h + 4k=0 1
a =3, P = 2
comparing with 2x +y2 - 8x + 8y +18 = 0, we get
2

4h - 4 = - 8 ...(i) a 2 +2p=9+2(½) =10.

2k+4a:8 ...(ii)
2h 2 + k2 - 4h + 4k =18 ...(iii) a+b _!. _!.
(d) k = = +
from(i), (ii) and(iii) we get h= - 1 and k = 2 46.
Transformed equation of st. line is
ab a b

(X- 1) + 2 (y + 2) + 2= 0 ⇒X+ 2y + 5= 0 at (k, k): '5_+'5_=k(!..+ !..) = k 2 etcI

43. (b) ·: OP ..l AC
a b a b

[ (a, 3)
at (J.. J.. : _!_+_!_ =_!.(_!.+_!.) = Lk = I
k' k ) ka kb k ,a b
��; a-(:=;]
k
p R eqmre . .1s 1 1j
• d pomt (k, k)
⇒ (b+ l)(b - 3) 0
(b) Let the equation of chord be Ix +my= 1
=

⇒ b=- l ,b=3
47.
3x2 - .v2 - 2x +4v=0
Also OQ ..lAB
3x --y 2x(lx +my)+4y(/x 4- my)= 0
2
-
⇒3x2 -_v2 - 2lx2 - 2mxy + 4/xy+4my2 = 0
q_;_;�I
2
=-(!=;) B(b, 5) C(a, b) ⇒ (3 - 2/) x2 +(4m - 1)_v2 +(41-2m) xy =0
 ·: Above pair line represents perpendicular lines ·of the 50. (a) x 2 + y2 = 4
form c,: (0, 0)
Ax 2 + 2Hxy + By = 0 ,.., = 2
A+B = 0
3 -2/ + 4m - 1 = 0 ⇒
2/ - 4m = 2 ⇒ l - 2m = 1
x2 + y2 - 6x - 8y-24=0
C2 : (3, 4)
Comparing with Ix + my = 1
r2 = 7
x = l ,y=-2
C1C2 = .j(3 .:_ 0)2 + (4- 0)2 = 5
⇒
Line passes through (1, -2).
48. (c) Let radms =r c,c2 = (r, -r2)
⇒
Centre (-r, r) They are touching each other internally.
One common tangent.
51. (a) Equation of family of circle passing through S1 = 0

⇒⇒
and point is S1 + AS : 0
(-6, 3) 2
x2 + y2 + 2x + 8y-23 + A{(x - 1)2 + (y- 2)2 } =0

⇒
x2 + y2 + 2x + 8y-23 + Ax2 + AY -2AX - 4Ay + 5A= 0
(A-+ l )x2 +(A+ l )y2 +(2-ZA)x
0
+(8-4A)y+ (5).,-23) = 0
Equation on the circle :
(x + r)2 + (y - r) 2 = r2 ⇒
2 (1- A-)
X +y 2 +2--X+ 2
(4-2A) 5).,-23
y+--: 0
y
⇒ x 2 + + 2xr - 2yr + r2 = 0 A+I A+ l A+I
lt passes through (-6, 3) ·: radius = Jw
⇒ r 2 - l 8r + 45= 0 ⇒
36 + 9- 12r- 6r + r2 = 0
r = 3,15 ⇒ -(�) A+l
2
+(
4-ZA.
2
) -(
5A-23
) =JO

⇒
A-+I A+I
r 3
=

Eqn. of circle : x2 + y2+ 6x - 6y + 9=0. (l - A-)2 +(4-ZA/ -(5A-23)(A+I) = I0(A+ 1)2

49. (b) x 2 +y2-10x = 0 ⇒ 2
I+ A2 - 2A+16+ 4)., -16)., - 5)., 2 +1 8A + 23
Equation of tangent at (9, 3) = 1Q).,2 +IO+20).,
9x + 3y - 5(x + 9) = 0
⇒ 2 ⇒ "'2
⇒
T: 4x + 3y - 45 = 0 1 0A- +20)., - 30 = 0 +2A- 3 =0
-4 3 ⇒ (A-+ 3)(A-1)=0 A=1,-3 ·: A;c-l
Slope of tangent = and slope of normal =
3 4 "- = -3
3 Equation of circle is
Equation of normal Y - 0 = (x - 5)
N: 4y=3x- 15
4 t2 + y2- 4x - l 0y + 19 = 0
, = -4, b =-10, c = 19
I a+ b + c I= 5 .

Centre lies ony = x ⇒

52. (;) ·: Circle passing through ori�in. :. c = 0
centre ( g-,-g)

T=0
x! +y2 + 2gx + 2gy = 0
:. 2g( 2) - +2g(-3) = 10 -lOt = 10 ⇒
g ⇒ = -1
Radius = 1 + 1 = ✓ 2 2
✓2
Required area = Ar(!l.PAB) Diameter = 2 . ✓2
At A andB,y = 0 B. (c) Equation of circle through poin ofintersection of S1
and S2 is
A(�, 0} B(5, 0) S1 + A.52 =0
9 3 x2 + y2 +6x+ 4y-12+A-(x2 +_v2-Lx-6y-12)=0
1 45 2 2
⇒ (A+l)x +(A-+l)y + (6- 4A)x
Area =
- - 0
2 4
+(4-6A)j· -(12+ 12A) = 0
5 0
 12(l+A) ⇒ a 2 sin 2 30°=12 • a cos 30°
=O
l+A
⇒ a= 48cos 30° =24✓3
Radius =✓13
✓3
3

Area=- ✓ a 2 =-(24v3)
r:; 2 =432v3.
r:;
3-2A. 2-3A 12(A+l)
2 2
⇒ ( ) +( ) + =l3 4 4
A+l A+l A+l
x 2 y2
⇒ (3-2A.)2 +(2-3A)2 +12(A+l)2 = 13(A+l)2 56. (c) �+ =1
!?
⇒ 9+4A2 -12A.+4+9A2 -12A -A2 -2A-l = 0 4 4 I I 1
⇒ -+-=l⇒-+-=- ... (i)
⇒ 12A2 -26A+l2=0 a 2
b 2
a 2
b2 4
9 1
⇒ 6A2 - l3A+6 = 0 ⇒ -+-==l ... (ii)
a 2
b2
⇒ 6A2 -9A-4A+6=0 Equation (ii) - (i),
⇒ (3A-2)(2A-3)=0 8 3 32
⇒ -2 =- ⇒ a2 =-
4 3
⇒ A=-23' -32 a
⇒ 3a == 32
2

2 2
at A = - , x2 + y2 + 2x - 12=0 ⇒ J_ - 1- � - 1- 7 - -2_
3 b 2 2
0 32 32
32
at A= i,
2
x2 + y2- 2y-- 12 = 0. ⇒ b2 = ⇒ 5b2=32
5
54. (b) 3a2 + 5b2 ==64.
'57. (c) y ==4x + c
x2 y 2
⇒ -+ -= l
4 l
If y == mx + c is tangent then
c2 ==a2m2 + b2
= c2 ==4(4)2 + 1 2 =65
c2 =±-.165..
If parameter of A and Bare ti, t then t1 • t2 =-1 58. (b) 2x +✓',y == 2
2
l ⇒ x2 -2y 2 == 4
⇒ at?= 1 ⇒ 2at1 =-4 ⇒ t1 =- 2 and a=4 Let point of contact == (xi, Yi)
f2 = 2 Equation of tangent at (xi, y 1 )
B(at?, 2at1 ) = (16, 16) =xxi - 2J'Yi -4=0
·: It represents same line as 2x +✓ y -2 == 0
6

Equation of normal : y +t2 x=2at2 +at1

XJ = -2yl -4
⇒ y+2x= 16, +32 ⇒ 2x +y- 48 = 0
2 ✓ =-2
6

55. (d) (a cos30° , a sin 30°)

X1= 4, Y1 =-✓6.
59. (c) A(l, 2, 3); B(3, -1, 5); C(4, 0, -3)
D.R. of AB= (3-l, -1-2, 5-3) = (2, -3, 2)
D.R. of BC= ( 4- 3, 0+I, - 3 - 5) = (l, I, -8)
0 D.R. of CA= (1-4, 2-0, 3+3) = (�3, 2, 6)
(0, 0)
AB· BC= 2-3 -16=-1 7
AB • AC=-6-6+12=0
B AB l. AC
y2 = 12.x A is right angle. ⇒ Circumcentre is mid point of
BC
 3
=( +4_ -1+0 5-3]"
2 2 ' 'C
=(2-=! 1)
. '
\2 2 _
,(2tanx+x-2sin 2
= hrn --�'-----,-----�--
i)
I a I + I � !=; _,_ ½ = 4 = 4 : y I . x ➔O si n2 x(4- · __} -) + sin x(-�- -1)
cos 2 x COSX

i)
60. (a) / + m + n = 0
2lm + 2nl - mn = 0 2( 2tanx+x-2sin2
.
l = --{m + n) = hm
⇒ -2m (m + n)-2n (m + n)- mn = 0 x➔Otan 2 x(4cos 2 x-3)+tanx(2-cosx)
•
⇒ -2m 2 - 2mn ·· 2mn - 2n2 - mn = 0

1·
X
⇒ -2m2 -2n2 ... 5mn = 0 sm-
1_
2 [ 2 •�:-i: +: -sin
⇒ 2m2 + 5mn + 2n2 = 0 �
⇒ (2m + n) (m + 2n) = 0
= Jim---�-------"'--'2 -/1---
⇒ n = -2m. m = -2n x➔ O tanx- tan- x ( os 2 x-3)+----
tan x
when n =-2m
4c - (2--cosx)
X X
I= - (m + n) "" - (m - 2m) = m = 2(2+ I)
=6
1 · (2- 1)

m n . col 3 x-tanx
⇒ -=-- = 63, (b) IJin
I l -2 x-· ► co (x
:
s +-�)
D.R. = (I, 1, - 2)
when m = -2n -- .. - tan x
I= - (m + n) = - (-2n + n) = n tan 3 x
= lim ----"�..:e______

11 7t 7t
l=n=.!!:_ x ➔ - cos x cos --sm x sm . -
-2 4 4 4
4
1-tan x
= lim ---------
I -2 I
D.R. e(l,- 2,1)
x➔
11
4
3
tail x • ✓2I (cosx-sm. x )
co s e "' I
1-2- 2 1
3 l . _✓2(1 tan 2 x)(I
_:......_+____ + tanx)(l- tan x)

rl. o.
+ = I1m '-----'--'--
I
✓l + 4 · ,/! � 4 + 11 = 6 "' 2 • tan 2 x • tan x •cos x(l - tan x)
x➔TT.
4
61. (b) ax + by+ cz = 2 -2)
D.R. of normal to plane ✓2----'--=---
= I.1m -
2
sec x(l+ tanx)
(2 -1, 0-0, -1 + 2) "'(l, 0. I) sinx·tan2 x

I
x-► 11
4
a = I • A, b = 0 • A, c = I • '),_
M+AZ=2 /
(2 .A,
= 2( ✓2/(1+I)= 8.
(2, 0, -1) lies on plane
⇒ 2A - 1. "' 2 ⇒ t. = 2
64. (d) f (x) = ✓x and g(x) =I+ x 2

a = 2, b = 0, c = 2 fog =-ri;;z ⇒ '(fog)'= � ✓t+ x 2

= �
a2 + b 2 + c2 = 4 + 0 + 4 = 8. dx -vi +x
2

2 tan x + cos x - I + x (fog)• ' (I)= �.

62. (c) lim -;========--,======= ⇒
-.J2
x ➔o.J4 2
sin x+2tanx+I-.J3tan2 x+sinx+I·

�J
65. {a) (i) x = a(0- sin 0)
(2tanx+x-2sin 2 x/2)
dx =a(l-cos0)=a(2sin 2
= . (✓4sin
lun
2
x+2tanx+l +J3tan x+sinx+I) 2
d0 2
.
x➔O (4sin 2 x+2tanx+l)-(3tan2 x+sinx+I) y = a(l-cos0)

= hm
2 (2 tan x + x - 2 sin 2
_ -----'----,--------''---
%) dy
-
d6
· c_ .e e
=asmo= 2asm-cos-
2 2
2 2
:r ➔0 (4�in x-3tan x)+(2tanx-sinx)
2023.-24

dy -ee
zasln cos- n Speed
5

6
m/min.
dy cot9
dx=m
dx --]-2= 9
=
2
zo"inz
dg 2
B
dvl \1
.6. v
*1.=o
3
A
(ii) x-3cos0-2cos30
7
d'
dg
= -3.ino+6cos2 osino 68. (b) 12 -f =t ...(i)
...(ii)
*2 +y2 =4J1
= 3sin0(2cos'g-t) = 3sin0cos20
Adding both equations,
.y=3sin0-2sin30 x2 =2(t*Ji)=.=Jr'[{z;
4 = 3coso-6sin2 0cos0 .'. v2 =2d1-\+ Y=J''Mj
d6
Differentiating both (i) and (ii)
= 3cos0(1-2sin2 e; = 3cos0cos20
2x-zY!Z=o={-* -^,
dy dxdxY
dy ag _ 3cos0cos20 = cot0 dv dv -x
=
dx L 3sinOcos20 and 2x+2y -!- =lJ:;. --:-
dx dx v
d0
dvl I xx
" -+-
vv
d*lnrt .6 tan o = l*'- ^'l =
(i) -+ C and 1it) -+ D. ll+m1m2l *2
Clearly
2
66. (c) y:xsinr v
d'-r.orr*r.n, zl
dx = lrr, y-'tvl 'tl =l ,., l=l1l=,
dvv lt -x- |
l-41 lv'-*'l
dx x= xcosx+sinx-sinx .'. $=-.
/L

dy r'rxc'osx+ffir)-xstn.x 4
x
dx
-v
69. (b) 122 =r2 +
(L\,
cosx I \z)
=-_--:-=---:_
rcos.x+sln.x-sll.r x
D
I

ct
h
67. (c) *=, - Yz+?=169

zr4*2rdt- =i
dt dt B

ly
+ 2.x(2)+2y
It )=o
V =rr2h
,2
whenx--5,y: I 2 + V=n A4-!- h
4
2(s)(2)+2(r2,*=o
= V =l44nh -Lh3
dy -20 -t
L:-
4
.dt 24 t =-
!!-=t+qn-.:1 t'
dh4
 2023-25

'. Kr = J1 * Jlx,
= 4L
dh4=o=144n=3-!h'
From (i), .5t.6 * J'lxr1+ K2 =r
+ h2 =48x4=h=8Ji |
.'. D2:P+qz> P:ga = 3+4K2=l=> Kz=
2
Volume = n 2
h = nx96x8..6 = 768.6t cm3 t;
.'. x, = ",6tt - K21=!1
70. (c) lr-- tanx dx 2
' sec' x1l + sec" x)''- '
tan -r f ,.or, +.6sinx)- 2
(sin x - 16 cos x)
dx dx
I / - ,213 J (sin x - .6 cos x)
,..6r[- | .,1 l;

rt
\sec-
tan -r
x )
=+[ cos.r + 16 sin x
slnx- cos x
-itsinx-.6cosx
- .6 x
sin -r cos
)*
=
J --------::::::--
,..6 ,1cor6 , +112'3
=--1
-l r* .6. F
'" lnIsinx-J3cosxI+C
Let 1+cos6x=l
- 6cos5 xsinx dx = dt =.1,
f
* 6 ,nzllrin, - .orrl*.
221221
- 6cos6 xtanx dx = dt
6,nzlrin[,
2 2 | \ -1)1..
=.f,*
-ilfr = _L1n * c =)o+ cos6 x)3 16'
3il

= l,*{,n I t n\l
*{rnr*,
71. (Bonus)i*,fftr,, 22 l''"l,'-l,Jl 2

a,*f ,n 1.,"1'r-l)l + C
=|_I
./r+l
JIx_l'
\5"7
' I
.dx
= 11
LL I \ 3/l

t
(-r + 1)'
(x-l)-(x+l)
/r+ l) t ___: 73. (a)
Let l_ l=
\r-ll
. dx=dt
(x - l)'
-
", cosx-sinx
J cosec x + cos

logi/(x)r-J
r
^

=-l2)1,s't o, =-J,tr,i +C:a(41'' '*a 2J1 2 + sin2x

24 24\x-l ) dx

tanx+16
i -dx+L
1+..6cotx
72. (a)
i 1-r/3cotx dx I tanr- sln x
3
sinx dx
-+cosr
.2 sin x
slnx r: =i l+sinx.cosx i 2 + sin2x
j Slnx E djr = Jrsinx+.,6.ot*,
cosr l-A.X
sin x - J3 .o., =I
sin x + cosx + sinx - cosx r..
__vJ 2 + sin2x -dx
cos x
slnx+cos.r It cosr-slnx
=i
= sinr+..6cos *= x, fts;nr-'JJcosr) 2 + sin2x J 2 + sin 2"r

+K2 (sin x -.6 cos x) I rsinx+cosx

----logil(x)i=l-^ ,

--
2J3 -dx Z+sin2x
+ sin x + .6 cos -r = Kr (cos -t + rE sin x)
slnr+cos-r -dx
+K2 (sin x -.6 cos x)
l= J dx
2
-- rsin2x
= {J*r+ K2)sin x + 1K1 -.6K2)cosx rI SlIl .r + COS.{ n\'
J3 x + 2sin xcosx
(i) -rin2 .. -.or2
"t1xr+Kz=t
r, -J1x, = Jl .(ii)
 20z3-26

r sln.Y + cos r
ffi
- l-_ra log a = lim 1 log tt-tz l*a 72 2
t+L
'3-{sin r cosr;l + lo8 + + log

Let. sin r - cos r : /, (cos -r + sin x) dx :

t ll
dt l,
t dt r
l-=-losl__l+('
' 3-t' 2Jj " Jl -/l
i..6+rl log Z =
--=,
I i. I lroni
'l r+ II
\, )']
I
J3+sinr-cosr L = J log(l
= -Lton" +C log +.r2.1 dx
2J3 .6 - sin r+cos* 0

./(r) = '6+rin,-co.t logrt + .2 1. [41 - [ ?r .

dx t'
"6
sln.x + cos -t ' 'l+r' ' lo
1t

3 t - *r ll
=.ylog(1+rrt,2l:drl
| ' l+.r' ln
vJ +^.6t
22 3,6 l
: ../3 I 16+t ,
22
=
L
[* tog1t +..2
-]-l^l ]o
't l*.tl
1- z [[

74. (d) Let 1=#-- T.,:1

r't"".J:!f,a ...(i) 2(x- ran ',)]n
lxloe{l+r" -
= r

f I

(2
n
)
)
col;r' . coscc2t
cot4r+l
dt
f t -\
=l toe2- 21I - ". 1-g' ,,..-' t-r
I

(z-f ;. ,"r.,1:
1\
tan r .sec2 -t log =rosz
r- ( 2
dx ( ii) )
JO
tanll+l
,1=;#ffiit!-1l. log Z = log 2 + log c, 2

Let tan2x = t 2tanx. sec2x dx = dt

log I = log 2.e 2

= .l

= t1t", I 4l
n'z
I-
!!il7a, = .. L=2e 2
77. (d) x7+i=6q) y={3,
r2=3rl = -r=+4
75. (b) t=l dt (i)
l ...6
-, * .. r=."Es

I dr =tfv,+b-r)ar r,t.,t!'lt

,-il=:
j r/r +."9- 1
o, ( ii)

Add (i)and ( ii),

4 8

lt,t* = t,l:
er.o = II
0
dr +J r'2 dx
4
l
3

=jr .6, dx *j G .,le.,

(l 1

1r1 t.t r+a l' +l-t.

\l ln )
76. (c) t*-! )2 2 t 64
/,)l'
1- = lim
i( 1
)t ll ,')l li =t
l 12
t0.
64-.r 2 +
-sln
2 lsilo
 2a,3-27

- f -] rlx rdv , Jt
=tJ:+llz- zJcs-12 1i t-:tt,
c

- l6tr 32n l1l*6

.33 =l6n 1r.," = - 1n, - 11on
" 2 v+ll
-=-
78. (b) y={acos(log.r)+bsin(logr)l
logr
tn'=tnlll-ltnnl'*l*c
2 "11 + rl
_v = axcos + b.rsin log.r
I I'J
dt ,[*^i'
a -r sin log x.1+ coslogr Jr=-^ +L
dx x
.r' ! t .r'

+h rog.t).1+ sin{rog atr=2,),= c=2 2J1 l .-

['(cos 'l]
^ -. l, t)
= a sin log ,;r + a cos log r + D cos log r + 6 sin log x - {r c) =- l.,'-"'-.,J |

= (D - a)sin log.x + (a + 6) cos log x

'' (r+ l')=-,2(r-c)2(-r-r)
d2y lb-a) cos logx la+h) )
,I
= ; -------- sin(logr r
;e
d2v
(i-a)coslog,r- (a+b)sinlogr
= \ ,S-. ,
,)
q) ar (2, l), ( ( x-C {2-2+2J3-.:\
= L,]
- .r2
dat
= x1b a)coslog.r r1a r b)sin log r .(i) I

- ,9 - rtt &)sinloBr r r(a rblcoslogr (ii) 80. (c)

dtr
dx
(i) - (ii) dlI
dxt
,' 4' ! - ,1' =' 2- .o. log ,- 26r sin log .r
p=!,Q=12
,1 ,

12 !J -r 4l12y=g.
= TLX
F ="lPe = "!J;* -"rn^ -"
19 (d\ )2dr+(x2-xv f)ay=O
v' tF =[ Q.lF' dr+C
' ,1

2
lIl rI - t.' r dx+C
dy -v [
d\ ,r2)-r/-} , ',] 4
r-l r l-ir '2 I \v =L+c
4

dv dv PHYSICS
Letv=y.x>:=v+tr-
'dtd\
,2
t1v 81. (c) Strong nuclear force is the strongest force- relative
d* l-"-rl strength (1); Gravitational force is the weakest force-
,2 relativc strength (lO 19) ; Elechomagnetic force - relative
.r._=__ strength (10 21 is stronger than weak nuclear force -
dxllv' 1_y
relative strength (10 1l).
dv -v2 -r1l ,-v2; 2k3 12

dx 82. (c) Givcn quantity X= a and percentage error

mvn
dx ,2 +r' I v1,+r'-l in the measurement of k : l%, | = 2o/o, m: l7o and n :
dr =
47n therefore value of X is uncertain by 3 x I +2 r 2+I
v2-v(v2+r'-11 r(rr - l)
.r-1.+=r:"".
-d| 2
20?3-28

disolacementls) E9, (d) Angular momentum, L = lo and rotational kinetic

83. (d) \clncrt\' \ - --- t. I
trmel t )
-_ K- ) llr- K=-l-ro
encrrlt
)
\i'u, lan30' l..fi a,=alrr,=1,.f-l
-Fromgrrcn
- s-t graph
- ., -- l:Vl.-
Yt'' lan45' I Lr Kr(Dt 224
E4, (b) Cartesian equation path ofprojectilc is given by 90. (c, Srn(e r . 4 r(u: :1 I :in n t) giren
2
sx
.'\ ',.n..,]
I

)= xlanu 4,,1 -.o"..,

2u_ cos_ 0
_n /[
Given velocity u: i+ 2j m s 1"2 srn cos,It+cos sln,Il
66
r -2 I -\
ui = r/ll + 2l =v5.tanU=-=j L,r. \ ' +\ j {rr --r Ib'] .. .rmJ'lrru,le., 4rt
I 91. (None) Potential energy on earth's surl'ace.
cose:
=
.,/ 5
CiMrn

...y=x\2 l0xx' R
;=2x I at a height 3R from the earth's surface,
--8x-
1/'[l'll
:.lvr, 'l
l 10,
/:l
v)
5 CNlm GMm CVm
.IR =,1(rYll
4R R ]R
(bi GM GMI
85 Centripetal rbrce 1t' :l;ii
2 O = *O ,

l- :m' r,rr r ,FR

a. mas''rn'and fo,cc'F
\;.,.r,JR F
A Fl"
92. (a) Froru l{ookcs lair. \' =
15 se1rj1,rn1 3L = I AI
R. ) lo

V, Ei[I F and 1,, same f'or tluee u,ircs

\. !R: !2 J2 I

86 (b) Angie between fbrce and displacement, c".e -- GivenA, :A. :A., :
ffi I : 2 : 3 andY, : Y. :Y, =3 : 2 ; I
Al, :-\1,:,\1, :=.1 :3:,1
3i+ 4j 5k (si*11*:i)
93. (b) Frorr Boyle's law, P, V, = P, V. or. p ghvt = (pgH +
50 x 50 p8d)\':
- 15+lb
co\¤, =
15 Vl - 5\'and \'2 = Vl d ='l
= 50
''.H>5V=(ll+d)V
I,r.0- cr)s--rl1;,t .H
Io t
cosIt0.32r =5H:H+d.. d=5H H:,lH
e4. (d)
87. (d) Using conservation oflinear momentum, 95. (a) Ijeat gain by water: Hcar lost bv steam
illvl mrvr= 12 i.1:(16 12)i\1+v.: 12m/s ms(10):m ! L+ms(16)
.'. Kincrjc energy of second piece I50,1,(40 20 ) = mf 5.10 , 1 : ( 00( 1 40)l
l-l
Kt. - . tn,r.t i ,l (12)l 2b8 J = l-50 x 20 = m (540 + 60)
150 x 20
,,m:-=5q
aI l-ar'.- A" 6(X)
88. - :
tal TrrqL,.
.\t .l .lI
*, .. Total mass ofwater = l5l) + -i 1559.
 2023-29

96. (b) Temperature to which the iron ring rnust be heated so . . Image distance fon:'ed by the objective lens fiorn the

objective lens = l5 3 : 12 cm.

ro fir the wheel T'= 9.-4 - 1
dicr 1rll11
lJsing lens formula.
i = ;- ;= r= D -;
5.012_5 -_ 1.2t10, . x:
;t2l= "- - ;+27oC=227"C
^_"..
. -2.4 cm.
=
5xl.2xl0-' 5tl.2xl0' 102. (b) Angular width e - 2 sin ' [f] o., o
' i
e7. (b)
.'.0r:0:k2.r " (i)and0r:0-e :U''
:2i
fr
98. (d) V._, : At 27"c + 273: 3ooK
or. er
1g
- 10a - k).r ... (ii)
'ffi "
Dividing eq. (ii) bY (i)
3R ( 300 3R (432)
v,nrr, and v.nrr. = 70
M M kl: - lrl ,-, =' ...r-,.] rrotto -+lgun
at T': 159 + 273 = 432 kir e = 6000 l0 - lo
.'. Percentage increase in the r ms speed 103. (d) Charge on the hollow sphere. g: o ' 4nr2
According to Gauss's law. Thc flux through a singlc firct:
_ IV*,..-Vr.,,)
I " "- """, --
I v*,,
ly[QQ a1

) ofthe cube,
I q 6x4rr- _2rr-e
$ 6eo 6eo 3er,
(b)
,ffit*-'5oo) xl00= 20.78 -17 .32
x100 = 20o/o
104
105 (b) Net resistance of the circuit -' R = 5 + 4 + I
17.32
- l0O And resistance due to 3m balance lcngth.
ffil.r"t
R':: .3:3()
5

99. (d) Given. co :40 rad s l. I : r: 50 cm : 0.5m .'. Speed 5

\r : ro or vs - 0.5 " 40 : 20 m/s At balance length, both circuits have cqual currcnts
rvl lr') r=Er -Ez-19=E..0=,u
flmax =Il, =nt .; 'RR'103
\\'-vs/ \v-l v'' r

-jandn,,,i,
n.o* v*', 360 r 06. (b)
... = --340+20
Ir. -' "...n*..-
3+0-20- 320 8
'mirx : n,,,,n:9 : 8
I 07. (b) When direction olcrrrrent in the loop is rs'crscd' thc
".- change in the reading o1-spring balance
100. (d) When lift is moving upwards then tiequency
:2IaB
flr, =
IE; 108. (c) Potential energy in a uniform magncti'-- ficld.
2n\ I
u: ln B cosO
and when moving downrvards then tiequency
(i) For orientation I 0: 180' . u - IilB cos lll[r'"
] E;
n't =a'.{ wal'c velocity V - ato - a x 2n (n) rnB
t (ii) Fororientationll 0:90' .. u- rlrl3cr'''i;t1" i)

(iii)Fororientation III e:0'< 0 < 9U' .. -mil < u < (i

88-1.1 ln
Ir X
l0 + 2.1 , ll.lx2.t,2.1 (i.,') For orientation I\/ e - 90" ''' 0 '- 1r9")' () '- 'r
\ln
^
\l 88x88
mB
= 6.9 x 10 3m. When lift is mol'ing downrvards then r09. (c) Work required by an extemAl totc"'' l' tL"'r iilc
wave speed. rnagnet so as to align its mxgnetic lllLtlrij!rr normal to thc

/ 2T(n)- 2n,
I 10 - 1.9 field direction.
V= aco =a 1.9 ".
2n 6.c) x l0-3 W - MB (cos 0, cos 01 ) -' ' 2 x 0.3 (cos 9/.)' cos 0")
- 1.9 x 3..12 x 10
'.w:0.6(0 l)-06.1.
.'.V=72rnis.
I 10. (c)
101. (a) Giren f,,:2cm. f. = 3crn and f,, + tc: l5 crn. Final X, = col .' l0 - 'l;l (50tL"
lll. (c) Inductive reactallce.
inrage is fbrmcd at infinity. so objcct fbr e 1 e-picce i c" (l)
irnage fonned by oblectire lcns at f - Scnl lion.r it
2023-30 TS/fffiCETSdvd Papa
When AC source of 200!. l00Hz is connected across the ll8. (d) When an n-type semiconductor is heated. number
coil then of holes and clcctrons increascs equally as when a frce
X. : 2r(f)L: 2n(100)L :2n(50) L x 2 clectron is produced, simultaneously a hole is also
..X'r_=20x2:4Oe- produccd.
.. Impedance, 119. (a) Boolean expression lbr the combination of logic

z= +(xr12 = (:o)2 +(+012 sares Y =(a.s).1n.4)

R2 = soo
Thc truth table ol the circuit is
A B A E A.B A.B Y: (A.B) .(A.B)
Current in the coil, = ?$ = +e
I: ::150 0 0 1 I 0 0 0

L 0 0 0 0
tt2 (a) Lcngth. L: lnr - -i r
1 0 0 1 I 0 0

N'lagnetic moment, M : iA: tn

L I 0 0 0 o io
2n
:i^n" L2
. ...
tc
M=_ 120. (c) Digital signals represent values as discrete steps do
-ln- 4n not providc a continuous set ofvalues. Digital signals are
113. (a) Number of frss;ons per second, in the form of rectangular waves and can utilise binary
5 x l0'3 system.
n=
200 x 106 x 1.6 x 10 le

!9. l2l. (c) Power: 100 watt : is

- 32 '"'tos
I
100
:1.56 ' 108 mls
Number of photons ernitted: 2.0 x 1620 r I

114. (b) Wavelength: x

(A) X- rays -) (R) Crystal structure study
(B) uv- rays -+ (Q) Finger prints in tbrensic labs Energy of I photon = E^ -

(C) Radio waves (S) TV communication system As, Total Ilnergy (Pou,er) - Number of photons emittcd
(D) IR- rays (P,r Rernote switches x Energy of I photon
115. (c) The longest uavelength fbr Lyman series lOuJsl-2.rt'lo:ur' 19
(2--+ I) /.
3aJs
t( 1l : 2.0x 1020s-l x 6.63 x l0 x 3 x l08ms-l
l00Js-l
=R
LL(' =:R
(r)' (z)' 4
^ (r x 6.63 x 10-6m
/.- --- 100 = 39.78 t0 x m = 3978 A
And for Balmer series (3 + 2)
/: 122. (b) Thc difl'ercnce in energy betrvecn the first

t's +
and

l=* f.,=:^
(2)' )
sccond llohr orbit is
l.
ef 36
E, Er - 13.6 x 2.2 ,.
( )
)
n"L ni nl
2

,..
),8 . / 1 l)
- lJ.6 rltj.lj,- .t
t2. l_t
116. (d) The pair of materials I & 2 and 3 & 4 have same
stopping potential so I & 2 or 3 & 4 represents same 3) /
l
niatcrial.
--13.6. l-:l-l-1.6x-
\ 4, ...(i)
+
ll7. (d) tlalf. lit'e ot a radioactivesubsranceAistwo timesthe The difference in encrgy between the second and third
half-iit-e of- another radioactive substance B. Therefbre Bohr orbit is
threu hall'-lives of A is equivalenr to six half-lives of B. (t
r) 6 ^,
El E:--13.6.2: ^ | .---Tr)
*^ - N" ,'t )' nl njl
[;)' i ,)
+--
NB (r/ it
113/EAHCtY Sdt ¤d P.p6 2023-31

126. (b) Using PV : nRT

: 13.6 , (1)r ,
ri i) PVm
=n=-
RTM
= 13.6, /5 = ll.6 x ..
vl:m
Rl
36 36 " -PV
3 Both the containcrs contain same gas (CO.). So. molar

.'. Ralru
l-..1' "-, -l -lb )- rvill bc same.
mass (N,l)
Er-E: ,5 '1 S 5 nr. RTn ms RTg
l6 P,q \'.q rB'u
123. (c) The flrst ionisation cnthalpy ol oxygen is less than
thlr of nitrogen. This is due to the stabilit! of half- m^ (4Tts ) msTg
filled electronic configuration. Nitrogcn has hall lillcd (4 Pu )(4vts ) Povs
clcclroni( ionhcurJlron und hcn(( lt\ ioni.islion energt i{
m^
greater than oxygcr. In oxygen, aiier losing its elcctron.
it goes to halffilled clectronic conllguration and hence. it
ha:' les. ionr:llrun cncrEt th,rn r,ilro!en.
m":4xg
12.r. (b)
127, (a) The structure oiC. O. is
+1 0 'l
o=c=c=c=o
Considering the oxidation stale oleach oxygcn is 2. u'e
o
I 0,1.5'
to'7.
N
,<-:^"
rI 9.5'
get the two carbon atoms linked uith oxygen atoms arc
prescnt in'2 oxidation slate and central carbon atom has

Il zero oxidation state.

H
ll.o NH, so.
lncrcasing order of bond angle I I.O < r'r-H, < SO,
t28. td) !v\ nRl ln t l.ru.r nRl lur ::
", I l,'e to
Pl

125. (c) Bond order can bc calculatcd by using the tbrmula. \^ :..1u.',1 .:.R..tll I
I
w: 3ll.l9.l
B.o
ItNr N w: l.E2 r l0 r kJ
129. (b) KOH ) K* ' OH
lllolecular orbital clcclronlc conlisuration {) I 0.1
of B. (ols)l (o*1s)l (o2s)l (o*ls)l in2p] : rlp] I cd (ol l). .- cdr- + I oH
_ [h
I S25
Bund urder ol B. = 4l = l
Solubililv procluct k,. - [Sll [2S r 0. ]:
1

Molecular orbital elcctronic contiguration ol He. .,.: 10. |' (... r, t

k\t tslr tS)
r s. lo r - tSl 0.01
: ((, ): (o* ls)l
[S] = 2.5 , lo
1s
rr
[Sl 25,lt-t l]=xxl0Y
I
tsr'ntl trrder t I- HEt = [] l] =o
So.x-25.y:13.
Molecular orbital elecironic cor:fi guration of 130, (c) Zeolitc is hydrated sodium aluminium siiicrte' lts
N. - (o ls)l (('* I s): (ols)r (o*2s): (i2pi : rzpi) to2p,)r tbrmuia is Na. Al, Si. O". x H.O
I
- l3l, (b) 2 Li Nor \ ) 2Li. O''1NO" - O,
Bond ordtr ol \. r I lU '11
.l
Li sho*'s anomalorts behaviour as compared to othcr
Molecular orbital elcltronic conliguration of alkali metals.
: n lpi l3?. (b) (Otl), + NaOH + Nai [Bc (Ott)1]
1l) Ue
C. (6 I\ )l (o* ls)l (r.l ls )l (o*2s)l t;r 2p] t
r.\.esi) (x)
(ll) Al(OH). - NaOH -' Na lAl (OH)+l
tx aJ l
1

Bond ordcr ofC. = 1 (er.es:) (\')

'fhc covalencies ofBc and Al in X and Y respectivcly
. . Increasing ordeiof bond order values is
ur'--

TIc, < Llr ': (. < N. 1..1.

2023-32 ,f,ql
1J-1. (c) [)uc' to poor shiclding effect of d-electrons of
(iv) Ho-oly'i'
gliiirrm, it leads to increase in effective nuclear charge CH3 -iH-cursr+HBr >

rvhich inturn leads to decrease in the radius ofgallium as

CH3 CH2 CH2 Br + Br'
tt,rrrptreci to alurniniurl.
(major product)
!.1.i. {c) (-)n rnoving down the group, the melting point
(v) Hotolyt't
deireases rl'rth the exception of Pb whose melting point CH3 - C tt- iHa + HBr )
is slig:htiy greater than that of Sn. I

CH3 - CH- CH3 + Br'

Br
l he correct order of melting point is: C > Si > Ge > Pb > I

Br
Sn [-lence, Sn has lorvest melting point. (minor product)
135. (b) Acidic strength ct o/o
s-character. 138. (a) OH, CH, and -NO, are activating groups. They
Duc to rnaxirnum 9/o s-character of cthyne (50%), activates the benzene ring for the attack by an electrophile.
livclrogcn atorns attached to sp hybridised carbon of - NO, is a deactivating group. Due to its strong
ethvne arc nrost acidic followed by those attached to sp2 I effect, it reduces the electron density in the benzene
hybridised carbon of ethene (33%) and those attached to ring which tends to inhibit the electrophilic attack.
.pl hybridised carbon ofethane (Z5o/o) f39. (a) Contribution of W atoms to the unit cell
In case olpropyne, acidic character decreases than that of
cthvnc duc tt. r! cffect.
:8x-=l
I

8
Flence. order ofacidic strength is: Contribution of O atoms to the unit cell
{-Hl CH, .:911,: CHz. CH3 - C = CH < CH: CH I

IV I III II = 12x-=3
4
136. (c) (,r[{] - H..O j#-Ci C = CH. Contribution of Na atoms to the unit cell : I
I Thus, the formula of the compound will be NaWOr.
OH
txl 140. (a) Using formula,
-ol ATo: ko molality
cHr -c--cH3 (100.t7 - 100)'C : 0.512'C kg mol I x molality
L

0.l7
o molalitv
'
tYl 0.512
Propanone Now, depression in freezing point is given by,
Ilere. X is uri:aturated alcohol and y is ketone. ATr: k, molality
t37. (b) Addition of HBr to propene in presence of a peroxide
ATr= 1.30"a kg' 0 17 . =0.62"C
takes placc contrary to Markonikov rulc. This reaction is 0.512
known as peroxide or kharash effect or acldition reaction Thus, the lieezing point of the solution
anti to Markonikov rule. : 00c - 0.62.c -- - 0.62"C.
Peroxidc effcct proceeds via frec radical chain rnechanism
as given below: l4l. (d) Step t :: .L
NO N, O,
v
OO Step 2 :r\-lo2 + Hz S
N2O + H2O (slow)
(i)
l

Step 3 : N,O + H1 -+ N1 + H?O

c6us -c'-o-o c - c6Il5 llonrol
As slowest step is the rate determining step. So, rate ol
o
1 reaction will be givcn as,
2C6Hi - C' : O: + 2C6H!+ 2CO1 Rate : k, [N,O2] [H2] (i)
Frorn thc cquilibrium step,
Benzoyl pcroxide.
lN, orl: kr [No]2 ...(ii)
(ii) C6 Hi * fig. llornolvsis , CuHu + 81' Now, substitute equation (ii) in equation (i), we get
lri) 911., iH : CH. + Bl Rate -- k, kr [NO]2 [H2]
cH, cH-cH, Since k,, k, both are constants, put k,, k, : k in the above
I equation rate : k [No]2 []l,l
Homolysis Br 142. (b) Fe3* + e -+ Fe2+
(lcss stablc primary
liee radical )
Using Nernst equation.

cH.r cH C'H, - Br E1r"' E'1r.' n*- [..'. ]

(morc stablc secondaru
ll ee radical
r.'' )
=
,{f 'o* ta'*
)
]
I:llilileET $olied ?rp6 2023-33

Here. n : l. [Fe]]1 = 2M. lFcr-l = 0.02 M. Coordinatiorr numhcr: {r. surr =l 6=9
2.301RT (o
= 0.059. E' -. o 77lv (Fer','Fcr' ) C' CO

E(Fer''Fer',)-077r
-
E (Fe-r' Fer
-) : 0.653 V.
O.OSOros
fr (b) Co- Cr
143. (r) Bredig's Arc (lllectrical disintegration) mcthod is
used to prcpare colloidal sals of mctals such as gold.
silver. platinum ctc... ln this method, electric arc is
slruck bet$'ccn clectrodes of the nletal immersed in thc Oxidation
./l\.,
stalc
('()
0
-('a)

dispcrsion medium. The intense heat produced vapourises Coordination mcmber: 6

the metal. which then condenscs to lomr particles ol-thc sum'=0+6.=6
colloidal size. Melal sols acquire negative charge. CI
144. (a) Mondprocess isused forrefining ofnickel. VanArkel
method is used 1br refining zirconium or lilaniuru. Zone
c' CI
I
refining method is used for producing serniconductor and (c) K, cl- Ie
other metals ofvery high purity eg., gcrmanium. silicon.
boron. gallium and indium. -cl
1,15. (c) The thermal decomposition of ammonium ('l
dichromate produccs nitrogen gas, chromium (lll) oxidc CI

and watcr l apour. Oxidation statc - -4

\
(NHrl.(r,O- tN.'(r.,Ol'4H.O Coordination number = 6
146. (d) On moving dou n the group from S to Te, the boiling
Surn=4-6= 10
CN
point of hydrides increases due to increase in van der aN I ('\
$,aal force of attraction. But flro has highest boiling I

point due to presence ofhydrogen bonding. I

(d)

l\
Hence. the increasing order of boiling point ofgroup l6 K{ CN- CT
hydrides is given as : H,S < II" Se < H. Te < tl.O
Thus. H,S has loq,est boiling point while H,O has highest -CN
CN N
boiling point. CN
ll7. (a) 2NaNO., - 2llCl + 2NaCl * NO) + NO + HrO Oxidation stale - +2
ln casc of nitrogen, all oxidation states from +1 to r:1

tend to disproportionate in acid solution

Coordination numbcr - 6

148. (c) During the hydrolysis of interhalogen compounds.

Sum=2-6=8
oxyacids ofless electronegative or large sized halogen is 151. (b) A-lv. B- lll, ('-1, D li
(A) Ducron is a syitthctic 6bcr
formed and other halogen t'omrs halogen acid.
(B) Neoprcne is a s1'titltetic clasl,rmcr.
Thus. less electronegative iodine lbrrns HOI and morc
(C) Bakelitc js a thtnllosetting polyrntr.
electronegati! e chlorinc fbrms HCI
(D) Pollsty.t'nc is a tir.r:1'.plaslic polymcr.
lCl 'H"O r ilCl - HOt
(a) isaoollmeroltr-D(r-1-glucosc Atnylrsr.'is
149. (c) Bo;h Eu*l anrl Yb'l tends ro acqLtire common 152. Srarch

by loosing I clcctron and becomcs a uatcr solLtble componenl $hich c,.ltlstitrrtcs lboul l-i-
oxidation state of+l
20" o oI starch. Chcnrically. amylosc is a lon-q unbriln!l' -' J
highly stable
chail u'ith 100-100 o D ( )- glucosc unit' h'ld
ls0. (c)
together by Cl C'l glvcosirlic linkagc. (cllLrlosc r: "
e,o\ straight chain polysaccharide composcd otrll of [3 l)
- glucose units which are joined b1 glycosiclic link'1:c
\), ,--7_o. between Cl of onc glucose unit ilnd (!1'o1'thc rlc\t
(at Kr -.-)" glucosc ttnit.
153, (b) Dirnetapp (brolnpheniramine) is 1l slnthcti''
drug uhich acls l\ rnlihl'lanllne llt-uin t' 'r nar' '
C,O .l ) analgesic Nardil is an antidcprcssant drug' Vcronal
is

tranquilizcr-
Oxidation state = -l
2023-34 ?S/EU&E Sohmd P.r-
l5il- (b) Srvartz reaction is used lbr synthesis ol alkyl I58. (b) Uenzoic acid undergoes clcctrophilic substitution
fluorides b1 heating alkyl chloride,'bromidc in the -
reaction in prcsence of concentrated nitric acid and
prcsence ofa metallic fluoride such as Agl'. Hg.t',. CoF. concentrated sulphuric acid to form m-Nitrobenzoic acid.
trr SbF. It i. a hul,'gen erchrnge reaction Nitro compounds are reduced to aminesty using metars
tl,C Br-AgF)tlrc F+AgBr in acidic medium.
(d) Alkyl halides (R When a prirnary aronratic anine is dissolvcd in cold
155 X) on heating uith alcoholic
aqueoul mineral acid is treated with sodium nitratc and
KOH. eliminates one molccule of halogcn acid to form
addition of cuprous chloride results in the lbrnration of
alkenes. This reaction is knor-r'n as dehydrohalogenation.
aq,l halidc
\\'hcn alkenc is trcatcd rvith B.Ho in presence ofH.O,. it
co.Il (l.t{
folloss anti lvlarkonikov's additioo to give alcohol. It is
a hvdroboration - oxidation redclion. fon. H\Ol Sn HCI
,\lc KOH ( on(. tltS(J.r
cHr-cH-cHr .\
CHr Ctl=Cll.+HBr NO.
tx) (x)
Br
(r) I31H CO,H CO.H
1,
( Hr - CHIOH
(i, ) It.( )._ (*l
l\ I (i)\a.\.-o. H( I

156. (b) Whcn benzene reacts with acetylchloride in prcscnce {,, ) a'u.r'
NH. CI
of le$ is acid (AlCI,). it ).,ields acetophenone (X). {l',) 17.\
Thc reduction of ketones or aldehydes by using zinc 159. (b) In R\H.. N atom is sp3 hybridised. In RN = CHR'.
amalganr and concentrated hydrochloric acid yiclds N atom is spl hybridiscd whereas in RC = N. N atom
alkenes. This rcaction is knorln as cicmmensen reduction is sp hvbridised. The sp hybridised N atdh is mosl
C(X]H electronegati!e due to maximum s character More
clcctronegative elemcnt has lcss tendency to donate
4fi,( o( I
+ elcctrons and therefore is least hasic
Anhr. Ala ll
Thc order of basicity of aliphatic amines should be
CH ,CH, primary > secondary > tertiary
(x)
Thus. the order ofbasicity will be:
Zn I{9, Con. HCI
--) RNHr>RN=CHR'>RC=N
II1 I II
Lrhllbcnzcnc
160. (b) Aliphatic and aromalic primary amines on heating
l\''
u,ith chlorolbrm and alcoholic KOH form isocyanides
157. (a) In Etard reaction. chromyl chloride oxiJises methyl or carbylamines which are fbul smelling substances.
group to a chromium complex. which on hydrolysis givcs Secondary and tenjary amines do not show this reaction.
corresponding benzaldehyde. Thir raucl:oll ir koorrn a: carbl llmrne reactron or
cH, CI{(OCrOHCl,), isocyanide test. Hcnce. the compound should be
+ ('rO.Cl.( s. benzylarrrine.
- C}I,NH.
Chrornrunr complcx
+ cHclr + IKOH
- !91+
CHO
H,O'
Benzllamine
CTI,NC

Bcnzaldehvde + 3KCl + 3H,o

(Y)