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236 Chapter 4 Modified

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12 views

236 Chapter 4 Modified

Uploaded by

abraham123.eisa
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Analytical Chemistry I (CHEM 236)

Tutorial problems: Chapter 4


Calculations used in Analytical Chemistry

➢ Units of Concentration

Name Units Symbol

molarity moles solute / liters solution M

formality moles solute / liters solution F

normality equivalents solute / liters solution N

molality moles solute / kilograms solvent m

weight percent grams solute / 100 grams solution % w/w

volume percent mL solute / 100 mL solution % v/v

weight-to-volume percent grams solute / 100 mL solution % w/v

parts per million grams solute / 106 grams solution ppm

parts per billion grams solute / 109 grams solution ppb

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11- Find the number of millimoles of solute in
(a) 2.00 L of 0.555 M of KMnO4
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(c) 3.50 L of a solution that contains 3.33 ppm of CuSO4 (159.61)
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15- What is the mass in milligrams of solute in:


(c) 356 mL of a solution that contains 2.96 ppm of Pb(NO3)2
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27- Describe the preparation of
(a) 500 mL of 4. 75% (w/v) aqueous ethanol (C2H5OH, 46.1 g/mol).

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(b) 500 g of 4.75% (w/w) aqueous ethanol.

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(c) 500 g of 4.75% (w/w) aqueous ethanol

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3
31- Describe the preparation of

(a) 500 mL of 0.0750 M AgNO3 from the solid reagent.


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(c) 400 mL of a solution that is 0.0810 M in K1, starting with solid K4Fe(CN)6.
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(d) 600 mL of 3.00% (w/v) aqueous BaCl2 from a 0.400 M BaCl2 solution.
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4
32- Describe the preparation of
(a) 5.00 L of 0.0500 M KMnO4 from the solid reagent.

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(e)1.50 L of 0.215 M NaOH from the concentrated commercial reagent [50%


NaOH (w/w), sp gr 1.525].
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