ALLEN CHEMISTRY AT A GLANCE 79

INORGANIC CHEMISTRY
PERIODIC TABLE
1. If atomic numbers 117, 120 are discovered 8. Column-I Column-II
(Elements) (Periodic Properties)
then their blocks will be:
(1) s, p (2) p, s (3) p, d (4) d, p (A) F (P) Maximum ionization
energy
2. Correct order of metallic character will be
(1) P < Si < Be < Mg < Na (B) Cl (Q) Maximum
electronegativity
(2) P > Si > Be > Mg > Na
(3) P < Si < Be > Mg < Na (C) Fe (R) Maximum electron
affinity
(4) P > Si < Be < Mg < Na
3. Which of following statement concerning (D) He (S) Variable oxidation
state
element with atomic number 10 is false?
(1) Element is monoatomic Select the correct Match :-
(2) It has a almost zero electron affinity (1) (A) ® (P), (B) ® (Q), (C) ® (R), (D) ® (S)
(3) It forms a covalent network solid (2) (A) ® (R), (B) ® (Q), (C) ® (P), (D) ® (S)
(4) It has extremely high value of I.E. in own (3) (A) ® (Q), (B) ® (R), (C) ® (S), (D) ® (P)
period (4) (A) ® (Q), (B) ® (P), (C) ® (S), (D) ® (R)
4. Following are configuration of 4 atom :- 9. Highest floroanion of Boron and Aluminium is:
P = (Ne)3s2 3p3 (1) BF63– , AlF63– (2) BF4–, AlF6–
Q = (Ar)3d10 4s2 4p 3 (3) BF4–, AlF63– (4) BF4–, AlF4–
R = (He)2s 22p 5
10. Which of the following order is wrong :-
S = (Ne)3s1
Incorrect statement is :- (1) NH3 < PH3 < AsH3 — Acidic
(1) EA : Q > R (EA = electron affinity) (2) Li < Be < B < C — First IP
(2) EN : R > P (EN = electro negativity)
(3) Al2O3 < MgO < Na2O < K2 O — Basic
(3) IP : P > S (IP = Ionisation potential)
(4) Li+ < Na+ < K+ < Cs+ — Ionic Radius
(4) Atomic radius : S > R
5. Among P, S, Cl, F most and least negative DHeg 11. e configuration of
–
90
Th-
will be respectively of: (1) (n–2)f2 , (n–1)d1 ns1
(1) Cl, P (2) P, Cl (2) (n–2)f1 , (n–1)d1 ns2
(3) Cl, F (4) F, Cl (3) (n–2)f0 , (n–1)d2 ns2
6. Which of the following order is valid for
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(4) (n–2)f2 , (n–1)d0 ns2

Li < B < Be < C < O < N < F < Ne
12. Which property decreases from left to right
(1) IE (2) EGE
across the periodic table and increases from
(3) EN (4) size
top to bottom?
7. Which of the following represents the correct
(i) Atomic radius
order of increasing first ionization enthalpy for
(ii) Electronegativity
Ca, Ba, S, Se and Ar ?
(iii) Ionisation energy
(1) Ca < S < Ba < Se < Ar
(iv) Metallic character
(2) S < Se < Ca < Ba < Ar
(1) (i) only (2) (i), (ii) and (iii)
(3) Ba < Ca < Se < S < Ar
(3) (i), (iii) and (iv) (4) (i) and (iv)
(4) Ca < Ba S < Se < Ar
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80 CHEMISTRY AT A GLANCE ALLEN
13. Which of the following statements are not 19. Correct statements among the following is/are:-
correct:- (1) 2nd electron gain enthalpy is always
(1) The electron affinity of 'Si' is greater than endothermic for neutral atoms.
that of C (2) Electronegativity is the property of bonded
(2) BeO is amphoteric while B2O3 is acidic atoms
(3) The ionisation energy of 'Tl' is less than that (3) Al 2O3 and BeO are amphoteric oxide
of Al (4) None of these are incorrect
(4) The ionisation energy of elements of 'Cu' 20. Which has maximum number of unpaired e–?
group is less than that of the respective (1) Na (2) Mn
elements of Zn-group (3) Cr (4) Fe+2
14. Which order for atomic radii is incorrect? 21. In which of the following pairs, first member
(1) H– > Li+ ³ Mg+2 > Al+3 has higher first IP
(2) MnO2 > KMnO4 (a) N,O (b) B, Be (c) Al, Ga
(3) O–2 > F– > Na+ > Mg+2 (d) F, Cl (e) Zn, Ga (f) F–, Cl–
(4) B > Al ; Ga < In ; Tl Correct option is
15. Which is not incorrect for acidic strength? (1) a,c,f,d (2) a,d,e
(1) H2S < H2Se < H2Te (3) b, d, e, f (4) a, d, e, f
(2) HClO4 > HClO3 > HClO2 > HClO 22. Among the following statement identify not
(3) P4O10 > SiO2 correct statement?
(4) All are correct (1) O has least electron affinity in its group.
16. Which is incorrect? (2) I has largest E.A. among halogen.
(1) Na < Al < Mg < Si IP1 Order
(3) S – has higher I.E then O–
(2) V < Cr < Fe < Mn IP3 Order
(4) None of these
(3) P < Si < Be < Mg < Na Metallic Character
23. The electron affinity values in Kjmol –1 of
(4) Yb > Ce > Lu > Sm Order of atomic radius
halogen x, y and z are respectively –348,
17. Select the correct matching in column-I with
–331 and –312 then x, y and z are respectively:-
column-II
(1) F, Cl, Br (2) Cl, F, Br
Column-I Column-II
(3) Cl, Br, F (4) Br, Cl, F
(Atomic number) (IUPAC official name)
(a) 101 (P) Mendelevium 24. Which given order is wrong according to given
property :-
(b) 105 (Q) Dubnium
(1) K2O > CaO basic nature
(c) 107 (R) Bohrium
(2) NH3 > H2O basic nature
(d) 108 (S) Lawrencium
18. Match the column - (3) BH3 > NH3 lewis acid nature
Column I Column II (4) KH > NaH acidic nature
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(a) N2 O (P) Normal Oxide 25. Incorrect match ?

(b) Na2 O (Q) Neutral Oxide
I.P. Reason
(c) Ga2 O3 (R) Sub Oxide
(d) C3O2 (S) Basic Oxide Half filled
(A) N>O
configuration
(e) V3O4 (T) Amphoteric Oxide
(U) Mixed Oxide (B) Zr < Hf Lanthanoid contraction
(1) (a) - Q, (b) - P,S (c) - R, (d) - T, (e) - U (C) Na > K Zeff
(2) (a) - Q (b) - P,S (c) - T, (d) - R, (e) - U
(D) Al < Ga Transition contraction
(3) (a) - R,P (b) - Q,S (c) - U, (d) - T, (e) - R
(4) (a) - P,Q (b) - R,S (c) - T, (d) - U, (e) - R (1) only A (2) A, B, D
(3) Only C (4) Only C, D
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84 CHEMISTRY AT A GLANCE ALLEN
72. Which of the following sequence regarding the 79. In which pair do both speices have the same
first ionisation potential of coinage metal is electronic configuration ?
correct? (1) Se2–, Kr (2) Mn2+, Cr3+
(1) Cu > Ag > Au (2) Cu < Ag < Au
(3) Na+, Cl– (4) Ni, Zn2+
(3) Cu > Ag < Au (4) Ag > Cu < Au
73. The size of the following species increases in 80. Comment on the E.N. of Sb in SbF3 and SbF5:-

the order :- (1) E.N. of Sb (SbF3) > E.N. of Sb (SbF5)

(1) Mg2+ < Na+ < F– < Al
(2) E.N. of Sb (SbF3) < E.N. of Sb (SbF5)
(2) F– < Al < Na+ > Mg2+
(3) Al < Mg2+ < F– < Na+ (3) E.N. of Sb is identical in both cases
(4) Na < Al < F < Mg
+ – 2+

(4) No comment can be predicted

74. Which is not correct order for the stated
property? CHEMICAL BONDING
81. Which of the following molecule/species have
(1) Ba > Sr > Mg : Atomic radius
(2) F > O > N : First ionisation energy a same bond order as that of O+2 ?

(3) Cl > F > I : Electron affinity (1) NO (2) N-2

(4) O > Se > Te : Electronegativity (3) N +2 (4) All of these
75. In which of the following arrangements, the
82. Which of the following molecule/species are
sequence is not strictly according to the
iso-structural with N3- ion?
property written against it ?
(1) CO2 < SiO2 < SnO2 < PbO2 : increasing (1) I3+ (2) I3-
oxidising power (3) NH-2 (4) HCO-2
(2) HF < HCl < HBr < HI : increasing acid
83. Which of the following pair of species are
strength iso-electronic?
(3) NH 3 < PH 3 < AsH 3 < SbH 3 : increasing
(1) CN– & NO+ (2) N-2 & N +2
Lewis basic strength
(4) B < C < O < N : increasing first ionisation (3) HÅ2 & H 2- (4) CO & NO–
enthalpy 84. Which of the following molecule is
76. The atomic radius of elements of which of the hypovalent?
following series would be nearly the same :- (1) AlF3 (2) ICl-2
(1) Na, K, Rb, Cs (2) Li, Be, B, C (3) BCl3 (4) ICl+2
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(3) Fe, Co, Ni, Cu (4) F, Cl, Br, I

85. Determine the bond order & formal charge on
77. What is the total number of valence electrons
each oxygen atom in HCO-2 respectively?
in the peroxydisulphate, S2 O82–, ion ?
(1) 1.5, –0.5 (2) 2, –0.5
(1) 58 (2) 60
(3) 1.33, –1.5 (4) 1.5, –1.33
(3) 62 (4) 64
86. Determine the incorrect order of bond angle?
78. Which of the following electronic configuration
(1) NH3 < NF3 < NCl3
would be associated with the highest spin only
magnetic moment ? (2) OF2 < OH2 < OCl2
(1) d2 (2) d4 (3) SF2 < SCl2 < SBr2 < SI2
(3) d5 (4) d7 (4) ClO2 > ClO-2 1 > OCl2

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 ALLEN CHEMISTRY AT A GLANCE 85
87. Which of the following molecule is 95. The types of hybrid orbitals of nitrogen in NO2+,
non-polar & planar? NO3– & NH4 + respectively are expected to be
(1) XeF4 (2) NH-2 (3) PF3Cl2 (4) PCl3F2 (1) sp, sp3, sp2
(2) sp, sp2, sp3
88. Which of the following is covalent solid.
(3) sp2, sp, sp3
(1) Solid CO2 (2) SiO2 (4) sp2, sp3, sp
(3) Diamond (4) 2 & 3 both 96. Which halide has highest melting point ?
89. The percentage of p-character in the orbitals (1) NaCl (2) LiCl
forming P–P bonds in P4 is
(3) LiBr (4) NaI
(1) 25 (2) 33 (3) 50 (4) 75
90. Correct match is :- 97. If ABn4 , type species are tetrahedral, then which
Bond order of of the following is incorrectly matched ?
Ion
M-O bond A B n
(a) ClO4_ 1 (1) Xe O Zero
4 (2) Se F Zero
(b) –3 3 (3) P O –3
PO4
4 (4) N H +1
(c) NO2 – 2
98. The species having no pp – pp bond but its
3
(d) CO3 –2 5 bond order equal to that of O-2
3
(1) d (2) a, b (3) c, d (4) None (1) ClO3- (2) PO34-
91. Which is iso-structural? (3) SO24- (4) XeO3
-
(1) XeF2 , ICl ,ClF3
2
(2) ClF3, PCl3, NCl3 99. How many p-bond does C2 have?
(3) CO 2 ,XeF2 , I -
(4) PCl5, XeOF2, ICl5 (1) 1 (2) 2
3
(3) 0 (4) 3
92. Which of the following molecule have both
100. Which of the following is not true about H2O
pp – pp and pp – dp bonding?
molecule ?
(1) ClO +2 (2) NO+2 (3) SO32- (4) ClO -4 (1) The molecule has m = 0
93. Select correct order out of given options :- (2) The molecule can act as a base
(1) BeCO3 < BaCO3 ® Covalent character (3) Shows abnormally high boiling point in
(2) BeO > SrO ® Lattice energy comparison to the hydrides of other
(3) Be2+ < Li+ ® Hydration energy elements of oxygen group
(4) The molecule has a bent shape
2+ +
(4) Be(aq.) > Li(aq.) ® Ionic Mobility 101. Match the following and choose the correct
94. Which of the following statement are true and option given below.
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false ? (a) N2 ® N 2+ (p) bond order increases

(a) In PCl 5 hybridisation is sp3d and it has a
(b) N2 ® N 2- (q) bond order decreases
trigonal pyramidal structure.
(b) The angle between the P-Cl bonds is 90º, (c) O2 ® O2+ (r) paramagnetism increases
which is same for all the P and Cl bond (d) O2 ® O-2 (s) paramagnetism decreases
present in PCl5 (t) No change in bond order
(c) The bond length of P-Cl in axial position
(1) a - (q, r), b - (q, r), c - (p, s), d - (q, s)
is higher than in equitorial position
(2) a - (q, s), b - (q, s), c - (p, s), d - (q, r)
(d) PCl5 have zero dipole moment
(3) a - (p, q), b - (q, s), c - (p, r), d - (q, t)
Choose the correct option.
(1) TFTT (2) FTTT (3) FFTT (4) TFFT (4) a - (p, s), b - (q, p), c - (q, t), d - (q, t)

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 ALLEN CHEMISTRY AT A GLANCE 89
140. Which of the following is least stable 150. The correct order of A–O–A bond angle of
(1) O– (2) C– (3) B– (4) Be– (A=H, F or Cl)
141. The true statements from the following are (1) H2O > Cl2O > F2O (2) Cl2O > H2O > F2O
(1) PH5 , NCl5 and BiCl5 do not exist (3) F2O > Cl2O > H2O (4) F2O > H2O > Cl2O
151. There are some species given below :-
–
(2) I has bent geometry
3 (a) O+2 (b) CO
(3) XeF 4 is polar molecule
(c) B2 (d) O-2
(4) O2 and O2–2 has same bond order
142. The bond order for NO and NO+, respectively (e) NO + (f) He2+
are (g) C+2 2 (h) CN–
(1) 3.0, 2.5 (2) 2.5, 3.0
(i) N2-
(3) 3.0, 3.0 (4) 2.5, 2.5
143. Back bonding always changes Total no. of species which have their fractional
(1) bond angle bond order.
(2) hybridisation of central atom (1) 3 (2) 4 (3) 5 (4) 6
(3) planarity
152. Which of the following has fractional bond
(4) bond length
order
144. Bond angle in H2O is
(1) 104.5° (2) 120° (3) 109.5° (4) 107° (1) O22+ (2) O22–

145. The correct stability order of N2 and its given (3) F22– (4) H2 –
ions is 153. When AgNO3 is heated strongly, the product
(1) N2 > N2+ > N2– > N22– formed are
(2) N2– > N2+ > N2– > N22–
(1) NO and NO2 (2) NO2 and O2
(3) N2+ > N2– > N2 > N22–
(4) N2 > N2+ = N2– > N22– (3) NO2 and N2 O (4) NO and O2
146. Which of the following have same bond 154. Which of the following carbonate of a metals
order:- has the least thermal stability
(I) CO (II) CN– (III) O2+ (IV) NO+
(1) Li2CO3 (2) K2CO3
(1) I, II, III (2) I, II, IV
(3) I, III, IV (4) II, III, IV (3) Cs2 CO3 (4) Na2CO3
147. In XeF 2 , XeF 4 and XeF 6 the number of lone 155. Which of the following order is not correct :-
pairs of electron on Xe are respectively
(1) N2 < N2+ (Bond length)
(1) 2, 3, 1 (2) 1,2,3 (3) 4,1,2 (4) 3,2,1
(2) O2 < O2+ (Bond strength)
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148. Which one is most soluble in water

(1) Mg(OH)2 (2) Sr(OH)2 (3) O2 < O (IP)

(3) Ca(OH)2 (4) Ba(OH)2 (4) NO < NO+ (Magnetic moment)

149. The correct order of N–O bond length is 156. The state of hybridisation for the transition state
(1) NO3– > NO2+ > NO2– of hydrolysis mechanism of BCl3 and SF4 are
(2) NO3– > NO2– > NO2+ respectively

(3) NO2+ > NO3– > NO2– (1) sp2, sp3 d (2) sp3, sp2

(4) NO2– > NO3– > NO2+ (3) sp3, sp3 (4) sp3, sp 3d2

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PHYSICAL CHEMISTRY
MOLE CONCEPT 8. Two elements X and Y (atomic mass of X = 75
1. Number of moles of neutrons in 1.8 mL of and Y = 16) combine to give a compound having
water is :- 76% of X. The formula of compound is :-

(1) 4.8 × 1023 (2) 4.8 × 1022 (1) XY (2) X2 Y (3) X2Y2 (4) X2Y3

(3) 0.8 (4) 0.1 9. Mass of CO2 produced on heating 20 g of 40%

pure limestone :-
2. The weight of 350 mL of a diatomic gas at 0°C
and 2 atm pressure is 1 g. The weight of one (1) 8 g (2) 8.8 g
atom is :- (3) 3.52 g (4) none of these
16 32 10. Calculate the amount of 50% H2SO4 required
(1) N (2) N
A A to decompose 25 g of calcium carbonate :-
(3) 16 NA (4) 32 NA (1) 98 g (2) 49 g
3. 10 mL of gaseous hydrocarbon on complete (3) 24.5 g (4) 196 g
combustion gives 20 mL of CO2 and 30 mL of 11. 8 g H2 32 g O2 is allowed to react to form water
H2O(g). The hydrocarbon is :- then which of the following statement is
(1) C4H10 (2) C2H6 correct ?
(3) C4H8 (4) C8 H10 (1) O2 is limiting reagent
4. For the reaction A + 2B ® C, 5 moles of A and (2) O2 is reagent in excess
8 moles of B will produce :- (3) H2 is limiting reagent
(1) 5 moles of C (4) 40 g water is formed
(2) 4 moles of C 12. A compound contains 3.4% by weight of
(3) 8 moles of C sulphur, the minimum molecular weight of
(4) 13 moles of C compound is :-
5. If the atomic weight of carbon is set at 24 amu, (1) 941.176 (2) 944
the value of the avogadro constant would be :- (3) 945.27 (4) None
(1) 6.022 × 10 23
(2) 12.044 × 10 23
13. The maximum number of molecules are present
(3) 3.011 × 10 23
(4) none of these in :-
6. Boron has two isotopes, B-10 and B-11. The (1) 15 L H2 gas at STP
average atomic mass of Boron is found to be (2) 5 L of N2 gas at STP
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10.80 u. Calculate the percentage abundance (3) 0.5 g H2 gas

of B10 isotope :-
(4) 10 g of O2 gas
(1) 80 (2) 20 (3) 25 (4) 75
14. If the weight of metal chloride is x g containing
7. A compound on analysis gave the following y g of metal, the equivalent weight of metal
results C = 54.54%, H = 9.09% and vapour will be :-
density of compound = 88. Determine the
x 8(y - x )
molecular formula of the compound:- (1) y ´ 35.5 (2)
x
(1) C8H16 O4 (2) C4H16O8
y 8(x - y )
(3) C2 H4 O (4) CH 4O2 (3) x - y ´ 35.5 (4) E =
y
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4 CHEMISTRY AT A GLANCE ALLEN
45. The molecular mas of a gas is 45. Its density 54. The wavelength of a neutron with a translatory
(in g/L) at STP is :- kinetic energy equal to KT at 300 K is :-
(1) 22.4 (2) 11.2 (3) 5.7 (4) 2.0 (1) 178 pm (2) 200 pm
46. 20 mL of methane is completely burnt using (3) 17.8 pm (4) 20.0 pm
50 mL of oxygen. The volume of the gas left 55. Frequency of a matter wave is equal to :-
after cooling to room temperature is :-
(1) 80 mL (2) 40 mL ( KE ) 2 ( KE ) ( KE )
(1) (2) (3) (4) l
2h h h
(3) 60 mL (4) 30 mL
47. The mass of CaCO3 required to react completely 56. Ionisation energy of He+ is 19.6 × 10–18 J atom–1.
with 20 mL of 1.0 M HCl as per the reaction, The energy of first stationary state (n =1) of
CaCO3 + 2HCl ® CaCl2 + CO2 + H2O is :- Li+2 is :-

(1) 1 g (2) 2 g (3) 10 g (4) 20 g (1) 4.41 × 10–16 J atom–1

48. The equivalent weight of divalent metal is W. (2) –4.41 × 10–17 J atom–1
The molecular weight of its chloride is :- (3) –2.20 × 10–15 J atom–1
(1) W + 35.5 (2) W + 71 (4) 8.82 × 10–17 J atom–1
(3) 2W + 71 (4) 2W + 35.5 57. Kinetic energy of an electron in the second
49. 1.25 g of a solid dibasic acid is completely Bohr orbit of a hydrogen atom is (a0 is Bohr
neutralised by 25 mL of 0.25 molar Ba(OH)2 radius):-
solution. Molecular mass of the acid is :- h2 h2
(1) (2)
(1) 100 (2) 150 (3) 120 (4) 200 4 pma 20 16p2 ma 20

50. 0.45 g of an acid of mol. wt. 90 is neutralised h2 h2

by 20 mL of 0.5 N caustic potash (KOH). The (3) (4)
32p2 ma 20 64 p2 ma 20
basicity of acid is :-
(1) 1 (2) 2 (3) 3 (4) 4 58. The potential energy of an electron in the
second Bohr's orbit of the He+ ion is :-
51. The equivalent weight of a metal is double than
that of oxygen. How many times is the (1) –54.4 eV (2) –27.2 eV
equivalent weight of its oxide than the (3) –108.8 eV (4) –13.6 eV
equivalent weight of the metal ? 59. If the radius of the first bohr orbit is X, the
(1) 1.5 (2) 2 (3) 3 (4) 4 de Broglie wavelength of the electron in the
third orbit is nearly.:-
ATOMIC STRUCTURE
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(1) 2pX (2) 6pX (3) 9X (4) X/3

52. FM radio broadcasts at 900 KHz. What
wavelength does this correspond to ? 60. According to Bohr's theory, the angular
momentum of an electron in 5th orbit is :-
(1) 333 m (2) 3.03 × 10–3 m
(3) 330 cm (4) 3300 m h h h h
(1) 25 (2) 1.0 (3) 10 (4) 2.5
53. Energy of 1 mole of radio wave photons with p p p p
a frequency of 909 KHz is :- 61. The number of d electrons retained in Fe +2
(1) 6.02 × 10–28J (2) 3.62 × 10–4J (atomic number Fe = 26) ion is :-
(3) 1.00 × 10 J–4
(4) 6.02 × 10 J–3
(1) 3 (2) 4 (3) 5 (4) 6

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62. Which of the following nuclear reactions will 71. What will be the ratio of de-Broglie
generate an isotope ? wavelength of electron accelerated with
(1) Neutron particle emission 400 volt and 100 volt :-
(2) Positron emission (1) 1 : 2 (2) 2 : 1
(3) a particle emission (3) 3 : 10 (4) 10 : 3
(4) b particle emission 72. In an atom 2K, 8L, 8M , 2N electrons are
63. The wavelength (in nanometer) associated with present. If m = 0, s = 1/2, then find no. of
a proton (mass = 1.67 × 10–27 kg atom –1) at the electrons :-
velocity of 1.0 × 103 ms–1 is :-
(1) 6 (2) 2 (3) 8 (4) 16
(1) 6.032 nm (2) 0.400 nm
73. Which of following has maximum possibility
(3) 2.500 nm (4) 4.00 nm
to find electrons in dxz orbital :-
64. How many orbitals are possible for n = 3, l = 2 ?
(1) Along x axis
(1) 1 (2) 3 (3) 5 (4) 7
(2) Along z axis
65. Which of the following is violating Hund's rule:-
(3) Along xz plane (2D)
(1) (4) At an angle of 45° from z & x axis

(2) nh
74. In Bohr's model shows :-
2p
(3)
(1) Momentum (2) Kinetic energy
(4) All
(3) Potential energy (4) Angular momentum
66. In hydrogen atom, the energy of second shell
75. 2Py orbital electron has energy :-
electron is :-
(1) –5.44 × 10–19 J (2) –5.44 × 10–19 KJ (1) more than 2Px orbital

(3) –5.44 × 10–19 Cal (4) –5.44 × 10–19 erg (2) more than 2Pz orbital
67. 0.5 g particle has 2 × 10 –5 m uncertainity in (3) same as 2Px and 2Pz
position find the uncertainty in its velocity (m/s) (4) same as of 2s orbital
(1) 3.0 × 10 33
(2) 5 × 10 –27
76. Orbital angular momentum of d electron is:-
(3) 4 × 10 –30
(4) 4 × 10–10
68. Which of the following has similar spectrum 3h h
(1) (2) 6
as that of Li+ :- 2p 2p
(1) H (2) Na10+
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h 3h
(3) He (4) He+ (3) (4)
2p 2p
69. Radius of first Bohr's orbit of hydrogen atom
is 0.53 Å then the radius of 3rd Bohr orbit is :- 77. Which has lowest wavelength :-
(1) 0.70 Å (2) 1.59 Å (1) Balmer series (2) Brackett series
(3) 3.18 Å (4) 4.77 Å (3) Humphrey series (4) Lyman series
70. If n = 3 then correct value of l is:- 78. Which of the following ion has magnetic
(1) 0 (2) 1 moment is 3.87 BM:-
(3) 2 (4) All of the above (1) Ti3+ (2) Sc+
(3) Ti+ (4) Mn+5
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 ALLEN CHEMISTRY AT A GLANCE 7
94. The momentum (in kg-m/s) of photon having 101. An excited state of H atom emits a photon of
12 MeV (Mega electron volt) energy is : wavelength l and returns in the ground state,
the principal quantum number of excited state
(1) 6.4 × 10–21 (2) 2.0
is given by :-
(3) 1.6 × 10–21 (4) 3.2 × 10–21

95. The increasing order for the values of e/m lR

(1) lR(lR - 1) (2)
(lR - 1)
(charge/mass) is :-

(1) e, p, n, a (2) n, p, e, a
(lR - 1)
(3) n, p, a, e (4) n, a, p, e (3) lR (4)
lR
96. What is the frequency of revolution of electron
102. A dye absorbs a photon of wavelenth l and
present in 2nd Bohr's orbit of H-atom?
re-emits the same energy into two photons of
(1) 1.016 × 1016 s–1 (2) 4.065 × 1016 s–1 wavel engths l 1 and l 2 respectively. The
(3) 1.626 × 1015 s–1 (4) 8.2 × 1014 s–1 wavelength l is related with l1 and l2 is :-

97. What is the ratio of time periods (T1 /T 2 ) in l1 + l 2 l1l 2

second orbit of hydrogen atom to third orbit of (1) l = l l (2) l = l + l
1 2 1 2
He+ ion?

(1) 8/27 (2) 32/27 l12 l 22 l1 l 2

(3) l = (4) l =
l1 + l 2 (l1 + l 2 )2
(3) 27/32 (4) None of these

98. Number of waves produced by an electron in 103. Be3+ and a proton are accelerated by the same
one complete revolution in nth orbit is :- potential, their de-Broglie wavelengths have
the ratio (assume mass of proton = mass of
(1) n (2) n2 (3) (n + 1) (4) (2n + 1)
neutron) :-
99. Electronic transition in He+ ion takes from n2
(1) 1 : 2 (2) 1 : 4 (3) 1 : 1 (4) 1: 3 3
to n1 shell such that :

2n2 + 3n1 = 18 104. The energy of an electron of 2py orbital is :-

(1) Greater than 3s orbital
2n2 – 3n1 = 6
(2) Less than 2px orbital
What will be the total number of photons
(3) Equal to 2s orbital
emitted when electrons transit to n1 shell ?
(4) Same as that of 2px and 2pz orbital
(1) 21 (2) 15 (3) 20 (4) 10
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105. Which of the following subshell can

100. Which of the following expressions represents accommodate as many as 10 electrons?
the spectrum of Balmer series (If n is the
(1) 2d (2) 3d (3) 3dxy (4) 3dz2
principal quantum number of higher energy
level) in Hydrogen atom? CHEMICAL EQUILIBRIUM
106. By dissociation of 4 g mol of PCl 5 produce
R(n - 1)(n + 1) R(n - 2)(n + 2) 0.8 mol of PCl3 if volume of container is 1 litre
(1) v = (2) v =
n2 4n 2 the equilibrium constant is :-
(1) 0.2 (2) 0.1
R(n - 2)(n + 2) R(n - 1)(n + 1) (3) 0.4 (4) 1
(3) v = 2 (4) v =
n 4n 2
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8 CHEMISTRY AT A GLANCE ALLEN
107. In a system P(s) ƒ 2Q(g) + R(g), at equilibrium 112. A gaseous mixture was prepared by taking
if concentration of 'Q' is doubled then how 3 mol of H2 and 1 mol of CO. If the total pressure
many times the concentration of R at of the mixture was found 2 atmosphere then
equilibrium will become :- partial pressure of hydrogen (H2) in the mixture
(1) Double of its original concentration is :-

1 3 1
(2) of its original concentration (1) (2) (3) 1 (4) 2
4 2 2
1
(3) of its original concentration 113. The value of K c at 900 K temperature for
2
following reaction is 5.
(4) 4 times of its original concentration
N2(g) + O2(g) ƒ 2NO(g) if equilibrium concn of
108. 1 mol of XY(g) and 0.2 mol of Y(g) are mixed in N2 and O2 is 0.5M then value of KP is :-
1L vessel. At equilibrium 0.6 mol of Y(g) is (1) 0.02 (2) 0.2
present. The value of K for the reaction :-
5
(3) 5 (4)
XY(g) ƒ X(g) + Y(g) is RT

(1) 0.04 (2) 0.06 (3) 0.36 (4) 0.40 114. The equilibrium constant KC for the following
reaction at 842°C is 7.90 × 10–3 . What is KP at
109. In which of the following reaction is almost
same temperature ?
completed :-
(1) Keq = 10 (2) Keq = 1 1
F ƒ F(g)
2 2( g)
(3) Keq = 105 (4) Keq = 10–2
110. If the concentration of Y– ion in the reaction (1) 8.64 × 10–5 (2) 8.26 × 10–4
(3) 7.90 × 10–2 (4) 7.56 × 10–2
XY3(s) ƒ X +3
+ 3Y -
( aq ) is
115. NH4HS(s) ƒ NH3(g) + H2S(g)
(aq )

1 The equilibrium pressure at 25°C is 0.660 atm

decreased times, then how many times the
2 What is Kp for reaction ?
equilibrium concentration of X+3 will increase:
NH4NH(s) ƒ NH3(g) + H2S(g)
(1) 2 times (2) 4 times
(1) 0.109 (2) 0.218
(3) 8 times (4) 16 times
(3) 1.89 (4) 2.18
111. For the reaction :- 116. At a certain temperature only 50% HI
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X 2( g ) + Y2 ( g ) + Z 2( g ) ƒ 2XYZ(g) dissociated at equilibrium in the following reaction

2HI(g) ƒ H2(g) + I2(g)
At equilibrium concentration of X2 = 3M, The equilibrium constant for reaction
Y2 = 6M, Z2 = 9M, XYZ = 6M. If the reaction
(1) 0.25 (2) 1.0 (3) 3.0 (4) 0.5
takes place in a sealed vessel at 527°C, then
117. For the reaction CO(g) + Cl2(g) ƒ COCl2(g) the
the value of KC will be :
KC
27 2 value of K is equal to :-
(1) (2) P
2 9
(3) 36 (4) 24 1
(1) RT (2) RT (3) (4) 1
RT
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 ALLEN CHEMISTRY AT A GLANCE 9
118. The equilibrium constant (Kc) for the reaction 123. For N2+3H2 ƒ 2NH3 ; DH = –ve then :-
2HCl(g) ƒ H2(g) + Cl2(g) (1) KP = KC (2) KP = KC RT
is 2 × 10 at 25°C. What is the equilibrium constant
–2 (3) KP = KC (RT) –2
(4) KP = KC (RT)–1

for the reaction H 2( g ) + Cl 2( g ) ƒ 2HCl(g):- 124. Consider equilibrium constant for the reaction:
2CO(g) + 2H2O(g) ƒ 2CO2(g) + 2H2(g) eq. const = K1
(1) 2 × 10–2 (2) 50 CH4(g) + H2O(g) ƒ CO(g) + 3H2(g) ; eq. const = K2
(3) 5 × 10 (4) None of these CH4(g) + 2H2O(g) ƒ CO2(g) + 4H2(g) ; eq. const = K3
2

119. If K1 and K2 are the equilibrium constant for Which of the following relation is correct ?
the two reactions
K1 K12
XeF6(g) + H2O(g) ƒ XeOF4(g) + 2HF(g) ; K1 (1) K3 = (2) K 3 =
K2 K 22
XeO4(g) + XeF6(g) ƒ XeOF4(g) + XeO3 F2(g) ; K2
The equilibrium constant for the reaction (3) K3 = K1K2 (4) K3= K1 × K 2
XeO4 (g) + 2HF(g) ƒ XeO3F2(g) + H2O(g) is 125. One mole of X2 is mixed with one mole of Y2
(1) K1 K2 (2) K1/K2 2 in a flask of volume 1 litre. If at equilibrium
0.5 mole of Y2 are obtained. Then find out Kp
(3) K2 /K1 (4) K1 /K2
for reaction
120. For which of the following gaseous reaction X2(g) + Y2(g) ƒ 2XY(g)
Kp is less than KC at 298 K temperature :-
(1) 12 (2) 9 (3) 4 (4) 36
(1) N2O4 ƒ 2NO2
1
(2) 2HI ƒ H2+F2 126. For the reaction 2NO2(g) + O ƒ N2O5(g)
2 2(g)
(3) 2SO2 + O2 ƒ 2SO3
if the equilibrium constant is K p , then the
(4) N2+O2 ƒ 2NO equilibrium constant for the reaction
121. At 25°C the equilibrium constant K1 and K2 of 2N2O5(g) ƒ 4NO2(g) + O2(g) would be :-
two reactions are
2 1 1
2NH3 ƒ N2+3H2 ; K1 (1) KP2 (2) K (3) K 2 (4)
p p Kp
1 3
N 2 + H 2 ƒ NH3 ; K2 127. In the reaction X(g) + Y(g) ƒ 2Z(g)
2 2
2 mol of X, 1 mol of Y and 1 mol of Z are
The relation between K1 and K2 is :- placed in a 10 litre vessel and allowed to reach
equilibrium. If final concn of Z is 0.2M, then
1 KC for the given reaction is :-
(1) K1 = K2 (2) K 2 = 2
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K1 (1) 1.6 (2) 80/3

(3) 16/3 (4) None of these
1 1 128. For the reversible reaction
(3) K1 = 2
(4) K1 = K
K2 2
PCl3(g) + Cl2(g) ƒ PCl5(g) + heat
122. For the reaction 2SO3(g) ƒ 2SO2(g) + O2(g) the The equilibrium will shift in forward direction:-
KC (1) By increasing conc of PCl5(g)
value of K will be :-
p
(2) By decreasing pressure
(1) (RT)1 (2) (RT)–1
(3) By decreasing concn of PCl3(g) and Cl2(g)
(4) ( RT )
-2
(3) RT (4) By increasing pressure and decreasing temp.
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12 CHEMISTRY AT A GLANCE ALLEN
151. Increase in the pressure for the following 155. At constant temperature, Kp for the equilibrium
equilibrium
4x 2 P
N2 O4 ƒ 2NO2 is expressed by Kp = ,
ˆˆˆ†
H2O (l) ‡ˆˆˆ H2O(g) result in the 1 - x2

I : Formation of more H2O(l) where P = pressure, x = extent of

decomposition. Which of the following
II : Formation of more H2O(g)
statement is true ?
III : Increase in b.p. of H2O(l)
(1) Kp increases with increase of P
IV : Decrease in b.p. of H2O (l)
(2) Kp increases with increase of x
Hence, correct statements are–
(3) Kp remains constant with change in P and x
(1)I, II (2) II, III
(4) Kp increase with decrease of x
(3)I, III (4) I, IV
IONIC EQUILIBRIUM
152. For the reaction N2 + 3H2 ƒ 2NH3, the value
of KC would depend upon 156. What is the Kb of weak base that produce one
OH– ion per molecule if a 0.05 M solution is
(1) initial concentration of the reactants
2.5% ionised ?
(2) pressure
(1) 7.8 × 10–8
(3) temperature
(2) 1.6 × 10–6
(4) all of these
(3) 3.1 × 10–5
153. For the reaction :
(4) 1.2 × 10–3
2HI(g) ƒ H2(g) + I2(g);
157. Solubility of calcium phosphate (molecular
the degree of dissociation (a) of HI(g) is related
mass, M) in water is w g per 100 ml at 25°C,
to equilibrium constant Kp by the expression
its solubility product at 25°C will be
1 - 2 Kp 1 - 2K p approximately :-
(1) (2)
2 2 5 5
æwö 7æ w ö
(1) 10 ç ÷
9
(2) 10 ç ÷
èMø èMø
2K p 2 Kp
(3) (4) æwö
5 5
1 - 2K p 1 + 2 Kp 5 3æ w ö
(3) 10 ç ÷ (4) 10 ç ÷
èMø èMø
154. At temperature T, a compound AB 2 (g) 158. 0.2 g sample of benzoic acid C6H5 COOH is
dissociates according to the reaction titrated with 0.12 M Ba(OH)2 solution, what
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2AB2(g) ƒ 2AB(g) + B2(g) volume of Ba(OH)2 solution is required to reach

the equivalence point ?
With degree of dissociation a, which is small
compared with unity. The expression of Kp, in (1) 6.83 ml (2) 13.6 ml
terms of a and total pressure PT is : (3) 17.6 ml (4) 35.2 ml
159. The Ksp of Ag2 CrO4 is 1.1 × 10–12 at 298 K,
a 3
a 3
(1) PT (2) PT solubility in (mol/L) of Ag 2 CrO 4 in 0.1M
2 3
AgNO3 solution is :-
(1) 1.1 × 10–11 (2) 1.1 × 10–10
a2 Pa
(3) PT (4) T (3) 1.1 × 10–12 (4) 1.1 × 10–9
3 2

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 ALLEN CHEMISTRY AT A GLANCE 13
160. For a sparingly soluble salt Ap Bq , the relation 168. Calculate the pH of a 10–5 M HCl solution if 1ml
of its solubility product (Ls) with its solubility of it is diluted to 1000 ml , Kw = 1 × 10–14 :-
(S) is :- (1) 7.98 (2) 6.98
(1) LS = S P+q
.P.q P q
(2) LS = S P+q
P.q q P
(3) 7.0 (4) 5
(3) LS = S . P . q
Pq P q
(4) LS = S . (Pq)
Pq P+q
169. Calculate the degree of hydrolysis of the
161. The degree of dissociation of water at 25°C is 0.01 M solution of salt (KF KHF = 6.6 × 10–4) :-
1.8 × 10 –7 % and density 1.0 g/cm 3 , t he (1) 3.87 × 10–6 (2) 3.87 × 10–5
ionisation constant of water is :-
(3) 3.87 × 10–2 (4) None of these
(1) 1.0 × 10 –15
(2) 1.0 × 10 –14
170. For poly basic acid, the dissociation constant
(3) 1.8 × 10 –16
(4) 1.0 × 10 –6
have a different values for each step.
162. A certain weak acid has a dissociation constant
H3A ƒ H+ + H 2 A – ; Keq = Ka1
1.0 × 10–4 , the equilibrium constant for its
H2A– ƒ H+ + HA–2; Keq = Ka2
reaction with strong base is :-
HA2– ƒ H+ + A3– ; Keq = Ka3
(1) 1.0 × 10–4 (2) 1.0 × 10–10
What is the observed trend of dissociation
(3) 1.0 × 1010 (4) 1.0 × 1014
constant in successive stages ?
163. A certain buffer solution contains equal
(1) Ka1 > Ka2 > Ka3
concentration of X– and HX. The Kb for X– is
10–10 the pH of the buffer is :- (2) Ka1 = Ka2 = Ka3

(1) 4 (2) 9 (3) 10 (4) 7 (3) Ka1 < Ka2 < Ka3

164. Find the pH of a solution prepared by mixing (4) Ka1 = Ka2 + Ka3
25 ml of a 0.5M solution of HCl, 10 ml of a 171. Equimolar solutions of HF, HCOOH and HCN
0.5 M solution of NaOH and 15 ml of water :- at 298 K have the values of Ka are 6.8 × 10–4,
(1) 4 (2) 3 1.8 × 10–4 and 4.8 × 10–9 respectively, what will

(3) 0.82 (4) 0.10 be the order of their acidic strength ?

165. Calculate the pH of a 10 –3 M solut ion of (1) HF > HCN > HCOOH
Ba(OH)2 if it undergoes complete ionisation. (2) HF > HCOOH > HCN
(Kw = 1 × 10–14) :- (3) HCN > HF > HCOOH
(1) 12.30 (2) 11.30 (4) HCOOH > HCN > HF
(3) 10.00 (4) 9.00 172. NH 4 CN is a salt of weak acid HCN
166. 0.01 mole of sodium hydroxide is added to (K a = 6.2×10 –10 ) and a weak base NH 4 OH
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10 litres of water, How much will the pH of (Kb = 1.8 × 10–5) A molar solution of NH4CN
water change? will be :-

(1) 4 (2) 7 (1) Neutral (2) Strongly acidic

(3) 5 (4) 8 (3) Strongly basic (4) Weakly basic

167. The degree of dissociation of acetic acid in a 173. The solubility product of BaCl2 is 4 × 10–9 .
0.1 M solution is 1.32 × 10–2 , find out the pKa :- What will be its solubility in mol/L :-

(1) 5.75 (2) 3.75 (1) 4 × 10–3 (2) 3.2 × 10–9

(3) 4.00 (4) 4.75 (3) 10–3 (4) 1 × 10–9

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16 CHEMISTRY AT A GLANCE ALLEN
203. In a saturated aqueous solution of AgBr, 211. What will be the approximate degree of
concentration of Ag+ ion is 1 × 10–6 mol L–1. If dissociation of 0.005 M NH4 OH solution. If
Ksp for AgBr is 4 × 10–13, then concentration pKb for NH4OH is 4.7
of Br– in the solution is
(1) 2% (2) 0.03%
(1) 1 × 10–6 mol L–1 (2) 4 × 10–8 mol L–1
(3) 0.40% (4) 6.32%
(3) 4 × 10–7 mol L–1 (4) 4 × 10–19 mol L–1
212. Which of the following pairs can be used to
204. A solution of an acid has pH = 4.70. Find out
the concentration of OH– ion (pKW = 14) form a buffer solution?
(1) 5 × 10–10 (2) 6 × 10–10 (1) H2SO4 and Na2SO4
(3) 2 × 10–6 (4) 9 × 10–6 (2) NaOCl and NaCl
205. Which of the following is not an example of (3) NH3 and NH4Cl
buffer solution? (4) NaH2PO4 and NaCl
(1) HNO2 + KNO2
213. What is the molar solubility of MgF 2 in a
(2) HF + KF 0.2 M solution of KF? (Ksp = 8 × 10–8)
(3) PhNH2 + PhNH3+Cl–
(1) 8 × 10–8M (2) 8 × 10–7M
(4) NH4Cl + HCl
(3) 2 × 10–6 M (4) 2.7 × 10–4 M
206. Which of the following acid will release
maximum amount of heat when completely 214. If pKa of acetic acid and pKb of ammonium
neutralized by strong base NaOH? hydroxide are 4.76 each. The pH of ammonium
(1) 1 M HCl (2)1M HNO3 acetate at 25°C is

(3) 1M HClO4 (4) 1M H2SO4 (1) 7 (2) less than 7

207. Which of the following is an example of (3) more than 7 (4) zero
hydrolysis reaction? 215. What is the hydronium ion concentration of
(1) NH4 Cl ƒ NH4+ + Cl - 0.25 M HA solution? (Ka = 4 × 10–8)
(1) 10–4 (2) 10–5
(2) NH+4 + H 2 O ƒ NH 4OH + H +
(3) 10–7 (4) 10–10
(3) Na + H 2 O ƒ NaOH + H
+ +
216. The solubility of PbF2 (molecular wt = 245) is
(4) CH 3COOH + HOC 2H 5 ƒ CH 3COOC2 H 5 + H 2 O 0.46 g/L. What is solubility product?

208. Which of the following salt will have the lowest (1) 1.1 × 10–10 (2) 2.6 ×10–8
pH?
(3) 1.1 × 10–7 (4) 6.8 × 10–9
(1) Na2SO4 (2) (NH4)2SO4
217. What is molar solubility of Ag 2 CO 3
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(3) Na2CO3 (4) NaCl

(Ksp = 4 × 10–13) in 0.1 M Na2CO3 solution
209. What will be pH of 0.1 M NaCN solution if Ka
for HCN is 10–6 at 25°C (1) 10–6 (2) 10–7
(1) 6.5 (2) 9.5 (3) 3 (4) 7 (3) 2 ×10–6 (4) 2 ×10–7
210. The conjugate base of strong acid in the reaction 218. When 50 mL of 0.10 M ammonia solution is
CH3COOH + HCl ƒ Cl + CH3 COOH will be
- +
2
treated with 50 mL of 0.05 M HCl solution then
pH is :- (pKbof ammonia = 4.74)
(1) HCl (2) Cl–
(1)8.26 (2)9.26
(3) CH 3COOH (4) CH3COOH 2+
(3)4.74 (4)None