ChE3 44

Che
mic
alReac
tionEngi
nee
ring
Wint
er1 9
99
Fi
nalExam

So
lut
ion
(
25pt
s)1)Thegasphas
eir
reve
rsi
bler
eac
tion
A+B C
ise
lement
ary.Theente
ringflow rat
eofA i
s10mol/minandi
sequalmol
ari
nA
andB.Theenter
ingconcent
rat
ionofA i
s0.
4mol/dm3.

a)Wha
tist
heCSTRr
eact
orvolumenec
essar
ytoac hi
eve90% c
onve
rsi
on?
b)Wha
tPFRvol
umeisne
cess
arytoac
hieve90% c
onversi
on?

Addi
ti
ona
lInf
orma
tio
n
k=2dm3/mol
•mi
n
T0=500K

Not
e:Youdonotneedtous
ePOLYMATH,butifyoudowri
teyourpr
ogr
am
bel
ow i
ncaseyoudonotobt
aint
hec
orr
ectanswe
r.

a) FA 0X  rA V
FA 0 10
x 0.9
V ?
2
2  X 
 rA kC A C B  2C A20 1 X  1
 2 

2 0.42 
0.12
0.01057
0.552
100.9
V 851dm3
0.01057

b)FA 0 dX   rA dV
2
 X
dX 1 
0.9  2  kC2
0  A0 V
1 X 2 FA0

 
2
 1 1  1
2 1 12 0.9 2 0.42V
2 1 ln1 0.9  0.9  
 2 2  2  1 0.9 10
3.63 10
V .3 dm3
113
2 0.44

1
W’
99Fi
nal
Exa
m
 2
W’
99Fi
nal
Exa
m
 Too long to read on
your phone? Save to
(
15pt
s)2)Thei
rreve
rsi
blezeroor dergasphasedimeri
zat
ion
2A A2 read later on your

m.Pucomputer
i
scar
riedoutinapac kedbe dreact
orwith5kgofc a
tal
yst.Theent
eri
ngpress
ure
i
s10atma ndtheexitpr e
ssurei
s1a t reAentersa
taflow r ateof10
mol
/mi
n.Therea ct
ioni szer
oor
deri
nA.
P0 = 10 atm Save to
P =a Studylist
1 atm
FA0 = 10 mol/min
X=?
a)Wha
tist
hepre
ssuredropparame
ter?
b)Wha
tist
heexi
tconver
sion?

Addi
ti
onalI
nfo
rma
tion
k=1.5mol/kg•mi
n
T0=500K

Not
e:Youdonotneedtous
ePOLYMATH,butifyoudowri
teyourpr
ogr
am
bel
ow i
ncaseyoudonotobt
aint
hec
orr
ectans
wer.
1
A 
 A2
2
dX
FA 0  rA 
dW
x k

0
dX 
FA 0
W

1.5
X W 0.15W
10
dy d 1 X

dw 2 y
x 5 1
02y dy   1  0.15W 
dW
0 2 
5
0.1  0.15 2
y2   w  w
1  4 0

 0.1525
 0.99  5 
 4 
   4.0625

 0.2437kg 1

X 0.15 5 0.75

3
W’
99Fi
nal
Exa
m
(
10pt
s)3)Thes
peci
esA andBreac
ttofor
ms peci
esC,D,andEinapac
kedbedr
eac
tor
.
Thec
atal
ystdoe
snotdec
ay.Thefol
lowi
ngprofileswer
eobt
aine
d

X .4 T
500

0 W W

Ci
rcl
ethec
orr
ectt
rue(
T)orFal
se(
F)ans
werf
ort
hiss
yst
em
T F a)Theaboveprofile
sc oul
dr epr
e s
entanadi
abat
ics
yst
em wher
ethe
addi
ti
onofinert
swillinc
reasetheconve
rsi
on.
T F b)Theabovepr
ofil escoul
dre
pr es
entasyst
em wher
ede
creas
ingt
he
flow rat
ewilli
nc r
easet
heconvers
ion.
T F c
)Theaboveprofilescouldrepres
e ntasyst
em wherei
fthefee
d
t
empera
turei
sincr
eas
e d,onecannottellf
rom t
heaboveprofile
s
whe
therornott
heconversi
onwi llinc
reaseordec
reas
e.
T F d)The
recoul
dbeahe
ate
xchange
ront
her
eac
torf
orwhi
cht
hehea
t
flow i
s
Ý 1000kJ
dQ
 T  500
dW kg s K

T F e
)Theabover
eac
tionma
ybeane
xce
llentc
andi
dat
eforr
eac
tor
s
tagi
ng.

a)I
fiti
sana di
abat
ics
ystem,theni
thast
obee xot
hermi
c.Addi
tionofi
ner
tswi
ll
l
owerthee
xitt
emperat
ureandhencewi
lli
ncr
easethec
onve
rsi
on.

b)Decr
easi
ng t
heflow ra
tewi
llnotc
hanget
hee
xitc
ondi
ti
on be
caus
eiti
san
equi
li
bri
um c
ondi
ti
on.
c
)Onec
ans
ayt
hatt
hee
xitc
onver
sionwi
llnoti
ncr
eas
e.

d)Be
caus
etheambi
entt
emper
atur
eis500,s
ameasfinale
qui
li
bri
um t
empe
rat
ure
.

e
)Be
caus
eitma
ybeane
xot
her
micr
eve
rsi
bler
eac
tion.

4
W’
99Fi
nal
Exa
m
(
3pt
s) 4)Thegasphas
ere
act
ion
2A  B
 C
i
scar
riedoutinaPFR.Thefeedisequalmolari
nAandBandt heent
eri
ng
t
emperat
ureis500Kandtheenter
ingpress
ureis16.
4at
m.I
ftheexi
tconver
sion
3
i
sX,thentheexi
tconce
ntr
ati
onofB( inmol/dm )is

a)C B 0.41 X 1 .5X

b)C B 0.41 X1 1.5X 
c) C B 0.4
d)C B 0.41 0.5X 1 X 
e)Noneoft heabove
f) Cannotbec al
culat
edwi thoutknowi
ngt
hee
xitc
onver
sion.
1 1
A B
 C
2 2
1  1 1 
 yA0     1
2 2 2 
1

2
 X   X
CA 0  B  C A 0 1 
 2   2 
CB 
1 X  X
1
 2
 C A 0  0.2

5
W’
99Fi
nal
Exa
m
Recommended for you
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11
BS
100% (2)
Chemical…
(
6pt
s) 5)a)Thef
oll
owi
nge
leme
ntar
yli
qui
dphas
ere
act
ionsar
etobec
arr
iedout
A  B
 R

R  B
 S
Speci
esRi
sthede
sir
edpr
oduct
.Whi
chofthef
oll
owi
ngs
cheme
sshoul
dbe
used?
A B
B
A
B A
(
a)PFR (
b)PFR (
c)CSTR
A B
B t=0 A

A B

(
d)Se
miba
tch (
e)Ba
tch (
f)Se
miba
tch
A B
A B
A

(
g)
b)I
nther
eac
tor
s
2
A 
 B rB kBC A

A  B
 2C rC kC C A C B
Wha tisthei
ns t
ant
aneouss
elec
tivi
tyofCt
oB?Whichre
actororcombi
nati
on
ofreact
orsanda twhatt
emperat
ureswoul
dyouus
eforthefol
lowingr
eac
tion
sys
tem?
Cisthede si
redproduct
.
DataforPart(b)
C A 0 4 mol dm3 k B 1 dm3 molmin at 300K with 
E 4000
cal mol

k C 1 dm3 molmin at 300K with 12000

E cal mol A

High Temp.

6
W’
99Fi
nal
Exa
m
(
a)
r1R k1R C A C B
r2R k 2RC R C B

r r  r2R k1RC A C B  k2SC R C B

SRS  R  1R 
k2S r2S k 2S C RC B
k1R C A
  1
k2R CR

WecanmaximizeSRSbykee
pingCA hi
ghandCR l
ow.Forke
epi
ngCR l
ow,ke
ep
CBl
ow be
cause
rR r1R  r2R

k1R C A  k2SC R C B

rR  CB
He
nce
,us
eei
the
r(b)or(
d).

(
b)
rC k CCA CB
SCB  
rB k C 2  1 K C C
B A
2 C A B
1
k C
B A 1

kC C B 2
1

8000C A 1
exp 
 RT C B 2
Wec
anmaxi
mizeSCBbykee
ping
Thigh
CAlow
CBhigh
Us
esemi
bat
ch
A

andhi
ghr
eac
tort
empe
rat
ure
.

7
W’
99Fi
nal
Exa
m
(
8pt
s) 6)a)Thef
oll
owi
ngpl
otofac
tivi
tyasaf
unc
tionoft
imewa
sobt
aine
d.

1
a
1.0

t
Whattypeofdecaywoul
dbe
stdes
cribet
oda
ta?(
cir
clet
hec
orr
ectans
wer
)
1)Poisoning
2)Sint
ering
3)Coking
4)Noneoft heabove
b)Thef
oll
owi
ngpr
ofil
eswer
emeas
ure
dinaPBR
t=0 t=10 min
X X

W W
Thet
ypeofcatal
ystde
cayc
anbes
tbedes
cri
bedby(
cir
clet
hec
orr
ectans
wer
)
1)Pois
oning
2)Sint
eri
ng
3)Coking
4)Noneoftheabove

c
)Thefoll
owingcat
alystac
tivi
typr
ofil
ewa
sme
asur
edi
naPBRf
ort
he
i
some
rizat
ionofAt oB.
Thede ca
yl a wt
hatbes
tde
scr
ibe
sthi
sda
tais(circ
let
hec
orr
ectans wer)
da
1)  ka
dt
1.0 t = 40 min
da a
2)  ka2
dt
da
3)  ka C A
dt 0
da 0 W
4)  ka2 C B
dt
5)Noneoft heabove

8
W’
99Fi
nal
Exa
m
(
8pt
s) 7)(P10-4)Therat
elawforthehydr
ogenat
ion(H)ofet
hyl
ene(
E)tof
orm et
hane(A)
overac obal
t-
molybdenum ca
tal
ys Co
t[ l
lec
ti
onCzec
h.Che
m.Commun.
,51,2760
(1988)]i
s
kPE PH
 rE
1 K E PE
Sugges
tamechanis
m andra
te-
li
mit
ings
tepc
ons
ist
entwi
tht
her
atel
aw.
(Canbedonebyinspe
cti
on.
)

E  S 

 E  S


E  S  H 2 
 A  S (rate limiting ste

9
W’
99Fi
nal
Exa
m
(
5pt
s) 8)Supposethehea
texchangerinExampleE8-
12bec amefoul
edsot
hattheover
all
heattr
ansf
ercoe
ffic i
entwasreducedby50%?
Wha twouldbethenews te
adystat
etempera
turesins
idether
eac
tor
?

10
W’
99Fi
nal
Exa
m
 11
W’
99Fi
nal
Exa
m
(
20pt
s)9)Thee
lement
aryl
iqui
dphas
ere
act
ions
(1) A 
 B

(2) 2A 
 C

arecar
rie na100dm3PFRwher
douti espe
cie
sBisthedesi
redpr oduc
t.Pur
eA
ente
rsatamol
arflow r
ateof40.
0mol
/minandataconc
entra
tionof4.0
mol/dm3.

Addi
ti
ona
lInf
orma
tio
n
C PA C PB 20 cal mol K

C PC 40 cal mol K

H Rx1A 10, 000cal mol

H Rx2A  20,000 cal mol

cal
Ua 100 with Ta 400
K
dm3 min K
k1A 0.05 min 1 at 400
K with E 10,000 cal mol

k 2C 0.0005dm3 mol min at 400

K with E 19,000 cal mol
a)Foraf
eedtempera
tureof450K,wha tar
etheexitc
onc
ent
rationsand
t
empera
tur
e
CA =__
2_
.5
_5
__,CB=__
1_
.
3_
5__,CC=__0
_.
0
_5
__,T=__
3_
9_
1__K
b)Thef
eedte
mper
atur
ecanbevar
iedbe
twee
n400a
nd700.Whatfee
d
t
empera
tur
edoyourec
ommendtomaximi
zet
heexi
tmolarflow ra
teofB?
T(K) FB(
mol/min
400 12.
03
500 18.06
600 2.29
550 3.78
525 5.73
505 15.49
495 16.
81

75% Marksf
orset
ti
nguptheprobl
emc
orr
ect
lywi
thal
lcor
rec
tequa
tionsand
numbersinPOLYMATH Notat
ion

25% Fi
nalAns
wer

(
9)

12
W’
99Fi
nal
Exa
m
 13
W’
99Fi
nal
Exa
m
a)Tr
uebe
caus
eini
ti
all
yther
eac
tort
empe
rat
urede
creas
es.
b)Fal
sebec
aus
eint
hisc
ase
,thet
empe
rat
ures
houl
dnotc
omebac
ktot
hei
nit
ial
val
ue.
c
)Tr ue
.Thereac
tionisendothermi
cand itshowsade c
reas
eintempe
rat
urefir
st
andthent
heheatex
changertakesi
tbac
kt othei
nit
ialt
empera
tur
e.

(
a)(2)secondorder(
sint
ering?
)
(
b)(3)coking
(
c)acti
vityprofilemi s
sing
(
d)

14
W’
99Fi
nal
Exa
m
 15
W’
99Fi
nal
Exa
m
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BS
100% (6)
Chemical…

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Problems
15
BS
100% (3)
Chemical…

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2 100% (3)
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notes 1
11
BS
100% (2)
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