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Virudhunagar District Common Examinations
Common Half Yearly Examination December 2022
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Standard 11
eet t eet t Marks: 70

.iN .iN
CHEMISTRY
.N .N
Time: 3.00 hrs

l
aaalai aa l a
l i
a Part-I
15x1=15
Choose the correct answer:
1) a
dd s
a s
Match the List-I and List-1I using the correct code
d
given below the list

P
.. Pa
List Ia List II
P
..Paa
ww ww
(Molecular Formula)

wwww ww
(Empirical Formula)
A] Benzene CH
B] Fructose CH,O
1) H,O
2) CH
w
w
C] Acetylene CH 3) Ch

et
e t D] Hydrogen Peroxide -

HO
eet t 4) CHO

et
lalai.iN
.N Code:
l a
l i
a .iN
.N B C D

aa a)
a s
a aa
s 4

.N
b
PPaadd 3
P Paad
c)
w
w .. 4
w w .. 3

wwww www w
d) 1 4 2
nodes respectively.
for 3P orbital are 1, 1

t
Reason lai
2) Assertion: Number of radial and angular
Number of radial and angular nodes depends only on principal
quantum number

t
ee t
a) Both assertion and
e t
reason are

e
true and reason is the correct explanation
sa
l a
l i
a .iN
.N b) of assertion

l a
l i
a .iN
.N true but reason is not the correct
aa aa
Both assertion and reason are

a
dd s
a s
explanation of assertion

d
aa is false
aa
da

c) Assertion is true but reason

d)
ww P
.. P
Both assertion and reason are
w
w
false P
.. P
wwww wwww
2p6 3p6
1s2 2s2 3s2 3d8 4s2.
3) An element has the electronic configuration
What will be its position in the periodic table?
Pa

a) period 4, group 10 b) period 2, group 2

c) period 4, group 2 d) period 2, group 8

eet t eet t
H,DPO, +HDO indicates that hypo-phosphorous
.iN .iN
The reaction HPO,+D,0
.N .N d)
4)

l
aaal i
a acid is
c)la
aa l ai
w.

monobasic acid none of these

b)
a) tribasic acid
a
dd s
a s dibasic acid
In which process, fused sodium
d
hydroxide is electrolysed for extraction of
5)
sodium?
P
.. Paa P
.. Paa
w
w ww b) Cyanide Process

wwww wwww
ww

a) Castner's process
c) Down Process d) All of these
Consider the following statements
6)
the top of a mountain than at sea level.
i) Atmospheric pressure is less at

eet t i) Gases are much more compressible

et
e tthan solids or liquids.

l a
l i
a .iN
.N l a
lai.iN
.N
ii) When the atmospheric pressure increases the height of the mercury

aa column rises

a s
a aa
s
Select the correct statement

b) a
P P add II and III
P Pad
a c) I and III d) I, II and III
a) I and II

ww.. ww..
7) Which of the following relationships is not correct for the relation between

a)
wwww
AH and AU?
when Ang =
0 then AH = wwww
U b) when Ang> 0 then AH > AU
AU d) when Ang RT = 0 then AH > aU
c) when Ang < 0 then AH <

eet t eet t
.NN .NN
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8) Kc
8) for
Kp the reaction,
e et t N2(0) + 3H2(g)
e t t
2NH3(9)
e
s

laalai.iN
.Na)RT b) RT
ssaa l a
l i
a
) (RT)2
.
i N
. N d) RT
9) Which one of the
a
followingaddaa aad
constant?
w w P
.. P gases has the lowest value of
Henry's
w w P
..P law

10)
a) N
Which typewwwhybridisation
w
of
b) He c) CO
by carbon
is shown
c)
w
w
H wwright
atoms from left to in
thegiven compound CH, =
CH C= N?
a) Sp, Sp, SP b) Sp2, Sp, SP c)SP, SP?, SP d) SP3, SP, SP
11) The type of isomerism shown by the following compounds is
e et t e et t

et
laalai.iN
.N CH3
ss l a
l ai .iN
aaCH -C-CH
.N
CH
aa

.N
P P add
CH-CH,CH,CH,CH, CH -CH-CHCHg,
a P Pad
a
ww .. CH w
w ..
wwww
a) position isomerism
wwww
b) chain isomerism
c) metamerism
lai
12) Hyper conjugation is also known as
a) no bond resonance
d) ring-chain isomerism

b) Baker-nathan effect
t t
c) both (a) and (b)
ee ee t t
sa
d) none of these
N
.N
laalai.i13) l a
l i
a .iN
.N CE CH CH3
The IUPAC name
a assaa
of the following compound is
,
a add aad
da

P
.. P
a) trans-2-chloro-3-iodo-2-pentene
w w b) cis-3-iodo-4-chloro-3-pentane
ww P
.. P
wwww b) Freon-113 c)Freon-114 ww
c) trans-3-iodo-4-chloro-3-pentene d) cis-2-chloro-3-iodo-2-pentene
14) The name of CFAC!2 is
a) Freon-112 ww
d) Freon-115
Pa

15) Which of the following is natural and human disturbance

in ecology?
a) Forest fire b) Floods c) Acid rain
eet t eet
d) green house effect
t
laalai.iN
.N questions. i .iN
.N
Part-II
Answer any six
compulsory: la l a
a a
w.

Q.No. 24 is
16) Define limiting reagent
d da as s 6x2 12
d
17)
18) Explain what to meantP
.. P a
Define Hund's rule of maximum
a multiplicity.
by efflorescence.
..PPaa
ww ww
wwwwchemical ww
19) What is meant by Joule-Thomson effect?
ww

20)
21)
State the third law of
Write a balanced
thermodynamics.
equation
for a equilibrium
w
wreaction for which the

t NH, t[O
ee t e e t
equilibrium constant is given by expression Ke

laalai.iN
.22)N Grignard reagent? example. lalai.iN NOT
What is .N H.O1

a a aa
Give
s s
23) What are the uses of alkanes?
24) Compound CHO(A)
P aadd
reacts with
(anhydrous ZnCe, and
Con.HC)
P aad
reagent to give compound (B) and water. identify compounds A and B lucas
P P
ww .. w
w ..
wwww Part-III
Answer any six questions. Q.No. 33 is compulsory:
25) Write short not on principal Quantum number.
wwww 6x3 18
26) What is effective nuclear charge?

t t
27) How do you convert para hydrogen into ortho hydrogen?
ee eet t
.NN
28) Define Hess's law of constant heat summation.
.NN
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29) Explain homogeneous

and
30) Write a note on heterogeneous equilibrium.
eet t homologous
31) Write Fitting reaction. series.
usseries.
eet t
laalai.iN
.N i .iN
.N
32) Differentiate BOD and
33) A 60 miof paracetamolCOD
s s l
aa a
l a
Find the mass by
volume
aa dda a
pediatric oral suspension contain
percentage? pararetan:ol 3 g of

aa
. P
. P
ww Part IV ww . P
. P
ww
Answer all the questions:w
w ww w w 5x5::255
34) a] i) Define Avagadro number. (2)
An organic compound present in Vinegar has 40% carbon, 6.6%
e et t e t t
nyarogen and 53.4% oxygen. Find the empirical formula of the
e

et
a i.iN
. N Compound
a i .
i N
. N (3)
al la b) i) Explain Pauling's method(OR) a a s sa
of ionic al lacalculation.
radii

.N
i) What is
P P aa d
Hydrogen bonding?d (3)
P Paa
ww . . they classified?
How are

ww .
(2)
.
w
35) a) i) Compare w
wwthe uses of calcium oxide.
the
proprties Berylliumof w w
ww (3)
with other elements of the
group.(2)
i) Write
lai (OR)
b) i) State Charles law and write its mathematical expression.
eet t t
ee t (3)
sa
laalai.iN
.N N N
i) What is Boyle temperature or Boyle Point?

l a
lai .
i . (2)

aassaa
36) a) i) Phenol dimerises in benzene having Van't Hoff factor 0.54. What is

aadd
the degree of association? (2 aa
da

. P
. P
ww (OR) 3).P
ww
i) Explain the effect of pressure on the solubility.
. P
wwww w
w
ww (5)
b) Discuss the formation of N, molecule using MO theory.
Pa

37) a) i) Compare the structures of H,O and H,02. (3)

eet
i) t Write the uses
e
of sodium chloride.
et t (2)
laalai.iN
.N (OR)
a al a
l ai .iN
.N
w.

b) i)

d da ss
Write the IUPAC name for the following compounds.
a CH-C C-CH-CH
(2)
CH CH2
. P
. Paa -

CH- CHO

. P
. Paa
(1)
w www OH
(2) C
w
w ww
ww

ww
i) Distinguish between Nucleophiles and
electrophiles. ww (3)
BenzeneStruture. (5)
eet t
38) a) Explain
e
(OR)
et t
laalai.iN
.N a i.iN
.N
DDT?
b) i) How do you prepare
Write Finkelstein
ssaal
reaction.l a (3)
(2)
i)
aaddaa aa
ww.P. P ww . P
. P
wwww wwww

eet t eet t
.NN .NN
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