JEE MAIN MOCK TEST # 6

M.M.: 300 Time: 3 Hours

Important Instructions:
1. The test is of 3 hours duration.
2. The Test Booklet consists of 75 questions. The maximum marks are 300.
3. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics having
25 questions in two section (Section A and Section B).
4. Section A contain 20 multiple choice questions with single correct answer. Section B contains 5 integer type
questions.
5. Each question is allotted 4 (four) marks for each correct response.
6. Candidates will be awarded marks as started above in instruction No. 5 for correct response of each question.
¼ (one fourth) marks of the total marks allotted to the question (i.e. 1 mark) will be deducted for indicating
incorrect response of each question. No deduction from that total score will be made if no response is
indicated for an item in the answer sheet.
7. Do not fold or make any stray mark on the Answer Sheet.

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 JEE Main Mock Test # 6

PART 1 : PHYSICS
SECTION 1
This section contains 20 multiple choice questions. Each question has four choice (A), (B), (C) and
(D) out of which ONLY ONE is correct.
1. A small coin is resting on the bottom of a beaker filled with a liquid. 6 cm Air
A ray of light from the coin travels upto the surface of the liquid and
moves along its surface. How fast is the light travelling in the liquid?
8 cm
(a) 1.8 108 m / s
(b) 2.4  108 m / s Coin
8
(c) 3.0  10 m / s
(d) 1.2  108 m / s
2. Angle of a prism is  and its one surface is silvered. Light rays falling at an angle of incidence 2 on the
first surface return back through the same path after suffering reflection at the second silvered surface.
Refractive index of the material is
(a) 2 sin  (b) 2 cos 
(c) (1/2) cos  (d) tan 

3. In the figure, an electron moves a distance d in a uniform electric E as shown

in the figure. Does the electric field do a positive or negative work on the E
electron? Does the electric potential energy of the electron increase or
decrease?
(a) Negative, increase (b) Positive, decrease e
(c) Negative, decrease (d) Positive, increase
4. For the circuit shown in figure, the charge on the capacitor is C
CER 1 R2
(a) CE (b)
(R1  r )
CER 2 CER 1 R1
(c) (d)
(R 2  r ) (R 2  r )
E r
5. Two resistors of resistances r1 and r2 (r1  r2 ) are joined in parallel. The equivalent resistance R is such
that
(a) R  r1  r2 (b) r2  R  r1  r2
(c) r2  R  r1 (d) R  r2  r1
6. The de Broglie wavelength of a neutron at 927º C is . What will be its wavelength at 27º C?

(a) (b) 
2
(c) 2 (d) 4

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7. A wire is bent as a parabolic curve and kept in the x - y plane. The

y
curve can be described by the equation x 2  6 y . The wire carries
 6m
a current i = 2A. If a uniform magnetic field B  2  10 3 kˆ tesla is
applied, force experienced by the wire is nearly i
(a) 1.5 jˆ N (b)  1.5 jˆ N
x (m)
(c)  0.05 jˆ N (d) 2.5 jˆ N O
8. A thin hollow sphere of radius R is made of a material of specific gravity . It will float if the thickness t is
(t << R )
R 2R
(a) t  (b) t 
3 3
R 4R
(c) t  (d) t 
3 3
9. A 50 Hz ac source of 20 volts is connected across R and C as shown in
R C
figure. The voltage across R is 12 volt. The voltage across C is
(a) 8 V
(b) 16 V
(c) zero ~
(d) not possible to determine unless values of R and C are given
10. The wavelength of radiation emitted is  0 when an electron in hydrogen atom jumps from 3rd to 2nd
orbit. If in the hydrogne atom itself, the electron jumps from fourth orbit to second orbit, wavelength of
emitted radiation will be
25 17
(a) 0 (b) 0
16 20
20 16
(c) 0 (d) 0
27 25
11. The ratio of the de Broglie wavelengths of a proton and an -particle will be 1 : 2 if their
(a) kinetic energies are in the ratio 1 : 8 (b) kinetic energies are in the ratio 8 : 1
(c) velocities are in the ratio 1 : 8 (d) velocities are in the ratio 8 : 1
12. Tension in the light rope shown in the figure is
(m < M and  < tan ) m
(a) (M + m ) g sin 
(b) (M + m ) g sin  –  mg cos  M

(c) zero

(d) (M + m ) g cos 
13. A particle of mass m initially at rest is acted upon by a variable force F for a brief interval of time T. It
begins to move with a velocity u after the force stops acting. Value of u is
F02 T 2 F
(a) (b)
4m 4m F0
F0T FT
(c) (d) 0
4m 2m
t
T

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Re
14. When a body of mass m is taken upto height h  (Re : Radius of earth), then increase in its
2
gravitational potential energy is
1 1
(a) mg Re (b) mg Re
2 3
3
(c) mg Re (d) zero
2
15. A ball rotating with angular velocity  about its centre of mass strikes a

smooth horizontal surface as shown in the figure. After the collision
angular velocity of ball will
(a) remain unchanged
(b) be halved
(c) be doubled v
(d) information is insufficient
16. Consider two configurations of a system of three particles of masses m, 2m and 3m. The work done by
external agent in changing the configuration of the system from figure (i) to figure (ii) is
3m 2m

a a a

m 2m m 3m
a a
(i) (ii)
6Gm 2  1 
(a) Zero (b)  1  
a  2
6Gm 2  1  6Gm 2  1 
(c)  1   (d)  2  
a  2 a  2
17. A small spherical ball is dropped in a viscous liquid. The velocity-time graph is best represented by
v A B

D
t
(a) A (b) B
(c) C (d) D
t 
18. Equation y  4 cm cos 6.28   2x  , represents a wave of wavelength (x in cm, t in sec)
2 
(a) 0.25 cm (b) 0.5 cm
(c) 2 cm (d) 4 cm

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19. An ideal gas undergoes a process A to B as shown in figure. P

A
Choose the correct option for the process AB 3P0
(a) Q = W
(b) Q < W
(c) Q > W P0 B
(d) Data not sufficient to compare Q and W. V
V0 3V 0
20. A standing wave having 3 nodes and 2 antinodes is formed between two atoms having a distance 1.21 Å
between them. The wavelength of the standing wave is
(a) 1.21 Å (b) 6.08 Å
(c) 3.63 Å (d) 2.42 Å

SECTION 2
This section contains 5 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9.
21. An electric network is shown in figure. The potential drop across 5 3 4
will be
A
6 Amp

6 5
B
22. A transformer is used to lit 140 W, 24 V lamp from 240 V ac mains. The current in the mains cable is 0.7
ampere. The efficiency of the transformer is
23. If a coil of 40 turns and area 4.0 cm2 is suddenly removed from a magnetic field, it is observed that a
charge of 2.0 × 10–4 C flows into the coil. If the resistance of the coil is 80 , the magnetic flux density in
Wb/m2 is
24. The potential difference between the points x and y in the circuit 2 x 6V
shown is

3

5 2V y
25. A disc of mass 10 kg and radius 1 m rolls without slipping on a rough
surface. The total kinetic energy of the rolling disc will be 2 m/s

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 JEE Main Mock Test # 6

PART 2 : CHEMISTRY
SECTION 1
This section contains 20 multiple choice questions. Each question has four choice (A), (B), (C) and
(D) out of which ONLY ONE is correct.
26. For an endothermic reaction where H represents the enthalpy of the reaction in kJ mol–1, the
minimum value for the energy of activation of forward reaction will be
(a) less than H (b) zero
(c) more than H (d) equal to H
27. How many unit cells are present in a cube shaped ideal crystal of 1.46 g of NaCl? (Molecular
weight of NaCl = 58.5)
(a) 3.75  10 21 (b) 3.75  1019
(c) 3.75  1020 (d) 3.75  1023
28. The dissociation constant for HCN at 300 K is 8.1 1010 . Calculate the degree of hydrolysis of a
0.1 N solution of NaCN
(a) 1.11 10 3 (b) 1.11 10 2
(c) 1.11 102 (d) 1.11 10 4
29. Which of the following has bond order equal to 3?
(a) CN– (b) O 2
(c) NO (d) CN+
30. The electronegativity of the following elements increases in the order
(a) C < N < Si < P (b) N < Si < C < P
(c) Si < P < C < N (d) P < Si < N < C
31. The correct order of first ionisation potentials of Ca, Rb, Cs and K is
(a) Ca > K > Rb > Cs (b) K > Rb > Cs > Ca
(c) Cs > Rb > K > Ca (d) Ca > Cs > Rb > K
32. Among TiF62  , CoF63 , Cu 2 Cl 2 and NiCl24 the colourless species are
(Atomic numbers Ti = 22, Co = 27, Cu = 29, Ni = 28)
(a) TiF62  and Cu 2 Cl 2 (b) Cu 2 Cl 2 and NiCl24
(c) TiF62  and CoF63 (d) CoF63 and NiCl24
33. What is not correct about diborane?
(a) The hybrid state of B is sp3
(b) On reaction with water it gives boric acid
(c) Four of the H-atoms lie in the plane of B-atoms and the other two H-atoms lie perpendicular
to this plane
(d) During complete methylation it gives B2(CH3)6

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34. Which of the following is the weakest acid?

OH COOH

(a) (b)

OH
COOH COOH
OH
(c) (d)
OH
35. Which is not correct with regards to Be and its compounds?
(a) BeF2 is soluble in water whereas MF2 (M = Mg2+, Ca2+, Sr2+, Ba2+ are almost insoluble
(b) Compounds of Be are largely covalent
(c) BeO and Be(OH)2 are amphoteric while other oxides are basic
(d) Be can show a coordination number of 6 in their compounds
36. Ag2S + NaCN  (P)
(P) + Zn  (Q), (Q) is a metal.
Hence P and Q are
(a) Na2 Zn (CN)4; Zn (b) Na [Ag (CN)2] ; Ag
(c) [Na2 Ag(CN)4] ; Ag (d) Na3 [Ag(CN)4] ; Ag
37. Tautomerism is not exhibited by

(a) CH = CH · OH (b) O O

(c) O (d) O

O O
38. The restricted rotation about C = C in but-2-ene is due to
(a) overlap of p orbitals
(b) overlap of one p and one sp2 hybridised orbitals
(c) overlap of two sp2 hybridised orbitals
(d) overlap of one s and one sp2 hybridised orbitals
39. For a reaction at 25º C enthalpy change (H) and entropy change (S) are  11.7  103 J mol–1 and
105 J mol–1 K–1 respectively. The reaction is
(a) spontaneous
(b) non-spontaneous
(c) neither spontaneous nor non-spontaneous
(d) cannot be predicted

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40. Which of the following carbanions is most stable?

(a) CH2 (b) CH2

NO2 NO2

(c) O2N CH2 (d) all are equally stable

41. Which has strongest nucleophilicity?

(a) CH3 (b) OH
(c) F (d) NH2
42. Identify the correct statement
(a) in sp2 hybridisation, two p-orbitals remain unused
(b) among alkyl carbanions, t-alkyl carbanion is most stable
(c) ethene is more stable than 2-butene
(d) in CH3 – CH2 – Br, the bromine atom is more reactive than in vinyl bromide
1 1
43. If H 2 (g )  O 2 (g)  H 2O(g )  57 kcal and H 2 (g )  O 2 (g )  H 2 O()  68.3 kcal ,
2 2
calculate the heat change involved in the transition, H 2O() 
 H 2O(g )
(a) + 11.3 kcal (b) – 11.3 kcal
(c) + 22.6 kcal (d) – 22.6 kcal
44. The statement that is not true about aromatic sulphonation is
(a) sulphonation is catalysed by presence of I2, Hg or HgSO4
(b) the electrophile that attacks the aromatic ring is SO 32 
(c) aromatic sulphonation shows some kinetic isotope effect
(d) sulphonation is reversible
45. The correct increasing order of reactivity in electrophilic substitution of the following compounds
is
CH3 OCH3 CHO

(I) (II) (III) (IV)

(a) III < IV < I < II (b) I < III < IV < II
(c) III < IV < II < I (d) III < II < I < IV
SECTION 2
This section contains 5 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9.
46. The relative lowering of vapour pressure of a dilute aqueous solution containing nonvolatile solute
is 0.009. The molality of the solution is
47. In the complex MCl3 · 5H2O, the coordination number of the metal is 6 with no molecule of
hydration. The volume of 0.1 M AgNO3 solution needed to precipitate the free chloride ions in
200 mL of 0.01 M solution of the complex is
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48. An aqueous solution containing 28% by weight of a liquid A (molecular weight 140) has a vapour
pressure 160 mm at 30º C. Find the vapour pressure of pure liquid A (vapour pressure of water at
30º C is 150 mm)
49. Heat evolved in the reaction, H2(g) + Cl2(g)  2HCl (g) is 182 kJ. Bond energies of H – H bond
= 430 kJ mol–1 and that of Cl – Cl bond is 242 kJ mol–1. The H – Cl bond energy is
50. Number of moles of formic acid formed during oxidation of one mole of fructose by periodic acid
is

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PART 3 : MATHEMATICS
SECTION 1
This section contains 20 multiple choice questions. Each question has four choice (A), (B), (C) and
(D) out of which ONLY ONE is correct.
1 1 0
 
51. For the matrix A = 1 2 1 , which of the following is correct?
 
 2 1 0

(a) A3  3 A 2  I  0 (b) A3  3 A2  I  0
(c) A3  2 A2  I  0 (d) A3  A2  I  0
log e 2 [sin 2  sin 4  sin 6  ..... to  ] 
52. If e is a root of equation x 2  9 x  9  0 , where 0    , then the
2
 2 
principal value of sin 1 sin   is
 3 
(a)  (b) 2
(c) –  (d) – 2
 2  8
53. The value of cos cos cos cos is equal to
5 5 5 5
1
(a) (b) 0
16
1 1
(c)  (d) 
8 16
54. If z + 2 |z + 1| + i = 0, then z is equal to
(a) 2 + i (b) 2 – i
(c) – 2 + i (d) – 2 – i
n 1
r
55.  cos2 n
is equal to
r 1
n n 1
(a) (b)
2 2
n
(c) 1 (d) none of these
2
2
56. If tan  and tan  are the roots of x  3 x  1  0, then value of tan ( + ) is
1
(a) (b) 1
2
3
(c) (d) none of these
2

57. In a triangle ABC, let C = . If r is the inradius and R is the circumradius of the triangle, then 2(r + R) is
2
equal to
(a) a + b (b) b + c
(c) c + a (d) a + b + c

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 JEE Main Mock Test # 6
n 2 n
58. If (1  x )  C0  C1 x  C2 x  .....  C n x , then the sum of the series C0  3C1  5C2  .....
 (2n  1)Cn will be
n
(a) n  2 n (b) (n + 1) 2
(c) n  2n  1 (d) 0
59. The angle of elevation of the top of an incomplete vertical pillar at a horizontal distance of 50 m from its
base is 45º. If the angle of elevation of the top of the complete pillar at the same point is to be 60º, then
the height of the incomplete pillar is to be increased by
(a) 50( 3  1) m (b) 50( 3  1) m
(c) 50 m (d) 25 2m
a ab a  2b
60. The value of a  2b a a  b is equal to
ab a  2b a
2 2
(a) 9a (a  b) (b) 9b (a  b)
2 2
(c) a (a  b) (d) b (a  b)
61. The straight lines l1 , l 2 , l 3 are parallel and lie in the same plane. A total number of m points are taken on
l1 , n points on l 2 , k points on l 3 . The maximum number of triangles formed with vertices as these
points are
m n  k m n k
(a) C3 (b) C 3  m C 3  nC 3  k C 3
m
(c) C 3  nC 3  k C 3 (d) none of these
62. Three distinct numbers are selected from first 100 natural numbers. The probability that the three
numbers are divisible by 2 and 3 is
4 4
(a) (b)
25 35
4 4
(c) (d)
55 1155
63. If P ( x ) : 2  4  6  .....  2n , n  N , then P ( m )  m ( m  1)  2
 P ( m  1)  ( m  1)( m  2)  2m  N .
So, we can conclude that P ( n )  n ( n  1)  2 for
(a) n > 1 (b) n > 2
(c) all n N (d) nothing can be said
2 2 2
64. Value of the expression C 0  2C 1  .....  (n  1)C n is

(a) ( 2n  1) ( 2 n C n ) (b) ( 2n  1) ( 2 n C n )
 n  2n  n  2n 1
(c)   1 ( C n ) (d)   1 ( C n )
2  2 
xk x k 2 x k 3
1 1 1
65. If y k y k 2 y k 3 = (x  y ) ( y  z ) (z  x )     then
x y z 
zk z k 2 z k 3
(a) k = – 3 (b) k = – 1
(c) k = 1 (d) k = 3

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a2
66. If a sin 2 x  b cos 2 x  c , b sin 2 y  a cos 2 y  d and a tan x = b tan y, then is equal to
b2
(b  c ) (d  b ) (a  d ) (c  a )
(a) (b)
(a  d ) (c  a ) (b  c ) (d  b )
(d  a ) (c  a ) (b  c ) (b  d )
(c) (d)
(b  c ) (d  b ) (a  c ) (a  d )
67. The equation sin 1 x  2 sin 1 a has a solution
1
(a) in all values of a (b) a 
2
1 1
(c) a  (d) a 
2 2
1 10 2n 102 2n 103 2n 10 2 n
68. The value of n  n C1  n C2  n C 3 + ..... + is
81 81 81 81 81n
(a) 2 (b) 0
1
(c) (d) 1
2
69. Which of the following pairs does not represent the negation of each other?
(a) p : For every real number x, x 2  x .
~ p : There exists a real number x for which x 2  x
(b) p : There exists a rational number x such that x 2  3 .
~ p : there does not exist a rational number x such that x 2  3
(c) p : All birds have wings
~ p : There exists a bird which has no wings
(d) none of these
3
70. The probability of a man hitting a target is . He tries 5 times. The probability that the target will be hit
4
at least 3 times, is

291 371
(a) (b)
364 464

471 459
(c) (d)
502 512

SECTION 2
This section contains 5 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9.
71. Set A has 3 elements and set B has 4 elements. The number of injections that can be defined from A to B
is
1 1 3
72. If in a  ABC,   , then the value of the angle C is
ac bc abc
73. An observer standing on a 300 m high tower observes two boats in the same direction their angles of
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depression are 60º and 30º respectively. The distance between boats is
74. A student is to answer 10 out of 13 questions in an examination such that he must choose atleast 4 from
the first five questions. The number of choices available to him is
75. 10 different letters of English alphabet are given. Words of 5 letters are formed from these given letters.
How many words are formed when at least one letter is repeated?

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JEE MAIN MOCK TEST # 6

ANSWERS & SOLUTIONS

1 6
1. (a) sin C  
 10
5
 
3
3  108
 v   1.8  108 ms 1
(5 / 3)
2. (b) 1 sin 2 =  sin 
  = 2 cos 

3. (b)
4. (b) As capacitor blocks D.C.
ER1
 Potential across capacitor =
R1  r
CER1
 Charge on capacitor =
R1  r
5. (d) In parallel combination, Req is lesser than the least resistance.
h
6. (c)  , K T
2mK
1
 
T
7. (c) For y = 6, x  6  6  6
 l eff  12m
F  2  2 103 12 = 0.048 N along negative (–ve) Y axis.
8. (c) It will float if weight  upthrust
4 R
4R 2t    g  R 3  1 g  t 
3 3
9. (b) V  V R2 V C2

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 20  (12) 2 V C2
v C  16 volt
1 1 1 
10. (c) R  4  9  ..... (i)
0
1 1 1 
R  4  16  ..... (ii)

20
Solving,   0
27
h h
11. (d) Use  and  
2mK mv
12. (c) Mg sin  – T –  Mg cos  = Ma ..... (i)
T + mg sin  –  mg cos  = ma ..... (ii)
Solving (i) and (ii)
T=0

13. (c) p = Area enclosed by F – t curve
 T 1 1
mu  0   F0 ·  [ Area of semi-ellipse = ab ]
 22 2
F T
u 0
4m
mgh mg (Re/ 2) 1
14. (b) U    mg Re
 h   1 3
1   1  
 Re   2
15. (a) There is no external torque.
16. (c) Work done by external agent = U f  U i
 2m  3m 3m  m 2m  m   2m  m m  3m 3m  2m 
 G       
 a a a   a a a 2 
6Gm 2  1 
 1  
a  2
17. (c)
2
18. (b)   0.5 cm
4
3P0 ·V 0 3V 0 · P0
19. (a) 
TA TB
T A T B
 U = 0
By Ist law of thermodynamics Q = W
20. (a)
6
21. (10) Current through 5 resistor =  6  2A
6  12
 Potential drop across 5 = 10 volt
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O /P 140
22. (83.3)   100 =  100 = 83.3%
I /P 0.7  240
 NBA
23. (1) Q 
R R
2  10 4  80
 B  1 Tesla
40  4  10  4
62
24. (4.8) i   0. 4A
10
V x  6  3  0.4 V y
 V y V x  4.8 volt

1  I   MR 2 
25. (30) K T  V cm2  M  cm2   I cm 


2  R   2 
= 30 J

26. (c) E fa > H

E fa
P
H
R

Progress of endothermic reaction

27. (a) In NaCl, one unit cell has 4 NaCl units, therefore mass of one unit cell
4  58.5
= gram
6.02 10 23
1.46  6.02 10 23
No. of unit cells =  3.75 10 21
4  58.5
Kw Kh
28. (b) Kh  and h 
Ka conc.

Kw 1 110 14 10 4 10 2
Hence h  ·  10
   1.1110  2
K a conc. 8.110  0.1 0.81 0.9
29. (a)
30. (c) Electronegativity decreases down the group and increases along the period. Hence the correct
order is Si < P < C < N.
31. (a) Ionisation potential increases along the period and decreases down the group
Ca > K > Rb > Cs.
0 0
32. (a) In [TiF6 ]2 , Ti 4 is 3d 4s ; no d-d transition
6 0
In [CoF6 ]3 , Co 3 is 3d 4s
 10 0
In [Cu 2Cl 2 ], Cu is 3d 4s ; no d-d transition
In [ NiCl 4 ]2 , Ni 2 is 3d 8 4s 0
2
Hence [TiF6 ] and [Cu 2 Cl 2 ] are colourless species.

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33. (d) During complete methylation it gives only B2(CH3)4. Bridged H-atoms cannot be methylated.
B 2 H 6  6H 2 O 
 2H 3 BO 3  6H 2
Boric acid
34. (a)
35. (d) Be 1s 2 2s 2 2p 0 can use only 2s and three p-orbitals in coordination showing a maximum C.N. 4
while other elements of s-block can use their d-orbitals and can show C.N. 6.
36. (b) Ag 2S  4CN  
 2 [Ag (CN ) 2 ]  S2
2{Ag (CN ) 2 }  Zn 
 2Ag  [ Zn (CN ) 4 ] 2
37. (b) Does not have labile hydrogen atom on -carbon

38. (a) CH 3  CH  CH  CH 3

-bond in a molecule gives rise to hindered rotation
39. (b) G = – 11.7 × 1000 – [298 × (– 105)]
= – 11700 + 31290
= + 19590 J mol–1
G is positive, hence non-spontaneous
40. (a) – I effect is maximum at orthoposition. So the negative charge of carbanion is dispersed to a
greater extent in the orthoisomer.

41. (a) CH3 is the strongest nucleophile whereas F– is the weakest nucleophile. Electronegativity of
carbon is less; its hold on the electrons is also less. Hence CH3 ion can donate electron pair
readily.
42. (d) In vinyl bromide CH2 = CHBr, there is double bond character in C – Br.
1
43. (a) H 2 (g )  O 2 (g ) 
 H 2O(g )  57 kcal
2
1
H 2O()  68.3 kcal   H 2 (g )  O 2 (g )
2
Adding both the equations, we get
H 2O()  68.3 kcal 
 H 2 O(g)  57 kcal
or H 2 O ( ) 
 H 2O(g )  11.3 kcal
Hence, H = + 11. 3 kcal
Conversion of liquid into gas is endothermic.
2
44. (b) The electrophile that attacks the aromatic ring in sulphonation is SO3 (neutral) and not SO3 ,
so statement B is wrong. Other 3 statements are correct.
45. (a) – CHO is a deactivating group – OCH3 is more activating then – CH3 because of + M effect in –
OCH3 as compared to hyperconjugation in – CH3.
46. (0.5) RLVP = XA = 0.009 (given)
X A1000
m  0.5
(1  X A )18
X A = mole fraction of solute
47. (40) As per the data the molecular formula of the complex is [MCl·(H2O)5]Cl2

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[MCl(H2O)5]Cl2  [MCl(H2O)5]2+ + 2Cl–

200 mL of 0.01 M solution contains Cl– ions,
= 2 × moles of complex
= 2 (200 × 10–3 × 0.01) = 4 × 10–3 mol
 Moles of AgNO3 required = moles of Cl– = 4 × 10–3 mol
4 10 3 1000
Volume of 0.1 M required = mL = 40 mL
0.1
48. (358) Pt  p 0A  A  p 0B  B
where Pt = total pressure, p 0A and p0B are the vapour pressures of A and B,  A and  B are
the mole fractions of A and B respectively.
28
Number of moles of A   0.2
140
72
Number of moles of B  4
18
Total number of moles = 4 + 0.2 = 4.2
0. 2
A   0.048
4.2
4
B   0.952
4.2
  
160  p 0A  0.048  (150  0.952)
160  142.8
p 0A   358.3  358.0 mm
0.048
49. (427) H2 (g) + Cl2 (g)  2HCl (g) ; H = – 182 kJ
H = B.ER – B.EP
– 182 = (430 + 242) – 2B. EHCl
430  242  182
B.EHCl =  427 kJ mol 1
2
50. (3) CH 2 OH
|
CO
|
CHOH
|
5 HIO
CHOH  4  3 HCOOH  2 H  CHO  CO 2
|
CHOH
|
CH 2 OH

 1 1 0 2 3 1   7 9 3
51. (b)
  2   3 
Since, A = 1 2 1 ,  A  5 6 2 and A  15 19 6 .

     
 2 1 0 3 4 1   9 12 4
Hence, A3  3 A 2  I  0

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52. (a) Roots of equation x 2  9 x  8  0 are 1 and 8.

Let y  log e 2 [sin 2   sin 4   sin 6   ..... to ]
sin 2  2
 log e 2 2
 tan 2  log e 2  log e (2 tan 
)
1  sin 
2
 e y  2 tan 

2
Given 2 tan 
 8  23
 tan 2   3
 tan   3

 
3
 2  2    2 3 
Now sin 1  sin       2  3  2 
 3  3 3
53. (d)
54. (d) We have z + 2 |z + 1| + i = 0  x + iy + 2 | x + iy + 1 | + i = 0
 x  2 ( x  1) 2  y 2  i ( y  1)  0

 x  2 x 2  y 2  2 x  1  0 ..... (i)
and y+1=0 ..... (ii)
(ii) y=–1
(i)  x 2  2( x 2  ( 1) 2  2 x  1)

 x 2  2 x 2  4 x  4  ( x  2) 2  0  x = – 2.  z = x + iy = – 2 – i.

1 n 1  2r  1 1 n 1 2r 
55. (c) Sum =  
2 r 1 
1  cos 
n  2
= ( n  1)  
2 r 1
cos
n

 2 
 Angles are in AP with common difference 
 n 
1  2 2(n  1(  (n  1)
cos    sin
1 1 2 n n  n
= (n  1) 
2 2 
sin
n
1 1 n
= (n  1)  = 1.
2 2 2
56. (c)  tan , tan  are the roots of x 2  3 x  1  0
 tan  + tan  = 3 and tan  tan  = – 1
tan   tan  3
 tan ( + ) =  .
1  tan  tan  2

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 1  B
 c  ab 
  2 c
57. (a) 2(r + R) = 2    = 2    ( sin C = 1) a c
 s 2 sin C   abc 2
 
 2 
C A

58. (b) C0  3C1  5C2  .....  (2n  1)Cn

= (C0  C1  C2  .....  Cn )  2(C1  2C2  .....  nCn )
n n(n  1) 
= 2n  2   2   .....  n 1 = 2n  2n(1  (n  1)  .....  1)
1 1.2 
= 2n  2n ( n1C0  n 1
C1  .....  n 1
Cn1 ) = 2n  2n  2 n1  (n  1)2 n .
59. (a) Here AB is an incomplete vertical pillar and AC is a
complete pillar. C
CDA = 60º ; AD = 50 m
h
and BDA = 45º
we have AB = AD = 50 m B
Let BC = h be the increased height of the pillar, then AC =
AB + BC = 50 + h
 From triangle CAD, 60º
45º A
AC 50  h D
tan 60º   50 m
AD 50
50  h
or 3
50
or h  50 ( 3  1) m .
60. (b) Operating C1  C2  C3 , we get

3a  3b a b a  2b 1 ab a  2b
3a  3b a a  b = 3(a  b) 1 a a  b = 9b 2 (a  b) .
3a  3b a  2b a 1 a  2b a
61. (b) Total number of points = m + n + k
m n  k
 Number of selections taking 3 at a time = C3
The points on the same line will not give any triangle.
m n k
 Number of triangles = C 3  m C 3  nC 3  k C 3 .
62. (d) The number should be divisible by 6.
16
 Number of favorable cases = C3 (as there are 16 numbers in first 100 natural divisible
16
C3 4
by 6);  Required Prob. =  .
100 1155
C3
63. (d) Since P (1)  2 , therefore P (n )  n (n  1)  2 is not true for n = 1
 Principle of induction is not applicable.
So, nothing can be said about the truth of the statement P (n )  n (n  1)  2 .

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64. (c) Let S  C 02  2C 12  .....  nC n21  (n  1)C n2 ..... (i)

Using C r  C n r , we write (i) and (ii), we get
2S  (n  2) [C 02  C 12  .....  C n2 ] = (n  2) ( 2n C n )
n 
 S    1 ( 2n C n ) .
2 
65. (b) We can write the given expressions as
1
x k y k z k 1  (x  y ) ( y  z ) (z  x ) ( yz  zx  xy )
xyz
1 x2 x3
Where 1  1 y 2 y3
1 z2 z3

 x k 1 y k 1z k 11 = (x  y ) ( y  z ) (z  x ) ( yz  zx  xy )
degree of 1 is 5.
 Degree of LHS = 3k + 3 + 5 = 3k + 8
Also degree of RHS = 5
 3k + 8 = 5 or k = – 1
66. (b) a sin 2 x  b cos 2 x  c
 a tan 2 x  b  c (1  tan 2 x )
 (a  c ) tan 2 x  c  b
c b
 tan 2 x 
a c
d a
Similarly tan 2 y 
b d
a 2 tan 2 y (d  a ) (a  c ) (a  d ) (c  a )
Since given that 2    .
b tan 2 x (b  d ) (c  b ) (b  c ) (d  b )
    1 1
67. (d) sin 1 x  2 sin 1 a    2 sin 1 a     sin 1 a    a
2 2 4 4 2 2
1 10 2n 10 2 2n 103 2n 10 2 n
68. (d) n
 n C1  n C2  n C 3 + ..... +
81 81 81 81 81n
1 2n 2n 2n
= [ C0  C 1 10  C 2102  2n
C 3103  .....  2n
C 2 n 10 2n ]
81n
1 2n (9) 2 n (1) 2 n 9 2n
= n (1  10)    1.
81 (9 2 ) n 9 2n
69. (d)
70. (d) Using binomial distribution, we have to find P(3) + P(4) + P(5). This probability is

3 2 4 1 5 0
5 3 1 3 1  3  1 270  405  243 918 459
C3      5C4      5C5     =   .
 4  4 4 4  4  4 45 1024 512

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71. (144)
72. (60°)
73. (346.4 m)
First part 5 4 from first and 6 from second = 5 C  8 C  5  28  140 .
74. (196)
Second part 8 4 6

5 8
5 from first and 5 from second = C5  C 5  1 56  56
Total number of ways = 140 + 56 = 196.
75. (69760) No. of words with repetition = 105  100000
No. of words without repetition = 10.9.8.7.6 = 30240
 No. of words when at least one letter is repeated = 100000 – 30240 = 69760.

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