Sec: SR_*CO-SC Date: 18-07-21

Time: 3 Hrs Max. Marks: 240

18-07-21_SR.IIT STAR CO-SC(MODEL-A&B)_Jee-ADV_WAT-51_SYLLABUS

PHYSICS: PRESENT WEEK (80%): Hertz and Lenard's observations, Atomic
Physics
PREVIOUS WEEK (20%): Moderen Physics: Debroglie's wavelength,
Photo Electric Effect

CHEMISTRY: PRESENT WEEK (80%): bonding in metal carbonyls, structures of

mononuclear & dinuclear metal carbonyles, CFT & stability of
complexes, isomerism in complexes
PREVIOUS WEEK (20%): CO-Ordination Compounds :
Introduction, Definition of important terms related to co-ordination
compound, types of ligands, IUPAC rules, Nomenclature, Werner
theroy and Sidgwick theory, VBT

MATHEMATICS: PRESENT WEEK (80%): Probability: Classical definition of

probability, types of events, Addition & Multiplication theorem,
Problems based on P & C
` PREVIOUSWEEK(20%): Number of functions, division of different
things ( identical / distinct into different groups )
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
Time: 3:00 Hour’s IMPORTANT INSTRUCTIONS Max Marks: 240
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 9 – 16) Questions with Multiple Option Correct 4 -2 8 32
Questions with Comprehension Type
Sec – II(Q.N : 17 – 20) 4 -2 4 16
(2 Comprehension -2+2=4Q)
Total 20 80

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 28) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 29 – 36) Questions with Multiple Option Correct 4 -2 8 32
Questions with Comprehension Type
Sec – II(Q.N : 37 – 40) 4 -2 4 16
(2 Comprehension -2+2=4Q)
Total 20 80

MATHS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 48) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 49 – 56) Questions with Multiple Option Correct 4 -2 8 32
Questions with Comprehension Type
Sec – II(Q.N : 57 – 60) 4 -2 4 16
(2 Comprehension -2+2=4Q)
Total 20 80

Sr.IIT_*CO SC Page 2
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
PHYSICS Max Marks : 80
SECTION – I
(INTEGER ANSWER TYPE )
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
1. A hydrogen like ion has the wavelength difference between the first lines of Balmer
and Lyman series equal to 59.3 nm. Identify the atomic number of ion.

2. A hydrogen atom in n = 6 makes two successive transitions & reaches the ground
state. In the first transition a photon of 1.13eV is emitted. Find the energy of the
photon emitted in the second transition in eV(say x) and value of n for the
intermediate state.

Now report the value of x – n rounded to nearest integer.

3. Find the quantum number n corresponding to the excited state of He+ ion if on
transition to the ground state that ion emits two photons in succession with wave
lengths 108.5 and 30.4 nm.

4. Suppose, in certain conditions only those transitions are allowed to hydrogen atoms in
which the principal quantum number n changes by 2.

(a) find the smallest wavelength emitted by hydrogen.

(b) find the wavelength emitted by hydrogen in the visible range (380 nm to 780 nm)

Now report the ratio of answer to the b part to that of the a part rounded off to nearest
integer.

5. A particle of mass m moves along a circular orbit in a Centrosymmetrical potential

kr 2
field U(r)  . Using the Bohr’s quantization condition, find the permissible energy
2

k
levels of that particle If your answer is an report the value of a
m

6. Whenever a photon is emitted by hydrogen in Balmer series, it is followed by another

photon in Lyman series. What wavelength does latter photon correspond to?

Find your answer (say x) in Angstrom units and report the value of x / 200 rounded off
to nearest integer.

Sr.IIT_*CO SC Page 3
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
7. Monochromatic radiation of wavelength  is incident on hydrogen sample in ground
state. H – atoms absorb a fraction of light and subsequently emit radiation of six
different wavelengths. Find the value of  in nm.

If your answer is x, report the value of x/100 rounded to nearest integer.

8. A hydrogen like atom (atomic number Z) is in a higher excited state of quantum

number n. This excited atom can make a transition to the first excited state by
successively emitting two photons of energies 10.20 eV and 17.00 eV respectively.

Alternatively, the atom from the same excited state can make a transition to the second
excited sate by successively emitting two photons of energies 4.25 eV and 5.95 eV
respectively. Determine the value of n and Z. (Ionization energy of hydrogen atom

= 13.6eV)

Report the value of n/z rounded to nearest integer

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
9. An electron with kinetic energy E eV collides with a hydrogen atom in the ground
state. The collision is definitely observed to be elastic for:

A) 0 < E <  B) 0 < E < 10.2EV

C) 0 < E < 13.6EV D) 0 < E < 3.4EV

10. A sample of hydrogen atoms is in the 4th excited state, then:

A) the maximum number of emitted wavelengths will be 10

B) the maximum number of emitted wavelengths will be 6

C) it can emit three wavelengths in ultraviolet region

D) if an infrared photon is generated, by an atom then a visible photon may follow this
infrared photon from the same atom.

Sr.IIT_*CO SC Page 4
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
11. The figure above shows an energy level diagram for the hydrogen atom. Several
transitions are marked as I, II, III etc. The diagram is only indicative and not to scale.

III

II

A) The transition in which a Balmer series photon absorbed is VI.

B) The wavelength of the radiation involved in transition II is 486 nm.

C) IV transition will occur when a hydrogen atom is irradiated with radiaiton of

wavelength 103nm.

D) IV tansition will emit the logest wavelentgh line in the visible portion of the
hydorgen spectrum.

12. A particular hydrogen like atom has its ground state binding energy 122. 4eV. It is in
ground state. Then

A) Its atomic number is 3

B) An electron of 90 eV can excite it

C) An electron of kinetic energy nearly 91.8eV can be brough to almost rest by this
atom

D) An electron of kinetic energy 2.6eV may emerge from the atom when electron of
kinetic energy 125 eV collides with this atom

13. If radiation of all wavelengths from ultraviolet to infrared are passed through
hydrogen gas at room temperature, absorption lines will be observed in the

A) Lyman series B) Balmer series

C) Both (A) and (B) D) Neither (A) nor (B)

Sr.IIT_*CO SC Page 5
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
14. Choose the correct statement(s) for hydrogen and deuterium atoms (cosidering the

motion of nucleus)

A) The radius of first Bohr orbit of deuterium is less than that of hydrogen

B) The speed of electron in first Bohr orbit of deuterium is more than that of hydrogen

C) The wavelength of first Balmer line of deutrium is more than that of hydrogen

D) The angular momentum of electron in the first Bohr orbit of deuterium is more than

that of hydrogen

15. The electron in a hydrogen atom jumps back from an excited state to ground state, by
16
emitting a photon of wavelength  0  , where R is Rydberg’s constant. In place of
15R
emitting one photon, the electron could come back to ground state by

1 1 1 15R
A) Emitting 3 photons of wavelengths 1 ,  2 and  3 such that   
1  2  3 16

1 1 15R
B) Emitting 2 photons of wavelength 1 and  2 such that  
1  2 16

16
C) Emitting 2 photons of wavelength 1 and  2 such that 1   2 
15R

16
D) Emitting 3 photons of wavelength 1 ,  2 and  3 such that 1   2   3 
15R

16. Which of the following statements about hydrogen spectrum is /are correct?

A) All the lines of Lyman series lie in ultraviolet region

B) All the lines of Balmer series lie in visible region

C) All the lines of Paschen series lie in infrared region

D) none of these

Sr.IIT_*CO SC Page 6
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 17 to 18:
Consider a classic experiment on the photoelectric effect in which a monochromatic
plane wave of light falls on a metal plate of area 66.3 cm2 at an angle 30° as shown in
the figure. Electric field in the light wave varies according to equation E = E0cos
15
(t  0 ) , where amplitude is E0 = 15 V/m, angular frequency is  = 9.5 × 10 rad/s
and 0 is some initial phase angle. For a plane wave, the density u of electromagnetic
1
energy is given by the equation u  0 E 02 . Dependence of photoelectric current I on
2
voltage V applied between the electrodes is shown by a graph.
Speed of light is c = 3.0 × 108 m/s, Planck’s constant is h = 6.63 × 10–34 Js, electrical
permittivity of free space is 0  8.85  10–12 F / m and charge on an electron is e = – 1.6 ×
10–19C.

17. What is quantum yield in this experiment?

A) 0.019
B) 0.038
C) Unity when saturation current flows otherwise less than unity.
D) It has no unique value as it depends on photoelectric current registered.
18. If amplitude of electric field in the incident light is made 25V/m, how much will the
saturation current become?
A) 8.00 A B) 10.00 A
C) 16.6 A D) None of these

Sr.IIT_*CO SC Page 7
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
Paragraph for Question Nos. 19 to 20:
Two thin partially silvered glass plates are rigidly joined at an angle 45°. The structure
is placed in gravity free region and a short light pulse is made to incident on the
structure as shown. Coefficient of reflection of light from each plate is  for all angles
of incidence.

19. Find the direction of total force of light pressure on the plate

1  (1  )3 
A) tan –1   from the x – axis towards the negative y – axis.
 (1  ) 

1  (1  )3 
B) tan –1   from the x – axis towards the negative y – axis.
 (1   ) 
2

 (1  )3 
C) tan –1  2 
from the x – axis towards the negative y – axis.
 (1 –    ) 

 1  (1  )3 
D) tan –1  2 
from the x – axis towards the negative y – axis.
 (1 –    ) 

20. Choose the correct statement for the shown setup

A) After processing from the system, no light is observed moving along positive x axis

B) After processing from the system, no light is observed moving along positive y axis

C) After processing from the system, no light is observed moving along negative x axis

D) None of the above

Sr.IIT_*CO SC Page 8
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
CHEMISTRY Max Marks : 80
SECTION – I
(INTEGER ANSWER TYPE )
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
21. [Pt (NH3)2(Py)2 Cl2]+2 ion can theoretically exist in how many geometrical isomeric
forms

22. [Ti(H2O)6]3+ absorbs energy equal to wavelength 498 nm. On this basis crystal field
splitting energy comes out to be a  10-19 J. What is the value of a? Give answer as
closest integer

23. The EAN of nickel in K2[Ni(CN)4] is xy. what is the value of ((x*y) – (x+y)):

24. What is the oxidation number of Fe in the brown ring complex used in the
identification/confirmation of Nitrate ion?

25. Consider the following complex compounds.

 Pt  NH 3 2  SCN 2  Co  NH 3 3  NO2 3 
i)  (ii) 

 Pt  en  Cl2  Cr  en  2 Br2 
iii)  (iv) 
3
 Rh  en 3 
(vi) 
CoCl2 Br2 
2

(v) 
Then calculate sum of total number of geometrical isomers in all above complex
compounds. – Note – if a compound does not show geometrical isomerism its count is
to be taken as 0.

26. Total number of complexes among the following which are optically active?
3
Cr  Ox 3  cis   Pt  Cl2  en  
(i)  (ii)
 3
cis   Rh  Cl2  NH 3 4   Ru  dipy 3 
(iii) (iv) 
cis  Co  NO2 3  dien   Trans  Co  NO2 3  dien  
( v) (vi)
cis  Co  NO2 3  NH 3 3 
(vii)

Sr.IIT_*CO SC Page 9
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
27. The total number of all stereoisomer’s possible for [M(AA)a2bc] is X and the total
number of all stereoisomer’s possible for [M(AB)2ab] is Y. Given – AA is a
symmetrical Bidentate ligand like en – AB is a unsymmetrical Bidentate Ligand like
Glycine – a, b, c are different mono dentate ligands. Assume none of the ligands have
chiral centre in their molecules themselves. Find y-x.
3  
Co  ox 3  , Cr Cl2  en 2  CoBrCl  en 2 
28. Among the 6 given complexes, 

 Pt  NH 3 2 Cl2  , Co  NH 3 3 Cl3  , Cr  NH 3 4 Cl2 

The no. of complexes which can exhibit both geometrical and optical isomerism is

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
29. The correct statement (s) regarding the binary transition metal carbonyl compounds is
(are) (Atomic numbers :

Fe = 26, Ni = 28)

A) Total number of valence shell electrons at metal centre in Fe(CO)5 or Ni(CO)4 is 16

B) These are predominantly low spin in nature

C) Metal-carbon bond strengthens when the oxidation state of the metal is lowered

D) The carbonyl C—O bond is stronger when the oxidation state of the metal is
increased

30. Which of the following observations/statements is/are incorrect ?

A) Anhydrous CuSO4 becomes blue in aqueous medium due to the complex formation

B) Ni(CN)2 dissolves in KCN giving an orange-red solution

C) Fe(OH)3 can be precipitated by adding NH4OH to K3[Fe(CN)6]

D) None of the above

Sr.IIT_*CO SC Page 10
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
31. Which of the following statements is/are correct?

A) Greater the stability/formation constant of a complex ion, greater is its stability

B) Greater the charge on the central metal ion, greater is the stability of the complex

C) Greater the basic character of the ligand, the greater is the stability of the complex

D) Presence of Chelation and/or Synergic Bonding increases the stability of the

complex

32. Match List I with List II and Select the correct answer using the codes given below the
lists:

List 1 List 2

Complex Ions Magnetic Moment µm (Bohr Magnetons)

a. [Fe(CN)6]-4 1. 1.73

b. [Ti(H2O)6]3+ 2. 5.93

c. [Cr(H2O)6]3+ 3. 0.00

d. Ni(H2O)6]2+ 4. 2.83

e. [FeF6]–3 5. 3.88

Codes :

a b c d e

A) 1 2 3 4 5

B) 3 1 5 4 2

C) 2 3 4 5 1

D) 4 5 1 2 3

Sr.IIT_*CO SC Page 11
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
33. The correct option(s) regarding the complex [Co(en)(NH3)3(H2O)]3+ (en=

H2NCH2CH2NH2 ) is (are)

A) It has two geometrical isomers

B) It will have three geometrical isomers, if bidentate ‘en’ is replaced by two cyanide

ligands

C) It is paramagnetic

D) It absorbs light at longer wavelength as compared to [Co(en)(NH3)4] 3+

34. Choose incorrect statements

A) CFT does not account for the possible orbital overlap through either or both
together

B) The correct order of octahedral field splitting for ligands in the lower oxidation
sates of transition metal ions is
4
C)  t   0
9
D) If the electrons remain paired in the lower orbitals for octahedral Field
Split.
35. Atomic numbers of Cr and Fe are 24 and 26 respectively, which of the following is
diamagnetic ?

A) Cr(CO)6 B) Fe(CO)5 C) Fe(CN)64– D) Cr(NH3)63+

36. Addition of excess aqueous ammonia to a pink coloured aqueous solution of

MCl2.6H2O( X ) and NH4Cl gives an octahedral complex Y in the presence of air. In
aqueous solution, complex Y behaves as 1 : 3 electrolyte. The reaction of X with
excess HCl at room temperature results in the formation of a blue coloured complex Z.
The calculated spin only magnetic moment of X and Z is 3.87 B.M., where as it is zero
for complex Y.

Sr.IIT_*CO SC Page 12
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
Among the following options, which statement(s) is/are correct?

A) The hybridization of the central metal ion in Y is d2sp3

B) Addition of silver nitrate to Y given only two equivalents of silver chloride

C) When X and Y are in equilibrium at 0°C, the colour of the solution is pink

D) Z is a tetrahedral complex

SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 37 to 38:
Coordination compounds play a vital role in our lives. The importance of these
compounds can be realised from the fact that would not have been possible without the
existence of chlorophyll in plants and heamoglobin in the blood of the animals. The
field of such compounds has expanded very fast in recent years and coordination
compounds are playing important role in analytical chemistry, polymerisation
reactions, metallurgy and refining of metals, organic synthesis, electroplating,
biochemistry water purification, textile dyeing and bacteriology.

37. Which of the following statements is/are correct ?

A) The anti– pernicious anaemia factor, is a coordination compound of cobalt.

B) Chlorophyll is a Magnesium complex.

C) Wilkinson’s Catalyst is a Rhodium complex

D) Lead poisoning is treated using the chelating ligands D–penicillamine and

desferrioxime B via the formation of coordination compounds.

Sr.IIT_*CO SC Page 13
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
38. Which of the following statements is/are correct ?

A) Silver Thio Sulphate Complex finds use in photography

B) Cis-Platin – a complex of platinum finds use in chemotherapy as it inhibits the

growth of tumours.

C) Hardness of Water can be removed by using EDTA to form stable complexes with
Ca+2 and Mg+2 ions which cause hardness.

D) Cyanide complexes of Au, Ag and Carbonyl Complex of Ni find use in metallurgy.

Paragraph for Question Nos. 39 to 40:

Reaction of hydrated cadmium ion with different ligands is represented as follows:
2
Cd  H 2O 4   CH 3 NH 2  complex X+H 2O
I) 
2
Cd  H 2O 4   en  complex Y +H 2O
II) 
2
Cd  H 2O 4   trien  complex Z +H 2O
III)  .
All the reactions are not balanced - X , Y & Z are complexes which show similar
conductance values with small variations for a 1 molar solution as the original
complex taken – same number of overall ions are produced in solution if same anion is
present in the ionization sphere.

39. Which of the following statements is correct about complex Z -

A) It has a total of 2- (5 member) rings

B) It has a total of 3 – (5 member) Rings

C) It has 2 – (8 member) rings

D) It has a 11 member ring

2
40. In the given complexes – X, Y, Z coordination number of Cd ion is not -

A) 4,6,4 B) 2,4,6 C) 4,4,4 D) 6,6,6

Sr.IIT_*CO SC Page 14
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
MATHEMATICS Max Marks : 80
SECTION – I
(INTEGER ANSWER TYPE )
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
41. 10 identical balls are to be distributed in 5 different boxes kept in a row and labeled A,
B, C, D and E. If the number of ways in which the balls can be distributed in the
boxes, such that no two adjacent boxes remain empty is k, then find the remainder
when k is divided by 10.

42. Sixteen players s1 ,s 2 ,.....,s16 play in a tournament. They are divided into eight pairs at
random. From each pair a winner is decided on the basis of a game played between the
two players of the pair. Assume that all the players are of equal strength. Find the
greatest integer less than or equal to reciprocal of the probability that “exactly one of
the two players s1 and s 2 is among the eight winners”.

43. Three numbers are chosen at random without replacement from set of first 10 natural
numbers. If the probability that the minimum of the chosen numbers is 3 or the
a
maximum of the chosen numbers is 7 is , where a and b are co-prime natural
b
numbers, then number of ciphers at the end in (b-a)! is

44. There are n different gift coupons, each of which can be placed in N (N > n) different
envelopes, with the same probability 1/N. Consider following:
P1: The probability that there will be one gift coupon in each of n perticular envelopes
out of N given envelopes.
P2: The probability that there will be one gift coupon in each of n arbitrary envelopes
out N given envelopes.
Given that each envelope can have any number of coupons.
Find the number of correct statements from the following :
n! N!
(i) P1  P2 (ii) P1  (iii) P2 
Nn N n  N  n !

n! N!
(iv) P2  (v) P1 
N n  N  n ! Nn

Sr.IIT_*CO SC Page 15
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
45. A determinant is chosen at random from the set of all determinants of order 2 with
elements 0 or 1 only. The probability that the determinant chosen has non-negative
a
value is , where a and b are co-prime natural numbers, then find the number of
b
positive integral factors of a  b .

46. 5 different marbles are placed in 5 different boxes randomly. Given that each box can
hold any number of marbles. If p is the probability that exactly two boxes remain
1
empty, then find the value of   , where [.] represents GIF.
p

47. m red socks and n blue socks (m > n) in a cupboard are well mixed up, where
m  n  101 . Let two socks are taken out at random and the probability that they have
1
the same colour is . If the largest value of m is k, then find the remainder obtained,
2
when k is divided by 8.

48. Integers a, b, c and d not necessarily distinct, are chosen independently and at random
from the set S  1,2,3,.......2006,2007,2008 . If the probability that ad  bc is even

p
(zero included) is , where p and q are relatively prime, then find the sum of digits of
q

p  q .
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
49. The number of ways in which 8 non-identical apples can be distributed among 3 boys,
such that every boy should get atleast 1 apple and atmost 4 apples is (K. 7 P3 ), then
sum of all prime divisors of K is greater than or equal to
A) 5 B) 11 C) 13 D) 17

Sr.IIT_*CO SC Page 16
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
50. The number of ordered triplets (p, q, r), where 1  p,q,r  10 , such that ( 2p  3q  5r ) is
a multiple of 4, is k, then k is a factor of  where p,q,r  N 

A) 605 B) 1503 C) 3610 D) 2010

51. Let mn distinct coins have been distributed into m different purses, n coins into each
purse. If p is probability that two specified coins will be found in the same purse, then

n 1 n 1 n 1 n 1
A) p  B) p  C) p  D) p 
mn  1 mn  1 mn  1 mn  1

52. An unbiased dice with faces numbered 1, 2, 3, 4, 5 and 6 is thrown ‘n’ times and the
list of ‘n’ numbers showing up is noted. If the probability that among the numbers 1,
20
2, 3, 4, 5 and 6 only three numbers appear in the list is f  n  , then
6n

A) f(4) = 36 B) f(4) = 72 C) f(5) = 75 D) f(5) = 150

53. Consider all functions f : 1, 2,3, 4 

 1, 2,3, 4 which are one-one, onto and satisfy

the following property: “If f  k  is odd, then f  k  1 is even, k  1,2,3 ”. If n is the

number of such functions, then n is divisible by

A) 2 B) 3 C) 4 D) 5

m
54. Suppose that there are 5 red points and 4 blue points on a circle. If (where m and n
n
are relatively prime) be the probability that a convex polygon whose vertices are
among the 9 points has at least one blue vertex, then  n  m  is less than or equal to

A) 5 B) 50 C) 100 D) 200

55. A is a set containing n distinct elements. A non-zero subset P of A is chosen at

random. The set A is reconstructed by replacing the elements of P. A non-zero subset
Q of A is again chosen at random. If f(n) is the probability that P and Q have no
common elements, then

2 180 4 360
A) f (4)  B) f (5)  C) f (4)  D) f (5) 
9 961 9 961
Sr.IIT_*CO SC Page 17
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-51_Q’P
56. A coin is tossed (m + n) times, where (m > n). If f(m, n) be the probability of getting “
atleast m consecutive heads”, then

1 3 7 1
A) f (10,6)  B) f (10,4)  C) f (9,5)  D) f (9,6) 
256 1024 1024 128

SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 57 to 58:
Suppose E1 , E 2 , E 3 be three mutually exclusive events such that P  E i   pi ,
where 0<p i <1 for i  1,2,3
1 1 1
57. If p1  1  p  ,p 2  1  2p  and p3   2  3p  , then which of the following
2 3 5
intervals is contained in the set of values of p :
 1   1 2  1 7   2 1
A)   ,0  B)   ,  C)   ,  D)   ,  
 2   3 3  2 23   5 3
58. If p1 , p 2 , p3 are the roots of equation 27x 3  27x 2  ax  1  0 , then value of a is
A) 9 B) 6 C) 3 D) 12
Paragraph for Question Nos. 59 to 60:
Box 1 contains three cards bearing numbers 1, 2, 3; box 2 contains five cards bearing
numbers 1, 2, 3, 4, 5 and box 3 contains seven cards bearing numbers 1, 2, 3, 4, 5, 6, 7.
A card is drawn from each of the boxes. Let xi be the number on the card drawn from
the ith box, i = 1,2,3.
59. The probability that x1  x 2  x 3 is odd, is
29 53 57 1
A) B) C) D)
105 105 105 2
k
60. The probability that x1 , x 2 , x 3 are in an arithmetic progression is , then sum of
105
digits of ‘k’ is divisible by
A) 2 B) 3 C) 5 D) 11

Sr.IIT_*CO SC Page 18
Sec: SR.IIT_*CO-SC WAT-51 Date: 18-07-21
Time: 3HRS 2015_P2 Max. Marks: 244
KEY SHEET
PHYSICS
1 3 2 9 3 5 4 5 5 1
6 6 7 1 8 2 9 BD 10 AD
11 ABD 12 ACD 13 A 14 AC 15 AB
16 AC 17 B 18 C 19 D 20 D

CHEMISTRY
21 5 22 4 23 5 24 1 25 6

26 2 27 5 28 2 29 BCD 30 BCD

31 ABCD 32 B 33 ABD 34 BD 35 ABC

36 ABD 37 ABC 38 ABCD 39 BCD 40 ABD

MATHEMATICS
41 1 42 1 43 6 44 2 45 2

46 2 47 7 48 4 49 ABC 50 ABD

51 AC 52 AD 53 ABC 54 BCD 55 AB

56 ABCD 57 D 58 A 59 B 60 A
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
SOLUTIONS
PHYSICS
1. According to the given question we have to find that in hydrogen – like ion has the wavelength
difference between the first lines on Balmer and Lymen series equal to 59.3nm (RH = 109678cm–1)
so, let us solve this problem step by step:
Wavelength of 1st line in Balmer series,
1 1 1 5
 Z2 R H  2  2   R H Z2
B  2 3  36
36
B 
Or 5R H Z2
Wavelength of 1st line in Lyman series is,
1 1 1 
 Z2 R H  2  2 
L 1 2 
4
Or  L 
3  R H Z2
36 4 1  36 4 
Difference  B   L = 593 × 10–7 =   
2
5R H Z 3R H Z 2
R H Z2  5 3 
88
Z2  = 9.0
593 10 109678 15
–7

2. Given: n = 6 to n = 1.
Let after first transition hydrogen atom reaches nth state.
Energy released in first transition = 1.13eV. E6 -0.377 N =6
Now we have to energy released in second transition. 1.13ev
En = –13.6 [1.13 + (–0.377)] n
En = –12.1eV
-13.6eV
Hence 12.1eV is released in second transition.
Now, we have to find intermediate state i.e. n. E1 n=1
 Energy of nth state is [–13.6 – (12.1)] = –1.5eV.
–13.6 2
Now we know, En = Z
n2
En = –1.5eV (here)
Z=1
 –1.5 = –13.6
n2
n2  q
n=3

3. Suppose excited state of He+ is n2. The electrons falls from n1 to n1 and then n1 to 1 energy level to
emit two successive photons.
1 1 1 
  R H  Z2  2  2 
2  1 n1 

SR.IIT_CO-SC Page 2
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
1 1 1 
Or  109678  4  2  2 
30.4 10 –7
 1 n1 
 n1 = 2
Now for 1 : n1 = 2 and n2 = n
1 1 1
Or  109678  4  2  2 
108.5  10 –7
 2 n2 
 n= 5

4. Correct option is
(a) 103 nm (b) 487 nm
(a) n1 = 1, n2 = 3
1 1  8 hc
E  13.6     13.6  
1 9  9 
13.6  8 4.14 10 –15  3 108
Or 
9 
4.14 10 –7  3
  103nm
13.6  8
(b) As n changes by 2, we may consider n = 2 to n = 4 then E = 13.6
1 1  16  4
   =13.6× =2.55eV
 4 16  64
1242 1242
And 2.55 = or    487nm
 2.55

5. We have the following equation (we ignore reduced mass effects)

mv 2
 kr
r
mvrn
so mv  m kr
n
And r
mk

And v  n mk / m
The energy levels are
1 1
En = mv 2  kr 2
2 2
1 n mk 1 n
  k
2 m 2 mk
k
= n
m

6. Correction option 122nm

SR.IIT_CO-SC Page 3
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
1 1 1 
Wavelength of photon in Lyman series of H – atom  R   2 
 1 n 
As another photon is emitted after a photon being emitted in Balmer series, this means a transition
takes place from n = 2 to n = 1. \
1 1 1 
  1.097  10 –2   2     122nm
 1 2 
n(n  1)
7.  10
2
 n=5
1  1
 R 1  2 
  5 
1  25  1 
 R
  25 
25
 cm
24 109677
   95nm
8. As we know,
 1 1 
E  13.6Z2   2  2 
2 n 
For the transition from excited state n to first excited state i.e. n1 = 2,
 1 1 
(10.20 + 17.00) eV = 13.6 Z2 ×  2  2  ……..equation (1)
2 n 
For the transition from excited state n to second excited state i.e. n1 = 3, (4.24 + 5.95) eV
1 1 
= 13.6Z2 ×  2  2  …….equation (2)
3 n 
On dividing equation 1 and 2,
n2  4
1.18 =
n2  9
0.18 n2 = 6.6
n2 = 36
n=6
Putting n = 6 in equation 1 we get Z = 3
9. Any fraction of incident electron energy can be absorbed by the atom hence minimum energy
required for excitation is 10.2 eV hence option (B) and (D) are correct.
10. The hydrogen atom is in n = 5 state.
Thus maximum number of possible photons = 5 C 2 = 10.
To emit photon in ultra violet region, it must jump to n = 1,
Because only Lyman series lies in UV region. Once it jumps to n = 1 photon, it reaches to its ground
state and no more photons can be emitted. So only one photon in u.v. range can be emitted. If H –
atom emits a photon and then another photon of Balmer series, option D will be correct.
11. For Balmer series,
n1 = 2, n2 = 3, 4, ……
(lower) (higher)

SR.IIT_CO-SC Page 4
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
In transition (VI), photon of Balmer series is absorbed.
In transition II
E 2  –3.4eV, E 4  0.85eV
E  2.55eV
hc hc
E  
 E
  = 486 nm

Wavelength of radiation = 103 nm = 1030 A
12400
E  
1030 A
 E  12.0eV

12. Binding energy of hydrogen like atom is given as

Z2
E  –13.6  –122.4eV
n2
For n = 1 we get Z = 3 so option (A) is correct.
Excitation energy of this hydrogen like atom for excitation from
n = 1 to n = 2 is given as
E12  10.2Z2  10.2  9  91.8eV
Thus option (C) is correct.
When an electron of 125eV collides with this atom, 122.4 eV emery is absorbed by the atom for
ionization of electron and remaining energy 2.6eV will get converged to kinetic energy of the ejected
electron hence option (D) is correct.

13. Hydrogen atoms at room temperature are all in ground state so these can absorb radiations only of
Lyman series as electrons can excite from n = 1 to higher energy levels so in absorption spectrum
only Lyman series is observed.
14. As discussed in the basic theory the affect of mass of nucleus is accounted by considering the
reduced mass of electron in the orbital motion. So considering the effect of reduced mass in the
expressions of radius and energy we can state that option (A) and (C) are correct.
15. Using the Rydberg’s formula for the given transition.
1 1 1 
R 2  2
0 l n 
Solving we get n = 4. Thus electron can come to ground state by emitting two or three photons such
that the sum of energies of each transition remain same so we can use
hc hc hc
 
 0 1  2
16. It is already been studied in spectral series of hydrogen atom that some of the lines of Balmer series
are also lying outside the visible region hence options (A) and (C) are correct.

SR.IIT_CO-SC Page 5
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
17. Saturation current = 6A  is
is = nee,   30
E = E0 cos (t  )
1 1
u  0 E 2rms  2  0 E 02
2 2
1
I  c  0 E 02 c
2
I S sin 
np   2
hw
n i h
Now   e  s 
n p e 2IS sin 
is h 2
   0.038(b)
e 2S sin  0 E 02  c
is  saturation current
u  energy density
I  Intensity
ne  no of elctrons /sec.
np  no of photons / sec.
2
 E'
18. Intensity  E  i  is   
2 '
s
E
2
 25 
= 6A     16.67A (c)
 15 

20.

Initial Poynting vector : Iiˆ

Final Poynting vector :  2 [1  ]    ˆi  (1  ) 2  (1  ) 2  ˆi  I

Initial Final: (1    2 )iˆ  (1  (1  )3 ˆi  I

 
 1  (1  )3 
 direction of force = tan –1  2 
 (1     ) 

SR.IIT_CO-SC Page 6
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
CHEMISTRY
21. KEY: 5
22. KEY: 4
hc 6.626  1034  3  108
E   3.99  1019 J
HINT:  498  109
23. Sol - 5 EAN of Ni in K2 [Ni(CN)4]
EAN of Ni = 28–2 + 8 = 26 + 8 = 34 ; Hence x = 3 and y = 4 .. (12 – 7 = 5)
24.. state due to configuration , NO exists as NO+ here.
25. 6
Complexes No. of geometrical isomers
 Pt  NH 3 2  SCN 2 
(i) 2
Co  NO2 3  NH 3 3 
(ii) 2
 Pt  en  Cl2 
(iii) 0

Cr  en  2 Br2 
(iv) 2
3
 Rh  en 3 
(v) 0
CoCl2 Br2 
2

(vi) 0
Hence, sum of total number of geometrical isomers = 6
26. 2
3
Cr  ox 3  :
(i)  optically active.
cis   Pt  Cl2  en   :
(ii) optically inactive
cis   Rh  Cl2  NH 3 4  :
(iii) optically inactive
3
 Ru  dipy 3  :
(iv)  optically active
cis  Co  NO2 3  dien   :
(v) optically inactive
 Co  NO2 3  dien   :
(vi)Trans  optically inactive
cis  Co  NO2 3  NH 3 3  :
(vii) optically inactive
 Total number of optically active complexes = 2
27. 5 – y = 11 ; x = 6; - Conceptual
28. Conceptual
29. BCD; Slightly modified 2018 JEE advanced question;
If metal can donate electrons more effectively – Metal Carbon bond gets stronger with more double
bond character and consequently – the Carbon Oxygen bond gets weaker with more electron density
in the ABMO.
Metals donation happens more effectively when –
central metal atom/ion has more d electrons;
lesser number of CO groups are sharing the back/synergic bonding;
if metal is more willing to donate its electron density via synergic bonding which is better when the
Electro negativity of the metal is lower in lower oxidation states.

SR.IIT_CO-SC Page 7
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
30. BCD;
Anhydrous CuSO4 become blue in aqueous medium due to the complex formation.
31. [ABCD] Factual
32. [B]
(a)[Fe(CN)6]–4 Fe2+ = 3d6 = n = 0
(b) [Ti (H2O)6]3+ Ti3+ = 3d1 n = 1
(c) [Cr (H2O)6 ]3+ Cr3+ = 3d3 n = 3
(d) [Ni (H2O)6]2+ Ni2+ = 3d8 n = 2
(e) [Fe F6]3– Fe3+ = n = 5
magnetic moment µ = n (n  2) B.M.
n = number of unpaired e–
33. ABD – JEE Advanced 2018 Question
34. BD - Conceptual
35. [A,B,C]
(i) Cr(CO)6 , Cr = (0) oxidation state CO-strong ligand . so, pairing occurs

3d54s1 =
Diamagnetic
(ii) Fe(Co)5 , Fe = (0) oxidation state
3d6 4s2

Diamagnetic

(iii) [Fe(CN)6]4– Fe2+ = 3d6 4sº strong ligand pairing

Diamagnetic

(iv) [Cr(NH3)6]3+ Cr3+ = 3d3 strong ligand pairing

Paramagnetic

36. [ABD]
[Co(H2O)6]2+ + 4HCl  [CoCl4]2–
[Co(H2O)6]2+ octahedral light pink colour [CoCl4]2– Tetrahedral deep blue colour
The above reaction is actually in equilibrium with the equilibrium shifting according to temperature
and Enthalpy change of the reaction.
Previous JEE Advanced 2017 Question – refer NCERT Class 11 Chemical Equilibrium – Lechatliers
Principle – Temperature Dependence for more detailed information.
37. [ABC] – REFER NCERT
38. ABCD – REFER NCERT
39. Trien is a tetra dentate ligand which forms 3 – 5 member rings, 2 – 8 member rings and 1 large 11
member ring.
Example figure of a trien complex with pt+2 is shown below to count rings easily - opposite
diagonal ends result in 8 member chelated rings. To have opposite ends (bond angle – 180) to be

SR.IIT_CO-SC Page 8
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
chelated in either octahedral or square planar complex, the chelated ring must have ring size as
atleast 8.
The left over possibility results in the 11 member chelated ring.
Student is encouraged to try the same for EDTA to understand its chelation.

40. Given – same overall number of ions produced as the original complex hence coordination number is
the same as the original complex as well – 4 for all 3 complexes – X, Y and Z.

MATHS
41. 9  216  420  126  771 ways
42. Solve for same group and different group cases.
8
P 
15
7
C  6 C  3C1 11
43. P  2 10 2 
C3 40
 b  a  29
n
44. P1  n
N
N
Cn  n N
and P2  
N n
N  n  Nn
45. n  5   24  16
Favourable cases  All   Negative   16  3  13
13
P   a b 3
16
46. n  s   55
Favorable cases  5 C2  5  1  1  8 or 5  1  2  2   1500
 P  12/25
m
C2  n C2 1
47.  mn mn
 m  n C 2 2

and m  n  101
 Largest m is 7
48. ad  bc is even if
A) Even-Even OR

SR.IIT_CO-SC Page 9
Narayana IIT Academy 18-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-51_KEY&SOL
B) ODD-ODD
5
P    13
8
49. 8  4  3  1 or 8=4+2+2  or 8  3+3+2 
 K  22  1,2,11,22   13
50.   P  2;q is odd; r can be any no.
or  P=1;q is even; r can be any no.  500
 K  500  4  125  22  53
51. Conceptual
6
C3  3n  3  2n  3
52. p
6n
53. n = 12
225
54. p n  m  8
233
3n  2n  2n  1
55. f n  n
4  2n  2n  1
n2
56. P  m1
2
57, 58. P1  0;P2  0;P3  0
 1 7 
and P1  P2  P3  1  P , 
 2 23 
1
also A.M.  G.M.  P1  P2  P3  a  9
3
59, 60. n  s   C1  C1  C1  105
3 5 7

59. n  x1  x 2  x 3 is odd    3 odd   1 odd and 2 even 

 2 C1  3C1  4 C1   2 C1  2 C1  3C1  1C1  3C1  3C1  1C1  2 C1  4 C1 
 24  12  9  8  53
 P  53/105
60. Also n  x1 , x 2 , x 3 are in AP    x1  x 3  2x 2   17cases

SR.IIT_CO-SC Page 10