1.

A concentration cell Pt | H 2 ( g ) | HCl (aq) || H 2 SO4 (aq) | H 2 ( g ) | P t is B,C,D MCQ

constructed using equal concetration of acids and equal number of moles
of H2 gas in both the conpartments at the same temperature. If volume of
1
H2 gas at the anodic compartment is times the volume of H2 gas at
9
cathodic compartment.
Which of the following is/are correct for the given cell (log 2 = 0.3, log 3
2.303RT
= 0.48) = 0.06V
F
Pressure of H2 gas in both the cell compartments are equal
Concentraton of H+ ion in both the cell compartments are unequal
o
Ecell = 0 for the above cell
Ecell ≠ 0 for the above cell
Sol.
2. Indicate the correct statements : A,B,C,D MCQ

Conductivity cells have cell constant values independent of the solution

filled into the cell
DC (direct current) is not used for measuring the resistance of a solution.
Kohlrausch law is valid both for strong and weak electrolytes.
The k decreases but λM and λE increase on dilution.
Sol.
3. Select the correct statements : A,C,D MCQ

pK H 2CO3 + pK HCO−
pH of NaHCO3 solution can be given by 3

2
Al 3+ ion is amphoteric
K SP values of metal nitrates are very – very high

Na + (aq ) is conjugate acid of NaOH (aq).

Sol.
4. 2.25 g of a Non volatile substance dissolved in 250 g of C6H6. This A,B,C MCQ
solution shows depression in F.P. by 0.256 K. Which of the following
is/are correct :
Given that : (Kb and Kf for C6H6 is 2.53 Kmolal-1 and 5.12 Kmolal-1, BP
of C6H6 = 353.3 K)
 Molar mass of substance is = 180
B.P. of solution is = 353.42 K
Relative lowering in vapour pressure of solvent = 0.0038
All are not correct
Sol.
5. The densities of three gases O2, SO2 and H2 are measured at 400K and 1 A,D MCQ
32 1
atm. They are 0.8 g/L, g/L and g/L respectively. Which of the
15 25
following statements is/are correct for these gases ? (Use
1
=R L atm / mol − K )
12
SO2 is showing negative deviation from ideal behaviour
O2 is more compressible than ideal gas under these conditions.
H2 is behaving ideally
Boyle’s temperature of O2 is less than 400 K.
Sol.
6. In the aqueous solution of soaps above CMC (Critical Micelle B,C MCQ
Concentration) :

The cations assoicate to form the aggregates.

The anions associate to form the clusters of colloidal dimension
The polar ends forming the clusters are directed towards water
The non polar (Hydrocarbon) ends are directed towards water
Sol.
7. Select that pair(s) in which bond angle of first member is higher than B SCQ
second one.
BrO3− , CiO3−

Asl3 , Sbl3

SbBr3 , Sbl3

NF3 , NH 3
Sol.
8. In which of the following pair(s) both the complexes show optical A,B SCQ
isomerism ?
 3−
cis − Cr ( C2O4 )2 Cl2  , mer CO ( gly )3 

Co ( en )3  Cl3 , c is − CO ( en )2 Cl2  Cl

 PtCl ( dien )  Cl ,  NiCl2 ( PPh3 )2 

Co ( NO3 )3 ( NH 3 )3  , cis −  Pt ( en )2 Cl2  Cl2

Sol.
9. Which of the following statements is(are) correct ? A,B,C,D SCQ
+
S 2O82− oxidises Ag in presence of pyridine and give red colour
compound
MnO42− disproportionates to yield MnO4− and MnO2 in presence of H+ ions.

In Cr2O72− each Cr is linked to four oxygen atoms.

Ti 2+ is coloured while Ti 4+ is colourless in aqueous solution.
Sol.
10. For chloroform and acetone or for a solution of chloroform and acetone if A,B,C,D SCQ
ps [observed (actual)] is compared with ps [Theoretical (Raoult)] then
which of the following is/are true ?
ps ( actual ) < ps ( Raoult )

Limit
X →
chloroform
0
(p o
acetone − ps actual ) =
0

Limit
X 
acetone
→0
(p o
chloroform − ps actual ) =
0

p o acetone > p o chloroform near room temperature

Sol.
11. Match the column : B SCQ
Column-I Column-II
(A) (p) Aromatic electrophilic
substitution
(B) (q) Electrophilic addition

(C) (r) Nucleophilic

substitution
(D) (s) σ complex

(t) Nucleophilic addition

(A-r,p,s), (B-q), (C-s,p), (D-p, s)
 (A-p,r,s), (B-q), (C-p,s), (D-p, s)
(A-p,r,s), (B-q), (C-p,s), (D-s, p)
None of these
Sol.
12. Match Column-I (Compounds) with their most appropriate mechanism C SCQ
(Column-II).
Column-I Column-II
(A) (p) E2

(B) (q) E1cB

(C) (r) SN2

(D) (s) Intermediate carbanion

(t) D-exchange in presence
of OD-/D2O
(A-q,s,t), (B-p), (C-r), (D-r)
(A-q,s,t), (B-q), (C-r), (D-t)
(A-q,s,t), (B-r), (C-p), (D-r)
(A-s,q,t), (B-p), (C-r), (D-s)
Sol.
13. Match the complexes listed in column-I with characteristics(s) / type of A SCQ
isomerism listed in column-II.
Column-I Column-II
(A) CoCl3 .5 NH 3 .H 2O (p) In one of the isomeric forms, the
metal satisfies its secondary
valences by only neutral
molecules
(B) Co ( NH 3 )5 BrSO4 (q) The magnetic moment of one of
the isomeric form is 3.87 B.M.
(C) CrCl3 .6 H 2O (r) Show ionisation isomerism.
(D) Cr ( NO2 )2 .6 H 2O (s) Show hydrate isomerism.
(t) Show linkage isomerism.
(A-p,s), (B-r), (C-p,q,s), (D-p,s,t)
(A-q,p,s), (B-r), (C-p,s), (D-t,p,s)
(A-s,p), (B-r), (C-p,s,q), (D-p,s,t)
 (A-p,s), (B-r), (C-q,p,s), (D-p,s,t)
Sol.
14. Match the compounds listed in column-I with characteristic (s)/type of D SCQ
reaction(s) listed to column-II
Column-I Column-II
(A) XeF2 (p) Undergoes hydrolysis with water.
(B) XeF4 (q) Acts as oxidising agent
(C) XeF6 (r) Undergoes addition reaction.
(D) XeO3 (s) Has lone pair(s) of electrons.
(t) Gives disproportionation reaction
with H2O or OH-
(A-p,q,r,s), (B-p,q,r,s,t), (C-q,p,r,s), (D-q,s,t)
(A-p,q,r,s), (B-q,p,r,s,t), (C-p,q,r,s), (D-q,s,t)
(A-q,p,r,s), (B-p,q,r,s,t), (C-p,q,r,s), (D-t,q,s)
(A-p,q,r,s), (B-p,q,r,s,t), (C-p,q,r,s), (D-q,s,t)
Sol.
15. Match Matrix B SCQ
Column-I Column-II
(A) 2+ 2+
Zn | Zn (C ) || Zn (2C ) | Zn (p) Spontaneous cell
reaction
(B) H 2 ( P ) | HCl (1N ) || H 2 SO4 (1N ) | H 2 ( P ) (q) Working cell
representation
(C) Cu | Cu 2+ ( 0.01M ) || Ag + ( 0.1M ) | Ag (r) Concentration of
cation in cathodic
compartment
increases upto
equilibrium
(D) Ag | AgCl | ( KCl , 0.1M ) || Ag + ( 0.01M ) | Ag (s) Concentration
cell
(t) Concentration of
Cl- in anodic
compartment
decreases
(A-p,q,s), (B-s,r), (C-q,p), (D-p,q,s,t)
(A-p,q,s), (B-r,s), (C-p,q), (D-p,q,s,t)
(A-p,q,s), (B-r,s), (C-p,q), (D-q,p,t,s)
(A-q,p,s), (B-r,s), (C-p,q), (D-p,q,s,t)
Sol.
16. In how many of the following reactions, one of the products is obtained 3 Integer
as a yellow precipitate ?
Ba 2+ + CrO42− → products
Hg 2+ + Co 2+ + 4 SCN − → products
Bi 3+ + C6 H 3 (OH )3 → products
Na (OH ) 2 ↓ +O2 → products
Zn 2+ + 2 H PO42− → products
NH 4+ + [ PtCl6 ] → products
2−

Sol.
17. Total number of position isomers of tetrachlorocyclobutane shows 3 Integer
geometrical isomerism.
Sol.
18. The minimum concentration of an electrolyte required to cause 8 Integer
coagulation of a sol is called its flocculation value. It is expressed in
millimoles per litre. If the flocculation value of MgSO4 for standard
As2S3 sol is 3.33. How many milligrams of MgSO4 is to be added to 20
ml standard As2S3 sol so that flocculation just starts ?
Sol.
19. In the assembly as shown below, the potential difference across the plates 6 Integer
is 4 volts. A positive particle of charge +4e is projected from the negative
plate with an initial kinetic energy of 4eV and the negative particle of
charge(-2e) is projected from the positive plate. Both the particles reach
point ‘A’ with zero kinetic energy. Find the initial energy of the negative
particle in eV.

Sol.
20. 0.5 mole of SO2 gas at 27 ℃ is expanded in reversible adiabatic condition 3 Integer
to make volume 8 times. Final temperature (in K) and work done by gas
y
(in Cal) respectively are x and y. Report your answer as . (Take ideal
x
behaviour of gas, R = 2 Cal/K mol and 21.2 = 2.3)
Sol.
21. A mixture contains 61.2% BaO, 28% CaO and 10.8% (silica) 9 Integer
 impurities. What volume in mL of 3.00 M HCl would be required to
react completely with 1 g of the mixture ?
Sol.
22. The number of dipepetides that can be made from alanine and glycine 4 Integer
are.
Sol.
23. 3 Integer

When is mixed and reacted with

Br2/KOH then many products are obtained.
Sol.
24. How many products (structural isomers) are formed by monochlorination 13 Integer
of given compounds ?

Sol.