LATEST EXAMINATION PAPER 2023

lime 4l owed how

|Muxunun Mart
General Instructions:
Read the following intutions caeull and follow them

(«) In section A yueon mbo oN ae Multiple Choce (M Q)type quetuns carry1ny l t

( ) In seoion B Jueson nunber 19 o 25 are Very Shert Answer (VSA)ype qestutis casyh
marks c h

(c) n Nevtion quesvon nunber 26 to 30 are Short Answer (SA) type questions caftying
In svtion ) question nunber 31 and 32 are case-based questions carry1ng 4 marks caci.
(a) In section F yusion number 33 lo 35 are Long Answer (LA) type questions carrying trart
) There IN no oveall choice lHowever, an intemal choice has been provided in 2 questions ir e r
2qucstons in Scction C, 2 questions in Section D and 2 questions in Section E.
(0) se of calculator is NOT allowed.

SECTION A

1. Which of the following belongs to the class of Vinyl halides? 1

(a) CH,FCHCH,CH,CI (6) CH,Ç-CH,

Br
(c) CH,=CH-CH,-Br (d) CH=C-Br
2. What is the secondary valency of cobalt in (Co(en,)CI,] ?
(a) 6 (b) 4 (c) 2
3. When Benzene diazonium chloride reacts with phenol, it forms a dye. This reacion is called
(u) Diazotisation reaction (b) Condensation reaction
(c) Coupling reaction (d) Acetylation reaction
4. The slope in the plot of [R] Vs. time for a zero order reaction is
+k -k (d) +k
(a) 2.303 (b) -k (c) 2.303
5. Proteins are polymers of
(a) Nucleic acids (b) Anmino acids
(c) Monosaccharides (d) Amines
6. Retention of configuration is observed in
(a) S1 reaction (b) S,2 reaction
(c) Neither S1 nor S2 reaction
(d) S,2 reaction as well as S,,1 reactio1
28
Together wck EAD Chemistry-12
 7 An aweotropie mIxlUre 0l lwo liquds will have a boiling point Jower than cither of
when it the two liquids
a) shows negative deviation rom Raoul's aw
(b) lons an ideal solutio)
e) shows a posilive deviation fron Raoult% Jaw
(d) is saturated
R Which of the follownp sohations of KO wil have thc
(w) 0.01 M
hughest valuc of mnolar conductivity?
(b) IM
() 05 M (d) 01 M
Which of he lollowm does hot ive CnnzzHo
Caion?
(a) (C),C HO) (b)(H,),LOHO

10. \Whiwh of he lollowny reaons ae fecasible?

(a) CHHB+ Na'O CO),
(b) (CU)C + Na'o H,CH, CHO|, 0 (H)
() Both (a) and (b)
(d) Neither («) nor (b)
11. Aldchvdes and ketoncs rcact with hydroOxylanmine to form
(e) hvdrazones (b) cyanohydrins
(c) semicarbazones (d) oxime
12. For areaction 2A 3B, rate of reaction d|A]
d is equal to
+3 d|B] +2 d[B] +1 d[B] 2d(B
(a) dt (6) 3 dt (c) (d) - dt
dt
13. The formula of the complex dichloridobis (ethane -1, 2-diamine) platinum(IV) nitrate is 1
(a) [PrCI,(en), (NO)] (0) [PICI,(en),] (NO),
(c) [PIC,(en), (NO)] NO, (d) [Pr(en), (NO,),]CI,
14. Which one among the following metals of 3d series has the lowest melting point? 1
(a) Fe (b) Mn (c) Zn (d) Cu
Given below are two statements labelled as Assertion (A) and Reason (R).
Select the most appropriate answer from the options given below :
(a) Both (A) and (R) are true, and (R) is the correct explanation of (A).
(b) Both (A) and (R) are true, but (R) is not the correct explanation of (A).
(c) (A) is true, but (R) is false.
(d) (A) is false, but (R) is true.
15. Assertion (A): Elevation in boiling point is a colligative property.
Reason (R): The lowering of vapour pressure of solution causes elevation in boiling point.
16. Assertion (A): Chlorobenzene is resistant to electrophilic substitution reaction. 1

Reason (R): C CIbondin chlorobenzene acquires partial double bond characters due toresonance.
17. Assertion (A): Conductivity decreases with decrease in concentration of electrolyte.
Reason (R): Number of ions per unit volume that carry the current in asolution decreases on
dilution.
1
18. Assertion (A): Transition metals have high enthalpy of atomisation.
Reason (R): Greater number of unpaired electrons in transition metals results in weak metallic
bonding.
Latest Examination Paper 29
 SECTION - B

19, (a) Give reasons: potential during its ifetimc.

deivers a constant Direct Current (DO
() Mercurycell delemination of clectrolytic conductance,
cxperimental
(1) Inthe
hotused
OR
over priman
What advantages do the fuel cells have
with an exmple
(b) Denc fuct ccll 160 m
scConda battepes?
huid Y at 25C are 120mm Hg and the v
and pue calculate
pessure of pure hqud X are mixed to fom an ideal solution,
20. The vapem of N and Y
respectivch If cqual moles
soluio,
Pressure of the
ol the following:
21. (a) Write the lUPAC names (i) K|NiCOJ
0)Co(NIH),(ONO)''
OR

Give one example.

(b) ) What is a chelate complex? example.
comnplexes? Give one
(u) What are heteroleptic followed second order kinetics. If concentratíon
molecule A to B
22. (a) The conversion of it affect the rate of
formation of B?
increased to three times, how will
with an example.
(b) Define Pseudo first order reaction
between a nucleoside and nucleotide?
23. (a) What is the difference from DNA containing thymine is hydroiy
a nucleotide
(b) Whatproducts would be formed when
the following:
24. Write the chemical equation involved in (b) Williamson synthesis
(a) Kolbe's reaction
than two steps:
25. Do the following conversions in not more
(a) CH,CN to CHCH,
(b) cooH to

SECTION C
geometrical isomer of [Co{en).C
26. (a) Draw the geometrical isomers of [Co(en),ClL,j*, Which 24
is not optically active and why?
(b) Write the hybridisation and magnetic behaviour of [CoF.
(Given : Atomic number of Co = 27]
500gof wa
27. When 19.5 g of FCH,-C0OH (Molar mäss = 78 g mol), is dissolved in dissoCiato
the depression in freezing point is observed to be 1°C. Calculate the degree of
F-CH,COOH.
(Given : K, for water = 1.86 Kkg mol} 3X
28. Answer any 3 of the following:
(a) Which isomer of C,H,gives asingle monochlorÝ compound CH,CI in bright sunlignt
(b) Arrange the following compounds in increasing order of reactivity towards SN2 reacto
2-Bromopentane, 1-Bromopentane, 2-Bromo-2-methylbutane
(c) Why p-dichlorobenzene has higher melting point than those of ortho- and meta-isomers:
(d) Identify A and B in the following:
Br
Mg H,0
Dryether A ’ B

30 Together wit EADChemistry-12

 Calculate
order reaction is 50% complete in 30 minutes at 300 K and in 10 minutes at 320 K.
Afirst J K-mol
3
29. 8.314
activation energy (E,)for thc reaction. [R =
0.6021|
IGiven: log 2 = 0.3010, log 3= 0.4771, log 4 = 2+1
reaction:
20 (a) (i) Write the mechanism of the following
2CH,CH,0H 413 K'CH, CH, 0 CH, CH, +H,0
not?
(i) Why ortho-nitrophenol is steam volatile while para-nitrophenol is
OR
3X1
(b) What happens when
(i) Anisole is treatcd with CTH,C/anhydrous AlC,?
(ii) Phenol is oxidised with Na,Cr,0,/H?
(iii) (CH),C-OH is heated with Cu/573 K?
Write chemical cquation in support of your answer.

SECTION -D
passage carefully and answer the questions
The following questions are case-based questions. Read the
that follow:
aldehydes and ketones. They are also called
31. Carbohydrates are optically active polyhydroxy reagent are referred
saccharides. All those carbohydrates which reduce Fehling's solution and Tollen's
energy for mammals, is obtained by
to as reducing sugars. Glucose, the most important source of
the diet. Proteins are the
the hydrolysis of starch. Vitamins are accessory food factors required in the organisms.
polymers of a-amino acids and perform various structural and dynamicfunctions in
Deficiency of vitamins leads to many diseases.
Answer the following:
Hydroxylamine. What does it indicate?
(a) The penta-acetate of glucose does not react with
1
(b) Why cannot vitamin C be stored in our body?
2x1
(c) Define the following as related to proteins:
(i) Peptide linkage (iü) Denaturation
OR
2x1
(c) Define the following as related to carbohydrates:
(i) Anomers (ii) Glycosidic linkage
32. The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity
a number
of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with
of nucleophiles such as HCN, NaHSO, alcohols, ammonia derivatives and Grignard reagents.
Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group
of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably
more acidic than alcohols and most of simple phenols.
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in presence of dry
HCI.
1
(b) Why carboxylic acid is a stronger acid than phenol?
(c) ) Arrange the following compounds in increasing order of their reactivity towards CH,MgBr:
2X1

CH,CHO, (CH),C-f CH, CH,

(ii) Write a chemical test todistinguish between propanal and propanone.

Latest Examination Paper31

 OR
(c) Write the main product in the
following: 2x1
CHO
(i) [Ag(NH),1 (ü)
H,NCONHNH,

CHO 1.
2
SECTION E 3.
33. (a) Conductivity of 2 x 10 Mmethanoie acid is 8 ×10Scm. C¡lculate its molar
and degree of dissociation ifA° for methanoic acid is 404 S cm mol'.
(b) Calculate the AG° and log K for the gjven reaction at 298 K:
conducti3+2vity 6
5

Ni(s) + 2Agt (ag) N(ag) + 2Ag(s) 3+2 7

Given: ENPN = -0.25 V, EAp'/A! = +0.80 V
1 F= 96500 C mol. 8
34. (a) I. Account for the following:
(i) E value for Mn/Mn couple is much more positive than that for Crt/c2+ 342 10
(i) Sc+ is colourless whereas Ti is coloured in an aqueous solution.
11
(iii) Actinoids show wide range of oOxidation states.
II. Write the chemical equations for the preparation of KMn0, from 12
MnO,.
OR 13
(b) I. Account for the following:
14
(1) Transition metals form alloys. 2+2+1
1:
(ü) Ce* is a strong oxidising agent.
II. Write one similarity and one difference
between chemistry of Lanthanoids and Actinoids
III. Complete the following ionic
equation:
Cr,0 + 20H
35. (a) 17
I. Give reasons: 1
(i) Aniline on nitration gives good 3+2
amount of m-nitroaniline, though -NH, group is op
directing in electrophilic substitution reactions.
(iü) (CH), NH is more basic than 19
(CH),N in an aqueous solution.
(üi) Ammonolysis of alkyl halides is not a
II. Write the reaction good method to prepare pure primary
involved in the following: amines.
(i) Carbyl amine test
(iü) Gabriel phthalimide synthesis
OR
(b) I. Write the
structures of A, Band Cin the
following reactions: 3+1+1
CuCN H,0/H
A B NH, 2

NO,
Fe/HCI
(ü) ’A
NaNO, + HCI CH,0H
’ B ’C
273 K
II. Why aniline does not
undergo
Friedal-Crafts reaction?
III. Arrange the following in increasing order of their boiling point:
CH,0H, C,H,NH, (CH,),N
32 Together wie
EAD Chemistry--12
 -ANSWERS
1. (b) Carbon attached to halogen is linked with double bond. (sp hybridised)
(a) bccause 'en' is didentate ligand.
3. (c) II is Coupling reaction.
4. (b) Slope = -k
5. (b) Proteins are polymers of a-anmino acids.
6 a) S,Ireaction has retention as well as inversion lecading to racemisation.
7. (c) The vapour pressure of solution is higher than predicted by Raoult's law, .:. boiling point is
lower.
1000 K
8. (a) : A,, is inversely proportional to concentration. A,. = M
9. (b) : It has a-hydrogen.
10. (a) Nucleophilic substitution reaction will take place.
1. (d) R-CH=NOH and R,C=NOH
Id[A] (B] -d[A] +2 d[B]
12. (b) 2 dt =t7 dt dt
=

3 dt
13. (b) : NO, is counter ion.
14. (c) Znhas melting point 419.5°C, due to completely filled d-orbitals, it has weak metallic bonds.
15. (b) Both (A) and (R) are true, but (R) is not the correct explanation of (A).
16. (d) (A)is false, but (R) is true.
Chlorobenzene undergoes electrophilic substitution reactions due to +R effect inspite of -I
effect.
17. (a) Both (A) and (R) are true, and (R) is the correct explanation of (A).
18. (c) (A) is true, but (R) is false.
Transition metals have strong metallic bonding due to presence of unpaired electrons.
19. (a) () It is beccause no ions are involved in net cell reaction.
(i) DCcurrent is not used because it may cause electrolysis and change in composition of
electrolyte.
OR

(b) Fuel Cell: The cellin which chemical energy of a fuel is converted into electrical energy is
called fuel cell, e.g. H-0, fuel cell.
Advantage: It has higher efficiency and does not create pollution as compared to primary and
secondary batteries.
20. (a) 1 1 1
Xg 1+1 (: x t xp = 1)

PA =PÅA= 120x; = 60mm Hg; Pg =P= 160 x = 80 mm Hg

[Given: p& = 120 mm Hg, p= 160mm Hg]
Pr = PA t PB = 60 + 80= 140 mm Hg
21. (a) (i) Pentaammine nitrito-0-cobalt(III)
(ii) Potassium tetrachloridonickelate(|I)
 OR

(b) () The complex which have polydentate ligand is called e.g. chelate complex,
(ii) Those complexes which have more than one type of ligands, are called (Co(en),s
22. (a) A ’B
complexes, e.g. |Co(NH),CI
heterolep
rate = k|AF. rate = k|3A|' =9k|AP
The rate of formation of B' will be 9 times faster.

(b) ThOse reactions which are binolccul:ar but their order of the reaction is one as one
reactant is in large anount, c.g., of the

CH,COOCH, +lH,0 CHCO01| +CI,0H

23. (a) Nucleoside is made up of ribose or deoxyribose sugar along with heterocyclic base A, T,
and G, e.g., Adenosine. U,C
Nucleotides consist of ribose or deoxy ribose sugar, A, T, U, C,G bases and phosphoric acit
residuc, c.g. ATP. (Adenosine triphosphate)
(b) It willform deoxyribose, A, T, C, Gand phosphoric acid.
ONa OH OH
3-7 atm -ONa H* -C00H
24. (a) Kolbe's reaction:
340K

Salicylic acid
(b) Williamson synthesis: C,H,0Na + CH,I’ C,H,0CH, + Nal

CH,MgBr H,OH+ Br
25. (a) CH,C=N CH,Ç=NMgBr ’ CH,-C-CH, + Mg
Ethane nitrile
CH,
Propanone NH,
ÇOOH ÇOONa

(b) + NaOH heat

+ NaOH (CaO) + Na,CO,
Benzoic acid Sodium benzoate Benzene
-en
CI
26. (a)

Co en
Co en

en
CI
cis-isomer
trans-isomer
Trans-isomer optically active. :: it is achiral.
is not
(b) [CoFJ: Co(27) (Ar] : 4s
3d', Co't |Ar] 4310
[CoF:AT
3d 4s
4d;
It has sp'd sp'a
hybridisation and paramagnctic in nature.
34Together witk EAD Chemistry-12
 27. WB I000
M W,
IMol. wt. ot CHCOOH = 12 + 2 +19 + 12 +
32 +|= 78 nol|
NT, = K, x m
AT, L80x .3 I000
).93
78 500

Observed AT,
Caleulated A; 0,93 L0753

CH,FCOOH

Degree of dissociation («) L.0753 I

2 | - 0,0753, (, 753%,

28. (a) + Cl, + HCI

(yclopentane
1-Chlorocyclo pentane
(C;H,CI)
(b)
2-Bromo-2-methylbutane < 2-Bromopentane < 1-Bromopentane
(c) It is because it is symmetrical and fits into crystal lattice
readily.
Br
Mg MgBr
(d) Dry ether
H,0 + Mg
Br
A' OH
B

(Cyclobutyl Magnesiunm (Cyclobutanc)

Bromide)
29. 0.693 0.693
k, 0.693
k 30 min at 300 K, k, = 10min at 320 K

Ea
2.303 R
Ea 1
log 3 =
2.303 x 8.314300 320
0.4771x 19.147 × 300 × 320
E, = kJ mol
20 x 1000
= 43.848 kJ moll
H+
30. (a) (i) CH,CH,OH ’ CH,-CH,-0-H
H

CH, CH, )--H +i0-C,H, ’CH,-CH,--cH, +H,0

H H

CH,-CH,-C,H, H
’ CH,-CH, -0 CH, + H*

(i) It is because o-nitrophenol has weaker intra molecular H-bonding than inter molecular
H-bonding in p-nitro phenol.

Latest Examination Paper 35

 OR

(6) () o and p-methyl anisole are formed.

OCH, 0CH, OCH,
CH/Anhy. Al1
CH,
+ HCI

Anisole omethyl anisole C

p methyl anisole

(i) pbenzoquinone is lomed.

Na,(i,0,

Phenol

p-Benzoaquinone

(ii) 2-methyl propene is formed.

Cu
CH,
CH,-C=CH, + H,0
CHfcH,
OH
S73 K
2-Methyl propene

31. (a) It indicates glucose has cyclic structure which does not have free aldehyde group.
(b) It is because vitamin C is soluble in wate, gets excreted in urine.

(c) (i) Peptide linkage: The bondNHH between two or more amino acids in
polypeptides
and proteins.
(ü) Denaturation: On heating or change in pH, hydrogen bonds are
unfold and helix get uncoiled and leads to loss of biological disturbed, globules
activity, e.g. coagulation of
egg white, curdling of milk.
OR
(c) (i) Anomers: They differ in the position of -OH
group on C-1 (anomeric carbon) of
glucose, e.g. a-glucose and B-glucose.
(ii) Glycosidic linkage: It is Oxide linkage
between two or more monosaccharide units in
oligosachharides and Polysaccharides.
OH
32. (a) Acetal is formed.
R-C-H R'OH (excess) R'OH
HCI(dry) HCl(dy) R-c-H
OR' OR'
(b) Itis because carboxylate ion is more stable
than phenoxide ion due to
charge over two Oxygen atoms. delocalisationof negative
,<CH,-G-CH, <CH,CHO
(ii) Add I, and NaOH, propanalwill
not react, propanone will give yellow ppt. of lodoi0r.
or
Add Tollen's reagent. Propanal will give
silver mirror, propanone will not react.
36ogether witk EADChemistry--12
 OR

() 0)
+ Ag
CHO
(00

(HN NI (NI|
(ii) ||NCONII N|

Benzalklchvde
Benzaklehvde sCCtba/0De
000 % I000 ×8 x 0
J3. (a) M 40 S cn' mol
2x 0
40
404 0.099: 0= 0099 X |00 = 9 9%

(b) Ni(s) + 2Ag'(ag)Ni' (aq) + 2Ags) =2

ENN = +0.80 V-(-0.25) = 1.05 V
AG° = -nE°F = -2 x 1.05 V × 96500 C= -202,650J
1000
= -202.65 ks mo
nE 2x1.05
log K, = 0.0591 0.0591 =35.53
34. (a) I. () It is because Mn (3d) is more stable than Cr
(3d2).
(iü) Sc does not have unpaired electron where as Ti has
one unpaired electron,
undergoes d-d-transition by absorbing light from visible region and radiate
complementary colour.
(iü) 7s, 6d and 5f orbital electrons have nearly equal
energy, therefore, more electrons
take part in bond formation.
I. 2MnO, + 4KOH + O, ’
2K,MnO, + 2H,0
electrolysis
MnO? MnO, + e
OR
(b) I. (i) Transition metals have almost equal size, can
replace each other in metallic bonds to
form alloys.
(ü) Ce** can gain one electron to form Ce* and
Eottioa3+ is positive.
II. Both show contraction in atomic and ionic
size.
Both have f-orbitals.
Difference: Lanthanoids show +3 oxidation state mostly along with +2 and +4,
show +3 to +7 oxidation states. Actinoids
III. Cr,0 + 20H ’ 2Cr0f + H,0
(Orange) (Yellow)
35. (a) I. () It is because CHNH, formed is
electron withdrawing and m-directing.
(ii) It is due to more electron density on Nand less
steric hinderance in (CH),NH than
(CH,),N.
(iüi) It gives mixture of amines which are
difficult to separate.

Latest Examination Paper 37

 II. () Carbylaminc reaetion: When prinary aminc reacts with CHCI, and KOH, it forms
iSOCyanide which is an offensive smclling compound.
> RNC+ 3KCI + 3H,O
RNII, +CHC, +3KOI
(ii) Gabriel phthalimide synthesis:
-CO
Alcoholic, N K CGH,Br
, INCH.
-CON
CO
NH KOT
N-Ethylphthalimide
Phhalimide
Potassiun phthalimide
-COOH
H,0 + C,H,NH,
INCH,
-CO OH
Phthalic acid
Ethylamine
N-Ethylphthalimide
OR
NH,
I. ()
CuCN
H,0H*
cooH
B
A

NO, NH,
Fe/HCI NaNO, + HCI C,H,OH
(iü) 273 K
'B' C
A'

: C,HNH, (Lewis base) forms salt with AlCI, (Lewis acid).

II.
III. (C,H),N <C,H,NH, < C,H,OH